Title:
AMIDATE COMPOUND, CATALYST FOR POLYURETHANE PRODUCTION, AND METHOD FOR PRODUCING POLYURETHANE RESIN
Document Type and Number:
WIPO Patent Application WO/2018/025970
Kind Code:
A1
Abstract:
An amidate compound which is represented by formula (1).
(In formula (1), A represents a substituted or unsubstituted hydrocarbon group; n represents an integer of 1 or more; and D represents a nitrogen-containing organic group represented by formula (2).)
(In formula (2), R1, R2 and R3 may be the same or different, and each represents a hydrocarbon group which may contain a heteroatom, or alternatively, some or all of the R1, R2 and R3 moieties may combine with each other and form a ring structure; X represents a nitrogen atom, an oxygen atom or a sulfur atom; and a represents 0 or 1. Specifically, a represents 1 in cases where X represents a nitrogen atom, and a represents 0 in cases where X represents an oxygen atom or a sulfur atom.)
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Inventors:
MIYAGI MOTOYOSHI (JP)
NITTA SHINGO (JP)
TSUBOI HITOMI (JP)
TAKAHASHI SHOGO (JP)
NITTA SHINGO (JP)
TSUBOI HITOMI (JP)
TAKAHASHI SHOGO (JP)
Application Number:
PCT/JP2017/028314
Publication Date:
February 08, 2018
Filing Date:
August 03, 2017
Export Citation:
Assignee:
KOEI CHEMICAL CO (JP)
International Classes:
C07D233/90; C08G18/18
Foreign References:
| US20110046301A1 | 2011-02-24 | |||
| JPH0545763A | 1993-02-26 |
Other References:
STURALA, JIRI ET AL.: "Electron-Deficient Heteroarenium Salts: An Organocatalytic Tool for Activation of Hydrogen Peroxide in Oxidations", JOURNAL OF ORGANIC CHEMISTRY, vol. 80, no. 5, 2015, pages 2676 - 2699, XP055459771, ISSN: 0022-3263
SCHMIDT, ANDREAS ET AL.: "Imidazol-2-and-4- ylidene by decarboxylation. Studies on the cross-conjugated mesomeric betaine-alkaloid norzooanemonine and its pseudo-cross-conjugated isomer", ORGANIC & BIOMOLECULAR CHEMISTRY, vol. 6, no. 2, 2008, pages 287 - 295, XP055459772, ISSN: 1477-0520
COUTELIER, OLIVIER ET AL.: "N-HETEROCYCLIC CARBENE-CATALYZED SYNTHESIS OF POLYURETHANES", POLYMER PREPRINTS, vol. 52, no. 2, 2011, pages 290 - 291, XP055459773
BANTU, BHASKER ET AL.: "CO2, Magnesium, Aluminum, and Zinc Adducts of N-Heterocyclic Carbenes as (Latent) Catalysts for Polyurethane Synthesis", EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, vol. 13, 2009, pages 1970 - 1976, XP055459774, ISSN: 1434-1948
BANTU, BHASKER ET AL.: "CO2 and SnII adducts of N-Heterocyclic Carbenes as Delayed-Action Catalysts for Polyurethane Synthesis", CHEMISTRY - A EUROPEAN JOURNAL, vol. 15, no. 13, 16 March 2009 (2009-03-16), pages 3103 - 3109, XP055459777, ISSN: 0947-6539
WINKLER, ANDREA ET AL.: "Preparation and reactivity of an isolable N-heterocyclic carbene-borane", JOURNAL OF ORGANOMETALLIC CHEMISTRY, vol. 775, 2015, pages 164 - 168, XP055459782, ISSN: 0022-328X
LI, CHIA-YI ET AL.: "Amine-Linked N-Heterocyclic Carbenes: The Importance of an Pendant Free-Amine Auxiliary in Assisting the Catalytic Reaction", CHEMISTRY - AN ASIAN JOURNAL, vol. 6, no. 6, 2011, pages 1520 - 1524, XP055459787, ISSN: 1861-4728
WANG, XIAOJIE ET AL.: "High-Spin Iron(II) Alkynyl Complexes with N-Heterocyclic Carbene Ligation: Synthesis, Characterization, and Reactivity Study", ORGANOMETALLICS, vol. 34, no. 12, 2015, pages 2775 - 2782, XP055459791, ISSN: 0276-7333
See also references of EP 3495353A4
SCHMIDT, ANDREAS ET AL.: "Imidazol-2-and-4- ylidene by decarboxylation. Studies on the cross-conjugated mesomeric betaine-alkaloid norzooanemonine and its pseudo-cross-conjugated isomer", ORGANIC & BIOMOLECULAR CHEMISTRY, vol. 6, no. 2, 2008, pages 287 - 295, XP055459772, ISSN: 1477-0520
COUTELIER, OLIVIER ET AL.: "N-HETEROCYCLIC CARBENE-CATALYZED SYNTHESIS OF POLYURETHANES", POLYMER PREPRINTS, vol. 52, no. 2, 2011, pages 290 - 291, XP055459773
BANTU, BHASKER ET AL.: "CO2, Magnesium, Aluminum, and Zinc Adducts of N-Heterocyclic Carbenes as (Latent) Catalysts for Polyurethane Synthesis", EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, vol. 13, 2009, pages 1970 - 1976, XP055459774, ISSN: 1434-1948
BANTU, BHASKER ET AL.: "CO2 and SnII adducts of N-Heterocyclic Carbenes as Delayed-Action Catalysts for Polyurethane Synthesis", CHEMISTRY - A EUROPEAN JOURNAL, vol. 15, no. 13, 16 March 2009 (2009-03-16), pages 3103 - 3109, XP055459777, ISSN: 0947-6539
WINKLER, ANDREA ET AL.: "Preparation and reactivity of an isolable N-heterocyclic carbene-borane", JOURNAL OF ORGANOMETALLIC CHEMISTRY, vol. 775, 2015, pages 164 - 168, XP055459782, ISSN: 0022-328X
LI, CHIA-YI ET AL.: "Amine-Linked N-Heterocyclic Carbenes: The Importance of an Pendant Free-Amine Auxiliary in Assisting the Catalytic Reaction", CHEMISTRY - AN ASIAN JOURNAL, vol. 6, no. 6, 2011, pages 1520 - 1524, XP055459787, ISSN: 1861-4728
WANG, XIAOJIE ET AL.: "High-Spin Iron(II) Alkynyl Complexes with N-Heterocyclic Carbene Ligation: Synthesis, Characterization, and Reactivity Study", ORGANOMETALLICS, vol. 34, no. 12, 2015, pages 2775 - 2782, XP055459791, ISSN: 0276-7333
See also references of EP 3495353A4
Attorney, Agent or Firm:
SAEGUSA & PARTNERS (JP)
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