TITLE: CARBON FIBRE COMPOSITIONS COMPRISING LIGNIN DERIVATIVES

This disclosure relates to derivatives of native lignin recovered from lignocellulosic feedstocks, and applications thereof. More particularly, this disclosure relates to compositions, uses, processes and methods utilizing derivatives of native lignin.

BACKGROUND

Native lignin is a naturally occurring amorphous complex cross-linked organic macromolecule that comprises an integral component of all plant biomass. The chemical structure of lignin is irregular in the sense that different structural units (e.g., phenylpropane units) are not linked to each other in any systematic order. It is known that native lignin comprises pluralities of two monolignol monomers that are methoxylated to various degrees (trans-coniferyl alcohol and trans-sinapyl alcohol) and a third non-methoxylated monolignol (trans-p-coumaryl alcohol). Various combinations of these monolignols comprise three building blocks of phenylpropanoid structures i.e. guaiacyl monolignol, syringyl monolignol and p- hydroxyphenyl monolignol, respectively, that are polymerized via specific linkages to form the native lignin macromolecule.

Extracting native lignin from lignocellulosic biomass during pulping generally results in lignin fragmentation into numerous mixtures of irregular components. Furthermore, the lignin fragments may react with any chemicals employed in the pulping process. Consequendy, the generated lignin fractions can be referred to as lignin derivatives and/or technical lignins. As it is difficult to elucidate and characterize such complex mixture of molecules, lignin derivatives are usually described in terms of the Kgnocellulosic plant material used, and the methods by which they are generated and recovered from lignocellulosic plant material, i.e. hardwood Ugnins, softwood lignins, and annual fibre Hgnins.

Native lignins are partially depolymerized during the pulping processes into lignin fragments which are soluble in the pulping liquors and subsequentiy separated from the cellulosic pulps. Post-pulping liquors containing lignin and polysaccharide fragments, and extractives, are commonly referred to as "black liquors" or "spent liquors", depending on the pulping process. Such liquors are generally considered a by-product, and it is common practice to combust them to recover some energy value in addition to recovering the cooking chemicals. However, it is also possible to precipitate and/ or recover Ugnin derivatives from these liquors. Each type of pulping process used to separate cellulosic pulps from other lignocellulosic components produces lignin derivatives that ate very different in their physico-chemical, biochemical, and structural properties.

Given that lignin derivatives are available from renewable biomass sources there is an interest in using these derivatives in certain industrial processes. For example, US5,173,527 proposes using lignin-cellulosic materials in phenol-formaldehyde resins. A. Gregorova et al. propose using lignin in polypropylene for it radical scavenging properties (A. Gregorova et al., Radical scavenging capacity of lignin and its effect on processing stabilization of virgin and recycled polypropylene, Journal of Applied Polymer Science 106-3 (2007) pp. 1626-1631). However, large-scale commercial application of the extracted lignin derivatives, particularly those isolated in traditional pulping processes employed in the manufacture of pulp and paper, has been limited due to, for example, the inconsistency of their chemical and functional properties. This inconsistency may, for example, be due to changes in feedstock supplies and the particular extraction/generation/recovery conditions. These issues are further complicated by the complexity of the molecular structures of lignin derivatives produced by the various extraction methods and the difficulty in performing reliable routine analyses of the structural conformity and integrity of recovered lignin derivatives.

Carbon fibres are known to have certain mechanical and physio-chemical properties that make them useful in many applications. For example, carbon fibres may have high tensile strength, low density, low weight, and/or low thermal expansion. Individual strands of carbon fibres can be twisted together to form a yarn that can be used by itself or woven into fabrics. Carbon fibre yarns can also be combined with plastic resins that can be wound or molded to form composite materials such as carbon fibre -reinforced plastics. However, while carbon fibre- containing composites may have certain advantages over similarly sized steel materials, ^' they are usually much more costly because of the high cost of manufacturing carbon fibres.

Carbon fibres are generally manufactured by carbonization of polymerized acrylonitrile (polyacrylonitrile). Polyacrylonitrile is converted to carbon fibres with a multistep process wherein the first step is heating the polyacrylonitrile to 300° C to break the hydrogen bonds and add oxygen molecules thereby creating a fireproof and stable material. This new material is then carbonized by heating to between 1 ,500° C and 3,000° C in an inert gas resulting in a material that comprises almost 100% carbon. The carbonized material is then surface-treated and sized with an epoxy resin to protect the carbon fibre. Different grades of carbon fibre can be produced by selection of the temperatures for carbonization. For example, carbon fibres that have very high tensile strengths are formed at temperatures between 1,500° C to 2,000° C degrees, Carbon fibres with high modulus (i.e., more elasticity) are produced by carbonization at higher temperatures, e.g., up to 3,000° C.

Lignin derivatives recovered from kraft pulping processes (i.e., commercial kraft lignins) and from organosolv processes have been evaluated for production of low-cost carbon fibre that may be used to partially or completely replace carbon fibres produced from polyacrylonitrile. For example, US3,461,082 proposed a method for producing a carbonized lignin fiber from alkali- lignins, thiolignins, or ligninsulfonates. J.F. Kadla et al. proposed using commercial kraft lignin for production of carbon fibres (J.F. Kadla et al., 2002, Lignin-based carbon fibers for composite fiber applications, Carbon 36: 1119-1124). S. Kubo et al. proposed using acetic acid organosolv lignin for production of carbon fibres (S. Kubo et al., 1998, Preparation of Carbon Fibers from Softwood Lignin by Atmospheric Acetic Acid Pulping, Carbon 36: 1119-1 24). Unfortunately, in each of these systems, production costs have not significantly decreased because of the purification steps required to remove volatiles, ash and particulates. Furthermore, purified lignins required the addition of co-polymers and plasticizers to form carbon fibres. S. Kubo et al. proposed using Alcell ^® organosolv lignin for production of carbon fibres (S. Kubo et al., 2004, Poly(Ethylene Oxide) /Organosolv Lignin Blends: Relationship Between Thermal Properties, Chemical Structures, and Blend Behaviour, Macromolecules 37: 6904-6911). However, they found that while a small amount of Alcell ^® lignin increased the crystallinity of poly(ethylene oxide), incorporating more than 25% Alcell ^® lignin hindered crystallinity and crystalline domain size. Other investigators have suggested using lignin derivatives in carbon fibre compositions. See, for example, US6,765,028; WO2009/028969; US7.678.358; US5.344.921; US2010/0311943.

