Title:
5-HYDROXYMETHYL-2-FURFURAL PRODUCTION METHOD
Document Type and Number:
WIPO Patent Application WO/2018/003295
Kind Code:
A1
Abstract:
The present invention addresses the problem of providing: a 5-hydroxymethyl-2-furfural (5-HMF) production method which is suitable for the production of 5-hydroxymethyl-2-furfural (5-HMF) on an industrial scale; and a novel catalyst composition for use in the synthesis of 5-HMF. According to the present invention, the followings are provided: a 5-HMF production method comprising carrying out a dehydration reaction of a carbohydrate that contains hexose as a constituent sugar or a derivative of the carbohydrate using activated carbon as a catalyst; and a catalyst composition for use in a reaction for producing 5-HMF from a carbohydrate that contains hexose as a constituent sugar through a dehydration reaction, wherein the catalyst composition contains activated carbon.
Inventors:
NISHIMURA YUICHI (JP)
HAMAGUCHI NORIHISA (JP)
TAKAGUCHI HITOSHI (JP)
HAMAGUCHI NORIHISA (JP)
TAKAGUCHI HITOSHI (JP)
Application Number:
PCT/JP2017/017552
Publication Date:
January 04, 2018
Filing Date:
May 09, 2017
Export Citation:
Assignee:
JAPAN MAIZE PROD (JP)
International Classes:
C07D307/46; A23L33/10; A61K31/341; A61P7/06; B01J21/18; B01J27/16; C08G63/58
Domestic Patent References:
| WO2014180979A1 | 2014-11-13 | |||
| WO2010077133A1 | 2010-07-08 |
Foreign References:
| US20140371473A1 | 2014-12-18 | |||
| JPH10265468A | 1998-10-06 | |||
| JP2008207995A | 2008-09-11 | |||
| JP2011176043A | 2011-09-08 | |||
| JP2010168238A | 2010-08-05 | |||
| JP2008088134A | 2008-04-17 | |||
| JP2009001519A | 2009-01-08 | |||
| JP2015506389A | 2015-03-02 | |||
| JP2008193933A | 2008-08-28 | |||
| JP2011136959A | 2011-07-14 |
Other References:
KILIC, EMRE ET AL.: "Fructose Dehydration to 5- Hydroxymethylfurfural over Sulfated TiO2-SiO2, Ti-SBA-15, ZrO2, SiO2, and Activated Carbon Catalysts", INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, vol. 54, no. 19, 7 May 2015 (2015-05-07), pages 5220 - 5225, XP055450723
WANG, JIANJIAN ET AL.: "Efficient catalytic conversion of fructose into hydroxymethylfurfural by a novel carbon-based solid acid", GREEN CHEMISTRY, vol. 13, no. 10, 2011, pages 2678 - 2681, XP055164374, ISSN: 1463-9262
YANG, LI ET AL.: "Dehydration of fructose into 5-hydroxymethylfurfural catalyzed by phosphorylated activated carbon catalyst", ASIAN JOURNAL OF CHEMISTRY, vol. 27, no. 8, 2015, pages 2979 - 2982
QI, XINHUA ET AL.: "Acid-Catalyzed Dehydration of Fructose into 5-Hydroxymethylfurfural by Cellulose-Derived Amorphous Carbon", CHEMSUSCHEM, vol. 5, no. 11, 2012, pages 2215 - 2220, XP055587098
LIU, RULIANG ET AL.: "Conversion of fructose into 5-hydroxymethylfurfural and alkyl levulinates catalyzed by sulfonic acid- functionalized carbon materials", GREEN CHEMISTRY, vol. 15, no. 10, 2013, pages 2895 - 903, XP055450744, ISSN: 1463-9262
RUSSO, P. A. ET AL.: "Solid acids with S03H groups and tunable surface properties: versatile catalysts for biomass conversion", JOURNAL OF MATERIALS CHEMISTRY A, vol. 2, no. 30, 2014, pages 11813 - 11824, XP055361004, ISSN: 2050-7496
FABICOVICOVA, KATARINA ET AL.: "Hydrogenolysis of cellulose to valuable chemicals over activated carbon supported mono- and bimetallic nickel/tungsten catalysts", GREEN CHEMISTRY, vol. 16, no. 7, 2014, pages 3580 - 3588, XP055358940
ANONYMOUS: "Page 664 paragraph e., Page 722 paragraph d.", KAGAKU BENRAN OYO KAGAKU-HEN, 2003, pages 664,772, XP009517447, ISBN: 4-621-07138-6
SAIRANEN, EMMA ET AL.: "Functionalized Activated Carbon Catalysts in Xylose Dehydration", TOPICS IN CATALYSIS, vol. 56, no. 9-10, 2013, pages 512 - 521, XP055450748
WANG, JIANJIAN ET AL.: "Efficient catalytic conversion of fructose into hydroxymethylfurfural by a novel carbon-based solid acid", GREEN CHEMISTRY, vol. 13, no. 10, 2011, pages 2678 - 2681, XP055164374, ISSN: 1463-9262
YANG, LI ET AL.: "Dehydration of fructose into 5-hydroxymethylfurfural catalyzed by phosphorylated activated carbon catalyst", ASIAN JOURNAL OF CHEMISTRY, vol. 27, no. 8, 2015, pages 2979 - 2982
QI, XINHUA ET AL.: "Acid-Catalyzed Dehydration of Fructose into 5-Hydroxymethylfurfural by Cellulose-Derived Amorphous Carbon", CHEMSUSCHEM, vol. 5, no. 11, 2012, pages 2215 - 2220, XP055587098
LIU, RULIANG ET AL.: "Conversion of fructose into 5-hydroxymethylfurfural and alkyl levulinates catalyzed by sulfonic acid- functionalized carbon materials", GREEN CHEMISTRY, vol. 15, no. 10, 2013, pages 2895 - 903, XP055450744, ISSN: 1463-9262
RUSSO, P. A. ET AL.: "Solid acids with S03H groups and tunable surface properties: versatile catalysts for biomass conversion", JOURNAL OF MATERIALS CHEMISTRY A, vol. 2, no. 30, 2014, pages 11813 - 11824, XP055361004, ISSN: 2050-7496
FABICOVICOVA, KATARINA ET AL.: "Hydrogenolysis of cellulose to valuable chemicals over activated carbon supported mono- and bimetallic nickel/tungsten catalysts", GREEN CHEMISTRY, vol. 16, no. 7, 2014, pages 3580 - 3588, XP055358940
ANONYMOUS: "Page 664 paragraph e., Page 722 paragraph d.", KAGAKU BENRAN OYO KAGAKU-HEN, 2003, pages 664,772, XP009517447, ISBN: 4-621-07138-6
SAIRANEN, EMMA ET AL.: "Functionalized Activated Carbon Catalysts in Xylose Dehydration", TOPICS IN CATALYSIS, vol. 56, no. 9-10, 2013, pages 512 - 521, XP055450748
Attorney, Agent or Firm:
YOKOTA Nobutaka et al. (JP)
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