JEWELL STAN (US)
CORNER CHRISTOPHER GARRINGTON (US)
JEWELL STAN (US)
US6192520B1 | 2001-02-27 | |||
US20010009832A1 | 2001-07-26 | |||
US20020182967A1 | 2002-12-05 |
1. | We claim: An outer shell fabric for use in firefighter turnout gear, the outer shell fabric comprising: a plurality of yarns that comprise at least three different types of inherently flame resistant fibers. |
2. | The outer shell fabric of claim 1, wherein the three different types of inherently flame resistant fibers comprise paraaramid fibers, meta aramid fibers, and polybenzoxazole (PBO) fibers. |
3. | The outer shell fabric of claim 1, wherein the fabric comprises about 40% to about 70% paraaramid, about 10% to about 40% metaaramid, and about 5% to about 30% polybenzoxazole (PBO). |
4. | The outer shell fabric of claim 1, wherein the fabric comprises about 60% paraaramid, about 20% metaaramid, and about 20% polybenzoxazole (PBO). |
5. | The outer shell fabric of claim 1, wherein the fabric comprises a rip stop weave. |
6. | The outer shell fabric of claim 5, wherein the rip stop weave is a twoend rip stop weave. |
7. | The outer shell fabric of claim 1, wherein the yarns have yarn counts in the range of approximately 1035 cc. |
8. | The outer shell fabric of claim 1, wherein the fabric has a weight of about 5 ounces per square yard to about 10 ounces per square yard. |
9. | The outer shell fabric of claim 1, wherein the fabric has a tensile strength in the warp direction that exceeds 200 pounds and a tensile strength in the filling direction that exceeds 175 pounds after a 7 second exposure in accordance with the thermal protective performance (TPP) test method defined in NFPA 1971, 2000 edition. |
10. | , A fabric suitable for use in firefighter turnout gear, fabric comprising: a blend of inherently flame resistant fibers, the blend including: a plurality of paraaramid fibers; a plurality of metaaramid fibers; and a plurality of polybenzoxazole (PBO) fibers. |
11. | The fabric of claim 10, wherein the fabric comprises about 40% to about 70% paraaramid fibers, about 10% to about 40% metaaramid fibers, and about 5% to about 30% PBO fibers. |
12. | The fabric of claim 10, wherein the fabric comprises about 60% paraaramid fibers, about 20% metaaramid fibers, and about 20% poiybenzoxazole (PBO) fibers. |
13. | The fabric of claim 10, wherein the fabric comprises a rip stop weave. |
14. | The fabric of claim 13, wherein the rip stop weave is a twoend rip stop weave. |
15. | The fabric of claim 10, wherein the fabric comprises a plurality of yarns, each yarn including paraaramid fiber, metaaramid fiber, and PBO fibers. |
16. | The fabric of claim 15, wherein the yarns have yarn counts in the range of approximately 1035 cc. |
17. | The fabric of claim 10, wherein the fabric has a weight of about 5 ounces per square yard to about 10 ounces per square yard. |
18. | The fabric of claim 10, wherein the fabric has a tensile strength in the warp direction that exceeds 200 pounds and a tensile strength in the filling direction that exceeds 175 pounds after a 7 second exposure in accordance with the thermal protective performance (TPP) test method defined in NFPA 1971, edition. |
19. | A firefighter turnout garment, the garment comprising: a thermal liner that forms an interior surface of the garment; a moisture barrier that forms an intermediate layer of the garment; and an outer shell that forms the exterior surface of the garment, the outer shell comprising a fabric blend of inherently flame resistant fibers, the blend including paraaramid fibers, metaaramid fibers, and polybenzoxazole (PBO) fibers. |
20. | The garment of claim 19, wherein the outer shell fabric comprises about 40% to about 70% paraaramid fibers, about 10% to about 40% metaaramid fibers, and about 5% to about 30% PBO fibers. |
21. | The garment of claim 19, wherein the outer shell fabric comprises about 60% paraaramid fibers, about 20% metaaramid fibers, and about 20% polybenzoxazole (PBO) fibers. |
22. | The garment of claim 19, wherein the outer shell fabric comprises a rip stop weave. |
23. | The garment of claim 22, wherein the rip stop weave is a twoend rip stop weave. |
24. | The garment of claim 19, wherein the outer shell fabric comprises a plurality of yarns, each yarn including paraaramid fibers, meta aramid fibers, and PBO fibers. |
25. | The garment of claim 24, wherein the yarns have yarn counts in the range of approximately 1035 cc. |
26. | The garment of claim 19, wherein the outer shell fabric has a weight of about 5 ounces per square yard to about 10 ounces per square yard. |
27. | The garment of claim 19, wherein the outer shell fabric has a tensile strength in the warp direction that exceeds 200 pounds and a tensile strength in the filling direction that exceeds 175 pounds after a 7 second exposure in accordance with the thermal protective performance (TPP) test method defined in NPPA 1971, 2000 edition. |
28. | The garment of claim 19, wherein the garment is one of a jacket, trousers, and coveralls. |
CROSS-REFERENCETORELATEDAPPLICATION This application claims priority to U.S. utility application entitled
"BLENDED OUTER SHELL FABRICS" filed on October 19, 2004, and no
serial number has yet to be assigned, and is entirely incorporated herein by
reference.