SUMMARY

The present disclosure provides derivatives of native lignin suitable for production of carbon fibres wherein the derivatives of native lignin have a certain alkoxy content and/or a certain carbon content. The present lignin derivatives can have acceptable spinnability performance characteristics for producing carbon fibres having acceptable tensile strengths and acceptable modulus of elasticity.

BRIEF DESCRIPTION OF THE DRAWINGS

Figure 1 shows the HSQC spectrum of non-acetylated hardwood lignin derivatives (arrows indicate the signals corresponding to the efhoxyl groups).

Figure 2 shows the quantitative "C NMR spectrum of non-acetylated hardwood lignin derivatives. Figure 3 shows the quantitative ¹ C NMR spectrum of acetylated hardwood lignin derivatives.

Figure 4 shows a flow-chart of the key stages of manufacturing a carbon fibre.

DETAILED DESCRIPTION

The present disclosure provides derivatives of native lignin having certain alkoxy contents, and/ or certain carbon contents. While not wishing to be bound by theory, it is believed that lignin derivatives having higher alkoxy contents and/or carbon contents have acceptable spinnability performance for producing carbon fibres and that the resultant fibres can have acceptable tensile strengths and acceptable modulus of elasticity. Thus, selecting for derivatives of native lignin having a higher alkoxy content and/or higher carbon content can result in a product having better performance characteristics.

The derivatives of native lignin of the present disclosure having an alkoxy content of 0.45 mmol/g or greater and/or carbon content of about 64.5% or greater. For example, alkoxy content of about 0.5 mmol/g or greater; about 0.6 mmol/g or greater; about 0.7 mmol/g or greater; about 0.8 mmol/g or greater; about 0.9 mmol/g or greater; about 1 mmol/g or greater; about 1.1 mmol/g or greater; about 1.2 mmol/g or greater. The present lignin derivatives may, for example, have a carbon content of about 65.0% or greater; about 66.0% or greater; about 67.0% or greater; about 68.0% or greater; about 69.0% or greater.

The lignin derivatives may comprise any suitable alkoxy groups such as Q-Q alkoxy groups; C,-C ₄ alkoxy groups; C _r C ₃ alkoxy groups; methoxy and/or ethoxy; ethoxy. The present lignin derivatives may have an ethoxy content of about 0.5 mmol/g or greater; about 0.6 mmol/g or greater; about 0.7 mmol/g or greater; about 0.8 mmol/g or greater; about 0.9 mmol/g or greater; about 1 mmol/g or greater; about 1.1 mmol/g or greater; about 1.2 mmol/g or greater. The present lignin derivatives may, for example, have an ethoxy content of about 3.75 mmol/g or less; 3.5 mmol/g or less; 3.25 mmol/g or less; 3 mmol/g or less; 2.75 mmol/g or less; 2.5 mmol/g or less; 2.25 mmol/g or less; 2 mmol/g or less; 1.9 mmol/g or less; 1.8 mmol/g or less; 1.7 mmol/g or less; 1.6 mmol/g or less; 1.5 mmol/g or less; 1.4 mmol/g or less; 1.3 mmol/g or less.

Quantification of the alkoxy groups can be performed using high resolution ¹ C NMR spectroscopy. For example, quantification of ethoxyl group content can be performed by high resolution ⁿ C NMR spectroscopy. Identification of ethoxyl groups can be confirmed by 2D NMR HSQC spectroscopy. 2D NMR spectra may be recorded by a Bruker 700 MHz UltraShield Plus standard bore magnet spectrometer equipped with a sensitive cryogenically cooled 5mm TCI gradient probe with inverse geometry. The acquisition parameters are as follows: standard Bmker pulse program hsqcetgp, temperature of 298 K, a 90° pulse, 1.1 sec pulse delay (dl), and acquisition time of 60 msec.

Quantification of the carbon (C) contents can be performed by elemental analysis using suitable elemental analysis instruments. For example, samples can be combusted in a pure oxygen environment at 975"C in a Perkin-Elmer 2400 Series Elemental Analyzer to produce CC , Η,Ο, N ₂ , and SO,. Trace elements were removed from this gas mixture in a reduction zone at 500" C. The homogenous gas mixture was taken to exacdy known volume, temperature, and pressure before being passed through a column on which the constituent gases separated followed by thermal conductivity detection.

The present disclosure provides derivatives of native lignin recovered during or after pulping of lignocellulosic biomass feedstocks. The pulp may be from any suitable lignocellulosic feedstock including hardwoods, softwoods, annual fibres, and combinations thereof.

