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Title:
固体状ポリアルミノキサン組成物、オレフィン重合用触媒、オレフィン重合体の製造方法、および固体状ポリアルミノキサン組成物の製造方法
Document Type and Number:
Japanese Patent JP6290796
Kind Code:
B2
Abstract:
An object of the invention is to provide a solid polyaluminoxane composition suitably used as a cocatalyst and a catalyst carrier in combination with an olefin oligomerization or polymerization catalyst, without the use of solid inorganic carriers such as silica. The solid polyaluminoxane composition of the invention includes a polyalkylaluminoxane and a trialkylaluminum, and has a solubility in n-hexane at 25°C of less than 0.50 mol% as measured by a specific method (i), a solubility in toluene at 25°C of less than 1.0 mol% as measured by a specific method (ii), and a 13 mol% or more molar fraction of alkyl groups derived from the trialkylaluminum moieties relative to the total number of moles of alkyl groups derived from the polyalkylaluminoxane moieties and the alkyl groups derived from the trialkylaluminum moieties as measured with respect to tetrahydrofuran-d 8 soluble components by a specific method (iii).

Inventors:
Tsurugi dating
Shiori Hanada
Atsushi Shibahara
Kawamura Norimori
Nishinobu Fumiaki
Yasuyuki Harada
Yamada
Hanako Matsumoto
Hara
Tatsuya Nakamura
Toshihiro Muroto
Application Number:
JP2014560813A
Publication Date:
March 07, 2018
Filing Date:
February 07, 2014
Export Citation:
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Assignee:
Mitsui Chemicals, Inc.
International Classes:
C07F5/06; C08F4/602; C08F10/00; C08G79/10
Domestic Patent References:
JP2001502714A
JP2005538203A
Attorney, Agent or Firm:
Patent corporation ssinpat