BACKGROUND
Firefighters typically wear protective garments commonly referred to in
the industry as turnout gear. Turnout gear normally comprises various
garments including, for instance, coveralls, trousers, and jackets. These
garments usually include several layers of material including, for example, an
outer shell that protects the wearer from flames, a moisture barrier that
prevents the ingress of water into the garment, and a thermal barrier that
insulates the wearer from extreme heat.
Turnout gear outer shells typically comprise woven fabrics formed of
one or two types of flame resistant materials. In addition to shielding the
wearer from flames, the outer shells of firefighter turnout gear further provide
abrasion resistance and protection from sharp objects, hi that the outer shell
must withstand exposure to flame and excessive heat, and must be resistant to
abrasion and tearing, it must be constructed of a flame resistant material that is
both strong and durable.
The selection process for the materials used to construct outer shell
fabrics, as with the selection process for other fabrics, often involves balancing
various factors. Such factors include fabric performance as well as cost. For
instance, outer shell fabrics that primarily comprise lower-performance fibers
are normally less expensive than fabrics that include higher-performance
fibers. Although the fabrics that comprise higher-performance fibers may
provide greater protection, that protection comes at a greater cost, both to the manufacturer and the consumer.
In view of the above, it would be desirable to be able to provide
relatively inexpensive outer shell fabrics having performance that approaches or even exceeds that of more expensive outer shell fabrics.
SUMMARY
The present disclosure relates to blended outer shell fabrics, hi one
embodiment, an outer shell fabric for use in firefighter turnout gear includes a
plurality of yarns that comprise at least three different types of inherently
flame resistant fibers.
hi another embodiment, a fabric includes a blend of inherently flame
resistant fibers, the blend including a plurality of para-aramid fibers, a plurality of meta-aramid fibers, and a plurality of polybenzoxazole (PBO) fibers.
BRIEF DESCRIPTION OF THE DRAWINGS
The disclosed fabrics can be better understood with reference to the
following drawings. The components in the drawings are not necessarily to scale.
FIG. 1 is a rear view of an example protective garment that includes a
blended outer shell fabric.
FIG. 2 is a schematic representation of a blended outer shell fabric that can be used in the construction of the garment of FIG. 1.
FIG. 3 is a schematic representation of an alternative blended outer shell
fabric that can be used in the construction of the garment of FIG. 1.
DETAILED DESCRIPTION
As is described in the foregoing, it would be desirable to be able to provide relatively inexpensive outer shell fabrics having improved
performance. As is described in the following, such a result can be achieved with certain blends of inherently flame resistant fibers. One such blend, for
example, includes a blend of para-aramid, meta-aramid, and polybenzoxazole
(PBO) fibers. As is described in greater detail below, such a blend provides
unexpectedly desirable physical properties at a relatively low cost.