Hardwood feedstocks include Acacia; Afzelia; Synsepalum duloijicum; Albizia; Alder (e.g. Alnus glutinosa, Alnus rubra); Applewood; Arbutus; Ash (e.g. F. nigra, F. quadrangulata, F. excelsior, F. pennsylvanica lanceolata, F. latijolia, F. profunda, F. amemand); Aspen (e.g. P. grandidentata, P. tremula, P. tremuloides); Australian Red Cedar Toona ci/iatd); Ayna [Distemonanthus benthamianus); Balsa (O chroma pyramidale); Basswood (e.g. T. ame ana, T. heterophylld); Beech (e.g. F. sylvatica, F. grandifolid); Birch; (e.g. Betula populijolia, B. nigra, B. papyrifera, B. lenta, B. alleghaniensis/B. lutea, B. pendula, B. pubescens); Blackbean; Blackwood; Bocote; Boxelder; Boxwood; Brazilwood; Bubinga; Buckeye (e.g. Aesculus hippocastanum, Aesculus glabra, Aesculus flava/ Aesculus octandrd); Butternut; Catalpa; Cherry (e.g. Prunus serotina, Prunus pennsylvanica, Prunus avium); Crabwood; Chestnut; Coachwood; Cocobolo; Corkwood; Cottonwood (e.g. Populus balsamifera, Populus deltoides, Populus sargentii, Populus heterophylld); Cucumbertree; Dogwood (e.g. Cornus jhrida, Cornus nuttallii); Ebony (e.g. Diospyros kur^ii, Diospyros elanida, Diospyros crassiflord); Elm (e.g. Ulmus a ericana, Ulmus procera, Ulmus thomasii, Ulmus rubra, Ulmus glabra); Eucalyptus; Greenheart; Grenadilla; Gum (e.g. Nyssa sylvatica, Eucaylptus globulus, Uquidambar styraciflua, Nyssa aquaticd); Hickory (e.g. Gary a alba, Carya glabra, Carya ovata, Carya laciniosd); Hornbeam; Hophornbeam; Ipe; Iroko; Ironwood (e.g. Bangkirai, Carpinus caroliniana, Casuarina equisetifolia, Choricbangarpia subargentea, Copaifera spp., Eusideroxylon ^wagm, Guajacum officinale, Guajacum sanctum, Hopea odorata, Ipe, Krugiodendron ferreum, Fyonothamnus y l onii (L floribundus), Mesua ferrea, Olea spp., Olneya tesota, Ostrya virginiana, Parrotia persica, Tabebuia serratijolia); Jacaranda; Jotoba; Lacewood; Laurel; Limba; Lignum vitae; Locust (e.g. Robinia pseudacacia, Gkditsia tnacantbos); Mahogany; Maple (e.g. Acer saccharum, Acer nigrum, Acer negundo, Acer rubrum, Acer saccharinum, Acer ^■ pseudoplatanus); Meranti; Mpingo; Oak (e.g. Ouercus macrocarpa, Oitercus alba, Ouercus stellata, Ouercus bicolor, Quercus virginiana, Querc s michauxii, Ouercus prinus, Ouercus muhlenbergii, Ouercus chtysolepis, Ouercus lyrata, Ouercus robur, Quercus petraea, Quercus rubra, Quercus velutina, Quercus laurifolia, Ouercus Jalcata, Quercus nigra, Quercus phellos, Ouercus texana); Obeche; Okoume; Oregon Myrtle; California Bay Laurel; Pear; Poplar (e.g. P. balsamifera, P. nigra, Hybrid Poplar {Populus x canadensis^); Ramin; Red cedar; Rosewood; Sal; Sandalwood; Sassafras; Satinwood; Silky Oak; Silver Wattle; Snakewood; Sourwood; Spanish cedar; American sycamore; Teak; Walnut (e.g. Juglans nigra, Jug/ans regi ); Willow (e.g. Salix nigra, Salix alba); Yellow poplar (Liriodendron tulipiferd); Bamboo; Palmwood; and combinations /hybrids thereof.

For example, hardwood feedstocks for the present invention may be selected from acacia, aspen, beech, eucalyptus, maple, birch, gum, oak, poplar, and combinations/hybrids thereof. The hardwood feedstocks for the present invention may be selected from Populus spp. (e.g. Populus tremuloides), Eucalyptus spp. (e.g. Eucalyptus globulus), Acacia spp. (e.g. Acacia dealbata), and combinations/hybrids thereof.

The present disclosure provides kgnin derivatives from hardwood biomass wherein the derivatives have an ethoxy content, of from 0.45 mmol/g to about 1.4 mmol/g; about 0.5 mmol/g to about 1.3 mmol/g; about 0.6 mmol/g to about 1.2 mmol/g; and/ or a carbon content from about 67.5% to about 75.5%; from about 68.0% to about 72.5%.

Softwood feedstocks include Araucaria (e.g. A. cunninghamii, A. angustifolia, A. araucana); softwood Cedar (e.g. Juniperus virginiana, Thuja plicata, Thuja occidentalis, Chamaecyparis thyoides Callitropsis nootkatensis); Cypress (e.g. Chamaecyparis, Cupressus Taxodium, Cupressus Taxodium distichum, Chamaecyparis obtusa, Chamaecyparis lawsoniana, Cupressus semperviren); Rocky Mountain Douglas fir; European Yew; Fir (e.g. Abies balsamea, Abies alba, Abies procera, Abies amabilis); Hemlock (e.g. Tsuga canadensis, Tsuga mertensiana, Tsuga heierophylld); Kauri; Kaya; Larch (e.g. Larix decidua, Tarix kaempferi, Larix laricina, Larix occidentalis); Pine (e.g. Pinus nigra, Pinus banksiana, Pinus contorta, Pinus radiata, Pinus ponderosa, Pinus resinosa, Pinus sylvestris, Pinus strobus, Pinus monticola, Pinus lambertiana, Pinus taeda, Pinus palustris, Pinus rigida, Pinus echinata); Redwood; Rimu; Spruce (e.g. Picea abies, Picea mariana, Picea rubens, Picea sitchensis, Picea glauca); Sugi; and combinations /hybrids thereof.

