Title:
AEROBIC OXIDATION SYSTEM CONTAINING SULFINIC ACID, SULFONIC ACID OR DERIVATIVES THEREOF AND PHOTOCATALYTIC OXIDATION METHOD THEREFOR
Document Type and Number:
WIPO Patent Application WO/2020/155595
Kind Code:
A1
Abstract:
Disclosed are an aerobic oxidation system and a photocatalytic aerobic oxidation method therefor. The aerobic oxidation system comprises: 1) at least one of the following substances 1a) -1d): 1a) sulfinic acid or a derivative thereof; 1b) sulfonic acid or a derivative thereof; 1c) a compound or mixture that can produce sulfinic acid or a derivative thereof by means of a reaction; 1d) a compound or mixture that can produce sulfonic acid or a derivative thereof by means of a reaction; and 2) a component containing molecular oxygen, including oxygen, an oxygen-containing gas and at least one raw material for a reaction system that can generate oxygen molecules in situ. When the aerobic oxidation system is used for an oxidation method, a series of compounds can be aerobically oxidized at room temperature to obtain corresponding oxidation products without adding a photosensitizing reagent under illuminated conditions, thereby reducing production costs; in addition, the method can greatly reduce the energy consumption, and completely solves the problem of environmental pollution caused by waste discharge of heavy metals and acidic solvents, and the problem of metal residues in products.
Inventors:
FU HUA (CN)
ZHU XIANJIN (CN)
ZHU XIANJIN (CN)
Application Number:
PCT/CN2019/098940
Publication Date:
August 06, 2020
Filing Date:
August 01, 2019
Export Citation:
Assignee:
UNIV TSINGHUA (CN)
International Classes:
C07B33/00; C07C37/07; C07C39/14; C07C41/56; C07C43/307; C07C45/32; C07C47/54; C07C49/78; C07D215/227; C07F9/53
Foreign References:
| CN108993590A | 2018-12-14 | |||
| CN108993591A | 2018-12-14 | |||
| JPS5692232A | 1981-07-25 |
Other References:
ZHIGUANG ZHANG,YUAN GAO, YUAN LIU, JIANJUN LI, HEXIN XIE, HAO LI, WEI WANG: "Organocatalytic Aerobic Oxidation of Benzylic sp3 C-H Bonds of Ethers and Alkylarenes Promoted by a Recyclable TEMPO Catalyst.", ORGANIC LETTERS, vol. 17, 29 October 2015 (2015-10-29), XP055724055, ISSN: 1523-7060, DOI: 10.1021/acs.orglett.5b02877
HONG YI , CHANGLIANG BIAN , XIA HU , LINBIN NIU ,AIWEN LEI: "Visible Light Mediated Efficient Oxidative Benzylic sp3 C-H to Ketone Derivatives Obtained under Mild Conditions Using O2.", CHEMICAL COMMUNICATIONS, vol. 51, no. 74, 24 July 2015 (2015-07-24), pages 14046 - 14049, XP055724058, ISSN: 1359-7345, DOI: 10.1039/C5CC06015J
HONG YI , CHANGLIANG BIAN , XIA HU , LINBIN NIU ,AIWEN LEI: "Visible Light Mediated Efficient Oxidative Benzylic sp3 C-H to Ketone Derivatives Obtained under Mild Conditions Using O2.", CHEMICAL COMMUNICATIONS, vol. 51, no. 74, 24 July 2015 (2015-07-24), pages 14046 - 14049, XP055724058, ISSN: 1359-7345, DOI: 10.1039/C5CC06015J
Attorney, Agent or Firm:
BEIJING ORIGINTELLIGENCE IP LAW FIRM (CN)
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