Title:
CATALYST MODIFIED WITH THIOL LIGAND, PREPARATION METHOD THEREFOR AND USE THEREOF
Document Type and Number:
WIPO Patent Application WO/2022/012005
Kind Code:
A1
Abstract:
The present invention provides a catalyst modified with a thiol ligand, a preparation method therefor and use thereof. The method comprises: introducing a hydrogen-containing gas, and modifying Pd4S or Pd4S/X by a thiol ligand under a gas atmosphere, so as to prepare and obtain an M-Pd4S catalyst or an M-Pd4S/X catalyst with a carrier. The catalyst prepared by the present invention achieves high selectivity for an intermediate alkyne compound in a semi-hydrogenation reaction of alkyne; in addition, the preparation method for the catalyst of the present invention has simple operation and universality.
Inventors:
ZHENG NAN FENG (CN)
LI ZHI KAI (CN)
LIU SHENG JIE (CN)
CHEN JIE (CN)
LI ZHI KAI (CN)
LIU SHENG JIE (CN)
CHEN JIE (CN)
Application Number:
PCT/CN2021/071075
Publication Date:
January 20, 2022
Filing Date:
January 11, 2021
Export Citation:
Assignee:
UNIV XIAMEN (CN)
International Classes:
B01J31/22; C07C5/09; C07C11/02; C07C15/44; C07C15/52; C07C29/17; C07C33/30; C07C45/62; C07C49/217; C07C67/303; C07C69/618
Foreign References:
| CN111774096A | 2020-10-16 | |||
| US20140287237A1 | 2014-09-25 | |||
| US20140242389A1 | 2014-08-28 |
Other References:
ZHAO XIAOJING, LINGYUN ZHOU, WUYONG ZHANG, CHENGYI HU, LEI DAI, LITING REN, BINGHUI WU, GANG FU, NANFENG ZHENG: "Thiol Treatment Creates Selective Palladium Catalysts for Semihydrogenation of Internal Alkynes", CHEM, CELL PRESS, US, vol. 4, no. 5, 10 May 2018 (2018-05-10), US , pages 1080 - 1091, XP055887522, ISSN: 2451-9294, DOI: 10.1016/j.chempr.2018.02.011
YANG ZHIQIANG, KLABUNDE KENNETH J., SORENSEN CHRISTOPHER M.: "From Monodisperse Sulfurized Palladium Nanoparticles to Tiara Pd(II) Thiolate Clusters: Influence of Thiol Ligand on Thermal Treatment of a Palladium(II)−Amine System", THE JOURNAL OF PHYSICAL CHEMISTRY C, AMERICAN CHEMICAL SOCIETY, US, vol. 111, no. 49, 1 December 2007 (2007-12-01), US , pages 18143 - 18147, XP055887523, ISSN: 1932-7447, DOI: 10.1021/jp0765751
YANG ZHIQIANG, KLABUNDE KENNETH J., SORENSEN CHRISTOPHER M.: "From Monodisperse Sulfurized Palladium Nanoparticles to Tiara Pd(II) Thiolate Clusters: Influence of Thiol Ligand on Thermal Treatment of a Palladium(II)−Amine System", THE JOURNAL OF PHYSICAL CHEMISTRY C, AMERICAN CHEMICAL SOCIETY, US, vol. 111, no. 49, 1 December 2007 (2007-12-01), US , pages 18143 - 18147, XP055887523, ISSN: 1932-7447, DOI: 10.1021/jp0765751
Attorney, Agent or Firm:
XIAMEN SHICHENG ASSOCIATES INTELLECTUAL PROPERTY AGENCY (CN)
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