For example, softwood feedstocks which may be used herein include cedar; fir; pine; spruce; and combinations thereof. The softwood feedstocks for the present invention may be selected from loblolly pine Pinus taeda), radiata pine, jack pine, spruce (e.g., white, interior, black), Douglas fir, Pinus silvestris, Picea abies, and combinations /hybrids thereof. The softwood feedstocks for the present invention may be selected from pine (e.g. Pinus radiata, Pinus taeda); spruce; and combinations/hybrids thereof. The present disclosure provides lignin derivatives from softwood biomass wherein the derivatives have an ethoxy content, of from about 0.35 mmol/g to about 1.4 mmol/g; about 0.45 mmol/g to about 1.3 mmol/g; about 0.5 mmol/g to about 1.2 mmol/g; about 0.6 mmol/g to about 1.1 mmol/g; and/or a carbon content from 66.5% to about 80.0%; from about 67.0% to about 75.5%; from about 67.5% to about 73.5%).

Annual fibre feedstocks include biomass derived from annual plants, plants which complete their growth in one growing season and therefore must be planted yearly. Examples of annual fibres include: flax, cereal straw (wheat, barley, oats), sugarcane bagasse, rice straw, corn stover, com cobs, hemp, fruit pulp, alfa grass, switchgrass, and combinations/hybrids thereof. Industrial residues like corn cobs, corn fibre, distillers' dried grains (DDGs), fruit peals, seeds, etc. may also be considered annual fibres since they are commonly derived from annual fibre biomass such as edible crops and fruits. For example, the annual fibre feedstock may be selected from wheat straw, corn stover, corn cobs, sugar cane bagasse, and combinations/hybrids thereof.

The present disclosure provides hgnin derivatives from annual fibre biomass wherein the derivatives have an alkoxy content, such as ethoxy content, of from about 0.25 mmol/ g to about 1.4 mmol/g; about 0.35 mmol/g to about 1.3 mmol/g; about 0.45 mmol/g to about 1.2 mmol/g; about 0.5 mmol/g to about 1.1 mmol/g; and/or a carbon content from 64.5% to about 75.5%; from about 65.0% to about 72.5%; from about 65.5% to about 70.5%.

The derivatives of native lignin will vary with the type of process used to separate native lignins from cellulose and other biomass constituents. Any suitable process may be used herein but it should be noted that kraft pulping, sulphite pulping, and ASAM organosolv pulping will generate derivatives of native lignin containing significant amounts of organically-bound sulphur which may make them unsuitable for certain uses.

Organosolv processes, such as the Alcell® process, can be used to separate highly purified lignin derivatives and other useful materials from biomass without excessively altering or damaging the native lignin building blocks. Such processes can, therefore, be used to maximize the value from all the components making up the biomass.

A description of the Alcell® process can be found in US Patent 4,764,596 (herein incorporated by reference). The process generally comprises pulping or pre-treating a fibrous biomass feedstock with primarily an ethanol/water solvent solution under conditions that include: (a) 60% ethanol/40% water, (b) temperature of about 180° C to about 210° C, (c) pressure of about 20 atm to about 35 atm, and (d) a processing time of 5-120 minutes. Derivatives of native lignin are fractionated from the native lignins into the pulping liquor which also receives solubilised hemicelluloses, other carbohydrates and other extractives such as resins, organic acids, phenols, and tannins. Organosolv pulping liquors comprising the fractionated derivatives of native lignin and other extractives from the fibrous biomass feedstocks, are often called "black liquors". The organic acid and extractives released by organosolv pulping significantly acidify the black liquors to pH levels of about 5 and lower. After separation from the cellulosic pulps produced during the pulping process, the derivatives of native lignin are recovered from the black liquors by depressurization followed by flashing with cold water which will cause the fractionated derivatives of native lignin to precipitate thereby enabling their recovery by standard solids/liquids separation processes. Various disclosures exemplified by US Patent No. 7,465,791 and PCT Patent Application Publication No. WO 2007/129921, describe modifications to the Alcell organosolv process for the purposes of increasing the yields of fractionated derivatives of native lignin recovered from fibrous biomass feedstocks during biorefining. Modifications to the Alcell organosolv process conditions included adjusting: (a) ethanol concentration in the pulping liquor to a value selected from a range of 35% - 85% (w/w) ethanol, (b) temperature to a value selected from a range of 100° C to 350° C, (c) pressure to a value selected from a range of 5 atm to 35 atm, and (d) processing time to a duration from a range of 20 minutes to about 2 hours or longer, (e) liquor-to-wood ratio of 3:1 to 15:1 or higher, (f) pH of the cooking liquor from a range of 1 to 6.5 or higher if a basic catalyst is used.

The present disclosure provides a process for producing derivatives of native lignin, said process comprising:

(a) pulping a fibrous biomass feedstock with an organic solvent/water solution,

(b) separating the cellulosic pulps or pre-treated substrates from the pulping liquor or pre-treatment solution,

(c) recovering derivatives of native lignin.

The organic solvent may be selected from short chain primary and secondary alcohols, such as such as methanol, ethanol, propanol, and combinations thereof. For example, the solvent may be ethanol. The liquor solution may comprise about 20%, by weight, or greater, about 30% or greater, about 50% or greater, about 60% or greater, about 70% or greater, of ethanol.

