Backround: Generally, Cs aliphatic hydrocarbon resins are synthesized using a piperylene concentrate stream that has been fractionated to minimize levels of isoprene and cyclic diolefins such as cyclopentadiene and/or methylcyclopentadienes, as well as dimers and codimers of these compounds. The presence of these components in significant quantities (i.e. greater than 3 to about 5 percent) in polymerization feed blends is known to adversely affect the molecular weight and properties of the resin produced via cationic polymerization. For example, U.S. 2,750,353 discloses that high isoprene content (greater than 3.5 weight %) in the feedstock leads to inferior yields and gel formation. Likewise, U.S. 2,754,288 teaches that gel formation and poor molecular weight control result from the use of feeds that initially contain greater than 2 weight % cyclopentadiene. Isoprene and / or dicyclopentadienes have traditionally been considered undesirable at high concentrations in hydrocarbon resin feed blends targeted for catalytic polymerization due to their tendency to crosslink and form gels or resins of undesirably high molecular weight.

U.K. Patent Specification GB 1,408,870 (ICI), describes the heat soaking of a crude Cs stream followed by direct polymerization without fractionation. The

patent uses an aluminum chloride complex and does not mention the incorporation of aromatic olefins.

U.K. Patent Specification 2,044,277A (Sumitomo), describes the copolymerization of cyclopentadiene with a copolymerizable monomer (chain conjugated diolefin or olefin) using an aluminum chloride/oxygen rich containing electron donor/aromatic solvent complex claiming no gel formation. Sumitomo teaches that aluminum chloride powder is not suitable for these type polymerizations and discloses the polymerization of feed blends containing cyclopentadiene:isoprene ratios of from 3:1 to 1:3. Further Sumitomo does not mention the incorporation of aromatic olefins.

U.S. patent 5,516,835, which discloses a tackifier comprising an isoprene based hydrocarbon resin obtained by the cationic polymerization (aluminum chloride) of a feed blend consisting of from 40-90 wt % isoprene and from 10-60 wt % of an aliphatic monoolefin (e.g., 2-methyl-2-butene). U.S. 5,516,835 also discloses hot melt and pressure sensitive adhesive systems based on amorphous polypropylene, natural rubber and styrenated block copolymers. Further, the optional use of piperylenes, DCPD and aromatic olefins is disclosed.

U.S. Patent 4,008,360 discloses resin produced from a Cs fraction that has been subjected to an adjustment of a weight ratio of acyclic diolefins to monoolefins and a weight ratio of cyclic diolefins to monoolefins of from 0.40 to 0.70 and from 0.07 to 0.35, respectively. The inclusion of aromatic olefins is not disclosed.

Likewise, U.S. 4,952,639 discloses resins produced from a Cs fraction having aromatic mono-olefin and certain ratios of diolefins and mono-olefins, however, dicyclopentadiene is absent.

Two other U.S. patents of interest are patent U.S. 3,950,453 (Nippon Zeon) and U.S. Patent 3,467,632 (Reichold). Both of these patents disclose the cationic

polymerization of feed blends containing up to 30 wt % isoprene, including the use of isoprene dimers (terpenes) as softening point boosters.

Hence, feedstocks with low levels of isoprene and dicyclopentadienes have been preferred in the industry. However, obtaining these feedstocks has required expensive purification procedures. Therefore, there is a need in the art to provide a method to polymerize the mix of isoprene cyclopentadiene/dicyclopentadienes, piperylene feedstocks into hydrocarbon resins without the undesirable gels or very high molecular weights.

Brief DescriPtion of the Invention: This invention relates to a process for producing a resin comprising combining a reactor feed blend comprising: (a) at least 2 weight % of isoprene, (b) at least 2 weight % of one or more of dicyclopentadiene, substituted cyclopentadienes and substituted dicyclopentadienes, (c) at least 2 weight % piperylene, (d) at least 1 weight % aromatic olefins, and (e) 0 to 92 weight % of additional aliphatic olefins, based upon the weight of the reactor feed blend, with a polymerization catalyst under polymerization conditions This invention further relates to adhesive compositions comprising the resins described above.

Detailed Description: In a preferred embodiment, this invention relates to a process for producing a resin comprising combining a reactor feed blend comprising: (a) 2 to 50 weight % isoprene, (b) 2 to 20 weight % of one or more of dicyclopentadiene, substituted cyclopentadienes and substituted dicyclopentadienes,

(c) 2 to 20 weight % piperylene, (d) 1 to 50 weight % aromatic olefins, and (e) 2 to 90 weight % of additional aliphatic olefins, based upon the weight of the reactor feed blend, with a polymerization catalyst under polymerization conditions, provided that the ratio of component (c) to component (b) is less than 8 and the ratio of component (a) to component (b) is less than 5, preferably the ratio of component (c) to component (b) is less than 5 and the ratio of component (a) to component (b) is less than 2.

The isoprene is preferably present at 2 to 30 weight percent, even more preferably at 2 to 20 weight percent.

