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Title:
CATALYTIC COMPOSITIONS AND METHODS FOR ASYMMETRIC ALLYLIC ALKYLATION
Document Type and Number:
WIPO Patent Application WO1999032225
Kind Code:
A9
Abstract:
Complexes of a selected class of chiral ligands with molybdenum, tungsten or chromium, preferably molybdenum, are effective as catalysts in highly enantioselective and regioselective alkylation of allylic substrates. Such compositions provide a versatile and low-cost alternative to existing catalysts.

Inventors:
TROST BARRY M
HACHIYA IWAO
Application Number:
PCT/GB1998/003850
Publication Date:
September 30, 1999
Filing Date:
December 21, 1998
Export Citation:
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Assignee:
UNIV LELAND STANFORD JUNIOR (US)
CHIROTECH TECHNOLOGY LTD (GB)
International Classes:
B01J31/18; B01J31/20; B01J31/22; C07B53/00; C07B61/00; C07C45/77; C07C49/92; C07C67/333; C07C67/343; C07C69/602; C07C69/608; C07C69/618; C07C69/738; C07D213/55; C07D213/81; C07D307/54; C07D309/20; C07D333/24; C07D401/14; C07D493/08; C07F11/00; C07F15/00; (IPC1-7): B01J31/00
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