Title:
A carbon-carbon joint formation method and the platinum group metal support catalyst for a carbon-carbon joint formation reaction
Document Type and Number:
Japanese Patent JP5943744
Kind Code:
B2
Abstract:
PROBLEM TO BE SOLVED: To provide a method of forming a carbon-carbon bond efficiently.SOLUTION: A carbon-carbon bond-forming method includes a reaction of an aromatic halide and an organoboron compound, a reaction of the aromatic halide and a compound having an alkynyl group at its terminal etc. in the presence of a platinum group metal carrier catalyst that is a platinum group metal carrier catalyst carrying nano particles of the platinum group metal having an average particle size of 1 to 100 nm on a non-particulate organic porous ion exchanger. The non-particulate organic porous ion exchanger contains a continuous skeleton phase and a continuous pore phase, and a thickness of the continuous skeleton is 1 to 100 μm, an average diameter of the continuous pore is 1 to 1000 μm, a total pore volume is 0.5 to 50 ml/g, an ion exchange capacity is 1 to 6 mg equivalent/g per a weight in dry conditions, and an ion exchange group is distributed in the organic porous ion exchanger uniformly, and an amount of the platinum group metal carried is 0.004 to 20 wt.% in dry conditions.
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Inventors:
Hitoshi Takada
Hiroshi Inoue
Akira Nakamura
Hironao Sajiki
Yasuya Kadoguchi
Yoshinari Sawama
Ryo Ito
Wakayama Fumika
Hiroshi Inoue
Akira Nakamura
Hironao Sajiki
Yasuya Kadoguchi
Yoshinari Sawama
Ryo Ito
Wakayama Fumika
Application Number:
JP2012154267A
Publication Date:
July 05, 2016
Filing Date:
July 10, 2012
Export Citation:
Assignee:
Organo Corporation
International Classes:
C07C41/30; B01J23/42; C07C43/205; C07C45/68; C07C49/784; C07C67/343; C07C69/618; C07C201/12; C07C205/06; C07C209/68; C07C211/45
Domestic Patent References:
| JP2010526659A | ||||
| JP2012061455A | ||||
| JP2010214320A | ||||
| JP2010214321A | ||||
| JP2011036807A | ||||
| JP2010259989A |
Foreign References:
| WO2010106925A1 |
Other References:
Wladimir Solodenko et al.,Development of a Continuous-Flow System for Catalysis with Palladium(0) Particles,EUROPEAN JOURNAL OF ORGANIC CHEMISTRY,2004年,(17),3601-3610
Klaas Mennecke et al.,Polyionic polymers - heterogeneous media for metal nanoparticles as catalyst in Suzuki-Miyaura and Heck-Mizoroki reactions under flow conditions,BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY,2009年,5 (21),1-6
Klaas Mennecke et al.,Polyionic polymers - heterogeneous media for metal nanoparticles as catalyst in Suzuki-Miyaura and Heck-Mizoroki reactions under flow conditions,BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY,2009年,5 (21),1-6
Attorney, Agent or Firm:
Kenji Akatsuka
Yasuo Fukuda
Yasuyuki Sakata
Yasuo Fukuda
Yasuyuki Sakata
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