Title:
BIO-OIL POLYOLS, ALKOXYLATED BIO-OIL POLYOLS AND BIO-OIL PHENOLIC RESINS
Document Type and Number:
WIPO Patent Application WO/2014/201185
Kind Code:
A3
Abstract:
Methods are provided for producing bio-oil polyols, alkoxylating bio-oil polyols to provide polyols, and for employing the alkoxylated bio-oil polyols for making polymers or copolymers of polyesters or polyurethanes. Compositions and methods are provided for incorporating bio-oils into phenolic resins such as phenol-formaldehyde resin and phenol- formaldehyde -urea resin, as well as hot melt adhesive compositions.
Inventors:
GARBARK DANIEL (US)
BENECKE HERMAN (US)
MOORE MEGAN (US)
PERRY MARK J (US)
CAFMEYER JEFFREY T (US)
BENECKE HERMAN (US)
MOORE MEGAN (US)
PERRY MARK J (US)
CAFMEYER JEFFREY T (US)
Application Number:
PCT/US2014/042016
Publication Date:
April 09, 2015
Filing Date:
June 11, 2014
Export Citation:
Assignee:
BATTELLE MEMORIAL INSTITUTE (US)
International Classes:
C08G8/20; C08G65/26; C08G16/02; C08G18/20; C08G18/28; C08G18/32; C08H8/00; C08L61/06; C08L97/02; C09J161/06
Foreign References:
| US4017474A | 1977-04-12 |
Other References:
LI YANG ET AL: "Kraft Lignin-Based Rigid Polyurethane Foam", JOURNAL OF WOOD CHEMISTRY AND TECHNOLOGY, vol. 32, no. 3, 3 April 2012 (2012-04-03), pages 210 - 224, XP009172057, ISSN: 0277-3813, [retrieved on 20120403], DOI: 10.1080/02773813.2011.652795
CINELLI PATRIZIA ET AL: "Green synthesis of flexible polyurethane foams from liquefied lignin", EUROPEAN POLYMER JOURNAL, PERGAMON PRESS LTD. OXFORD, GB, vol. 49, no. 6, 13 April 2013 (2013-04-13), pages 1174 - 1184, XP028562685, ISSN: 0014-3057, DOI: 10.1016/J.EURPOLYMJ.2013.04.005
CAROLINA ANDREIA CATETO ET AL: "Optimization Study of Lignin Oxypropylation in View of the Preparation of Polyurethane Rigid Foams", INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, vol. 48, no. 5, 4 March 2009 (2009-03-04), pages 2583 - 2589, XP055076453, ISSN: 0888-5885, DOI: 10.1021/ie801251r
GUO Z-X ET AL: "Polyesters from lignin-2. The copolyesterification of kraft lignin and polyethylene glycols with dicarboxylic acid chlorides", EUROPEAN POLYMER JOURNAL, PERGAMON PRESS LTD. OXFORD, GB, vol. 27, no. 11, 1 January 1991 (1991-01-01), pages 1177 - 1180, XP024055844, ISSN: 0014-3057, [retrieved on 19910101], DOI: 10.1016/0014-3057(91)90053-Q
MATJAZ KUNAVER, EDITA JASIUKAITYTE, NATASA CUK, JAMES T. GUTHRIE: "Liquefaction of wood, synthesis and characterization of liquefied wood polyester derivatives", JOURNAL OF APPLIED POLYMER SCIENCE, vol. 115, no. 3, 5 February 2010 (2010-02-05), pages 1265 - 1271, XP055167217, ISSN: 0021-8995, DOI: 10.1002/app.31277
FEI YU ET AL: "Liquefaction of Corn Stover and Preparation of Polyester From the Liquefied Polyol", APPLIED BIOCHEMISTRY AND BIOTECHNOLOGY, vol. 130, no. 1-3, 1 January 2006 (2006-01-01), pages 574 - 585, XP055167224, DOI: 10.1385/ABAB:130:1:574
CINELLI PATRIZIA ET AL: "Green synthesis of flexible polyurethane foams from liquefied lignin", EUROPEAN POLYMER JOURNAL, PERGAMON PRESS LTD. OXFORD, GB, vol. 49, no. 6, 13 April 2013 (2013-04-13), pages 1174 - 1184, XP028562685, ISSN: 0014-3057, DOI: 10.1016/J.EURPOLYMJ.2013.04.005
CAROLINA ANDREIA CATETO ET AL: "Optimization Study of Lignin Oxypropylation in View of the Preparation of Polyurethane Rigid Foams", INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, vol. 48, no. 5, 4 March 2009 (2009-03-04), pages 2583 - 2589, XP055076453, ISSN: 0888-5885, DOI: 10.1021/ie801251r
GUO Z-X ET AL: "Polyesters from lignin-2. The copolyesterification of kraft lignin and polyethylene glycols with dicarboxylic acid chlorides", EUROPEAN POLYMER JOURNAL, PERGAMON PRESS LTD. OXFORD, GB, vol. 27, no. 11, 1 January 1991 (1991-01-01), pages 1177 - 1180, XP024055844, ISSN: 0014-3057, [retrieved on 19910101], DOI: 10.1016/0014-3057(91)90053-Q
MATJAZ KUNAVER, EDITA JASIUKAITYTE, NATASA CUK, JAMES T. GUTHRIE: "Liquefaction of wood, synthesis and characterization of liquefied wood polyester derivatives", JOURNAL OF APPLIED POLYMER SCIENCE, vol. 115, no. 3, 5 February 2010 (2010-02-05), pages 1265 - 1271, XP055167217, ISSN: 0021-8995, DOI: 10.1002/app.31277
FEI YU ET AL: "Liquefaction of Corn Stover and Preparation of Polyester From the Liquefied Polyol", APPLIED BIOCHEMISTRY AND BIOTECHNOLOGY, vol. 130, no. 1-3, 1 January 2006 (2006-01-01), pages 574 - 585, XP055167224, DOI: 10.1385/ABAB:130:1:574
Attorney, Agent or Firm:
GEGENHEIMER, C., Michael et al. (505 King AvenueColumbus, OH, US)
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