Title:
ASYMMETRIC HYDROGENATION CATALYST
Document Type and Number:
WIPO Patent Application WO/2010/140636
Kind Code:
A1
Abstract:
Provided is a catalyst for producing optically active aldehydes and optically active ketones, which are optically active carbonyl compounds, by selective asymmetric hydrogenation of an α, β- unsaturated carbonyl compound, particularly a catalyst that is insoluble in a reaction mixture and is used to obtain optically active citronellal, which is useful as a fragrance, by selective asymmetric hydrogenation of citral, geranial or neral. Also provided is a method for producing an optically active carbonyl compound corresponding thereto. The catalyst for the asymmetric hydrogenation of the α, β- unsaturated cabonyl compound contains an optically active cyclic nitrogenated compound, an acid, and either a powder of at least one metal selected from groups 8 through 10 of the periodic table, or a supported metal obtained by supporting at least one metal selected from groups 8 through 10 of the periodic table upon a support.
Inventors:
MAEDA HIRONORI
HORI YOJI
HORI YOJI
Application Number:
PCT/JP2010/059387
Publication Date:
December 09, 2010
Filing Date:
June 02, 2010
Export Citation:
Assignee:
TAKASAGO PERFUMERY CO LTD (JP)
MAEDA HIRONORI
HORI YOJI
MAEDA HIRONORI
HORI YOJI
International Classes:
B01J31/28; C07C45/62; C07C47/21; C07D207/06; C07D207/08; C07D207/09; C07D207/16; C07D233/32; C07D241/44; C07D405/04; C07B53/00; C07B61/00
Foreign References:
| JP2008515843A | 2008-05-15 | |||
| JPS5414911A | 1979-02-03 | |||
| US20060161024A1 | 2006-07-20 | |||
| JPS5414911A | 1979-02-03 | |||
| JP2008515843A | 2008-05-15 | |||
| US20060161024A1 | 2006-07-20 | |||
| JP2002212121A | 2002-07-31 | |||
| JP2009134161A | 2009-06-18 |
Other References:
GABRIELLA FOGASSY ET AL.: "Enantioselective hydrogenation of exocyclic a,P-unsaturated ketones PartII. Hydrogenation in the presence of (S)-proline", JOURNAL OF MOLECULAR CATALYSIS A: CHEMICAL, vol. 179, 2002, pages 101 - 106, XP027396239
JOURNAL OF MOLECULAR CATALYSIS A: CHEMICAL, vol. 138, 1999, pages 123 - 127
JOURNAL OF MOLECULAR CATALYSIS A: CHEMICAL, vol. 170, 2001, pages 101 - 107
JOURNAL OF MOLECULAR CATALYSIS A: CHEMICAL, vol. 179, 2002, pages 101 - 106
JOURNAL OF MOLECULAR CATALYSIS A: CHEMICAL, vol. 179, 2002, pages 107 - 112
JOURNAL OF MOLECULAR CATALYSIS A: CHEMICAL, vol. 192, 2003, pages 189 - 194
ACC. CHEM. RES., vol. 40, 2007, pages 1327 - 1339
TETRAHEDRON, vol. 49, 1993, pages 5127 - 5132
TETRAHEDRON: ASYMMETRY, vol. 8, 1997, pages 149 - 153
TETRAHEDRON, vol. 49, 1993, pages 5127 - 5132
TETRAHEDRON, vol. 49, no. 23, pages 5127 - 5132
TETRAHEDRON: ASYMMETRY, vol. 8, no. 1, pages 149 - 153
JOURNAL OF MOLECULAR CATALYSIS A: CHEMICAL, vol. 138, 1999, pages 123 - 127
JOURNAL OF MOLECULAR CATALYSIS A: CHEMICAL, vol. 170, 2001, pages 101 - 107
JOURNAL OF MOLECULAR CATALYSIS A: CHEMICAL, vol. 179, 2002, pages 101 - 106
JOURNAL OF MOLECULAR CATALYSIS A: CHEMICAL, vol. 179, 2002, pages 107 - 112
JOURNAL OF MOLECULAR CATALYSIS A: CHEMICAL, vol. 192, 2003, pages 189 - 194
ACC. CHEM. RES., vol. 40, 2007, pages 1327 - 1339
TETRAHEDRON, vol. 49, 1993, pages 5127 - 5132
TETRAHEDRON: ASYMMETRY, vol. 8, 1997, pages 149 - 153
TETRAHEDRON, vol. 49, 1993, pages 5127 - 5132
TETRAHEDRON, vol. 49, no. 23, pages 5127 - 5132
TETRAHEDRON: ASYMMETRY, vol. 8, no. 1, pages 149 - 153
Attorney, Agent or Firm:
OGURI Shohei et al. (JP)
Shohei Oguri (JP)
Shohei Oguri (JP)
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