Preferred substituted cyclopentadienes include cyclopentadienes substituted with a with a C1 to C40 linear, branched or cyclic alkyl group, preferably one or more methyl groups. Methylcyclopentadiene is a preferred substituted cyclopentadiene.

The term dicyclopentadiene is defined to include both the endo and exo forms of dicyclopentadiene. Preferred substituted dicyclopentadienes include dicyclopentadienes substituted with a C1 to C40 linear, branched or cyclic alkyl group, preferably one or more methyl groups.

Preferred aromatic olefins include one or more of styrene, indene, derivatives of styrene and derivatives of indene. Particularly preferred aromatic olefins include styrene, alpha-methylstyrene, beta-methylstyrene, indene and methylindenes and vinyl toluenes. The aromatic olefins are typically present at 1 to 92 weight %, preferably 1 to 50 weight %, even more preferably 1 to 30 weight %, even more preferably 1 to 10 weight %.

In a preferred embodiment, the feed comprises 5 to 90 weight % of one or more- aliphatic olefins, preferably between 10 and 85 weight percent, even more

preferably between 50 and 70 weight %. In a preferred embodiment the aliphatic olefins are C4 to C20 linear, branched or alicyclic olefins or non-conjugated diolefins, preferably one or more of C4 to C7 linear, branched or alicyclic olefins or non-conjugated diolefins, even more preferably a mixture of C5 and C6 linear, branched or alicyclic olefins or non-conjugated diolefins. In another preferred embodiment the aliphatic olefins comprise one or more natural or synthetic terpenes, preferably one or more of alpha-pinene, beta-pinene, A-3-carene, dipentene, limonenes and/or isoprene dimers. The aliphatic olefins are preferably present at a ratio of weight % conjugated diolefin to weight % aliphatic olefin of 0.05 to 3.0, preferably 0.05 to 2.0.

Preferred resins produced herein have a ring and ball softening point of 10 to 140"C, preferably 80 to 120 OC In another embodiment, preferred resins produced herein have a weight-average molecular weight (Mw) of 4000 or less, preferably between 500 and 4000, more preferably 500-2500. In another preferred embodiment, the resins produced herein have an Mw/Mn of 3 or less, preferably between 1 and 2.5, even more preferably between 1 and 2.

The resins described above may be produced by methods generally known in the art for the production of hydrocarbon resins. See for example, the Kirk-Othmer Encyclopedia of Chemical Technology, 4th ed., Vol. 13, pp.717-744. A preferred method for production of the resins described above is combining the feed stream in a polymerization reactor with a Friedel-Crafts or Lewis Acid catalyst at a temperature between 0 "C and 200 "C, preferably between 0 "C and 120 "C, even more preferably between 20 "C and 80 "C. Friedel-Crafts polymerization is generally accomplished by use of known catalysts in a polymerization solvent and removal of solvent and catalyst by washing and distillation. The polymerization process utilized for this invention may be in a batchwise or continuous mode using techniques known in the art. Continuous polymerization may be accomplished in a single stage or in multiple stages as is taught in U.S. patents 3,701,760 and 4,276,396. The Friedel-Crafts catalysts to be used as a

polymerization catalysts are generally Lewis Acids such as metallic halides or alkyls such as aluminum trichloride, boron trifloride, aluminum tribromide or a mixture thereof, as well as ternary complexes of the halides, aromatic compounds and hydrogen halides. Possible aromatic compounds include benzene and mono-, di- and poly-alkylbenzenes such toluene, xylene, cymene, and cumene. Examples of hydrogen halides to be used in the complexing include hydrogen chloride, hydrogen bromide, hydrochloric acid, and hydrobromic acid. The amount of Lewis Acid to be used in the catalyst is in the range of from 0.3 to 3.0 weight %, based upon the weight of the feed blend, preferably 0.3 to 3.0 weight %, even more preferably 0.5 to 1.0 weight %. The aluminum trichloride catalyst is preferably used as a powder.

For additional description of feedstream derivation, monomer composition, methods of polymerization and hydrogenation, see Hydrocarbon Resins, Kirk- Othmer Encyclopedia of Chemical Technology, v. 13, pp. 717-743 (J. Wiley & Sons, 1995); Encyclopedia of Polymer Science and Engineering, vol. 7, pp. 758- 782 (John Wiley & Sons, 1987), EP 0 240 253 and the references cited in all three of them.

