Title:
光学活性なアジリジン化合物及びアミン化合物の製造方法、並びに該方法に用いる錯体及びその中間体
Document Type and Number:
Japanese Patent JP4564010
Kind Code:
B2
Abstract:
This invention provides a method for producing an optically active aziridine compound or amine compound, which uses as a catalyst a Ru(salen)(CO) complex represented by the following formula (I) or its enantiomer having a high stability, in a high turnover number (TON) and a high enantioselectivity. In the formula (I), Ar is represented by the following formula (VI) or (VII), wherein in the formula (VI), Xs are independently a halogen or a halogenated alkyl group and R 1 and R 2 s are independently hydrogen or an alkyl group or a trialkylsilyl group having a carbon number of 1-4, and in the formula (VII), R 3 is a bulky group.
More Like This:
| WO/2009/096907 | AZIRIDINE SYNTHESIS |
| WO/2015/120820 | CLASS OF CARBOXYLIC ACID DERIVATIVES AND USE THEREOF IN PREPARATION OF PRODRUGS |
Inventors:
Katsuki Tsutomu
Kazufumi Komura
Tatsuya Uchida
Ryo Irie
Kazufumi Komura
Tatsuya Uchida
Ryo Irie
Application Number:
JP2006528490A
Publication Date:
October 20, 2010
Filing Date:
June 16, 2005
Export Citation:
Assignee:
Japan Science and Technology Agency
International Classes:
C07D203/02; C07B53/00; C07C43/20; C07C47/57; C07C47/575; C07C251/24; C07C303/36; C07C311/16; C07D203/24; C07D203/26; C07B61/00; C07F15/00
Other References:
日本化学会第85回春季年会(2005)講演予稿集II,2005年,p.1091
日本化学会第83回春季年会(2003)講演予稿集II,2003年,p.1199
第36回酸化反応討論会講演要旨集,2003年,p.50-52
Tetrahedron,1998年,54(34),p.10017-10028
Chemistry Letters,2003年,32(4),p.354-355
Tetrahedron Letters,2003年,44(43),p.7965-7968
日本化学会第83回春季年会(2003)講演予稿集II,2003年,p.1199
第36回酸化反応討論会講演要旨集,2003年,p.50-52
Tetrahedron,1998年,54(34),p.10017-10028
Chemistry Letters,2003年,32(4),p.354-355
Tetrahedron Letters,2003年,44(43),p.7965-7968
Attorney, Agent or Firm:
Kenji Sugimura
Kosaku Sugimura
Shiro Fujitani
Kiyoshi Kuruma
Kazuyuki Tomita
Kosaku Sugimura
Shiro Fujitani
Kiyoshi Kuruma
Kazuyuki Tomita