Title:
CALIXARENE POROUS POLYMER WITH ULTRA-HIGH REMOVAL RATE AND ULTRA-HIGH ADSORPTION CAPACITY AND APPLICATION THEREOF IN SELECTIVE SEPARATION OF DYES
Document Type and Number:
WIPO Patent Application WO/2023/092608
Kind Code:
A1
Abstract:
Disclosed in the present invention are a calixarene porous polymer with a ultra-high removal rate and a ultra-high adsorption capacity and an application thereof in the selective separation of dyes. According to the present invention, octafluoronaphthalene and decafluorobiphenyl are used as cross-linking agents, and two calixarene-based porous polymers, namely, POP-8F and POP-10F, are synthesized by means of a simple and mild reaction without using a catalyst. The two polymers show an extraordinary adsorption capacity and adsorption rate on cationic dyes including Rhodamine B (RhB), Methylene Blue (MB) and Crystal Violet (CV), which exceed those of all previously reported porous adsorbents, including COFs, MOFs, POPs, a biomass adsorbent, activated carbon, etc. More importantly, the calixarene-based POPs can effectively remove cationic dyes by means of simple column filtration, and shows excellent reusability. Because of the characteristics, the POP-8F and the POP-10F become porous adsorption materials which can be used for treating and purifying water pollutants.
Inventors:
LU JIANMEI (CN)
XU QINGFENG (CN)
XU QINGFENG (CN)
Application Number:
PCT/CN2021/134169
Publication Date:
June 01, 2023
Filing Date:
November 29, 2021
Export Citation:
Assignee:
UNIV SOOCHOW (CN)
International Classes:
B01J20/26; C08G8/36; B01J20/28; B01J20/30; C02F1/28; C08G8/04
Foreign References:
| CN114085345A | 2022-02-25 | |||
| US20190015814A1 | 2019-01-17 | |||
| JP2009173625A | 2009-08-06 | |||
| CN102880003A | 2013-01-16 |
Other References:
SHETTY DINESH, JAHOVIĆ ILMA, SKORJANC TINA, ERKAL TURAN SELMAN, ALI LIAQAT, RAYA JESUS, ASFARI ZOUHAIR, OLSON MARK A., KIRMIZIALTI: "Rapid and Efficient Removal of Perfluorooctanoic Acid from Water with Fluorine-Rich Calixarene-Based Porous Polymers", APPLIED MATERIALS & INTERFACES, AMERICAN CHEMICAL SOCIETY, US, vol. 12, no. 38, 23 September 2020 (2020-09-23), US , pages 43160 - 43166, XP093069250, ISSN: 1944-8244, DOI: 10.1021/acsami.0c13400
DENG, WENXIU ET AL.: "Synthesis of Calixarene-Based Porous Organic Framework(CalixPOF) in situ Solvent-Assisted Friedel-Crafts Coupling and Their Dye Adsorption Properties", JOURNAL OF FUNCTIONAL POLYMERS, vol. 30, no. 01, 30 March 2017 (2017-03-30), XP009546706
CHEN YANLI; FANG YISHAN; YU JINGKUN; GAO WENQIANG; ZHAO HUIJUAN; ZHANG XIAOMEI: "A silsesquioxane-porphyrin-based porous organic polymer as a highly efficient and recyclable absorbent for wastewater treatment", JOURNAL OF HAZARDOUS MATERIALS, ELSEVIER, AMSTERDAM, NL, vol. 406, 5 December 2020 (2020-12-05), AMSTERDAM, NL , XP086469503, ISSN: 0304-3894, DOI: 10.1016/j.jhazmat.2020.124769
GE, YUN ET AL.: "Alkylation and Amidation of Tetra(hydroxyphenyl)calix[4]resorcine", CHINESE JOURNAL OF ORGANIC CHEMISTRY, no. 05, 25 May 2006 (2006-05-25), XP009546707
DENG, WENXIU ET AL.: "Synthesis of Calixarene-Based Porous Organic Framework(CalixPOF) in situ Solvent-Assisted Friedel-Crafts Coupling and Their Dye Adsorption Properties", JOURNAL OF FUNCTIONAL POLYMERS, vol. 30, no. 01, 30 March 2017 (2017-03-30), XP009546706
CHEN YANLI; FANG YISHAN; YU JINGKUN; GAO WENQIANG; ZHAO HUIJUAN; ZHANG XIAOMEI: "A silsesquioxane-porphyrin-based porous organic polymer as a highly efficient and recyclable absorbent for wastewater treatment", JOURNAL OF HAZARDOUS MATERIALS, ELSEVIER, AMSTERDAM, NL, vol. 406, 5 December 2020 (2020-12-05), AMSTERDAM, NL , XP086469503, ISSN: 0304-3894, DOI: 10.1016/j.jhazmat.2020.124769
GE, YUN ET AL.: "Alkylation and Amidation of Tetra(hydroxyphenyl)calix[4]resorcine", CHINESE JOURNAL OF ORGANIC CHEMISTRY, no. 05, 25 May 2006 (2006-05-25), XP009546707
Attorney, Agent or Firm:
SUZHOU CREATOR PATENT AND TRADEMARK AGENCY, LTD. (CN)
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