Title:
メタセシス反応における使用のための、環式リン含有リガンドおよび環式有機リガンドを有する、遷移金属化合物
Document Type and Number:
Japanese Patent JP5131987
Kind Code:
B2
Abstract:
According to the present invention there is provided a compound in the form of a transition metal compound including a transition metal, a phosphorus containing ligand, and a cyclic organic ligand. The phosphorus containing ligand is a heterocyclic organic compound with a ligating phosphorus atom which ligates with the transition metal, and which ligating phosphorus atom is an atom in the heterocyclic ring structure of the heterocyclic organic compound. The cyclic organic ligand is a cyclic organic compound with a ligating carbon atom in the cyclic ring structure of the cyclic organic compound which ligates with the transition metal by means of a double bound. The invention also relates to a method preparing such a compound and a metathesis reaction wherein such a compound is used as a catalyst.
Inventors:
Winde, Roland
Kalha, Ralph Wilheim
Rivas-Nas, Andreas
Briel, oliver
Toulouse, Robert Paul
Forman, Grant Stephen
Meyer, Wolfgang Hubert
Kalha, Ralph Wilheim
Rivas-Nas, Andreas
Briel, oliver
Toulouse, Robert Paul
Forman, Grant Stephen
Meyer, Wolfgang Hubert
Application Number:
JP2008521021A
Publication Date:
January 30, 2013
Filing Date:
July 12, 2006
Export Citation:
Assignee:
Umicore AG & Co.KG
International Classes:
C07F15/00; B01J31/24; C07C1/213; C07C6/04; C07C11/02; C07C67/475; C07C69/533; C07F9/6568; C07F19/00; C07B61/00
Domestic Patent References:
| JP2006523670A | ||||
| JP2004506032A |
Foreign References:
| WO2004005223A1 |
Other References:
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Ned J. Hardman, Michael B. Abrams, Melanie A. Pribisko, Thomas M. Gilbert, Richard L. Martin, Gregory J. Kubas, R. Tom Baker,Molecular and electronic structure of platinum bis(M-arylamino)phosphenium complexes including [Pt(phosphane)(phosphenium)(N-heterocyclic carbene)],Angewandte Chemie, International Edition,ドイツ,Wiley-VCH,2004年 4月 2日,vol.43, No.15,p.1955-1958
Peter Csabai, Ferenc Joo,Synthesis and Catalytic Properties of New Water-Soluble Ruthenium(II)-N-Heterocyclic Carbene Complexes,Organometallics,米国,ACS Publications,2004年11月 8日,vol.23, No.23,p.5640-5643
Colin H. Game, Michael Green, John R. Moss, Gordon A. Stone,Chemistry of the metal carbonyls. LXVIII. Complexes of manganese, iron, and ruthenium containing the cyclic carbene 2-oxacyclopentylidene,Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry,英国,RSC Publishng,1974年 4月 4日,vol.3,p.351-357
Alois Fuerstner,Olefin metathesis and beyond,Angewandte Chemie, International Edition,ドイツ,Wiley-VCH,2000年,vol.39,p.3013-3043
Alois Fuerstner, Oliver Guth, Arno Duffels, Gunter Seidel, Monika Liebl, Barbara Gabor, Richard Mynott,Indenylidene complexes of ruthenium: optimized synthesis, structure elucidation, and performance as catalysts for olefin metathesis-application to the synthesis of the ADE-ring system of nakadomarin A,CHEMISTRY A EUROPEAN JOURNAL,ドイツ,Wiley-VCH,2001年,vol.7, No.22,p.4811-4820
Laleh Jafarpour, Hans-Joerg Schanz, Edwin D. Stevens, Steven P. Nolan,Indenylidene-Imidazolylidene Complexes of Ruthenium as Ring-Closing Metathesis Catalysts,ORGANOMETALLICS,米国,ACS Publications,1999年11月10日,vol.18, No.25,P5416-5419
Tom Opstal, Francis Verpoort,Ruthenium indenylidene and vinylidene complexes bearing schiff bases: Potential catalysts in enol-ester synthesis,SYNLETT,ドイツ,Georg Thieme,2002年,vol.6,p.935-941
Tom Opstal, Francis Verpoort,From atom transfer radical addition to atom transfer radical polymerization of vinyl monomers mediated by ruthenium indenylidene complexes,NEW JOURNAL OF CHEMISTRY,2003年 2月 1日,vol.27, No.2,p.257-262
