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Title:
3座配位子を有する新規ルテニウムカルボニル錯体、並びにその製造法及び用途
Document Type and Number:
Japanese Patent JP5671456
Kind Code:
B2
Abstract:
The present invention relates to a ruthenium carbonyl complex that is represented by the following Formula (1): €ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒRuXY(CO)(L)€ƒ€ƒ€ƒ€ƒ€ƒ(1) (in the Formula (1), X and Y, which may be the same or different from each other, represent an anionic ligand and L represents a tridentate aminodiphosphine ligand which has two phophino groups and a -NH- group), its production method, and a method for production of alcohols by hydrogenation-redcution of ketones, esters, and lactones using the complex as a catalyst. The ruthenium carbonyl complex of the invention has a high catalytic activity and it can be easily prepared and handled.

Inventors:
栗山 亙
松本 崇司
猪野 恭規
小形 理
Application Number:
JP2011514945A
Publication Date:
February 18, 2015
Filing Date:
June 30, 2010
Export Citation:
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Assignee:
高砂香料工業株式会社
International Classes:
C07F9/50; C07C29/145; C07C29/149; C07C29/17; C07C31/20; C07C33/20; C07C33/22; C07C41/26; C07C43/13; C07C43/178; C07C213/00; C07C215/16; C07C269/06; C07C271/16; C07F7/18
Foreign References:
US20050107638A12005-05-19
US20050107638A12005-05-19
Other References:
JPN6010054830; R.CELENLIGIL-CETIN, et al.: 'Decarbonylation of Acetone and Carbonate at a Pincer-Ligated Ru Center' Organometallics Vol.24, No.2, p.186-189 (2005).
JPN6010054832; A.FRIEDRICH, et al.: 'Iridium Olefin Complexes Bearing Dialkylamino/amido PNP Pincer Ligands: Synthesis, Reactivity, and S' Organometallics Vol.28, No.3, p.708-718 (2009).
JPN6010054833; L.A.VAN DER VEEN, et al.: 'Origin of the Bite Angle Effect on Rhodium Diphosphine Catalyzed Hydroformylation' Organometallics Vol.19, No.5, p.872-883 (2000).
JPN6010054831; A.T.RADOSEVICH, et al.: 'Ligand Reactivity in Diarylamido/Bis(Phosphine) PNP Complexes of Mn(CO)3 and Re(CO)3' Inorganic Chemistry Vol.48, No.19, p.9214-9221 (2009).
JPN6010054830; R.CELENLIGIL-CETIN, et al.: 'Decarbonylation of Acetone and Carbonate at a Pincer-Ligated Ru Center' Organometallics Vol.24, No.2, p.186-189 (2005).
JPN6010054832; A.FRIEDRICH, et al.: 'Iridium Olefin Complexes Bearing Dialkylamino/amido PNP Pincer Ligands: Synthesis, Reactivity, and S' Organometallics Vol.28, No.3, p.708-718 (2009).
JPN6010054833; L.A.VAN DER VEEN, et al.: 'Origin of the Bite Angle Effect on Rhodium Diphosphine Catalyzed Hydroformylation' Organometallics Vol.19, No.5, p.872-883 (2000).
JPN6010054831; A.T.RADOSEVICH, et al.: 'Ligand Reactivity in Diarylamido/Bis(Phosphine) PNP Complexes of Mn(CO)3 and Re(CO)3' Inorganic Chemistry Vol.48, No.19, p.9214-9221 (2009).
Attorney, Agent or Firm:
Norio Saeki