In another preferred embodiment, the resins of this invention may be hydrogenated. The hydrogenation of hydrocarbon resins may be carried out via molten or solution based processes by either a batchwise or, more commonly, a continuous process. Catalysts employed for the hydrogenation of hydrocarbon resins are typically supported monometallic and bimetallic catalyst systems based on group 6, 8, 9, 10 or 11 elements. Catalysts such as Nickel on a support (for example, Nickel on alumina, Nickel on charcoal, Nickel on silica, Nickel on Kieselguhr, etc), Palladium on a support (for example, Palladium on silica, Palladium on charcoal, Palladium on magnesium oxide, etc) and copper and or zinc on a support (for example copper chromite on copper and or manganese oxide, copper and zinc on alumina, etc) are good hydrogenation catalysts in the practice of this invention. The support material is typically comprised of such

porous inorganic refractory oxides as silica, magnesia, silica-magnesia, zirconia, silica-zirconia, titania, silica-titania, alumina, silica-alumina, alumino-silicate, etc., with supports containing y-alumina being highly preferred. Preferably, the supports are essentially free of crystalline molecular sieve materials. Mixtures of the foregoing oxides are also contemplated, especially when prepared as homogeneously as possible. Among the useful supports materials in the present invention are the supports disclosed in the U.S. Pat. Nos. 4,686,030, 4,846,961, 4,500,424, and 4,849,093. Preferred supports include alumina, silica, carbon, MgO, TiO2, ZrO2, FeO3 or mixtures thereof.

Any of the known processes for catalytically hydrogenating hydrocarbon resins can be used to hydrogenate the resins of this invention; in particular the processes of U.S. 5,171,793, U.S. 4,629,766, U.S. 5,502,104 and U.S. 4,328,090 and WO 95/12623 are suitable. Generic hydrogenation treating conditions include reactions in the temperature of about 100 "C - 350 "C and pressures of between five atmospheres (506 kPa) and 300 atm. (30390 kPa) hydrogen, for example, 10 to 275 atm. (1013 kPa to 27579 kPa). In one embodiment the temperature is in the range including 180 "C and 320 "C and the pressure is in the range including 15195 kPa and 20260 kPa hydrogen. The hydrogen to feed volume ratio to the reactor under standard conditions (25 "C, 1 atm (101 kPa) pressure) typically can range from 20-200, for water-white resins 100-200 is preferred.

Another suitable processes for hydrogenating the resin of this invention is that described in EP 0 082 726. EP 0 082 726 describes a process for the catalytic or thermal hydrogenation of petroleum resins using nickel-tungsten catalyst on a gamma-alumina support wherein the hydrogen pressure is 1.47x107-1.96x107 Pa and the temperature is in the range of 250-330 °C. Thermal hydrogenation is usually done at 160 to 320"C, at a pressure of 9.8x105 to 11.7x105 Pa and for a period typically of 1.5 to 4 hours. After hydrogenation the reactor mixture may be flashed and further separated to recover the hydrogenated resin. Steam distillation

may be used to eliminate oligomers, preferably without exceeding 325 "C resin temperature.

In a preferred embodiment, the hydrogenation is carried out by contacting the resin in the presence of hydrogen and hydrogenation catalyst metal compounds supported on porous refractory substrate particles having: a) mean maximum diffusion path length less than or equal to twice the hydraulic radius; b) a pore volume distribution wherein: i) pores having diameters >150,000 A constitute greater than about 2% of the total volume, ii) pores having diameters >20,000 A and <150,000 A constitute greater than about 1% of the total volume, and iii) pores having diameters >2,000 A and <20,000 A constitute greater than about 12% of the total volume; and, c) a total pore volume of from about 45% to 86% of the total volume of the substrate particles. In a particularly preferred embodiment, the catalyst comprises nickel and/or cobalt on one or more of molybdenum, tungsten, alumina or silica supports. In a preferred embodiment, the amount of the nickel oxide and/or cobalt oxide on the support ranges from 2 to 10 weight percent. The amount of tungsten or molybdenum oxide on the support after preparation ranges from 5 to 25 weight percent. Preferably, the catalyst contains 4 to 7 weight percent nickel oxide and 18 to 22 weight percent tungsten oxide. This process and suitable catalysts are described in greater detail in copending application USSN 08/755,267 filed November 22, 1996, which is incorporated by reference herein.

In another preferred embodiment, the hydrogenation may be carried out by the process and catalysts described in U.S. patent 4,629,766. In particular, Nickel- Tungsten catalysts on gamma -alumina are preferred.

The resins of this invention may be combined with a base polymer to form an adhesive. Typical base polymers include homopolyethylene, ethylene copolymerized with up to 50 weight % of one or more C3 to C20 a-olefins, polypropylene, propylene copolymerized with up to 50 weight % of one or more

of ethylene and/ or C4 to C20 a-olefins, polybutene, ethylene vinyl acetate, low density polyethylene (density 0.915 to less than 0.935 g/cm3) linear low density polyethylene, ultra low density polyethylene (density 0.86 to less than 0.90 g/cm3), very low density polyethylene (density 0.90 to less than 0.915 g/cm3), medium density polyethylene (density 0.935 to less than 0.945 g/cm3), high density polyethylene (density 0.945 to 0.98 g/cm3 ), EMA, copolymers of acrylic acid, polymethylmethacrylate or any other polymers polymerizable by a high pressure free radical process, PVC, polybutene-l, isotactic polybutene, elastomers such as ethylene-propylene rubber (EPR), vulcanized EPR, EPDM, block copolymer elastomers such as SBS (Styrene-Butadiene-Styrene), SIS (Styrene- Isoprene-Styrene), nylons, polycarbonates, PET resins, crosslinked polyethylene, copolymers of ethylene and vinyl alcohol (EVOH), polymers of aromatic monomers such as polystyrene, copolymers of isobutylene and para-alkyl styrene, poly-l esters, high molecular weight HDPE, low molecular weight HDPE, graft copolymers generally, polyacrylonitrile homopolymer or copolymers, thermoplastic polyamides, polyacetal, polyvinylidine fluoride and other fluorinated elastomers, polyethylene glycols, polyisobutylene (PIB) or blends thereof.

