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Title:
The gaseous phase and the liquid phase catalyst Beckmann rearrangement of oxime for manufacturing lactam
Document Type and Number:
Japanese Patent JP6243340
Kind Code:
B2
Abstract:
Methods for producing lactams from oximes by performing a Beckmann rearrangement using a silicoaluminophosphate catalyst are provided. These catalysts may be used in gas phase or liquid phase reactions to convert oximes into lactams. High conversion of oxime and high selectivity for the desired lactams are produced using the disclosed methods, including high conversion and selectivity for ε-caprolactam produced from cyclohexanone oxime and high conversion and selectivity for ω-laurolactam produced from cyclododecanone oxime.

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Inventors:
Levy, Alan Bee
Raja, Robert
Potter, Matthew Y
Application Number:
JP2014538999A
Publication Date:
December 06, 2017
Filing Date:
October 25, 2012
Export Citation:
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Assignee:
Honeywell International Inc.
International Classes:
C07D201/04; B01J29/85; C07D223/10; C07D225/02
Domestic Patent References:
JP64016730A
JP2001072658A
JP59084829A
JP59035018A
Other References:
Borade, Ramesh B.; Clearfield, Abraham,A comparative study of acidic properties of SAPO-5, -11, -34 and -37 molecular sieves,Journal of Molecular Catalysis ,1994年,88(2),249-65
Briend, M.; Peltre, M. J.; Lamy, A.; Man, P. P.; Barthomeuf, D.,Dependence of the acidic properties of SAPO-37 molecular sieve on silicon content and heat treatment,Journal of Catalysis,1992年,138(1),90-100
Attorney, Agent or Firm:
Shinjiro Ono
Osamu Yamamoto
Toru Miyamae
Motoharu Nakanishi
Noriyuki Arai