FIG. 1 illustrates an example protective garment 100. More
particularly, FIG. 1 illustrates a firefighter turnout coat that can be donned by
firefighter personnel when exposed to flames and extreme heat. It is noted that, although a firefighter turnout coat is shown in the figure and described
herein, embodiments of this disclosure pertain to protective garments and
fabrics generally. Accordingly, the identification of firefighter turnout gear is
not intended to limit the scope of the disclosure.
As is indicated in FIG. 1, the garment 100 generally comprises an outer
shell 102 that forms the exterior surface of the garment, a moisture barrier 104
that forms an intermediate layer of the garment, and a thermal liner 106 that
forms the interior surface (i.e., the surface that contacts the wearer) of the
garment. In that it forms the exterior surface of the garment 100, the outer
shell 102 preferably is constructed so as to be flame resistant to protect the
wearer against being burned. In addition, the outer shell 102 preferably is
strong and durable so as to be resistant to abrasion and tearing during use in hazardous environments.
FIG. 2 is a schematic detail view of an example blended outer shell
fabric 200 that can be used in the construction of the protective garment 100,
and more particularly the outer shell 102 shown in FIG. 1. It is noted,
however, that the fabric 200 could be used in the construction of other protective garments either by itself or in combination with other fabrics. The
example fabric 200 illustrated in FIG. 2 is a rip stop fabric that comprises a plurality of body yarns 206, including picks 202 and ends 204, and a plurality
of rip stop yarns 208. Although a rip stop weave is illustrated in FIG. 2 and is
described herein, it will be appreciated that other configurations could be used
including, for instance, a plain weave, a twill weave, or a variation on a
conventional rip stop weave (see, e.g., FIG. 3).
Generally speaking, the fabric 200 comprises a blend of different
inherently flame resistant materials. Typically, at least three different inherently flame resistant materials are used to construct the fabric 200 so as to
obtain the distinct benefits of each, whether they be performance or cost
benefits. By way of example, the yarns of the fabric 200, including one or
more of the picks 202, ends 204, and rip stop yarns 208, comprise a blend of
para-aramid fibers, meta-aramid fibers, and PBO fibers.
Example para-aramid fibers include those that are currently available
under the trademarks KEVLAR ® (DuPont), and TECHNORA ® and
TWARON ® (Teijin). Example meta-aramid fibers include those sold under
the tradenames NOMEX T-450 ® (100% meta-aramid), NOMEX T-455 ® (a
blend of 95% NOMEX ® and 5% KEVLAR ® ), and NOMEX T-462 ® (a blend
of 93% NOMEX ® , 5% KEVLAR ® , and 2% anti-static carbon/nylon), each of
which is produced by DuPont. Example meta-aramid fibers also include fibers
that are currently available under the trademarks CONEX ® and APYEBL ® ,
which are produced by Teijin and Unitika, respectively. Example PBO fibers
include ZYLON ® from Toyobo ® .
It is noted that, for purposes of the present disclosure, when a material
name is used herein, the material referred to, although primarily comprising the named material, may not be limited to only the named material. For
instance, the term "meta-aramid fibers" is intended to include NOMEX ® T-
462 fibers, which, as is noted above, comprise relatively small amounts of
para-aramid fiber and anti-static fiber in addition to fibers composed of meta-
aramid material.
While a tri-blend of para-aramid, meta-aramid, and PBO fibers has been explicitly identified, other inherently flame resistant materials can be
added to the blend, if desired. Such other materials may, for example, include
one or more of polybenzimidazole (PBI), melamine, polyamide, polyimide,
polyimideamide, and modacrylic.
Moreover, non-mherently flame resistant materials can be added to the
blend, if desired. Examples of such materials include cellulosic fibers, such as
rayon, acetate, triacetate, and lyocell. These cellulosic materials, although not naturally resistant to flame, can be rendered flame resistant, if desired.
hi cases in which para-aramid, meta-aramid, and PBO fibers are used
to construct the fabric 200, the fabric can, for example, comprise about 40% to
about 70% para-aramid, about 10% to about 40% meta-aramid, and about 5%
to about 30% PBO. As is described below, one example blend is an
approximately 60/20/20 blend of para-aramid fibers, meta-aramid fibers, and
PBO fibers, respectively.