In a preferred embodiment, the base polymer is selected from the group consisting of: block copolymers of styrene and isoprene or butadiene, polyisoprene, butyl rubber, ethylene vinyl acetate, ethylene methyl acrylate, amorphous polypropylene, ethylene propylene diene monomer rubber, copolymers of ethylene and a C3 to C20 a-olefin, copolymers of propylene and ethylene or a C4 to C20 a-olefin, metallocene polyethylenes, metallocene polypropylenes, natural rubber, styrene butadiene rubber, copolymers of isobutylene and para-alkylstyrene. Particularly, preferred polymers are styrene-butadiene-styrene block copolymers, butyl rubber, natural rubber and styrene-butadiene rubber.

In a particularly preferred embodiment, the base polymer is a SIS (Styrene- Isoprene-Styrene) block copolymer. In another particularly preferred embodiment

the SIS block copolymer has 10 weight % or less diblock present, preferably 5 weight % or less. A preferred base polymer is styrene-isoprene-styrene block copolymer as commercially available from DEXCO POLYMERS under the trade name VECTOR@.

In another preferred embodiment, the base polymer is a polymer produced using a metallocene catalyst system. Typically, the metallocene homopolymers or copolymers are produced using mono- or bis-cyclopentadienyl transition metal catalysts in combination with an activator of alumoxane and/or a non-coordinating anion in solution, slurry, high pressure or gas phase. The catalyst system may be supported or unsupported and the cyclopentadienyl rings may be substituted or unsubstituted. Titanium, Zirconium and Hafnium are preferred transition metals.

Several commercial products produced with such catalyst/activator combinations are commercially available from Exxon Chemical Company in Baytown, Texas under the tradenames EXCEEDS and EXACTS. For more information on the methods and catalysts/activators to produce such metallocene homopolymers and copolymers see WO 94/26816; WO 94/03506; EPA 277,003; EPA 277,004; U.S.

5,153,157; U.S. 5,198,401; U.S. 5,240,894; U.S. 5,017,714; CA 1,268,753; U.S.

5,324,800; EPA 129,368; U.S. 5,264,405; EPA 520,732; WO 92 00333; U.S.

5,096,867; U.S. 5,507,475; EPA 426 637; EPA 573 403; EPA 520 732; EPA 495 375; EPA 500 944; EPA 570 982; WO91/09882; W094/03506 and U.S.

5,055,438.

The metallocene produced copolymers described above preferably have a composition distribution breadth index (CDBI) of 50 % or more, preferably above 60%, even more preferably above 70%. In one embodiment, the CDBI is above 80%, even more preferably above 90%, even more preferably above 95%. In another particularly preferred embodiment, the polyethylene copolymer has a CDBI between 60 and 85%, even more preferably between 65 and 85%.

Composition Distribution Breadth Index (CDBI) is a measure of the composition distribution of monomer within the polymer chains and is measured by the procedure described in PCT publication WO 93/03093, published February 18, 1993 including that fractions having a weight average molecular weight (Mw) below 15,000 are ignored when determining CDBI.

The resin may be present in the blend from 1 to 200 parts per 100 parts of base polymer in the adhesive formulation. In a preferred embodiment, the resin may be present in the blend from 25 parts to 200 parts per 100 parts of polymer. In another embodiment, the preferred range is 80 to 120 parts resin per 100 parts polymer.

The adhesive formulations may also contain additives well known in the art such as anti-block, anti-stat, antioxidants, crosslinking agents, silica, carbon black, talc, pigments, fillers, processing aids, UV stabilizers, neutralizers, lubricants, surfactants and/or nucleating agents. Preferred additives include silicon dioxide, titanium dioxide, polydimethylsiloxane, talc, dyes, wax, calcium stearate, carbon black and glass beads.

The resins of this invention may be formed into pressure sensitive adhesives, hot melt adhesives or contact adhesives and used in applications such as Tapes, Labels, Paper Impregnation, Hot Melt Adhesives including Woodworking, Packaging, Bookbinding or Disposables, Sealants, Rubber Compounds, Pipe Wrapping, Carpet Backing, Contact Adhesives, Road-Marking or Tire construction.

In a particularly preferred embodiment, the resins are formulated into a pressure sensitive adhesive application. Such a pressure sensitive adhesive composition may be applied to any conventional backing layer such as paper, foil, polymeric film, release liners, woven or non-woven backing material to make for example, packaging tapes.

