Title:
CATALYST FOR POLYMERIZING BIOMASS-DERIVED FURAN-BASED COMPOUND, AND METHOD FOR PREPARING POLYMER OF BIOMASS-DERIVED FURAN-BASED COMPOUND BY USING SAME
Document Type and Number:
WIPO Patent Application WO/2019/059515
Kind Code:
A1
Abstract:
The present invention relates to: a novel catalyst for preparing a transportation fuel precursor from a biomass-derived furan-based compound; and a method for preparing a polymer of a furan-based compound by using the same. The catalyst for preparing a transportation fuel precursor, according to the present invention, does not use a strong acid such as sulfuric acid, and thus does not require a complex process for the separation and recovery of remaining strong acid and is environmentally friendly. In addition, the catalyst has a very wide surface area, thereby having an excellent conversion rate, has high selectivity for a desired product and has excellent cycle characteristics. Further, since the acid strength of a terminal acidic functional group and the degree of hydrophobicity are further strengthened using an ionic liquid as a linking group, a more excellent yield and conversion rate can be exhibited.
Inventors:
SEO JEONG GIL (KR)
GEBRESILLASE MAHLET NIGUS (KR)
JEON HYEONG BIN (KR)
GEBRESILLASE MAHLET NIGUS (KR)
JEON HYEONG BIN (KR)
Application Number:
PCT/KR2018/008707
Publication Date:
March 28, 2019
Filing Date:
July 31, 2018
Export Citation:
Assignee:
MYONGJI UNIV INDUSTRY AND ACADEMIA COOPERATION FOUNDATION (KR)
International Classes:
B01J35/02; B01J21/08; B01J35/06; B01J37/00; C07D307/34
Foreign References:
| US8883308B2 | 2014-11-11 | |||
| KR101777735B1 | 2017-09-12 |
Other References:
CHERMAHINI, A. N. ET AL.: "Production of 5-hydroxymethylfurfural from fructose using a spherically fibrous KCC-1 silica catalyst", RSC ADVANCES, vol. 40, no. 6, 22 March 2016 (2016-03-22), pages 1 - 21, XP055584459
BALAKRISHNAN, M.: "Syntheses of biodiesel precursors: sulfonic acid catalysts for condensation of biomass-derived platform molecules", CHEMSUSCHEM, vol. 7, 2014, pages 1078 - 1085, XP055584460
ABOELHASSAN, M. M.: "Sulfonic acid functionalized silica nanoparticles as catalysts for the esterification of linoleic acid", NEW JOURNAL OF CHEMISTRY, vol. 41, no. 9, 3 April 2017 (2017-04-03), pages 1 - 36, XP055584463
YATI, I.: "Water-promoted selective heterogeneous catalytic trimerization of xylose-derived 2-methylfuran to diesel precursors", APPLIED CATALYSIS A: GENERAL, vol. 495, 2015, pages 200 - 205, XP029124244, DOI: doi:10.1016/j.apcata.2015.02.002
GEBRESILLASE, M. N.: "Sulfonic acid functionalized fibrous nano-silica (KCC-1) catalysts for the condensation of furanic p latform molecules to diesel precursors", THEORIES AND APPLICATIONS OF CHEMICAL ENGINEERING, vol. 23, no. 2, 25 October 2017 (2017-10-25), pages 2231, XP055584467
GEBRESILLASE, M. N.: "Sulfonic acid functionalized silica-supported catalysts for the condensation of furanic platform molecules to fuel precursors", 3RD GREEN & SUSTAINABLE CHEMSTRY CONFERENCE, 13 May 2018 (2018-05-13), Berlin, Germany, pages 1.11
BALAKRISHNAN, M.: "Syntheses of biodiesel precursors: sulfonic acid catalysts for condensation of biomass-derived platform molecules", CHEMSUSCHEM, vol. 7, 2014, pages 1078 - 1085, XP055584460
ABOELHASSAN, M. M.: "Sulfonic acid functionalized silica nanoparticles as catalysts for the esterification of linoleic acid", NEW JOURNAL OF CHEMISTRY, vol. 41, no. 9, 3 April 2017 (2017-04-03), pages 1 - 36, XP055584463
YATI, I.: "Water-promoted selective heterogeneous catalytic trimerization of xylose-derived 2-methylfuran to diesel precursors", APPLIED CATALYSIS A: GENERAL, vol. 495, 2015, pages 200 - 205, XP029124244, DOI: doi:10.1016/j.apcata.2015.02.002
GEBRESILLASE, M. N.: "Sulfonic acid functionalized fibrous nano-silica (KCC-1) catalysts for the condensation of furanic p latform molecules to diesel precursors", THEORIES AND APPLICATIONS OF CHEMICAL ENGINEERING, vol. 23, no. 2, 25 October 2017 (2017-10-25), pages 2231, XP055584467
GEBRESILLASE, M. N.: "Sulfonic acid functionalized silica-supported catalysts for the condensation of furanic platform molecules to fuel precursors", 3RD GREEN & SUSTAINABLE CHEMSTRY CONFERENCE, 13 May 2018 (2018-05-13), Berlin, Germany, pages 1.11
Attorney, Agent or Firm:
HAEUM PATENT & LAW FIRM (KR)
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