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Title:
ALKYNE SELECTIVE HYDROGENATION CATALYST FOR C2 FRACTION AND PREPARATION METHOD
Document Type and Number:
WIPO Patent Application WO/2024/016577
Kind Code:
A1
Abstract:
An alkyne selective hydrogenation catalyst for C2 fraction and a preparation method. A carrier for the catalyst is alumina or mainly alumina, and has a bimodal pore distribution structure. Active components of the catalyst at least comprise Pd, Ni, Cu, Ce and Pt, wherein Ni and Cu are mainly loaded in macropores by using a micro-emulsion method; Pd is mainly loaded in micropores of the catalyst by using a solution method; and Pt and Ce are loaded on Pd by using a solution method. After loading and roasting, on the basis of 100% of the weight of the carrier, the active components of the catalyst comprise 0.065-0.08% of Pd, 1-5% of Ni, 2-5% of Cu, 0.1-0.5% of Ce and 0.001-0.01% of Pt. The catalyst provided in the present invention has a low palladium loading capacity, simple preparation, good anti-coking performance and good regeneration performance, and can keep good hydrogenation activity and good selectivity for a long time.

Inventors:
TAN DUPING (CN)
ZHANG FENG (CN)
WEN HE (CN)
XIANG YONGSHENG (CN)
XIE YUAN (CN)
CHE CHUNXIA (CN)
HAN WEI (CN)
LI PINGZHI (CN)
BAI JIEJUN (CN)
BIAN HU (CN)
Application Number:
PCT/CN2022/139268
Publication Date:
January 25, 2024
Filing Date:
December 15, 2022
Export Citation:
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Assignee:
PETROCHINA CO LTD (CN)
International Classes:
B01J23/89; B01J23/10; C07C11/04
Domestic Patent References:
WO2021073640A12021-04-22
Foreign References:
CN112675871A2021-04-20
CN109772291A2019-05-21
Attorney, Agent or Firm:
BEIJING SANYOU INTELLECTUAL PROPERTY AGENCY LTD. (CN)
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