Title:
AMORPHOUS HYDROUS TITANIUM OXIDE AND SOLID LEWIS ACID CATALYST CONTAINING SAME
Document Type and Number:
WIPO Patent Application WO/2012/108472
Kind Code:
A1
Abstract:
Disclosed are: a novel substance which functions as a solid Lewis acid catalyst in the presence of water; a process for producing the same; use thereof as a solid Lewis acid catalyst; and a method for conducting a chemical reaction in an aqueous solution using the solid Lewis acid catalyst. Amorphous hydrous titanium oxide, which functions as a Lewis acid, can be obtained by subjecting an organotitanium compound which can be hydrolyzed in an aqueous solution to form an oxide to reaction with both water and an acid or base catalyst. This Lewis acid catalyst exhibits excellent effect in various reactions including a reaction of forming hydroxymethylfurfural from glucose.
Inventors:
NAKAJIMA KIYOTAKA (JP)
HARA MICHIKAZU (JP)
HARA MICHIKAZU (JP)
Application Number:
PCT/JP2012/052875
Publication Date:
August 16, 2012
Filing Date:
February 08, 2012
Export Citation:
Assignee:
KANAGAWA KAGAKU GIJUTSU AKAD (JP)
TOKYO INST TECH (JP)
NAKAJIMA KIYOTAKA (JP)
HARA MICHIKAZU (JP)
TOKYO INST TECH (JP)
NAKAJIMA KIYOTAKA (JP)
HARA MICHIKAZU (JP)
International Classes:
B01J21/06; B01J27/18; C07C29/40; C07C33/30; C07D307/50; C07B61/00
Foreign References:
| JP2001354422A | 2001-12-25 | |||
| JPH1081517A | 1998-03-31 |
Other References:
SHANGWEI HU ET AL.: "An investigation on the catalytic properties of titania-silica materials", JOURNAL OF CATALYSIS, vol. 220, no. ISSUE, 2003, pages 240 - 248
RYOHEI NOMA ET AL.: "Kotai Lewis-san ni yoru Suiyoekichu deno Allyl-ka Hanno", SHOKUBAI TORONKAI TORONKAI A YOKOSHU, vol. 108TH, 13 September 2011 (2011-09-13), pages 333
RYOHEI NOMA ET AL.: "Suichu deno Gansui Titanium Sankabutsu no Lewis-san Shokubaino", SHOKUBAI TORONKAI TORONKAI A YOKOSHU, vol. 107TH, 18 March 2011 (2011-03-18), pages 141
RYOHEI NOMA ET AL.: "Kotai Lewis-san ni yoru Suiyoekichu deno Allyl-ka Hanno", SHOKUBAI TORONKAI TORONKAI A YOKOSHU, vol. 108TH, 13 September 2011 (2011-09-13), pages 333
RYOHEI NOMA ET AL.: "Suichu deno Gansui Titanium Sankabutsu no Lewis-san Shokubaino", SHOKUBAI TORONKAI TORONKAI A YOKOSHU, vol. 107TH, 18 March 2011 (2011-03-18), pages 141
Attorney, Agent or Firm:
TANIGAWA, Hidejiro (JP)
Mountain stream Eijiro (JP)
Mountain stream Eijiro (JP)
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