Step (a) of the process may be carried out at a temperature of from about 100°C and greater, or about 120°C and greater, or about 140°C and greater, or about 160°C and greater, or about 170°C and greater, or about 180°C and greater. The process may be carried out at a temperature of from about 300°C and less, or about 280°C and less, or about 260°C and less, or about 240°C and less, or about 220°C and less, or about 210°C and less, or about 205°C and less, or about 200°C and less. Step (a) of the process may be carried out at a pressure of about 5 atm and greater, or about 10 atm and greater, or about 15 atm and greater, or about 20 atm and greater, or about 25 atm and greater, or about 30 atm and greater. The process may be carried out at a pressure of about 150 atm and less, or about 125 atm and less, or about 115 atm and less, or about 100 atm and less, or about 90 atm and less, or about 80 atm and less.

The fibrous biomass may be treated with the solvent solution of step (a) for about 1 minute or more, about 5 minutes or more, about 10 minutes or more, about 15 minutes or more, about 30 minutes or more. The fibrous biomass may be treated with the solvent solution of step (a) at its operating temperature for about 360 minutes or less, about 300 minutes or less, about 240 minutes or less, about 180 minutes or less, about 120 minutes or less.

The pH of the pulp liquor may, for example, be from about 1 to about 6, or from about 1.5 to about 5.5.

The present disclosure provides a process for producing a lignin derivative having an alkoxy content of 0.45 mmol/g or greater and/or a carbon content of 64.5% or greater, said process comprising:

a) pulping or pre-treating a fibrous biomass feedstock in a vessel with an organic solvent/ water solvent solution to form a liquor, wherein:

i. the solution comprises about 30% or greater, by weight, of organic solvent; and

ii. the pH of the liquor is from about 1 to about 6;

b) heating the liquor to about 100°C or greater;

c) maintaining the elevated temperature for 1 minute or longer;

d) separating the cellulosic pulps from the pulp liquor

e) recovering derivatives of native lignin.

The present disclosure provides a process for producing a hardwood lignin derivative having an alkoxy content of 0.45 mmol/g or greater result, said process comprising:

a) pulping or pre-treating a fibrous feedstock comprising hardwood biomass in a vessel with an organic solvent/ water solvent solution to form a liquor, wherein:

i. the solution comprises about 30% or greater, by weight, of organic solvent; and

ii. the pH of the liquor is from about 1 to about 6;

b) heating the liquor to about 100°C or greater;

c) mamtaining the elevated temperature for 1 minute or longer;

d) separating the cellulosic pulps from the pulp liquor e) recovering derivatives of native lig in.

The present disclosure provides a process for producing a softwood lignin derivative having an alkoxy content of 0.35 mmol/g or greater result, said process comprising:

a) pulping or pre-treating a fibrous feedstock comprising softwood biomass in a vessel with an organic solvent/water solvent solution to form a liquor, wherein:

i. the solution comprises about 30% or greater, by weight, of organic solvent; and

ii. the pH of the liquor is from about 1 to about 6;

b) heating the liquor to about 100°C or greater;

c) maintaining the elevated temperature for 1 minute or longer;

d) separating the cellulosic pulps from the pulp liquor

e) recovering derivatives of native Hgnin.

The present disclosure provides a process for producing an annual fibre lignin derivative having an alkoxy content of 0.25 mmol/g or greater result, said process comprising:

a) pulping or pre-treating a fibrous feedstock comprising annual fibre biomass in a vessel with an organic solvent/ ater solvent solution to form a liquor, wherein:

i. the solution comprises about 30% or greater, by weight, of organic solvent; and

ii. the pH of the liquor is from about 1 to about 5.5;

b) heating the liquor to about 100°C or greater;

c) maintaining the elevated temperature and pressure for 1 minute or longer;

d) separating the cellulosic pulps from the pulp liquor

e) recovering derivatives of native lignin.

The derivatives of native lignin herein may be incorporated into carbon fibres. A flow chart of one embodiment of a method for producing carbon fibre with the present derivatives is shown in figure 4.

Lignin samples may be placed into suitable thermal mixing extruders equipped with spinnerets. An exemplary suitable spinneret is a 1 /32 inch spinneret. Such equipment typically has maximum winding rates of about 74 m*min ¹ at temperatures from the range of about 130° C to about 300° C. Other suitable equipment for spinning lignin into fibres are exemplified by fusion spinning machines with mono-hole nozzles. Such equipment when provided with nozzles having 0.30 mm apertures typically have winding rates of about 140-250 m*min ' at temperatures from the range of about 130° C to about 300° C. Fibres thus produced from the derivatives of native lignin of the present disclosure may be stabilized prior to carbonization. A suitable stabilization method is to gradually heat the fibres to 250° C and then holding them at this temperature for a period of time. The thermostabilized fibres my then be carbonized in an inert atmosphere at a temperature from the range of about 1000° C to about 3000° C.

The derivatives of native lignin may be blended with polyacrylonitrile or other compatible polymers prior to extrusion of fibres. The lignin derivatives may comprise about 25% of the blend or greater; about 30% or greater; about 35% or greater; about 40% or greater; about 45% or greater; about 50% or greater. The fibres comprising a blend of polyacrylonitrile or other compatible polymers and the lignin derivatives, can then be thermostabilized and carbonized.

Carbon fibres comprising the derivatives of native lignin of the present disclosure or a blend of polyacrylonitrile or other compatible polymers and the lignin derivatives of the present disclosure may be used to reinforce composite materials comprising polymers. They may also be used to reinforce non-polymer materials. The fibres may also be woven into fabrics and textiles.

It is contemplated that any embodiment discussed in this specification can be implemented or combined with respect to any other embodiment, method, composition or aspect of the invention, and vice versa.

