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Title:
The lithium ion electrochemistry battery containing a fluorocarbon electrolyte additive agent
Document Type and Number:
Japanese Patent JP6054956
Kind Code:
B2
Abstract:
Lithium-ion electrochemical cells are provided that include a positive electrode that includes a lithium metal oxide or a lithium metal phosphate, a negative electrode capable of intercalating or alloying with lithium, and an electrolyte that includes an additive. The additive includes a multifunctional anion that has the formula, X—SO2—Rf—SO2—Y, wherein X and Y are, independently, either O— or RfSO2N—, Rf is a straight or branched fluoroalkyl moiety having from 1 to 6 carbon atoms, and can, optionally, contain one or more in-chain heteroatoms, wherein Rf is a straight or branched chain or cyclic fluoroalkylene having from 1 to 10 carbon atoms and can, optionally, contain one or more in-chain heteroatoms, and wherein both Rf and Rf have a maximum of 20% non-fluorine substituents. The provided additives can improve the performance, hydrolytic stability, and thermal stability of the provided electrochemical cells.

Inventors:
Ramanna, William M.
Xiao, Ann
Tory Mart, Matthew J.
Fem, Fat Tea.
Application Number:
JP2014514493A
Publication Date:
December 27, 2016
Filing Date:
May 30, 2012
Export Citation:
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Assignee:
3M INNOVATIVE PROPERTIES COMPANY
International Classes:
H01M10/0567; H01M4/58; H01M10/052; H01M10/0565
Domestic Patent References:
JP2001512714A
JP8268998A
JP2002305023A
JP2005203341A
JP2007294397A
JP2002543178A
JP2002508576A
Foreign References:
US20020127475
US5514493
WO2001052341A1
Attorney, Agent or Firm:
Yoshiki Hasegawa
Yoshinori Shimizu
Yasuki Yanagi