Examples: The feed streams used in the following examples are described in Table I.

In the following examples, the 2-methylbutene concentrate was 92% 2-Methyl-2- Butene and 6% 2-Methyl-l-Butene. Softening point was measured as a ring and ball softening point according to ASTM E-28.

Cloud point was the point at which there is a haze or "cloud" in a mixture of 40 parts 60 "C melt point paraffin wax, 20 parts ESCORENEX UL7750 (ethylene vinyl acetate, 28% vinyl acetate) from Exxon Chemical Company and 54 parts test resin heated to 200 OC and allowed to cool in air with stirring. The GPC was calibrated with polystyrene standards. Molecular weight is calculated as polyisobutylene equivalents from the following equation: Log(PIB)=(1 1. 1)(Log(PSrnw)-0.5 17 Table I: (Compositions Of Streams Used in Examples) Stream A" "Stream B" "Stream C" Steam Mixed Cracked Aromatic Raffinate Stream Composition (Wt %) Crude C5s 1 4-Pentadiene l-Pentene 2.98 0.04 2-Methyl-l-Butene 3.59 0.01 Isoprene 15.6 0.45 trans-2-Pentene 2.65 5.58 cis-2-Pentene 1.36 3.81 2-Methyl-1-Butene 3.41 1.33 trans-1,3-Pentadiene 7.94 1.21 Cyclopentadiene (CPD) 1.17 ----- 0.39 cis-1,3-Pentadiene 4.59 4.87 Cyclopentene 5.41 13.5 3/4-Methyl-1-Pentene 0.15 1.69 2,3-Dimethyl-1-Butene 0.03 0.46 E/Z4-Methyl-2-Pentene 0.37 7.79 3-Methyl-1,4-Pentadiene 0.25 1.90 2-Methyl-l-Pentene 0.11 0.55 l-Hexene 0.04 1.89 cis-1,4-Hexadiene 0.03 0.27 trans-3-Hexene 0.01 1.79 trans-2-Hexenel cis-3-Hexene 0.12 4.11 2-Methyl-2-Pentene 0.08 ----- 2,3-Dimethyl-2-Butene 0.01 3.67 cis-2-Hexene 0.19 0.26 Benzene 0.86 3.70 Styrene 7.93 Unreactive Aliphatics ----- 41.1 16.6 alpha-Methylstyrene ----- ----- 3.89 cis-beta-Methystyrene ----- ----- 0.89 meta-Methylstyrene ----- ----- 8.14 ortho-Methylstyrene ----- ----- 2.95 para-Methystyrene ----- ----- 3.18 trans-beta-Methylstyrene ----- ----- 2.08 DCPD (endo + exo) 18.9 ----- 0.66 Indene ----- ----- 13.7 Methylindene ----- ----- 0.46 Dimethylstyrene ----- ----- 1.78 Ethylstyrene ----- ----- 1.71 Divinylbenzene 4.38 MCPD Dimer ----- ----- 0.45 Propyl Styrene ----- -- ---- 0.78 Alkyl Aromatics ----- ----- 30.0

Examples 1 and 2 The resins produced in Table II were polymerized via a continuous process employing a continuously stirred tank reactor (CSTR) using aluminum chloride as the catalyst in a nitrogen atmosphere at approximately 45 psig (3.2 kg/cm2). The reactor feed blend composition, indicated in Table 1, was added continuously to the reactor at such a rate as to maintain an approximate 90-minute residence time in the reactor. The aluminum chloride catalyst of particle size distribution 5-200 mesh was added continuously to the reactor to maintain a 0.8 wt % catalyst concentration based on feed. Polymerizate was continuously discharged from the reactor and quenched with a 1:3 solution of isopropanol and water followed by water washing several times to remove the quenched catalyst residue. After each washing, the aqueous layer was discarded.

The resin was recovered by heating the washed polymerizate to 250 "C while sparging with nitrogen to remove the unreacted components and low molecular weight oligomers followed by steam stripping to remove the heavier oligomers (fill).

Examples 1 and 2 represent aromatic aliphatic resins produced from a crude Cs stream such as the one represented in Table I (Stream B).

Table II: Resins From Crude C5S Feed Composition (Wt %) Ex 1 Ex 2 Stream A 45.0 58.0 Stream B 42.8 18.5 2-Methylbutene Concentrate 7.0 15.5 Styrene 3.2 Mixed Aromatic Concentrate ---- 8.0 Benzene 2.0 2.0 Kev Components Pi e lenes 8.2 8A Isoprene 7.2 9.1 cyclics 9.0 | 11.6 Piperylene/Cyclics 0.9 0.7 Isoprene/Cyclics 0.8 0.7 Reaction Conditions AlCl3 (wt %) 0.8 0.8 Reaction Temperature(°C) 45 80 Reactor Pressure (psig) 15 45 Finishing Resin Yield (Wt %) 29.4 38.9 Fill Yield (Wt %) 4.9 Raffinate Yield (Wt %) 64.8 Wt % Gel Based On Feed -0- -0- Resin Properties Softening Point (°C) 93.2 94.8 20/54/40 Cloud Point (°C) 68 73 Gardner Color 5.5 7.0 GPC Molecular Weitht Mw 1,395 1,601 Mn 696 | 717 Mw/Mn 2.0 2.2 Mz 3,335 5,377

