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Title:
CATALYST FOR GAS-PHASE OXIDATION OF 1,2,4,5-TETRAALKYLBENZENE, PREPARATION METHOD FOR AND APPLICATION OF CATALYST, AND PREPARATION METHOD FOR BENZENE-1,2,4,5-TETRACARBOXYLIC DIANHYDRIDE
Document Type and Number:
WIPO Patent Application WO/2023/072247
Kind Code:
A1
Abstract:
Disclosed in the present invention are a catalyst for gas-phase oxidation of 1,2,4,5-tetraalkylbenzene to prepare benzene-1,2,4,5-tetracarboxylic dianhydride, a preparation method for and an application of the catalyst, and a preparation method for benzene-1,2,4,5-tetracarboxylic dianhydride. The catalyst according to the present invention comprises a carrier and a catalytically active component coating attached to the carrier; the catalytically active component coating comprises a first coating and a second coating; the first coating is close to the surface of the carrier, and the second coating is distant from the surface of the carrier; in the first coating, the mass ratio of titanium element denoted by Ti to vanadium element denoted by V is Ti/V1; in the second coating, the mass ratio of titanium element denoted by Ti to vanadium element denoted by V is Ti/V2, wherein Ti/V2=Ti/V1+ΔTi/V, and ΔTi/V is within a range of 3 to 9. The catalyst according to the present invention exhibits improved catalytic activity, and can effectively increase the yield of benzene-1,2,4,5-tetracarboxylic dianhydride.

Inventors:
AN XIN (CN)
YUAN BIN (CN)
LIU YUFEN (CN)
SHI HUIMIN (CN)
ZHANG DONGSHUN (CN)
ZHANG ZUOFENG (CN)
Application Number:
PCT/CN2022/128240
Publication Date:
May 04, 2023
Filing Date:
October 28, 2022
Export Citation:
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Assignee:
CHINA PETROLEUM & CHEM CORP (CN)
BEIJING RES INST CHEMICAL IND CHINA PETROLEUM & CHEMICAL CORP (CN)
International Classes:
B01J23/22
Foreign References:
CN111097466A2020-05-05
CN109158119A2019-01-08
US20110230668A12011-09-22
Attorney, Agent or Firm:
RUNPING & PARTNERS (CN)
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