Title:
CARBON FIBER COATED WITH SIZING AGENT, PROCESS FOR PRODUCING CARBON FIBER COATED WITH SIZING AGENT, PREPREG, AND CARBON FIBER REINFORCED COMPOSITE MATERIAL
Document Type and Number:
WIPO Patent Application WO/2013/099707
Kind Code:
A1
Abstract:
A carbon fiber coated with a sizing agent is provided. This carbon fiber exhibits excellent adhesion to a matrix resin, ensures excellent stability of composite physical properties of a prepreg even after long-term storage, and is excellent in high-order processability. A process for producing the carbon fiber coated with a sizing agent, a prepreg, and a carbon fiber reinforced composite material are also provided. A carbon fiber coated with a sizing agent which comprises (A) an aliphatic epoxy compound and (B) an aromatic compound that contains (B1) an aromatic epoxy compound as the essential component, characterized in that the (a)/(b) ratio is 0.50 to 0.90 wherein (a) is the height (cps) of the peak at a binding energy of 284.6eV assignable to CHx, C-C and C=C in the C1S core spectrum as determined by subjecting the surface of the sizing agent to X-ray photoelectron spectroscopy using AlKα1.2 as the X-ray source at a photoelectron emission angel of 15°, and (b) is the height (cps) of the peak at a binding energy of 286.1eV assignable to C-O therein.
Inventors:
ICHIKAWA TOMOKO (JP)
ENDO MAKOTO (JP)
TAIKO HIROSHI (JP)
KOBAYASHI MASANOBU (JP)
ARAI NOBUYUKI (JP)
MISUMI JUN (JP)
ENDO MAKOTO (JP)
TAIKO HIROSHI (JP)
KOBAYASHI MASANOBU (JP)
ARAI NOBUYUKI (JP)
MISUMI JUN (JP)
Application Number:
PCT/JP2012/082823
Publication Date:
July 04, 2013
Filing Date:
December 18, 2012
Export Citation:
Assignee:
TORAY INDUSTRIES (JP)
International Classes:
D06M13/11; D06M15/55; D06M101/40
Domestic Patent References:
WO2005082982A1 | 2005-09-09 | |||
WO2003010383A1 | 2003-02-06 | |||
WO2003010383A1 | 2003-02-06 |
Foreign References:
JP2005213687A | 2005-08-11 | |||
JP2005179826A | 2005-07-07 | |||
JP2005256226A | 2005-09-22 | |||
JPH02307979A | 1990-12-21 | |||
JPH04361619A | 1992-12-15 | |||
US3957716A | 1976-05-18 | |||
JPS57171767A | 1982-10-22 | |||
JPS6314114B2 | 1988-03-29 | |||
JPH07279040A | 1995-10-24 | |||
JPH08113876A | 1996-05-07 | |||
JPS57128266A | 1982-08-09 | |||
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JPS6233872A | 1987-02-13 | |||
JPH079444A | 1995-01-13 | |||
JP2000336577A | 2000-12-05 | |||
JPS6128074A | 1986-02-07 | |||
JPH01272867A | 1989-10-31 | |||
JP2005179828A | 2005-07-07 | |||
JP2005256226A | 2005-09-22 | |||
JP2008280624A | 2008-11-20 | |||
JP2005213687A | 2005-08-11 | |||
JP2002309487A | 2002-10-23 | |||
JPH02307979A | 1990-12-21 | |||
JP2002173873A | 2002-06-21 | |||
JPS5971479A | 1984-04-23 | |||
JPS5841973A | 1983-03-11 |
Other References:
See also references of EP 2799616A4
Attorney, Agent or Firm:
SAKAI, HIROAKI (JP)
Hiroaki Sakai (JP)
Hiroaki Sakai (JP)
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Claims:
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