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Title:
BIO-OIL ELECTROCHEMICAL UPGRADING METHOD AND BIO-OIL ELECTROCHEMICAL HYDROGENATION UPGRADING DEVICE
Document Type and Number:
WIPO Patent Application WO/2022/021909
Kind Code:
A1
Abstract:
The present invention relates to the field of biomass energy utilization. Disclosed are a bio-oil electrochemical upgrading method and a bio-oil electrochemical hydrogenation upgrading device. The bio-oil electrochemical upgrading method comprises the following steps: (a) mixing bio-oil, an organic solvent, and a supporting electrolyte to obtain a catholyte; (b) preparing an acid solution as an anolyte; (c) constructing an electrochemical reactor by using the catholyte and the anolyte, and separating the catholyte from the anolyte by means of one or two ion exchange membranes, thus forming a current loop; and (d) introducing a protective gas into one side of the catholyte, and then introducing current by means of a working electrode and an anode electrode to perform electrochemical reaction, thereby implementing the electrochemical upgrading of the bio-oil. According to the present invention, the problem that carbon deposition is easily formed when the bio-oil is upgraded by a thermochemical method can be effectively solved, the bio-oil is subjected to electrochemical upgrading under mild conditions, and the content of bio-oleic acid, the content of aromatic components and the content of heavy components can be reduced by upgrading, so that the bio-oil is suitable for transportation and storage.

Inventors:
WANG YI (CN)
DENG WEI (CN)
XIONG ZHE (CN)
WANG XUEPENG (CN)
DENG ZENGTONG (CN)
CHEN YUANJING (CN)
XIANG JUN (CN)
HU SONG (CN)
SU SHENG (CN)
JIANG LONG (CN)
XU JUN (CN)
HAN HENGDA (CN)
Application Number:
PCT/CN2021/083454
Publication Date:
February 03, 2022
Filing Date:
March 27, 2021
Export Citation:
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Assignee:
UNIV HUAZHONG SCIENCE TECH (CN)
International Classes:
B01D61/00; C10G32/02; B01J19/08; C10G45/00; C10L1/02
Domestic Patent References:
WO2013134220A12013-09-12
Foreign References:
CN111909736A2020-11-10
CN111871350A2020-11-03
CN108660477A2018-10-16
CN103497843A2014-01-08
Other References:
LAM CHUN HO, DENG WEI, LANG LIN, JIN XIN, HU XUN, WANG YI: "Minireview on Bio-Oil Upgrading via Electrocatalytic Hydrogenation: Connecting Biofuel Production with Renewable Power", ENERGY & FUELS, AMERICAN CHEMICAL SOCIETY, WASHINGTON, DC, US., vol. 34, no. 7, 16 July 2020 (2020-07-16), WASHINGTON, DC, US. , pages 7915 - 7928, XP055891000, ISSN: 0887-0624, DOI: 10.1021/acs.energyfuels.0c01380
Attorney, Agent or Firm:
HUAZHONG UNIVERSITY OF SCIENCE AND TECHNOLOGY PATENT AGENCY CENTER (CN)
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