Synthesis of Resins from Raw Cs The examples reported in Tables m and IV resulted from the polymerization via a semi-continuous process in a batch reactor except example 7, which was done in a continuous stirred tank reactor. The feed blend was added by portion over 75 min., as well as the catalyst (aluminum chloride powder), in a nitrogen atmosphere and under efficient stirring. Catalyst level was 0.75 wt % on total feed blend. The reactor mixture was stirred for an extra 15 min after all the ingredients had been added to the reactor. Total residence time was then 90 min. Reaction temperature was between 40 to 50 "C. The reactor content was quenched with water and neutralized with a solution of ammonia. The aqueous layer was discarded and the polymerizate was further stripped to remove unreacted monomers (nitrogen stripping at 200 "C) and low molecular weight oligomers (steam stripping up to 250 "C). Resin yield was the amount of resin recovered on total feed blend.

Example 7 was polymerized under the same conditions as example 1.

Raw Cs in Tables m, IV, and V comprised 12-17 weight % piperylene, 16-19 weight % isoprene, 10-20 weight % cyclopentadiene, dicyclopentadiene, substituted cyclopentadienes and substituted dicyclopentadienes and 21-26 weight % C4 to C6 aliphatic olefins.

Table m reports examples of low aromatic modified resins (Ex-3 to Ex-7) and high aromatic modified resins (Ex-8 to Ex-lO). For low aromatic modified resins, Ex-3 and Ex-4 are two reference examples made from traditional feed blends containing piperylene (Ex-3) or isoprene + piperylene (hexa) as conjugated dienes whereas Ex-5 to Ex-7 are made from crude Cs cut ("Raw Cs") and the reactor feed blend comprises three types of conjugated dienes (piperylene, isoprene, and cyclopentadiene/dicyclopentadiene). For high levels of aromatic olefins, Ex-8 is a reference sample made from traditional feed blend containing isoprene and piperylene, excluding cyclodiene and dicyclopentadienes. Ex-9 and Ex-lO are made from crude Cs cut and the reactor feed blend contains the three types of conjugated dienes, as indicated in Table m. Table IV reports two examples of high softening point resins with a high level of aromaticity made from crude Cs. Table: Aromatic Modified Resins Low Aromatic Modified High Aromatic Modified Example # Ex 3* Ex 4 Ex 5 Ex 6 Ex 7 Ex 8 Ex 9 Ex 10 Feed Blend (wt %) Piperylene cut (1) 40 24 24 10 - - - - IBP-70 (pip./isopr.) - 21 - - - 35 12 - Raw C5 - - 20 37 47 - 20 29 CS-C, monoolefins 49 31 46 43 43 7 16 28 Isomerat (3) 7 17 - - - 24 17 9 C8-C10 aromatics - 7 10 10 10 34 35 34 Styrene 4 i Key Components : Piperylene (wt %) 25.8 18.3 18.3 13.0 8.3 6.4 4.9 4.1 Isoprene (wt %) 038 4.6 3.6 6.9 8.6 7.0 5.7 4.8 cpd/dcpd (wt %) 1.0 1.2 4.8 4.3 5.0 <1 43 5.8 Diolefins/Olefins Ratio (4) 0.73 0.74 0.71 0.65 0.60 0.86 0.84 0.65 Piperylene/Cyclics 25.8 15.3 3.8 3.0 1.7 6.4 1.1 0.7 Isoprene/Cyclics 3.8 0.75 1.6 1.7 0.8 >7 1.3 1.2 Reaction Yield (wt %) 44 36 41 37 34 42 42 42 Resin Properties Softening Point (°C) 92 91 92 89 88 | 99 103 98 (30/45/25) Cloud Pt. (°C) (5) 80 86 83 83 83 85 86 86 Eq. styrene (wt %)(6) 7 9 9 10 32 32 33 Molecular Wt. (GPC) (7) Mn 1140 1210 1150 1220 1150 890 860 720 Mw 1760 2210 1860 2160 2020 1950 1750 1350 Mz 2900 4620 3180 4120 3830 5630 4850 3040 Mw/Mn 1.5 1.8 1.6 1.8 1.8 2.2 2.0 1.9 Melt viscosity @ 150°C (8) 1010 1131 1075 1115 988 1673 2510 1550 * Ex-3 was polymerized in a CSTR.

