Title:
BIS(6-METHYL-3-SULPHOPHENYL)(2-METHYLPHENYL)PHOSPHINE, AMMONIUM SALT THEREOF, AND METHOD FOR PRODUCING SAME
Document Type and Number:
WIPO Patent Application WO/2014/157403
Kind Code:
A1
Abstract:
Provided are: a water-soluble triaryl phosphine for a palladium catalyst that can be easily recovered in an efficient manner and that has high selectivity in telomerization reactions; an ammonium salt thereof; and a method for efficiently producing same. Specifically, provided are: bis(6-methyl-3-sulphophenyl)(2-methylphenyl)phosphine; diammonium bis(6-methyl-3-sulphophenyl)(2-methylphenyl)phosphinate obtained by reacting the phosphine with a ternary amine having 3-27 carbon atoms in a group bonded to one nitrogen atom; and a method for producing same.
Inventors:
MORI ERIKO (JP)
YOSHIKAWA TATSUYA (JP)
TSUJI TOMOAKI (JP)
KOIZUMI HITOSHI (JP)
SUGITA KYOKO (JP)
KUMAMOTO NOBUMICHI (JP)
YOSHIKAWA TATSUYA (JP)
TSUJI TOMOAKI (JP)
KOIZUMI HITOSHI (JP)
SUGITA KYOKO (JP)
KUMAMOTO NOBUMICHI (JP)
Application Number:
PCT/JP2014/058666
Publication Date:
October 02, 2014
Filing Date:
March 26, 2014
Export Citation:
Assignee:
KURARAY CO (JP)
HOKKO CHEM IND CO (JP)
HOKKO CHEM IND CO (JP)
International Classes:
C07F9/50; C07C209/68; C07C211/05; C07C211/07; C07C211/08
Domestic Patent References:
| WO1995030636A1 | 1995-11-16 |
Foreign References:
| JPS6388150A | 1988-04-19 | |||
| JPS6425739A | 1989-01-27 | |||
| JPH03232831A | 1991-10-16 | |||
| JPH06321828A | 1994-11-22 | |||
| JPH08501800A | 1996-02-27 | |||
| JPH08176167A | 1996-07-09 | |||
| JP2002371088A | 2002-12-26 | |||
| JP2003171388A | 2003-06-20 |
Other References:
M.FERREIRA ET AL.: "Biphasic Aqueous Organometallic Catalysis Promoted by Cyclodextrins: How to Design the Water-Soluble Phenylphosphane to Avoid Interaction with Cyclodextrin", ADVANCED SYNTHESIS & CATALYSIS, vol. 350, no. 4, 2008, pages 609 - 618, XP055284036
A.SAYEDE ET AL.: "Interaction of water-soluble triphenylphosphines with beta-cyclodextrin: a quantum chemistry study", JOURNAL OF PHYSICAL ORGANIC CHEMISTRY, vol. 24, no. 12, 2011, pages 1129 - 1135, XP055284037
JOURNAL OF MOLECULAR CATALYSIS A: CHEMICAL, vol. 97, 1995, pages 29 - 33
TETRAHEDRON LETTERS, vol. 41, 2000, pages 4503 - 4505
ORGANIC PROCESS RESEARCH & DEVELOPMENT, vol. 4, 2000, pages 342 - 345
TETRAHEDRON LETTERS, vol. 43, 2002, pages 2543 - 2546
ADVANCED SYNTHESIS & CATALYSIS, vol. 350, 2008, pages 609 - 618
JOURNAL OF ORGANIC CHEMISTRY, vol. 43, 1978, pages 2941 - 2956
See also references of EP 2980093A4
A.SAYEDE ET AL.: "Interaction of water-soluble triphenylphosphines with beta-cyclodextrin: a quantum chemistry study", JOURNAL OF PHYSICAL ORGANIC CHEMISTRY, vol. 24, no. 12, 2011, pages 1129 - 1135, XP055284037
JOURNAL OF MOLECULAR CATALYSIS A: CHEMICAL, vol. 97, 1995, pages 29 - 33
TETRAHEDRON LETTERS, vol. 41, 2000, pages 4503 - 4505
ORGANIC PROCESS RESEARCH & DEVELOPMENT, vol. 4, 2000, pages 342 - 345
TETRAHEDRON LETTERS, vol. 43, 2002, pages 2543 - 2546
ADVANCED SYNTHESIS & CATALYSIS, vol. 350, 2008, pages 609 - 618
JOURNAL OF ORGANIC CHEMISTRY, vol. 43, 1978, pages 2941 - 2956
See also references of EP 2980093A4
Attorney, Agent or Firm:
OHTANI, Tamotsu (JP)
Tamotsu Otani (JP)
Tamotsu Otani (JP)
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