CATALYZED SOOT FILTER MANUFACTURE AND SYSTEMS

CROSS-REFERENCE TO RELATED APPLICATIONS

[0001] This application is a continuation-in-part of United States patent application serial number 11/959,090, filed on December 18, 2007, the entire contents of which are incorporated herein by reference.

TECHNICAL FIELD

[0002] Catalyzed soot filters for diesel engine exhaust emissions systems and methods for their manufacture and use are disclosed.

BACKGROUND

[0003] Diesel engine exhaust is a heterogeneous mixture which contains not only gaseous emissions such as carbon monoxide ("CO"), unburned hydrocarbons ("HC") and nitrogen oxides ("NO _x "), but also condensed phase materials (liquids and solids) which constitute the so-called particulates or particulate matter. Often, catalyst compositions and substrates on which the compositions are disposed are provided in diesel engine exhaust systems to convert certain or all of these exhaust components to innocuous components. For example, diesel exhaust systems can contain one or more of a diesel oxidation catalyst, a soot filter and a catalyst for the reduction of NOx.

[0004] Oxidation catalysts that contain platinum group metals, base metals and combinations thereof, are known to facilitate the treatment of diesel engine exhaust by promoting the conversion of both HC and CO gaseous pollutants and some proportion of the particulate matter through oxidation of these pollutants to carbon dioxide and water. Such catalysts have generally been contained in units called diesel oxidation catalysts (DOCs), which are placed in the exhaust of diesel engines to treat the exhaust before it vents to the atmosphere. In addition to the conversions of gaseous HC, CO and particulate matter, oxidation catalysts that contain platinum group metals (which are typically dispersed on a refractory oxide support) also promote the oxidation of nitric

oxide (NO) to NO ₂ . The total particulate matter emissions of diesel exhaust are comprised of three main components. One component is the solid, dry, solid carbonaceous fraction or soot fraction. This diy carbonaceous matter contributes to the visible soot emissions commonly associated with diesel exhaust. A second component of the particulate matter is the soluble organic fraction ("SOF"). The soluble organic fraction is sometimes referred to as the volatile organic fraction ("VOF"), which terminology will be used herein. The VOF can exist in diesel exhaust either as a vapor or as an aerosol (fine droplets of liquid condensate) depending on the temperature of the diesel exhaust. It is generally present as condensed liquids at the standard particulate collection temperature of 52 ⁰ C in diluted exhaust, as prescribed by a standard measurement test, such as the U.S. Heavy Duty Transient Federal Test Procedure. These liquids arise from two sources: (1) lubricating oil swept from the cylinder walls of the engine each time the pistons go up and down; and (2) unburned or partially burned diesel fuel.

[0005] The third component of the particulate matter is the so-called sulfate fraction. The sulfate fraction is formed from small quantities of sulfur components present in the diesel fuel. Small proportions of SO ₃ are formed during combustion of the diesel, which in turn combines rapidly with water in the exhaust to form sulfuric acid. The sulfuric acid collects as a condensed phase with the particulates as an aerosol, or is adsorbed onto the other particulate components, and thereby adds to the mass of TPM,

[0006] One key aftertreatment technology in use for high particulate matter reduction is the diesel particulate filter. There are many known filter structures that are effective in removing particulate matter from diesel exhaust, such as honeycomb wall flow filters, wound or packed fiber filters, open cell foams, sintered metal filters, etc. However, ceramic wall flow filters, described below, receive the most attention. These filters are capable of removing over 90% of the particulate material from diesel exhaust. The filter is a physical structure for removing particles from exhaust, and the accumulating particles will increase the back pressure from the filter on the engine. Thus, the accumulating particles have to be continuously or periodically burned out of the filter to maintain an acceptable back pressure. Unfortunately, the carbon soot particles require

temperatures in excess of 500 ⁰ C to burn under oxygen rich (lean) exhaust conditions. This temperature is higher than what is typically present in diesel exhaust.

[0007] Provisions are generally introduced to lower the soot burning temperature in order to provide for passive regeneration of the filter. The presence of a catalyst promotes soot combustion, thereby regenerating the filters at temperatures accessible within the diesel engine's exhaust under realistic duty cycles. In this way _} a catalyzed soot filter (CSF) or catalyzed diesel particulate filter (CDPF) is effective in providing for >80% particulate matter reduction along with passive burning of the accumulating soot, and thereby promoting filter regeneration.

[0008] Conventional processes for coating diesel particulate filters on aluminum titanate and cordierite substrates often negatively impact the physical properties of the coated filter as compared to uncoated filters. It is believed that soluble and fine particles enter microcracks during the washcoating process. As a result, material in the microcracks limits the free movement of the microcracks and reduces the flexibility of the filter expansion upon heating. To minimize this issue, a polymer passivation step is used prior to washcoating the substrate. An example of such a polymer passivation step is described in United States Patent No. 7,166,555. This polymer passivation step increases manufacturing cost and complexity. Accordingly, it would be desirable to provide methods for manufacturing catalyzed soot filters that do not require polymer passivation prior to washcoating.

