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Title:
A method for the adsorption separation of Para - xylene from mixed xylene using the manufacturing method of binder Resuzeo light system adsorbent and binder Resuzeo light system adsorbent, and binder Resuzeo light system adsorbent
Document Type and Number:
Japanese Patent JP5972787
Kind Code:
B2
Abstract:
Binderless BaKX zeolitic adsorbents, methods for their production, and processes for their use in a liquid phase adsorptive separation process are provided. An adsorbent includes a binder-converted zeolite portion formed from x wt % kaolin clay binder and (100−x) wt % unconverted Zeolite X with a silica:alumina molar ratio of about 2.5. The kaolin clay binder is in the range of about 10 to about 20 wt %. Ba and K occupy cationic exchangeable sites within the adsorbent. K is in the range of about 0.25 to about 0.9% by weight and Ba is greater than about 31.6% by weight of the binderless BaKX zeolitic adsorbent. Cornstarch may be added to the Zeolite X and kaolin clay binder to increase adsorbent macro-porosity and pore volume. Productivity of the adsorbent is improved decreasing process operating costs. The mechanical strength of the adsorbent is also improved.

Inventors:
Chen, Linda Shi
Hearst, Jack E
Application Number:
JP2012521661A
Publication Date:
August 17, 2016
Filing Date:
July 06, 2010
Export Citation:
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Assignee:
UOP LLC
International Classes:
B01J20/18; B01J20/30; B01J20/34; C01B39/22; C07C7/13; C07C15/08
Domestic Patent References:
JP60238149A
JP2002537109A
JP2007238484A
JP4828503A
JP5027790A
Foreign References:
CN1565718A
Attorney, Agent or Firm:
Shinjiro Ono
Yasushi Kobayashi
Shigeo Takeuchi
Osamu Yamamoto
Naoshi Nakata