To obtain a woven fabric that has no unpleasantness even in perspiration, excellent wearing comfortableness free from performance deterioration even in repeated wearing and a uniform obtained by using the woven fabric at least in a part.

The woven fabric is a union cloth obtained by combining a hydrophilic fiber with a hydrophobic fiber and is a woven fabric of multiple weave structure comprising the surface of the woven fabric constituted mainly of a spun yarn using ≥10 wt.% and ≤80 wt.% of a cotton fiber as the hydrophilic fiber and the back of the woven fabric composed mainly of a hydrophobic synthetic fiber yarn having ≥0.1 dtex and ≤4.0 dtex single fiber fineness, has excellent skin separability, cold feeling prevention in perspiration, excellent water supply rate and wearing comfortableness. The uniform is obtained by using the woven fabric at least in part.