WILSON DAVID R (US)
VAIDYA TULAZA (US)
CARNAHAN EDMUND M (US)
FONTAINE PHILIP P (US)
IVERSON CARL N (US)
AMENDED CLAIMS received by the International Bureau on 5 April 2019 (05.04.2019) 40 CLAIMS 1. A procatalyst comprising a metal-ligand complex according to formula (I): M is a metal chosen from titanium, zirconium, or hafnium, the metal being in a formal oxidation state of +2, +3, or +4; X is selected from the group consisting of -OR or -NR 2; wherein each R is independently a (Ci-C5o)hydrocarbyl, (Ci-C5o)heterohydrocarbyl, or -H and at least one R is (Ci-C5o)hydrocarbyl, (Ci-C5o)heterohydrocarbyl, and, when X is -NR 2, optionally two R are covalently linked; the metal-ligand complex is overall charge-neutral; each Z is independently chosen from -0-, -S-, -N(Rn)-, or -P(Rp)-; R1 and R16 are independently selected from the group consisting of -H, (Ci-C4o)hydrocarbyl, (Ci-C4o)heterohydrocarbyl, -Si(Rc)3, -Ge(Rc)3, -P(Rp)2, -N(Rn)2, -ORc, -SRc, -N02, -CN, -CF3, RCS(0)-, RCS(0)2- (RC)2C=N-, RCC(0)0-, RC0C(0)-, RCC(0)N(R)-, (RC)2NC(0)-, halogen, radicals having formula (II), radicals having formula (III), and radicals having formula (IV): 41 H, (Ci-C4o)hydrocarbyl, (Ci-C4o)heterohydrocarbyl, -Si(R )3, -Ge(Rc)3, -P(Rp)2, -N(Rn)2, -N=CHRc, -ORc, -SRc, -N02, -CN, -CF3, RCS(0)-, RCS(0)2- (RC)2C=N-, RCC(0)0-, RC0C(0)-, RCC(0)N(Rn)-, (RC)2NC(0)-, or halogen, provided that at least one of R1 or R16 is a radical having formula (II), a radical having formula (III), or a radical having formula (IV); each of R2 4, R5-8, R9-12, and R13 15 S independently selected from -H, (Ci-C4o)hydrocarbyl, (Ci-C4o)heterohydrocarbyl, -Si(Rc)3, -Ge(Rc)3, -P(Rp)2, -N(Rn)2, -ORc, -SRc, -N02, -CN, -CF3, RCS(0)-, RCS(0)2-, (RC)2C=N-, RCC(0)0-, RC0C(0)-, RCC(0)N(R)-, (RC)2NC(0)-, and halogen; L is (C2-C4o)hydrocarbylene or (C2-C4o)heterohydrocarbylene; and each Rc, Rp, and RN in formula (I) is independently a (Ci-C3o)hydrocarbyl, (Ci-C3o)heterohydrocarbyl, or -H. 2. The procatalyst according to claim 1, wherein R is chosen from (C5-Cso)alkyl or -H. 3. The procatalyst according to claims 1 or 2, wherein R is linear. 4. The procatalyst according to claims 1 or 2, wherein R is branched. 5. The procatalyst according to claims 1 or 2, wherein X is chosen from a linear alkyl having the formula -OCxHx+i or -NHCxHx+i, where x is an integer from 10 to 40. 6. The procatalyst according to claim 1, wherein: M is zirconium or hafnium; each X is -OC22H45; and each Z is oxygen. 7. The procatalyst according to any one of claims 1 - 3, M is zirconium or hafnium; each X is -OCi8H37; and each Z is oxygen. 8. The procatalyst according to claim 1, M is zirconium or hafnium; each X is -N(CI8H37)Rx; and each Z is oxygen. 9. The procatalyst according to claim 1, wherein M is zirconium or hafnium; at least one X is -N(C22H45)2; and each Z is oxygen. 10. The procatalyst according to any one of claims 1 to 10, wherein the metal-ligand complex according to formula (I) has a wt.% solubility ratio W/Y of at least 1.5, wherein W is the wt. % solubility of the metal-ligand complex of formula (I) in MCH at STP; wherein Y is the wt. % of a corresponding comparative metal-ligand complex of formula (la) in MCH at STP; and wherein the corresponding comparative complex has a structure according to formula (la): in which M, each Z, each R1 16 and L, all are identical to corresponding groups of the metal- ligand complex according to formula (I) |