The body yarns 206 typically comprise spun yarns that, for example,
each comprises a single yarn or two or more individual yarns that are plied, or
otherwise combined, together. By way of example, the body yarns 206 comprise one or more yarns that each have a yarn count (or "cotton count") in
the range of approximately 5 to 60 cc, with 8 to 40 cc being preferred, hi some embodiments, the body yarns 206 can comprise two yarns that are plied
together, each having a yarn count in the range of approximately 10 to 35 cc.
The rip stop yarns 208 can have a construction similar to those of the
body yarns, but are provided in pairs that are woven through the fabric 200
side-by-side as is illustrated in FIG. 2. hi some embodiments, rip stop yarns
208 can be different in construction from the body yarns 206. For example, filament yarns could be used in the construction of the rip stop yarns 208, if
desired, hi other embodiments, filament yarns can be combined with spun
yarns or spun fiber to form rip stop yarns in the manner described in U.S.
Patent Application No. 10/165,795, which is hereby incorporated by reference
into the present disclosure, hi cases in which the rip stop yarns 208 have a
construction that is different than the body yarns 206, it is possible to use a
single yarn instead of two as is illustrated in FIG. 2. For example, if the rip
stop yarns 208 have a lower yarn count (and therefore larger size) than the
body yarns 206, then single rip stop yarns 208 may be enough to protect
against propagation of fabric tears.
The placement of the rip stop yams 208 within the fabric 200 can be
varied depending upon the desired physical properties, hi the embodiment
shown in FIG. 2, the rip stop yarns 208 are provided within the fabric 200 in a
grid pattern in which several body yarns 206 are placed between each
consecutive pair of rip stop yarns 208 in both the warp and filling directions of the fabric. By way of example, a pair of rip stop yarns 208 is provided in the
fabric 200 in both the warp and filling directions of the fabric for every
approximately 7 to 9 body yarns 206. hi some embodiments, the grid pattern is configured to form a plurality of squares. To accomplish this, a greater
number of body yarns 206 may need to be provided between consecutive rip
stop yarn pairs in the one direction (e.g., warp) as compared to the other
direction (e.g., filling).
FIG. 3 is a schematic detail view of an alternative example rip stop
fabric 300 that can be used in the construction of the protective garment 100.
The fabric 300 is similar to the fabric 200 shown in FIG. 2 and therefore, comprises body yarns 206 that form the body of the fabric and that have
composition and construction similar to those described above with regard to
FIG. 2. In the fabric 300, however, three rip stop yarns 208 are woven through
the fabric together in a grid pattern within the fabric body to form a three-end
rip stop weave (as opposed to the two-end rip stop weave shown in FIG. 2).
With the constructions described above, the fabrics 200, 300 have
weights of about 5 to about 10 ounces per square yard (osy).
As is noted above, unexpected results are achievable with the blends
described herein. More specifically, unexpectedly desirable physical
properties can be attained given the relatively low cost of the fabric, which is
dictated, in substantial part, by the cost of the materials used to produce the
fabric. In several instances, the physical properties of the disclosed blends exceed (i.e., are better than) those of competing fabrics and are substantially
lower in cost than "top-end" outer shell fabrics. A specific example fabric
having a construction within the parameters identified in the foregoing is
described in the following.
Example Fabric
A 60/20/20 blend of KEVLAR ® T-970 (para-aramid), NOMEX ® T-462
(meta-aramid), and ZYLON ® (PBO) was constructed having a fabric weight of
approximately 7.5 osy. The fabric was formed as a two-end rip stop fabric
(see, e.g., FIG. 2) having 56 ends per inch and 51 picks per inch, with 9 ends
provided between each pair of rip stop yarns in the warp direction, and 7 picks
provided between each pair of rip stop yarns in the filling direction. Each of
the yarns in the fabric (i.e., body and rip stop yarns in both directions) comprised two 60/20/20 KEVLAR ® /NOMEX ® /ZYLON ® yarns each having a
yarn count of 21 cc (i.e., 21/2 yarns).