Unless defined otherwise, all technical and scientific terms used herein have the same meaning as is commonly understood by one of ordinary skill in the art to which this invention belongs. Unless otherwise specified, all patents, applications, published applications and other publications referred to herein are incorporated by reference in their entirety. If a definition set forth in this section is contrary to or otherwise inconsistent with a definition set forth in the patents, applications, published applications and other publications that are herein incorporated by reference, the definition set forth in this section prevails over the definition that is incorporated herein by reference. Citation of references herein is not to be construed nor considered as an admission that such references are prior art to the present invention.

Use of examples in the specification, including examples of terms, is for illustrative purposes only and is not intended to limit the scope and meaning of the embodiments of the invention herein. Numeric ranges are inclusive of the numbers defining the range. In the specification, the word "comprising" is used as an open-ended term, substantially equivalent to the phrase "including, but not limited to," and the word "comprises" has a corresponding meaning.

The invention includes all embodiments, modifications and variations substantially as hereinbefore described and with reference to the examples and figures. It will be apparent to persons skilled in the art that a number of variations and modifications can be made without departing from the scope of the invention as defined in the claims. Examples of such modifications include the substitution of known equivalents for any aspect of the invention in order to achieve the same result in substantially the same way.

The present invention will be further illustrated in the following examples. However it is to be understood that these examples are for illustrative purposes only, and should not be used to limit the scope of the present invention in any manner.

EXAMPLES

EXAMPLE 1: Recovery of lignin derivatives from hardwood feedstocks

Hardwood feedstock chips were prepared from: (1) aspen (P. tremuloides) grown in British Columbia, Canada; (2) acacia (A. dealbatd) grown in Chile; and (3) eucalyptus (E. nitens) grown in Chile. Three samples of each feedstock where were individually pulped using an acid-cataly2ed ethanol organosolv pulping process wherein a different set of pulping conditions was used for each sample (Tables 1 , 2 and 3).

Table 1: Pulping conditions for aspen wood chip samples at 6:1 liquor-to-wood ratio.

Sample Time Temperature Ethanol OEt Carbon

_P H

# min "C % mmol/g %

1 2.26 63 190 47 0.59 68.33

2 2.06 27 193 51 0.61 69.64

2 2.03 104 197 68 0.69 71.14

Table 2: Pulping conditions for acacia wood chip samples at 6:1 liquor-to-wood ratio,

Sample Time Temperature Ethanol OEt Carbon

pH

# min "C % mmol/g %

4 2.1 1 114 195 43 0.45 68.16

5 2.00 67 194 58 0.67 68.21

6 2.01 104 197 68 0.76 69.35

Table 3: Pulping conditions for eucalyptus wood chip samples at 6:1 liquor-to-wood :

Sample Time Temperature Ethanol OEt Carbon

pH

# min "C % mmol/g %

7 2.01 65 196 60 0.65 68.13

8 1.88 104 197 68 0.64 69.00

For each wood chips sample, the ethanol pulping solvent was prepared to the specified concentration by first, partially diluting the ethanol with water after which, a suitable amount of sulphuric acid was added to achieve the target final acidity. Finally, the ethanol solution was further diluted with water to achieve the target ethanol concentration.

The original lignin content of each fibrous biomass subsample was determined using the methods described in National Renewable Energy Laboratory (NREL) Technical Report entitled 'TJetermination of Structural Carbohydrates and Lignin in Biomass" - Laboratory Analytical Procedure (TP-510-42618 (25 April 2008)). Then, after adding the fibrous biomass sample to a pressure vessel (2L or 7 L Parr reactor (Parr Instrument Company, Moline, IL, USA)) (100-700 g odw chips), the pH-adjusted ethanol-based pulping solvent was added to the vessel at a 6:1 liquor:wood ratio. The vessel was then pressurized and brought up to the target temperature listed in Tables 1-3 (aspen, acacia, eucalyptus, respectively). The biomass sample was then "cooked" for the specified period of time, after which, the pulping process was stopped. After pulping, the contents of the pressure vessel were transferred to a hydraulic 20 ton manual shop press (Airco, China). The liquor was separated from the solids by first squeezing the pulped materials in the press to express the liquor. The expressed liquor was then filtered through a coarse silk screen to separate expressed chip residues from liquor stream. Next, fine particles were separated out from the liquor stream by filtration through fine filter paper (Whatman N" 1). The recovered fine particles represent lignin derivatives that were extracted and self-precipitated out from the liquor during cooling of the pulped biomass. The particulate lignin is herein referred to as self-precipitated lignin derivatives (i.e., "SPL"). The solubilized lignin derivatives still remaining in the filtered liquor were precipitated from by dilution with cold water. The Ugnin derivatives precipitated by dilution with cold water are referred to as precipitated lignin or "PL". After determination of the dry weights of SPL and PL lignin derivatives, the relative yield of each lignin derivative was determined in reference to total native lignin (sum of the acid-insoluble lignin and acid-soluble lignin) value determined for the original biomass sample before pulping.

