Title:
ジオールの工業的製造方法
Document Type and Number:
Japanese Patent JP5074213
Kind Code:
B2
Abstract:
It is an object of the present invention to provide a specific apparatus and process for producing a diol by taking a cyclic carbonate and an aliphatic monohydric alcohol as starting materials, continuously feeding the starting materials into a continuous multi-stage distillation column A in which a catalyst is present, carrying out reactive distillation in the column A, continuously withdrawing a low boiling point reaction mixture A T containing a produced dialkyl carbonate and the aliphatic monohydric alcohol from an upper portion of the column A in a gaseous form, continuously withdrawing a high boiling point reaction mixture A B containing a produced diol from a lower portion of the column A in a liquid form, continuously feeding the high boiling point reaction mixture A B into a continuous multi-stage distillation column C, distilling off material having a lower boiling point than that of the diol contained in the high boiling point reaction mixture A B as a column top component C T and a side cut component C S so as to obtain a column bottom component C B , continuously feeding the column bottom component C B into a continuous multi-stage distillation column C, and obtaining the diol as a side cut component E S from a side cut outlet of the continuous multi-stage distillation column C. Moreover, it is an object to thus provide a specific industrial apparatus and industrial production process that are inexpensive and, for example, enable the diol to be produced in an amount of not less than 1 ton / hr, preferably not less than 2 tons / hr, more preferably not less than 3 tons / hr, stably for a prolonged period of time (e.g. not less than 1000 hours, preferably not less than 3000 hours, more preferably not less than 5000 hours). According to the present invention, the above objects can be attained by using a continuous multi-stage distillation column C having a specified structure, and withdrawing a liquid component from the side cut outlet, which is installed at the bottom of a chimney tray having a specified structure installed in an enrichment section of the continuous multi-stage distillation column C.
Inventors:
Shinichi Fukuoka
Yuki Miyaji
Hiroshi Hachiya
Kazuhiko Matsuzaki
Yuki Miyaji
Hiroshi Hachiya
Kazuhiko Matsuzaki
Application Number:
JP2007555916A
Publication Date:
November 14, 2012
Filing Date:
January 19, 2007
Export Citation:
Assignee:
Asahi Kasei Chemicals Corporation
International Classes:
C07C29/80; C07C27/02; C07C29/128; C07C31/20; C07C68/06; C07C69/96; C07B61/00
Domestic Patent References:
| JPH08170086A | 1996-07-02 | |||
| JPH09183744A | 1997-07-15 | |||
| JP2004131394A | 2004-04-30 |
Foreign References:
| WO2000051954A1 | 2000-09-08 | |||
| WO2005123638A1 | 2005-12-29 | |||
| WO2006030724A1 | 2006-03-23 |
Attorney, Agent or Firm:
Yoshiyuki Inaba
Shinji Oga
Toshifumi Onuki
Shinji Oga
Toshifumi Onuki