Title:
触媒担体用ビニルピリジン樹脂、その製造方法およびメタノールのカルボニル化反応用触媒
Document Type and Number:
Japanese Patent JPWO2017159466
Kind Code:
A1
Abstract:
耐熱性、耐摩耗性及びロジウムを担持させた触媒の触媒活性に優れた触媒担体用ビニルピリジン樹脂、その製造方法、およびメタノールのカルボニル化反応用触媒を提供する。そのビニルピリジン樹脂は、ピリジン基に由来する窒素含有量が３．００質量％以上８．００質量％以下、架橋度が３５モル％以上７０モル％以下、炭素原子と窒素原子とのモル比Ｃ／Ｎが１２．００以上３６．００以下、全細孔容積が０．２０ｃｃ／ｇ以上０．４５ｃｃ／ｇ以下、比表面積が７０．０ｍ２／ｇ以上２８０ｍ２／ｇ以下、平均細孔径が５．０ｎｍ以上２５．０ｎｍ以下、且つ１０ｎｍ以上の細孔径を有する細孔が全細孔に占める容積の割合が４．０％以上９０．０％以下である。
Inventors:
Chikako Hashimoto
Ryuichi Kanai
Yuu Shio
Tetsuro Matsumura
Yoichi Umehara
Ryuichi Kanai
Yuu Shio
Tetsuro Matsumura
Yoichi Umehara
Application Number:
JP2018505840A
Publication Date:
January 24, 2019
Filing Date:
March 07, 2017
Export Citation:
Assignee:
Chiyoda Kakoh Construction Co., Ltd.
International Classes:
B01J31/06; B01J32/00; B01J37/02; B01J37/04; C08F26/06
Domestic Patent References:
| JP2013035805A | 2013-02-21 | |||
| JP2010502571A | 2010-01-28 | |||
| JPH0892322A | 1996-04-09 | |||
| JPH07309800A | 1995-11-28 | |||
| JP2012081440A | 2012-04-26 |
Foreign References:
| EP2631010A1 | 2013-08-28 |
Other References:
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MAILLARD-TERRIER, M.C. ET AL.: "Texture poreuse de copolymeres 4-vinylpyridine divinylbenzene", EUROPEAN POLYMER JOURNAL, vol. Vo.20, No.2, JPN6017017929, 1984, pages 113 - 118, ISSN: 0004468603
DE SANTA MARIA, L. C. ET AL.: "Microscopic analysis of porosity of 2-vinylpyridine copolymer networks: 1. Influence of diluent", MATERIALS LETTERS, vol. 58, no. 5, JPN6017017932, February 2004 (2004-02-01), pages 563 - 568, XP004483141, ISSN: 0004468604, DOI: 10.1016/S0167-577X(03)00562-7
MALIK, M. A.: "Macroporous 4-Vinylpyridine-divinylbenzene - Estimation of Pore Volume, Surface Area, and Pore Size", E-POLYMERS, vol. 6, no. 1, JPN6017017936, 19 July 2006 (2006-07-19), pages 1 - 8, ISSN: 0004468605
MAILLARD-TERRIER, M.C. ET AL.: "Texture poreuse de copolymeres 4-vinylpyridine divinylbenzene", EUROPEAN POLYMER JOURNAL, vol. Vo.20, No.2, JPN6017017929, 1984, pages 113 - 118, ISSN: 0004468603
DE SANTA MARIA, L. C. ET AL.: "Microscopic analysis of porosity of 2-vinylpyridine copolymer networks: 1. Influence of diluent", MATERIALS LETTERS, vol. 58, no. 5, JPN6017017932, February 2004 (2004-02-01), pages 563 - 568, XP004483141, ISSN: 0004468604, DOI: 10.1016/S0167-577X(03)00562-7
MALIK, M. A.: "Macroporous 4-Vinylpyridine-divinylbenzene - Estimation of Pore Volume, Surface Area, and Pore Size", E-POLYMERS, vol. 6, no. 1, JPN6017017936, 19 July 2006 (2006-07-19), pages 1 - 8, ISSN: 0004468605
Attorney, Agent or Firm:
Okabe
Masami Saito
Shinichi Usui
Masami Saito
Shinichi Usui