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Title:
CATALYST FOR USE IN PRODUCTION OF 1,3-BUTADIENE, METHOD FOR PRODUCING SAID CATALYST, AND METHOD FOR PRODUCING 1,3-BUTADIENE
Document Type and Number:
WIPO Patent Application WO/2019/167323
Kind Code:
A1
Abstract:
[Problem] To provide a technique for producing 1,3-butadiene with high efficiency from 1,4-butanediol or 3-buten-1-ol under reaction conditions including a high inversion rate. [Solution] A catalyst for use in the production of 1,3-butadiene contains ytterbium oxide as an active ingredient that enables the production of 1,3-butadiene from 1,4-butanediol or 3-buten-1-ol. A method for producing 1,3-butadiene comprises the step of bringing a fluid containing 1,4-butanediol and/or 3-buten-1-ol into contact with the catalyst for use in the production of 1,3-butadiene to produce a liquid containing 1,3-butadiene.

Inventors:
SATO SATOSHI (JP)
WANG YUCHONG (JP)
HONDA KAZUNORI (JP)
Application Number:
PCT/JP2018/036713
Publication Date:
September 06, 2019
Filing Date:
October 01, 2018
Export Citation:
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Assignee:
UNIV CHIBA NAT UNIV CORP (JP)
JGC CORP (JP)
International Classes:
B01J23/10; C07C1/24; C07C11/167; C07B61/00
Domestic Patent References:
WO2007083736A12007-07-26
WO2013183590A12013-12-12
Foreign References:
JP2016516096A2016-06-02
JP2009023928A2009-02-05
JP2017508717A2017-03-30
JP2016204329A2016-12-08
JP2017186272A2017-10-12
Other References:
IGARASHI; SATO A; TAKAHASHI S; SODESAWA R; KOBUNE T; M: "Dehydration of 1,4-butanediol over lanthanide oxides", CATALYSIS COMMUNICATIONS, vol. 8, no. 5, 20 September 2006 (2006-09-20), pages 807 - 810, XP005916733, ISSN: 1566-7367, DOI: 10.1016/j.catcom.2006.09.003
WANG, YUCHAO ET AL.: "Efficient generation of 1,3-butadiene by dehydration reaction of 3-buten-1-ol", PROCEEDINGS OF THE FORUM A OF THE 120TH CATALYSIS SOCIETY OF JAPAN MEETING< SEPTEMBER 12TH TO SEPTEMBER 14TH, 2017, 5 September 2017 (2017-09-05), pages 316, XP009522577, ISSN: 1343-9936
S. SATOR. TAKAHASHIT. SODESAWAN. YAMAMOTO: "Dehydration of 1,4-butanediol into 3-buten-1-0l catalyzed by ceria", CATALYSIS COMMUNICATIONS, vol. 5, 2004, pages 397 - 400
D. SUNS. ARAIH. DUANY. YAMADAS. SATO: "Vapor-phase dehydration of C4 unsaturated alcohols to 1, 3-butadiene", APPLIED CATALYSIS A, vol. 531, 2017, pages 21 - 28, XP029859259, DOI: 10.1016/j.apcata.2016.11.035
S. SATO ET AL., CATALYSIS COMMUNICATIONS, vol. 5, 2004, pages 397
See also references of EP 3760308A4
Attorney, Agent or Firm:
YAYOY PATENT OFFICE (JP)
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