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Title:
The extraction separation method of a rare metal using Nitorirolotri aceto amide
Document Type and Number:
Japanese Patent JP6083862
Kind Code:
B2
Abstract:
PROBLEM TO BE SOLVED: To provide a method for extraction separation enabling many kinds of rare metals to be recovered at a time.SOLUTION: There is provided a method for extraction separation of rare metals from a hydrochloric acid solution or a nitric acid solution by using as an extractant, nitriloacetamide represented by the general formula, where R is an alkyl group having 6 to 12 carbon atoms. The rare metal is preferably one or more kind selected from among Nb, Ta, Cr, Mo, W, Re, Ru, Ir, Pd, Pt, Ga, In, Sb, Bi, Te, Hg, Tc and V. The rare metal is solvent-extracted from the hydrochloric acid solution or the nitric acid solution by using an extraction solvent obtained by solving nitriloacetamide in an organic solvent, or the rare metal is extraction-separated from the hydrochloric acid solution or the nitric acid solution by passing the hydrochloric acid solution or the nitric acid solution containing the rare metal through a solid adsorbent obtained by impregnating nitriloacetamide into a resin.

Inventors:
Yuji Sasaki
Yasuhiro Tsubata
Akihiro Kitatsuji
Application Number:
JP2013025879A
Publication Date:
February 22, 2017
Filing Date:
February 13, 2013
Export Citation:
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Assignee:
Japan Atomic Energy Agency
International Classes:
C22B3/38; B01D11/04; B01D15/00; B01J20/22; C08K5/20; C08L101/02; C22B3/24; C22B11/00; C22B30/02; C22B30/06; C22B34/22; C22B34/24; C22B34/32; C22B34/34; C22B43/00; C22B58/00; C22B61/00
Domestic Patent References:
JP63055117A
JP2010101641A
JP2011125840A
Other References:
IQBAL, M. et al.,New Journal of Chemistry,2011年,Vol.35(11),pp.2591-2600
Attorney, Agent or Firm:
Shinjiro Ono
Yasushi Kobayashi
Hiroyuki Tomita
Osamu Hoshino
Minako Matsuyama