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Title:
A manufacturing method of nitrous acid C1-C4 Alkyl
Document Type and Number:
Japanese Patent JP6027723
Kind Code:
B2
Abstract:
The present invention relates to a process for producing C1-C4 alkyl nitrite, comprising loading a resin catalyst layer and/or a porous filler layer into a reactor, passing nitrogen oxide, oxygen and C1-C4 alkanol as raw materials through the resin catalyst layer and/or porous filler layer in a counter current, parallel current or cross current manner, reacting under the conditions including a reaction temperature of from 0 to 150° C., a reaction pressure of from −0.09 to 1.5 MPa, a molar ratio of C1-C4 alkanol/nitrogen oxide of 1-100:1, a molar ratio of nitrogen oxide/oxygen of 4-50:1, to obtain an effluent containing C1-C4 alkyl nitrite, wherein said nitrogen oxide is NO, or a mixed gas containing NO and one or more selected from N2O3 and NO2.

Inventors:
Liu Shun
Lee
Lee bud
Zhang Lin
Application Number:
JP2011090875A
Publication Date:
November 16, 2016
Filing Date:
April 15, 2011
Export Citation:
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Assignee:
China Petrochemical Co. Ltd.
China Petroleum Industry Co., Ltd. Shanghai Petrochemical Research Institute
International Classes:
C07C201/04; C07C203/00
Domestic Patent References:
JP2004002336A
JP6277497A
JP2007112745A
JP2003327562A
JP2009057370A
JP2003128634A
JP2004107336A
JP6298706A
Foreign References:
CN101664656A
CN1895766A
US5649322
US20090043120
Other References:
「TOWER PACKINGS」,マツイマシン株式会社,第8-9頁,URL,http://www.matsuimachine.co.jp/download/pdf/matsuimachine.pdf
Attorney, Agent or Firm:
Yasuhiko Murayama
Shinya Mitsuhiro
Tatsuhiko Abe