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Title:
REACTIVATION METHOD OF CATALYST FOR IRON ACCUMULATION FLOW CONTACT DEGRADATION, REACTIVATION DEVICE AND FLOW CONTACT DEGRADATION METHOD
Document Type and Number:
Japanese Patent JP2017205744
Kind Code:
A
Abstract:
PROBLEM TO BE SOLVED: To provide a reactivation method of a catalyst for iron accumulation flow contact degradation having iron or nickel accumulated on a surface.SOLUTION: There is provided a method for reactivating an inactivated catalyst by closing pores due to iron accumulated on a surface of a catalyst for iron accumulation flow contact degradation, an abrasion removal of iron accumulated on the surface is conducted by flowing the catalyst for iron accumulation flow contact degradation in a container with an ascending current at a temperature of 800°C or less for 0.5 to 30 hrs and contacting catalysts each other to obtain a reactivated catalyst. There is provided a method for reactivating a catalyst for flow contact degradation where a fresh catalyst and a catalyst for iron accumulation flow contact degradation has a pore diameter in maximum pore volume in a range of 50 to 500 nm satisfying a condition represented by the following formula 1. D/D+0.05≤D/D≤1.0 Formula 1. (a) D: pore diameter in maximum pore volume of the fresh catalyst (nm). (b) D: pore diameter in maximum pore volume of the catalyst for iron accumulation flow contact degradation (nm). (c) D: pore diameter in maximum pore volume of the reactivated catalyst (nm).SELECTED DRAWING: Figure 1

Inventors:
SAKAI SHINGO
HAMADA REI
TEJIMA KATSUHIDE
SAKOTA HISAO
Application Number:
JP2016107239A
Publication Date:
November 24, 2017
Filing Date:
May 30, 2016
Export Citation:
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Assignee:
JGC CATALYSTS & CHEMICALS LTD
International Classes:
B01J38/00; B01J29/08; B01J29/90; B01J35/10; B01J38/02; C10G11/18
Domestic Patent References:
JP2000144151A2000-05-26
JP2009526632A2009-07-23
JPH04503373A1992-06-18
JPS5910347A1984-01-19
Foreign References:
US5393412A1995-02-28
WO2011136217A12011-11-03
US20150224465A12015-08-13
Attorney, Agent or Firm:
Patent corporation ssinpat