Title:
METHOD FOR PRODUCING FLUORINATED ORGANIC COMPOUND AND FLUORINATING REAGENT
Document Type and Number:
Japanese Patent JP2017203041
Kind Code:
A
Abstract:
PROBLEM TO BE SOLVED: To provide a method for producing, with a high yield, a fluorinated organic compound, the fluorinated organic compound having not been produced with a sufficient yield by a conventional method for producing a fluorinated organic compound with a fluorinating agent containing IF-pyridine-HF alone.SOLUTION: The present invention relates to a method for producing a fluorinated organic compound comprising a step A of fluorinating an organic compound by bringing the organic compound into contact with (1) IF-pyridine-HF and (2) at least one additive selected from the group consisting of amine-hydrogen fluorides, XF (wherein Xrepresents hydrogen, potassium, sodium, or lithium), oxidizers, and reducing agents.SELECTED DRAWING: None
Inventors:
AZUMA MASAHIRO
KISHIKAWA YOSUKE
SHIRAI ATSUSHI
NAMIKAWA TAKASHI
ISHIHARA SUMI
HARA MASAHARU
KISHIKAWA YOSUKE
SHIRAI ATSUSHI
NAMIKAWA TAKASHI
ISHIHARA SUMI
HARA MASAHARU
Application Number:
JP2017154640A
Publication Date:
November 16, 2017
Filing Date:
August 09, 2017
Export Citation:
Assignee:
DAIKIN IND LTD
UNIV HOKKAIDO
UNIV HOKKAIDO
International Classes:
C07C17/02; C07C19/16; C07C21/18; C07C22/08; C07C23/02; C07C41/22; C07C43/12; C07C43/174; C07C43/192; C07C43/225; C07C67/287; C07C67/307; C07C69/63; C07C69/65; C07C211/05; C07C319/20; C07C321/28; C07D213/20
Domestic Patent References:
| JP2015075179A | 2015-04-20 | |||
| JP2002363110A | 2002-12-18 | |||
| JP2002363111A | 2002-12-18 |
Foreign References:
| WO2001096263A1 | 2001-12-20 |
Other References:
HARA, SHOJI ET AL.: "IF5-pyridine-HF: air- and moisture-stable fluorination reagent", TETRAHEDRON, vol. 68, no. 49, JPN6016026885, 2012, pages 10145 - 10150, XP055612631, ISSN: 0004101596, DOI: 10.1016/j.tet.2012.09.104
AYUBA, SHINICHI ET AL.: "Fluorination of sulfides using IF5-Et3N-3HF", BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, vol. 75, no. 7, JPN6016026900, 2002, pages 1597 - 1603, XP093126682, ISSN: 0004101597
RE, SALVATORE ET AL.: "Fluorination for modern industry - A holistic approach", SPECIALITY CHEMICALS MAGAZINE, vol. 24, no. 2, JPN6016026887, 2004, pages 28 - 31, ISSN: 0004101598
YONEDA, NORIHIKO ET AL.: "Novel fluorination reagent: IF5/Et3N-3HF", CHEMISTRY LETTERS, JPN6016026890, 2001, pages 222 - 223, ISSN: 0004101599
AYUBA, SHINICHI ET AL.: "Fluorination of sulfides using IF5-Et3N-3HF", BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, vol. 75, no. 7, JPN6016026900, 2002, pages 1597 - 1603, XP093126682, ISSN: 0004101597
RE, SALVATORE ET AL.: "Fluorination for modern industry - A holistic approach", SPECIALITY CHEMICALS MAGAZINE, vol. 24, no. 2, JPN6016026887, 2004, pages 28 - 31, ISSN: 0004101598
YONEDA, NORIHIKO ET AL.: "Novel fluorination reagent: IF5/Et3N-3HF", CHEMISTRY LETTERS, JPN6016026890, 2001, pages 222 - 223, ISSN: 0004101599
Attorney, Agent or Firm:
Patent Business Corporation Saegusa International Patent Office
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