Title:
BINDER-FREE ZEOLITE CATALYST, PROCESS FOR ITS PREPARATION, AND CATALYTIC REACTION USING SAME
Document Type and Number:
WIPO Patent Application WO/1984/003452
Kind Code:
A1
Abstract:
Binder-free zeolite prepared by kneading and molding crystalline aluminosilicate with a silica/alumina binder and crystallizing the binder in the molding to convert 90 % or more of the whole molding into crystalline aluminosilicate. The obtained binder-free zeolite shows an improved catalytic effect without reducing the strength of the molding since so called secondary fine pores effectively show a catalytic action. Particularly good performance can be obtained when 50 % or more of the crystalline aluminosilicate is TSZ crystalline aluminosilicate, and this catalyst is excellent as a catalyst for selective cracking of n-paraffin hydrocarbons and as catalyst for aromatic alkylation with an alkylating agent such as an alcohol or olefin. Good binder-free zeolite can be obtained by kneading and molding a mixture of 30 to 70 wt % of one or more members selected from among crystalline aluminosilicate, silica/alumina xerogel, and hydrothermally treated silica/alumina xerogel and 70 to 30 wt % of silica/alumina gel containing 2 to 10 wt % alumina, and hydrothermally treating the molding.
Inventors:
SAKURADA SATOSHI (JP)
TAGAYA NOBUAKI (JP)
MIURA TADASHI (JP)
MAESHIMA TSUGIO (JP)
HASHIMOTO TAKAO (JP)
TAGAYA NOBUAKI (JP)
MIURA TADASHI (JP)
MAESHIMA TSUGIO (JP)
HASHIMOTO TAKAO (JP)
Application Number:
PCT/JP1984/000094
Publication Date:
September 13, 1984
Filing Date:
March 09, 1984
Export Citation:
Assignee:
TOA NENRYO KOGYO KK (JP)
International Classes:
B01J29/06; B01J29/40; B01J29/70; C01B39/00; C01B39/46; C07B61/00; C07C1/00; C07C2/66; C07C2/70; C07C2/86; C07C4/06; C07C5/393; C07C15/02; C07C67/00; C10G29/20; C10G45/64; (IPC1-7): B01J29/28; C07C2/66; C07C15/02; C10G45/64
Foreign References:
| JPS4845483A | 1973-06-29 | |||
| US3472617A | 1969-10-14 |
Other References:
See also references of EP 0152485A4
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