Lignin samples were acetylated by the following steps. First, 300 mg of sample were weighed into Buchi Multivapor P-12 tubes and dried overnight in a vacuum oven at 40° C. After removal from the oven, each stube was sealed with a metal foil-backed cap to prevent the dried sample from absorbing moisture. 1.5 mL pyridine and 1.5 mL acetic anhydride were added to each sample. The tube contents were mixed by a vortex mixer until the lignin ^' wass completely dissolved. Sample tubes were left, tightly sealed, in a fumehood for a minimum of two days to allow the acetylation reaction to proceed to completion. At the end of this period, 15 mL of e hanol was added to each sample, followed by rotary evaporation in the Multivapor P-12 at 50"C under maximum achievable vacuum. Nine subsequent rotary evaportation steps were carried out, each proceeded by addition of acetone (~ l-2 mL to dissolve any solid lignin in the tube) and ethanol (15 mL, as before). Once all acetic anhydride and acetic acid had been removed, 2 mL of acetone was added to the tube to dissolve the sample. This solution was transferred by glass pipette to a labeled scintillation vial and the tube washed with a further 0.5 - 1.0 mL of acetone, which was also transferred to the scintillation vial. To the lignin solution in the scintillation vial was added 2.0 - 3.0 mL of nanopure water, followed by mixing, to cause the lignin to precipitate out of solution. The vials were dried in a vacuum oven at 40°C. The lignin sample dried into a porous solid which was subsequendy ground to a fine powder. Two subsequent steps of addition of 1.0 mL nanopure water and drying were carried out to remove traces of entrained acetone.

Non-acetylated and acetylated lignin samples were weighed into labelled 2.0 mL screw cap glass vials at a target mass of 200 mg and then dried overnight in a 40°C vacuum oven. Immediately upon removal from the oven, the vials were capped and tighdy sealed to ensure sample dryness. The vials were left to cool to room temperature in an evacuated vacuum desiccator before recording weights. Internal standard stock solution was prepared by weighing into a vial 1 ,3,5-trioxane and chromium acetylacetonate and dissolving in d6-dimethylsulfoxide in respective concentrations of 333.3 mg/mL and 50 mg/ mL. To each lignin sample vial was added 600 uL d6-dimethylsulfoxide and the vial placed in the thermomixer at 40°C and mixed at 1400 rpm until the lignin was fully dissolved, are less soluble than others and require more time in the thermomixer or even vortex mixing. A 60 L aliquot of the previously prepared stock solution was added to each sample and mixing was continued for a short time to allow for a homogeneous solution. The samples were removed from the thermomixer and allowed to cool to room temperature before transferring 550 uL to labeled NMR tubes.

NMR spectra were recorded on a Bruker 700 MHz spectrometer equipped with Cryoprobe at 300 K using ca 30% solutions of sample in DMSO-a^. Chemical shifts were referenced to TMS (0.0 ppm). To ensure more accurate baseline, especially in the carbonyl region (215-185 ppm), the spectra were recorded the interval 240 ( 40) ppm. The following conditions were provided for the quantitative "C-NMR:

1. Inverse gate detection

2. a 90 pulse

3. Complete relaxation of all nuclei was achieved by addition of chromium (III) acetylacetonate; a 1.2 s acquisition time and 1.7 s relaxation delay were used.

The spectra were Fourier transformed, phased, calibrated using TMS signals as a reference (0 ppm) and the baseline was corrected by using a polynomial function. The correction of baseline was done using the following interval references to be adjusted to 2ero: (220- 215ppm)-(185-182ppm)-(97-92ppm)-(5-(-20)ppm). No other regions were forced to 0. The signals in the quantitative 13C NMR spectra were assigned on the base of 2D HSQC NMR and known database. After the baseline correction the spectra were integrated using the area of internal standard (IS), trioxane , as the reference. Each spectrum was processed (as described) at least twice to ensure good reproducibility of the quantification. The calculation of the quantity of specific moieties was done as follows: For non-acetylated lignins: X (mmol/g lignin) = I _x *m, _s /(30m _u *I _1S )*1000 For acetylated lignins: X (mmol/g lignin) = I _x *m _IS / (30m _Llg *I, _s - 42*I _OHtotal * m _IS )*1000 Where X was the amount of the specific moiety; I _x I, _s and I _ontoral were the resonance values of the specific moiety, the internal standard and total OH groups, correspondingly; m _L and m _IS are the masses of the lignin and internal standard. The numerical values for the OEt groups were calculated from the spectra of both acetylated and non-modified (non-acetylated). The data are shown in Tables 1-3. Quantification of the carbon (C) contents were determined by combustion in a pure oxygen environment at 975°C in a Perkin-Elmer 2400 Series Elemental Analyzer. The data are shown in Tables 1-3.

EXAMPLE 2: Recovery of lignin derivatives from softwood feedstocks

Softwood feedstock chips were prepared from: (1) hybrid spruce trees grown in British Columbia, (2) radiata pine grown in Chile, and (3) loblolly pine grown in south eastern USA. Three samples from each feedstock were individually pulped using an acid-catalyzed ethanol pulping process wherein a different set of pulping conditions was used for each sample (Tables 4, 5 and 6).

Table 4: Pulping conditions for hybrid spruce wood chip samples at 6:1 liquor-to-wood ratio.

S on

9 2.88 60 182 62 0.97 67.51

10 1.72 34 168 43 0.56 68.71

11 2.60 84 184 76 1.34 70.17

Table 5: Pulpin conditions for radiata pine wood chip samples at 6:1 liquor-to-wood ratio.

S on

12 1.73 34 168 43 0.54 67.62

13 1.92 33 179 57 0.67 69.13

14 2.04 58 191 46 0.58 70.58

Table 6: Pulping conditions for loblolly pine wood chip samples at 6:1 liquor-to-wood ratio.

S on

15 2.99 86 186 47 0.65 69.55

16 2.80 61 188 67 0.94 71.09

17 2.01 43 189 61 0.61 72.50

For each wood chips sample, the ethanol pulping solvent was prepared to the specified concentration by first, partially diluting the ethanol with water after which, a suitable amount of sulphuric acid was added to achieve the target final acidity. Finally, the ethanol solution was further diluted with water to achieve the target ethanol concentration.

