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Title:
A pH measurement method and pH measuring device of specimen solution
Document Type and Number:
Japanese Patent JP6164753
Kind Code:
B2
Abstract:
Provided is a simplified, rigorous and accurate method of measuring pH of an analyte solution with extreme precision, which does not cause errors against actual pH through compensating a pH variation by a liquid temperature or a concentration of potassium chloride of an internal liquid in a glass electrode or a reference electrode when pH is measured with respect to various analyte solutions such as a sample solution having a high concentration of salts, a sample solution contaminated with salts and a sample solution having a low concentration of salts. A method of measuring pH of an analyte solution comprises: using electrodes, in which a pair of the electrodes consists of a glass electrode 10 which encloses a glass electrode internal liquid 12 including potassium chloride and a glass electrode buffer solution inside and a reference electrode 20 which encloses a reference electrode internal liquid 22 including potassium chloride and a reference electrode buffer solution inside such that a potential difference between the pair of the electrodes 10 and 20 is regulated to 0mV in a solution having out-of-range of pH 7.2 to 8.2, sensing a voltage generated between the electrodes in the analyte solution 50, and detecting a pH value of the analyte solution 50 while compensating pH by a concentration of the potassium chloride in the reference electrode internal liquid and a liquid temperature of the analyte solution 50.

Inventors:
Kei Okamura
Application Number:
JP2015069185A
Publication Date:
July 19, 2017
Filing Date:
March 30, 2015
Export Citation:
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Assignee:
National University Corporation Kochi University
International Classes:
G01N27/416; G01N27/36
Domestic Patent References:
JP2012107986A
JP2001242134A
JP2003043007A
JP2010107421A
Attorney, Agent or Firm:
Patent business corporation Maku patent office
Yoshio Komiya
Hiroyuki Onishi