Title:
フッ素化されたイオン性スルホニルイミド及びスルホニルメチリド、それらの製造方法並びに光開始剤としての使用
Document Type and Number:
Japanese Patent JP4226672
Kind Code:
B2
Abstract:
Ionic compound is claimed which contains at least one A<+>X<-> group in which A<+> is cation selected from biaryliodonium, arylsulphonium, arylacylsulphonium, diazonium, and organometallic cations containing transition metal complexed by at least one 4-12C unsaturated cyclic compound; said cationic group eventually becoming part of polymer chain; and X<-> is imiduric anionÄFSO2NSO2R'fÜ<->, ÄRfCH2OSO2NSO2R'fÜ<->, Ä(Rf)2CHOSO2NSO2R'fÜ<->, or methyluric anion ÄFSO2C(Q)SO2R'fÜ<->, ÄRfCH2OSO2C(Q)SO2R'fÜ<->, or Ä(Rf)2CHOSO2C(Q)SO2R'fÜ<->; in which Q = H, Cl, F-, Br, CN, or 1-30C alkyl, or 6-30C aryl, alkylaryl, or arylalkyl, or groups selected from R"f, R"fSO2, R"fCH2OSO2, (R"f)2CHOSO2; Rf, R'f, R"f are selected, when X<-> is methyluric, from fluorine, 1-30C perhaloalkyl, 2-30C (perhaloalkyl)alkoxy, 3-30C perhalogenocycloaliphatic, possibly containing heteroatoms and/or perhaloalkyl chain, and 6-30C perhalogenated aryl; or better, Rf, R'f form divalent rad ical selected from 2-8C perfluoroalkene; or better still, R'f, R"f , or Rf, R"f form said divalent radical. Also claimed are: (1) preparation of the compound; (2) method for polymerisation or crosslinking using the compound as photoinitiator; and (3) modification of solubility properties of a polymer, containing acid-sensitive groups, which uses the compound.
Inventors:
Alan Valley
Michelle Armand
Xavier Oliveran
Christoph Mishoto
Michelle Armand
Xavier Oliveran
Christoph Mishoto
Application Number:
JP27162497A
Publication Date:
February 18, 2009
Filing Date:
October 03, 1997
Export Citation:
Assignee:
Hydro-Quebec
CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE
CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE
International Classes:
C07C19/07; C07C245/14; C07C307/02; C07C311/48; C07C317/02; C07C381/12; C08F2/46; C08F4/42; C08F12/02; C08F112/14; C08G59/68; C08G75/02; C08G77/08; C08G79/00; C09K3/00; G03F7/00; G03F7/004
Domestic Patent References:
| JP9241315A |
Foreign References:
| US5561216 |
Other References:
Tetrahedron Letters,(1983),24(1),p.87-90
Zeitschrift fuer Naturforschung Section B,(1976),31B(11),p.1497-1500
J.Fluorine Chemisry,(1992),58(1),p.43-51
Indian J.Chemistry,Section A,(1993),32A(3),p.232-5
Indian J.Chemistry,Section A,(1989),28A(10),p.890-2
Bulletin de la Societe Chimique de France,(1989),(3),p.331-3
Zeitschrift fuer Naturforschung Section B,(1976),31B(11),p.1497-1500
J.Fluorine Chemisry,(1992),58(1),p.43-51
Indian J.Chemistry,Section A,(1993),32A(3),p.232-5
Indian J.Chemistry,Section A,(1989),28A(10),p.890-2
Bulletin de la Societe Chimique de France,(1989),(3),p.331-3
Attorney, Agent or Firm:
Kazuo Shamoto
Shosuke Imai
Tadashi Masui
Tadahiko Kurita
Yasushi Kobayashi
Hiroko Ejiri
Shosuke Imai
Tadashi Masui
Tadahiko Kurita
Yasushi Kobayashi
Hiroko Ejiri