Table-IV: Aromatic Modified - High Softening Point Resins Example # Ex 11 Ex 12 Feed Blend (wt %) Raw C5 17 18 C5-C6 monoolefins 7 13 Isomerat (3) 31 16 C8-C10 aromatics 35 53 a-pinene 10 - Key Components: Piperylene (wt %) 2.3 2.5 Isoprene (wt %) 2.8 3.0 cpd/dcpd (wt %) 3.5 3.7 Diolefins/Olefins Ratio (4) 1.11 0.79 Piperylene/Cyclics 0.65 0.7 Isoprene/Cyclics 0.8 0.8 Reaction Yield (wt %) 34 45 Resin Properties Softening Point (°C) 118 114 (30/45/25) Cloud Point (°C) (5) 86 104 Eq. styrene (wt %)(6) 37 47 Molecular Weight (GPC) (7) Mn 760 710 Mw 1490 1470 Mz 3770 4230 Mw/Mn 2 2.1 Melt viscosity @ 1500C (8) | - 8910 5390 Notes for Tables m & IV: piperylene cut was a cut comprising piperylene (50 wt % min), less than 2 wt % isoprene, less than 2 wt % cyclopentadiene/methylcyclopentadiene and corresponding dimers.

(2) IBP-70 was a diolefin/olefin cut essentially containing 20-30 wt % isoprene and 15-25 wt % 1,3-cis, trans-pentadiene (piperylene) and less than 3 wt % cyclopentadiene/ dicyclopentadiene (removed by fractionation).

(3) Isomerat was a paraffinic cut comprising from C4 to C10 paraffins and was used as diluent.

(4) Diolefins / Olefins ratio (wt %). Diolefins were the total diolefins in the feed blend. Olefins were all the monoolefins.

(5) (30/45/25) = (EVA/resin/wax) - EVA was Escorenes UL02528 CC - wax was <BR> <BR> <BR> a 68°C melting point paraffin wax.<BR> <BR> <P> (6) Aromaticity level was the integration of aromatic protons in 1H-NMR given as weight % styrene equivalent.

(7) GPC: molecular weights were polystyrene equivalent.

Melt viscosity was measured with a Brookfield Thermosel, Series RVT, Spindle 21.

Examples 13-14 Two products were made in a commercial Continuous Stirred Tank unit at 55 °C using aluminum chloride in powder as catalyst according to the feed compositions given in the table below. The feed composition was completed to 100% with a non-interfering aliphatic solvent such as Isomerat, as described in the notes to Tables III and IV.

Ex. 13 was made with a C5 stream from which the dicyclopentadiene and alkylcyclodienes have been removed through distillation. Ex-14 was the Raw C5 based product.

Table-V: Examples of Resin made in Continuous Stirred Tank Reactor Ex 13 Ex 14 Feed Blend (wt %) Piperylene cut. 23 24 IBP-70 (pip./isopr.) 21 - Raw C5 - 20 C«-C monoolefins. 30 46 C -C aromatics 10 10 Styrene Key Components: Piperylene (wt %) 18.3 19.7 Isoprene (wt %) 4.2 3.5 cpd/dcpd (wt %) 1.3 2.9 Diolefins (wt %) 23.8 26.1 Olefins (wt %) 34.9 34.1 D/O 0.68 0.77 Piperylene/Cyclics 14.1 6.8 Isoprene/Cyclics 3.2 1.2 Softening Point (°C) 95 93

Examples 13b and 14b.

120 pts by weight of the product resin from examples 13 and 14 were blended with 100 pts by weight of Vectors 4111, 10 pts by weight of Flexon oil, and 1 pt by weight Irganox 1076. The components were mixed in a one-liter Z blade laboratory mixer at a temperature of 150 "C for 70 minutes. The data are reported in Table V-B.

TABLE V-B Adhesive properties Ex 13b Ex 14b Viscosity 1750C (mPa.s) 90500 80000 180 ° Peel on steel (N/cm) initially 7.7 7.13 3 days open air aging 6.9 6.91 Loop Tack on steel (N/25 mm) initially 23.5 24.2 3 days open air aging 19.5 i 21.4 Ball Tack (cm) initial 1.5 2.0 3 days open air aging 8.5 1.5 Example 14b, made from a Raw C5 feed blend, shows adhesive properties comparable to those of example 13b, made from a traditional feed, and superior properties regarding ball tack after aging.

In Examples 15-17, blends were made of resin and base polymer in a one liter Z blade laboratory mixer at a temperature of 150 °C for 70 minutes. The formulation and properties are reported in Table VI.