Stefan Randl, Simon Gessler, Hideaki Wakamatsu, Siegfried Blechert,Highly selective cross metathesis with acrylonitrile using a phosphine free Ru-complex,SYNLETT,ドイツ,Georg Thieme,2001年,vol.3,p.430-432
Grant S. Forman, Ann E. McConnell, Martin J. Hanton, Alexandra M. Z. Slawin, Robert P. Tooze, Werner Janse Van Rensburg, Wolfgang H. Meyer, Cathy Dwyer, Megan M. Kirk, D. Wynand Serfontein,A Stable Ruthenium Catalyst for Productive Olefin Metathesis,Organometallics,米国,ACS Publications,2004年10月11日,vol.23, No.21,p.4824-4827
Takanori Shima, Eike B. Bauer, Frank Hampel, J. A. Gladysz,Alkene metatheses in transition metal coordination spheres: dimacrocyclizations that join trans positions of square-planar platinum complexes to give topologically novel diphosphine ligands,Dalton Transactions,2004年,vol.7,p.1012-1028
Ned J. Hardman, Michael B. Abrams, Melanie A. Pribisko, Thomas M. Gilbert, Richard L. Martin, Gregory J. Kubas, R. Tom Baker,Molecular and electronic structure of platinum bis(M-arylamino)phosphenium complexes including [Pt(phosphane)(phosphenium)(N-heterocyclic carbene)],Angewandte Chemie, International Edition,ドイツ,Wiley-VCH,2004年 4月 2日,vol.43, No.15,p.1955-1958
Peter Csabai, Ferenc Joo,Synthesis and Catalytic Properties of New Water-Soluble Ruthenium(II)-N-Heterocyclic Carbene Complexes,Organometallics,米国,ACS Publications,2004年11月 8日,vol.23, No.23,p.5640-5643
Colin H. Game, Michael Green, John R. Moss, Gordon A. Stone,Chemistry of the metal carbonyls. LXVIII. Complexes of manganese, iron, and ruthenium containing the cyclic carbene 2-oxacyclopentylidene,Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry,英国,RSC Publishng,1974年 4月 4日,vol.3,p.351-357
Alois Fuerstner,Olefin metathesis and beyond,Angewandte Chemie, International Edition,ドイツ,Wiley-VCH,2000年,vol.39,p.3013-3043
Alois Fuerstner, Oliver Guth, Arno Duffels, Gunter Seidel, Monika Liebl, Barbara Gabor, Richard Mynott,Indenylidene complexes of ruthenium: optimized synthesis, structure elucidation, and performance as catalysts for olefin metathesis-application to the synthesis of the ADE-ring system of nakadomarin A,CHEMISTRY A EUROPEAN JOURNAL,ドイツ,Wiley-VCH,2001年,vol.7, No.22,p.4811-4820
Laleh Jafarpour, Hans-Joerg Schanz, Edwin D. Stevens, Steven P. Nolan,Indenylidene-Imidazolylidene Complexes of Ruthenium as Ring-Closing Metathesis Catalysts,ORGANOMETALLICS,米国,ACS Publications,1999年11月10日,vol.18, No.25,P5416-5419
Tom Opstal, Francis Verpoort,Ruthenium indenylidene and vinylidene complexes bearing schiff bases: Potential catalysts in enol-ester synthesis,SYNLETT,ドイツ,Georg Thieme,2002年,vol.6,p.935-941
Tom Opstal, Francis Verpoort,From atom transfer radical addition to atom transfer radical polymerization of vinyl monomers mediated by ruthenium indenylidene complexes,NEW JOURNAL OF CHEMISTRY,2003年 2月 1日,vol.27, No.2,p.257-262
Stefan Randl, Simon Gessler, Hideaki Wakamatsu, Siegfried Blechert,Highly selective cross metathesis with acrylonitrile using a phosphine free Ru-complex,SYNLETT,ドイツ,Georg Thieme,2001年,vol.3,p.430-432
Grant S. Forman, Ann E. McConnell, Martin J. Hanton, Alexandra M. Z. Slawin, Robert P. Tooze, Werner Janse Van Rensburg, Wolfgang H. Meyer, Cathy Dwyer, Megan M. Kirk, D. Wynand Serfontein,A Stable Ruthenium Catalyst for Productive Olefin Metathesis,Organometallics,米国,ACS Publications,2004年10月11日,vol.23, No.21,p.4824-4827
Takanori Shima, Eike B. Bauer, Frank Hampel, J. A. Gladysz,Alkene metatheses in transition metal coordination spheres: dimacrocyclizations that join trans positions of square-planar platinum complexes to give topologically novel diphosphine ligands,Dalton Transactions,2004年,vol.7,p.1012-1028
Attorney, Agent or Firm:
Hidesaku Yamamoto
Takaaki Yasumura
Natsuki Morishita
Takaaki Yasumura
Natsuki Morishita