The lignin content of each original fibrous biomass subsample was determined using the NREL method (NREL/TP-510-42618 (April 2008)). Then, after adding the fibrous biomass sample to a pressure vessel (2L or 7 L Parr reactor (Parr Instrument Company, Moline, IL, USA) (100-700 g odw chips), the pH-adjusted ethanol-based pulping solvent was added to the vessel at a 6:1 liquor:wood ratio. The vessel was then pressurized and brought up to the target temperature listed in Tables 8-10 (spruce, radiata pine, loblolly pine, respectively). The biomass sample was then "cooked" for the specified period of time, after which, the pulping process was stopped. After pulping, the contents of pressure vessel were transferred to a hydraulic 20 ton manual shop press (Airco, China). The liquor was separated from the solids by first squeezing the pulped materials in the press to express the liquor. The expressed liquor was then filtered through a coarse silk screen to separate expressed chip residues from liquor stream. Next, fine particles were separated out from the liquor stream by filtration through fine filter paper (Whatman N° 1). The recovered fine particles represent lignin derivatives that were extracted and self-precipitated out from the liquor during cooling of the pulped biomass. The particulate lignin is herein referred to as self-precipitated lignin derivatives (i.e., "SPL"). The solubilized lignin derivatives still remaining in the filtered liquor were precipitated from by dilution with cold water. The kgnin derivatives precipitated by dilution with cold water are referred to as precipitated lignin or "PL". After determination of the dry weights of SPL and PL lignin derivatives, the relative yield of each lignin derivative was determined in reference to the total lignin content (acid-insoluble plus the acid-soluble lignin) determined for the original biomass sample before pulping.

The efhoxy contents and carbon contents of the lignin derivatives samples were determined as described in Example 1, and are shown in Tables 4-6.

EXAMPLE 3: Recovery of lignin derivatives from annual fibre feedstocks.

Two sets of annual fibre feedstock materials were prepared from: (1) corn cobs produced in Europe, (2) bagasse produced from sugarcane grown and processed in Brazil, and (3) wheat straw produced in Alberta, Canada. Three samples of the each feedstock were individually pulped using an acid-catalyzed ethanol pulping process based wherein a different set of pulping conditions was used for each sample (Table 7, 8 and 9).

Table 7: Pulping conditions for wheat straw samples at 6:1 liquor-to-wood ratio. Sample Time Temperature Ethanol OEt Carbon

pH

# min °C % mmol/g %

18 2.45 79 178 49 0.45 65.61

19 1.85 70 185 47 0.53 67.04

20 2.86 90 195 41 0.41 68.36

Table 8: Pulping conditions for sugarcane bagasse samples at 6:1 liquor-to-wood ratio.

Sa on

21 2.92 88 171 73 0.64 65.74

22 2.10 28 171 46 0.72 67.63

23 2.19 61 178 66 0.69 69.51

Table 9: Pulping conditions for com cob samples at 6:1 liquor-to-wood ratio.

Sample Time Temperature Ethanol OEt Carbon

# PH

min °C % mmol/g %

24 2.14 87 181 66 0.53 65.57

25 1.85 42 179 51 0.55 66.25

26 2.18 100 190 67 0.54 66.83

For each biomass sample, the ethanol pulping solvent was prepared to the specified concentration by first, partially diluting the ethanol with water after which, a suitable amount of sulphuric acid was added to achieve the target final acidity. Finally, the ethanol solution was further diluted with water to achieve the target ethanol concentration.

The original lignin content of each fibrous biomass subsample was determined using the NREL method (NREL/TP-510-42618 (April 2008)). Then, after adding the fibrous biomass sample to a pressure vessel (2L or 7L Parr reactor (Parr Instrument Company, Moline, IL, USA) (100-700 g odw chips), the pH-adjusted ethanol-based pulping solvent was added to the vessel at a 6:1 liquor:biomass ratio. The vessel was then pressurized and brought up to the target temperature listed in Tables 14-15 (bagasse, corncobs, respectively). The biomass sample was then "cooked" for the specified period of time, after which, the pulping process was stopped. After pulping, the contents of pressure vessel were transferred to a hydraulic 20 ton manual shop press (Aicro, China). The liquor was separated from the solids by first squeezing the pulped materials in the press to express the liquor. The expressed liquor was then filtered through a coarse silk screen to separate expressed chip residues from liquor stream. Next, fine particles were separated out from the liquor stream by filtration through fine filter paper (Whatman N" 1). The recovered fine particles represent lignin derivatives that were extracted and self-precipitated out from the liquor during cooling of the pulped biomass. The particulate lignin is herein referred to as self-precipitated lignin derivatives (i.e., "SPL"). The solubilized lignin derivatives still remaining in the filtered liquor were precipitated from by dilution with cold water. The lignin derivatives precipitated by dilution with cold water are referred to as precipitated lignin or "PL". After determination of the dry weights of SPL and PL lignin derivatives, the relative yield of each lignin derivative was determined in reference to the total lignin (sum of acid-insoluble lignin plus acid-soluble hgnin) value determined for the original biomass sample before pulping.

The ethoxy contents and carbon contents of the lignin derivatives samples were determined as described in Example 1 , and are shown in Tables 4-6.

This disclosure provides methods for production and description of chemical properties of lignin derivatives with enhanced spinnability, improved engineering properties of resulting carbon fibres as measured by their tensile strength and modulus of elasticity. The lignin derivatives in this disclosure can be spun into lignin fibres and subsequently carbonized into carbon fibres at yields exceeding 45%, tensile strength higher than 388-550 MPa, and modulus of elasticity exceeding 30-60 GPa. Spinnability of these lignin derivatives into lignin fibres can exceed 100 m/min.