Table-VI: Formulations and PSA properties Ex 15 Ex 16 | Ex 17 V4111 100 ---- 100 DPX-511 ---- 100 ---- Resin from Ex 14 100 100 Resin from Ex 13 ---- ---- 100 Flexon 876 10 10 10 Irganox 1076 1 1 1 180 peel adhesion(N/cm) 5.97 6.07 5.45 Loop tack (N/25mm) 18.8 19.9 20.1 Shear on cardboard at RT (hrs) > 100 > 100 > 100 12.5 mm * 25 mm- 1 ka > 100 > 100 > 100 Shear on cardboard at 400C 25h21' > 50 0h03' af (hrs) 12.5 mm * 25 mm - 1 kg af > 50 13h25' 0h05' af 21h31' af 2h01af af > 50 > 50 2h22'af >50 SAFT (°C) 95.2 cf 92.6 cf 93.3 cf 12.5 mm * 25 mm - 1 kg Blend viscosity at 1750C (cps) 133000 98200 103750 (spindle 27/1.0 - 2.5 rpm - after 2 hrs) (Brookfield AS 1) Coating weight (gsm) 18 - 20 V4111 is an SIS linear triblock copolymer with 18 wt % styrene and MFR of 12 and an Mn of 120,000 produced by Dexco Polymers in Louisiana, USA and sold under the trade name VECTORTM 4111.

DPX-511 is a SIS linear triblock copolymer with 18 wt % styrene, and MFR of 15 and Mn of 110,000.

Flexon 876 is a processing oil.

Resin: Ring and ball-softening point was measured according to ASTM E-28.

. Melt viscosity was measured according to ASTM D-3236.

Wax cloud point was the temperature at which there is a haze or "cloud" in a mixture of parts of paraffin wax, Escorene and of test resin heated at 200 "C and allowed to cool in air with stirring.

. Molecular weight was measured by Gel Permeation Chromatography against polystyrene standards with molecular weights ranging from 162 to 66M.

Block copolymer: MFR was measured by ASTM D-1238.

. Molecular weight was measured by GPC using the method described by J.R.

Runyon et al., J. Polym. Sci. 13,2359, (1969).

Adhesive: 180°C peel (N/cm) was measured on steel according to AFERA TM 4001.

Loop tack (N/25mm) on steel was measured according to FINAT TM9.

Ball tack (cm) as measured according to PSTC6.

. Shear was measured according to PSTC7 except that the sample was 25mm x 12.5 mm with a l-kg weight.

SAFT (Shear Adhesion Fail Temperature) was measured by adhering a coated polyethylene strip of 25 mm width to stainless steel via press lamination with a contact area of 12.5mm x 25mm, hanging samples in an oven at 24 "C and suspending a 500 gram weight from the bottom of the strip. The temperature is raised at 0.4 "C/min and the bond failure temperature is measured. The SAFT is the average of three test samples.

Viscosity was measured according to ASTM D-3236.

Examples 18 and 19 - Hvdrogenation of Raw C based resins: Example 18 is the result of the hydrogenation in a continuous reactor of a solution of the product resin from Example 14 in a hydrocarbon solvent (Varsol 1) with a Ni-W on alumina catalyst (5 weight % nickel oxide, 21 weight % Tungsten

oxide). The catalyst was used at a feed rate of 1.5 volume resin solution per volume catalyst per hour (VVH) and had the properties described in Table vm.

Example 19 resulted from the hydrogenation in a batch reactor of a solution of the product of example 14 in Exxsol D 40 with a palladium on carbon catalyst (5 wt % of Pd on carbon and 15 weight % catalyst load, base upon the weight of the solution) under the autoclave conditions in Table VII. Example 20 was run according to the same procedure as example 18, except that a Nickel Tungsten catalyst on gamma-alumina was used. Example 21 was run according to the same procedure as Example 20, except that the catalyst was used at a feed rate of 1 volume resin solution per volume catalyst per hour (VVH).

Table-VII: Examples of Resin Hvdrogenation Ex 18 Ex 19 Ex 20 Ex 21 Process Conditions Mode Isothermal batch Isothermal Adiabatic Pressure (Bar) 55 50 50 57 Inlet Temperature (°C) 250 125 250 210 Resin in the solution (wt %) 40 15 15 30 Resin Properties Initial Color (YI) (*) 54 54 54 Color after Hydrog. (YI) (*) 4-7 28 3/4 ° A solution of 50 weight % resin and 50 weight % toluene p.a. was spectrophotometrically analyzed on a Hunterlab Ultrascan Spectrophotometer.

Total Transmittance mode was used and the Yellowness Index YID1925 was recorded.

Table VIII EX18 EX 20& 21 WO3/NiO (wt %/wt%) 22.4/5.0 20.1/5.3 Surface Area, m 1 172 234 ore Volume, cc/gm 0.65 0.64 Pore Vol. Dist. (cc/gm) 0-200 A Dia. 0.40 0.383 200-2000 A Dia. 0.06 0.112 2000-20,000 Å Dia. 0.16 0.081 20,000-150,000 A Dia. 0.01 0.065 >150,000 Å Dia. 0.03 - 0+ Shape, 1.6mm Radius* S R % >10,000 Å 4.6 10 %>1,000Å 29 23 * S = shaped particle support; R = cylindrical particle support + = below detectable level For the purposes of U.S. Law, all references, testing procedures, and priority documents are incorporated by reference herein. As is apparent from the foregoing general description and the specific embodiments, while forms of the invention have been illustrated and described, various modifications can be made without departing from the spirit and scope of the invention. Accordingly, it is not intended that the invention be limited thereby.