A gas separating apparatus and a gas storage device using a porous polymer metal complex, gas adsorption material, and this

Japanese Patent JP5988896

B2

PROBLEM TO BE SOLVED: To provide a novel porous polymer metal complex, a gas adsorbent having excellent property using the same, and a gas storage apparatus and a gas separation apparatus each housing the gas adsorbent having the excellent property.SOLUTION: There is provided the porous polymer metal complex which is represented by the following formula (1), [Zn(bpy)X](1) ( in the formula, bpy is 4,4'-bipyridine, X is a an isophthalic acid anion having a perfluoroalkyl group having 1 to 8 carbon atoms as a substituent at 5-position, n is one showing such a property that many constituent units consisting of Zn(bpy)X aggregate and a value of n is not limited specifically, and in which a zinc ion is at tetracoordinated state coordinated by three monodentate carboxyl groups and a nitrogen atom of one 4,4'-bipyridine molecule, and a whole network structure has a three-dimensional network structure corresponding to a so-called BCT skeleton in a classification of zeolite. There are also provided a use of the porous polymer metal complex as a gas adsorbent, a gas separation apparatus and a gas storage apparatus each using the gas adsorbent.

Retail price Hiroshi
Hirokazu Tamai
Koichi Nose
Susumu Kitagawa
Ryotaro Matsuda
Hiroshi Sato
All tolls

JP2013040005A

September 07, 2016

February 28, 2013

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Nippon Steel & Sumitomo Metal Corporation
Kyoto University

C07D213/22; B01D53/02; B01J20/26; C07C63/24; F17C11/00

JP2010201292A
JP201217268A
JP201137794A

WO2010042948A2

Atsushi Aoki
Takashi Ishida
Tetsuji Koga
Hiroshi Kamematsu
Nagasaka Tomoyasu
Yoshihiro Kobayashi

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