Login| Sign Up| Help| Contact|

Patent Searching and Data


Title:
A sulfide system solid electrolyte for lithium ion batteries
Document Type and Number:
Japanese Patent JP5957144
Kind Code:
B2
Abstract:
Provided is a solid electrolyte with which charge/discharge efficiency and cycle characteristics can be increased by reducing the electron conductivity of a compound which has a cubic crystal structure belonging to a space group F-43m, and is represented by Compositional Formula: Li 7-x PS 6-x Ha x (Ha is Cl or Br). Proposed is a sulfide-based solid electrolyte for a lithium ion battery, which includes a compound having a cubic crystal structure belonging to a space group F-43m, and being represented by Compositional Formula: Li 7-x PS 6-x Ha x (Ha is Cl or Br), in which x in the above Compositional Formula is 0.2 to 1.8, and the value of the lightness L* thereof in the L*a*b* color system is 60.0 or more.

Inventors:
Norihiko Miyashita
Takatsugu Chikumoto
Hideaki Matsushima
Kenji Matsuzaki
Application Number:
JP2015528195A
Publication Date:
July 27, 2016
Filing Date:
June 23, 2014
Export Citation:
Click for automatic bibliography generation   Help
Assignee:
Mitsui Mining & Smelting Co., Ltd.
International Classes:
H01M10/0562; H01M4/133; H01M4/62; H01M10/0525
Domestic Patent References:
JP2011096630A2011-05-12
JP2010540396A2010-12-24
JP2011096630A2011-05-12
JP2010540396A2010-12-24
Other References:
JPN6014019745; R.Prasada Rao et al.: 'Formation and conductivity studies of lithium argyrodite solid electrolytes using in-situ neutron di' Solid State Ionics Vol.230/Issue 10, 20130110, pp.72-76
JPN6014019746; Hans-Jorg Deiseroth et al.: 'Li7PS6 and Li6PS5X (X: Cl, Br, I): Possible Three-dimensional Diffusion Pathways for Lithium Ions an' Journal of Inorganic and General Chemistry Vol.637/Issue 10, 201108, pp.1287-1294
JPN6014019747; Hans-Jorg Deiseroth et al.: 'Li6PS5X: A Class of Crystalline Li-Rich Solids With an Unusually High Li+ Mobility' Angewandte Chemie International Edition Vol.47/Issue 4, 20080111, pp.755-758
JPN6014038122; Sylvain Boulineau et al.: 'Mechanochemical synthesis of Li-argyrodite Li6PS5X (X=Cl, Br, I) as sulfur-based solid electrolytes' Solid State Ionics Vol.221/Issue 3, 20120803, pp.1-5
JPN6014019745; R.Prasada Rao et al.: 'Formation and conductivity studies of lithium argyrodite solid electrolytes using in-situ neutron di' Solid State Ionics Vol.230/Issue 10, 20130110, pp.72-76
JPN6014019746; Hans-Jorg Deiseroth et al.: 'Li7PS6 and Li6PS5X (X: Cl, Br, I): Possible Three-dimensional Diffusion Pathways for Lithium Ions an' Journal of Inorganic and General Chemistry Vol.637/Issue 10, 201108, pp.1287-1294
JPN6014019747; Hans-Jorg Deiseroth et al.: 'Li6PS5X: A Class of Crystalline Li-Rich Solids With an Unusually High Li+ Mobility' Angewandte Chemie International Edition Vol.47/Issue 4, 20080111, pp.755-758
JPN6014038122; Sylvain Boulineau et al.: 'Mechanochemical synthesis of Li-argyrodite Li6PS5X (X=Cl, Br, I) as sulfur-based solid electrolytes' Solid State Ionics Vol.221/Issue 3, 20120803, pp.1-5
Attorney, Agent or Firm:
Takeuchi/Ichizawa International Patent Office