Once constructed, the example fabric was tested to determine its
physical and thermal properties. The results of the testing are provided in
Table I, in which the example fabric is designated as the "Tri-Blend Fabric."
Also included in this table are the test results for other fabrics ("Comparison
Fabrics A and B").
Comparison Fabric A comprised a 60/40 blend of KEVLAR ® T-970
and NOMEX ® T-462 having a fabric weight of approximately 7.2 osy. The
fabric was formed as a three-end rip stop fabric having 56 ends per inch and 51
picks per inch, with 8 ends provided between each group of three rip stop
yarns in the warp direction, and 8 picks provided between each group of three
rip stop yarns in the filling direction. Each of the yarns in the fabric (i.e., body
and rip stop yarns in both directions) comprised two 60/40
KEVLAR ® /NOMEX ® yarns each having a yarn count of 21 cc (i.e., 21/2
yarns).
Comparison Fabric B comprised a 60/40 blend of KEVLAR ® T-970 and PBI having a fabric weight of approximately 7.5 osy. The fabric was
formed as a two-end rip stop fabric having 44 ends per inch and 39 picks per
inch, with 9 ends provided between each pair of rip stop yarns in the warp
direction, and 7 picks provided between each pair of rip stop yarns in the
filling direction. Each of the yarns in the fabric (i.e., body and rip stop yarns
in both directions) comprised two 60/40 KEVLAR ® /PBI yarns each having a
yarn count of 15 cc (i.e., 15/2 yarns).
As is indicated in Table I, the example fabric and the comparison fabrics were tested for strength, thermal resistance, and abrasion resistance, hi
terms of strength, the trap tear strength of the fabrics was tested according to
test method ASTM D5733, as is required by NFPA 1971, 2000 edition
(hereafter "NFPA 1971"), both before and after 5 washing cycles, hi addition,
the fabrics were separately tested for tensile strength according to test method
ASTM D5034 prior to washing and thermal exposure, after 10 washing cycles,
and after thermal exposure. hi terms of thermal resistance, the fabrics were exposed to extreme
temperatures for seven (7) seconds in accordance with the thermal protective
performance (TPP) test method described in NFPA 1971, and were tested for
vertical flame in accordance with Federal Test Method 191 A as is required by
NFPA 1971.
Finally, the fabrics were tested for abrasion resistance using the Taber
Abrasion Test in accordance with ASTM3884.
TABLE T
As is evident from Table I, the example fabric ("Tri-Blend Fabric")
performed markedly better in terms of both trap tear strength and tensile
strength than Comparison Fabrics A and B. Although improved performance
could be expected over Comparison Fabric A due to the presence of the PBO
fiber in the Tri-Blend Fabric, the magnitude of the strength increases resulting
from only 20% PBO fiber is particularly surprising. For instance, the tensile
strength of the Tri-Blend Fabric tested to be as much as over 250% greater
than that of Comparison Fabric A.
Equally or even more surprising is the strength that the Tri-Blend
fabric exhibited after 7 seconds of TTP exposure as compared to Comparison
Fabric B. As is evident from the table, the Tri-Blend fabric was approximately
twice as strong as Comparison Fabric B after such exposure. This strength
difference was unexpected at least in part because Comparison Fabric B
contained a significant amount of PBI, which is generally regarded as much
more resistant to thermal exposure than less expensive materials, such as the meta-aramid of the Tri-Blend fabric.
In addition, marked improvement in abrasion resistance was observed
for the Tri-Blend Fabric. As is indicated in Table I, the Tri-Blend Fabric exhibited an abrasion resistance that is nearly three times that of Comparison
Fabrics A and B.
Notably, the above-described high strength and abrasion resistance is
achievable with a fabric that is significantly cheaper to produce than many
high-end fabrics, such as Comparison Fabric B, which comprises relatively
costly PBI fiber. Therefore, a high-strength, abrasion-resistant, and flame resistant fabric can be produced at a relatively low cost.
While particular embodiments of fabrics have been disclosed in detail in
the foregoing description and drawings for purposes of example, it will be
understood by those skilled in the art that variations and modifications thereof
can be made without departing from the scope of the disclosure.
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