Title:
メタロセン錯体及びその製造方法、触媒組成物
Document Type and Number:
Japanese Patent JP6302565
Kind Code:
B2
Abstract:
This invention provides a metallocene complex and the preparation method thereof and a catalyst composition. This catalyst composition comprises a metallocene complex represented by formula (I) and an organic boron salt. Compared to the prior art, the catalyst used in this invention, which is the metallocene complex represented by formula (I), does not contain any side chain, and the coordination space of the central metal has a large opening degree. Therefore, the catalytic activity for more sterically hindered monomers is higher, and the comonomer incorporation is also higher. Furthermore, the metallocene complex represented by formula (I) used in this invention is a heterocyclic ring fused cyclopentadienyl ligand. Heterocyclic rings have relatively strong electron-donating capacity. By fusing a cyclopentadienyl group using heterocyclic rings, it is possible to change the electronic effect of the metal center and in turn increase the activity of catalyst. Therefore, by using the metallocene complex represented by formula (I), it is possible to prepare copolymers of ethylene with other olefins at high activity and high comonomer incorporation, and it is also possible to catalyze the polymerization of styrene and substituted styrene at high syndiotacticity and high activity.
Inventors:
Kui, Don May
U, Chungji
Yao, Changan
U, Chungji
Yao, Changan
Application Number:
JP2016547209A
Publication Date:
March 28, 2018
Filing Date:
November 11, 2013
Export Citation:
Assignee:
Changchun Institute of Applied Chemistry, Chinese Academy of Sciences
International Classes:
C07F19/00; C08F4/6592; C08F10/00
Domestic Patent References:
| JP2011190288A | ||||
| JP2001504824A |
Foreign References:
| WO2006004068A1 |
Other References:
LI,X. et al,Aluminum Effects in the Syndiospecific Copolymerization of Styrene with Ethylene by Cationic Fluorenyl Scandium Alkyl Catalysts,Organometallics,2013年,Vol.32, No.5,p.1445-1458
XU,X. et al,Indenyl abstraction versus alkyl abstraction of [(indenyl)ScR2(THF)] by [Ph3C][B(C6F5)4]: aspecific and syndiospecific styrene polymerization,Chemistry - A European Journal,2009年,Vol.15, No.4,p.846-850
PARK,E.S. et al,Preparation of half-titanocenes of thiophene-fused trimethylcyclopentadienyl ligands and their ethylene copolymerization reactivity,Journal of Organometallic Chemistry,2011年,Vol.696, No.11-12,p.2451-2456
KISSOUNKO,D.A. et al,Journal of Organometallic Chemistry,2008年,Vol.693, No.6,p.1058-1064
編者 社団法人日本化学会,実験化学講座 18 有機化合物の合成 VI -金属を用いる有機合成-,2007年,第5版 第2刷,p1-2
YU,N. et al,Cationic scandium allyl complexes bearing mono(cyclopentadienyl) ligands: synthesis, novel structural variety, and olefin-polymerization catalysis,Chemistry - An Asian Journal,2008年,Vol.3, No.8-9,p.1406-1414
XU,X. et al,Indenyl abstraction versus alkyl abstraction of [(indenyl)ScR2(THF)] by [Ph3C][B(C6F5)4]: aspecific and syndiospecific styrene polymerization,Chemistry - A European Journal,2009年,Vol.15, No.4,p.846-850
PARK,E.S. et al,Preparation of half-titanocenes of thiophene-fused trimethylcyclopentadienyl ligands and their ethylene copolymerization reactivity,Journal of Organometallic Chemistry,2011年,Vol.696, No.11-12,p.2451-2456
KISSOUNKO,D.A. et al,Journal of Organometallic Chemistry,2008年,Vol.693, No.6,p.1058-1064
編者 社団法人日本化学会,実験化学講座 18 有機化合物の合成 VI -金属を用いる有機合成-,2007年,第5版 第2刷,p1-2
YU,N. et al,Cationic scandium allyl complexes bearing mono(cyclopentadienyl) ligands: synthesis, novel structural variety, and olefin-polymerization catalysis,Chemistry - An Asian Journal,2008年,Vol.3, No.8-9,p.1406-1414
Attorney, Agent or Firm:
Shinei Patent Office