SUMMARY

[0009] Catalyzed soot filters, methods for their manufacture and use and systems incorporating catalyzed soot filters are disclosed. In one embodiment, a catalyzed soot filter comprises a wall flow monolith having a plurality of longitudinally extending passages formed by longitudinally extending walls bounding and defining said passages, the passages comprising inlet passages having an open inlet end and closed outlet end, and outlet passages having a closed inlet end and an open outlet end, the wall flow monolith including microcracks having an average width less than about 0.4 μm, and pores having a mean pore size in the range of about 10 μm to about 25 μm; and a

washcoat disposed within the walls of the wall flow monolith, the washcoat including catalyst comprising support particles and at least one precious metal, where at least about 90% of the support particles have particle sizes greater than about the average size of the microcracks and at least about 90% of the support particles have particle sizes less than about the mean size of the pores of the wall flow monolith.

[0010] Another aspect of the invention pertains to methods of making a catalyst- coated wall flow monolith containing microcracks having an average width less than about 0.4 μm and pores having a mean pore size in the range of about 10 μm to about 25 μm, the methods comprising providing a wall flow monolith having a plurality of longitudinally extending passages formed by longitudinally extending walls bounding and defining said passages, the passages comprising inlet passages having an open inlet end and closed outlet end, and outlet passages having a closed inlet end and an open outlet end and coating the wall flow monolith with a washcoat in the form of an aqueous slurry, which contains a thermally decomposable catalytic material and solid particles, at least about 90% of the particles have a particle size greater than about the average size of the microcracks, and at least about 90% of the particles have a particle size less than about the mean size of the pores; and heating the coated wall flow monolith to a temperature sufficient to dry the washcoat.

BRIEF DESCRIPTION OF THE DRAWINGS

[0011] Figure 1 shows a schematic depiction of an embodiment of an emission treatment system;

[0012] Figure 2 shows a perspective view of a wall flow filter substrate;

[0013] Figure 3 shows a cutaway view of a section of a wall flow filter substrate;

[0014] Figure 4 shows a graph of the coefficient of thermal expansion for exemplary wall flow substrates;

[00 IS] Figure 5 shows a graph of the particle size distribution for jet milled alumina alumina powders mechanically separated to contain various degrees of fines;

[0016] Figure 6 shows a graph of the coefficient of thermal expansion for soot filters coated with the jet milled alumina powders of Figure 5;

[0017] Figure 7 shows a particle size distribution between wet milled and dry milled particles;

[0018] Figure 8 shows a graph comparing the coefficients of thermal expansion for soot filters prepared by wet milled and dry milled processes; and

[0019] Figure 9 shows a graph comparing the catalytic performance of filters prepared by wet milled and dry milled processes.

DETAILED DESCRIPTION

[0020] Before describing several exemplary embodiments of the invention, it is to be understood that the invention is not limited to the details of construction or process steps set forth in the following description. The invention is capable of other embodiments and of being practiced or being carried out in various ways.

[0021] As used in this specification and the appended claims, the singular forms "a", "an" and "the" include plural referents unless the context clearly indicates otherwise. Thus, for example, reference to "a catalyst" includes a mixture of two or more catalysts, and the like.

[0022] Aspects of the invention pertain to catalyzed soot filters, diesel engine exhaust treatment systems including a catalyzed soot filter and methods of making catalyzed soot filters. One or more embodiments of the invention relates to a coating process for making catalyzed soot filters for use as part of an emission treatment system.

[0023] A method for applying a catalyst composition to a soot filter is provided that results in a catalyzed soot filter having physical properties superior to the blank filter without using a polymer passivation step prior to application of the washcoat. The catalyzed soot filters comprise a wall flow monolith and a washcoat including catalyst. The wall flow monolith has a plurality of longitudinally extending passages formed by longitudinally extending walls bounding and defining the passages. The passages comprise inlet passages having an open inlet end and closed outlet end, and outlet

passages having a closed inlet end and an open outlet end. The wall flow monolith has microcracks with an average width less than about 0.4 μm, and pores having a mean pore size in the range of about 10 μm to about 25 μm. The catalyst comprises support particles and at least one precious metal. At least about 90% of the support particles have particle sizes greater than about the average size of the microcracks, and at least about 90% of the support particles have particle sizes less than about the mean size of the pores of the wall flow monolith.

[0024] Other aspects of the invention are directed toward methods of making a catalyst coated wall flow monolith containing microcracks having an average width less than about 0.4 μm and pores having a mean pore size in the range of about 10 μm to about 25 μm. According to one or more embodiments, the methods include coating a wall flow monolith with a washcoat in the form of an aqueous slurry. The aqueous slurry may contain a thermally decomposable catalytic material comprising support particles. The support particles are present in a range of sizes where at least about 90% of the particles are greater than about the average size of the microcracks, and at least about 90% of the particles are less than about the mean size of the pores. The coated wall flow monolith may be heated to a temperature which is sufficient to provide a deposit of catalytically-active compounds on the monolith surface.

[0025] In some embodiments, at least about 90% of the support particles are greater than about 0.5 μm. In detailed embodiments, the support particles are greater than about 1 μm, and in more detailed embodiments, the support particles greater than about 2 μm. In certain embodiments, at least about 90% of the support particles are less than about 15 μm, In specific embodiments, the support particles are less than about 10 μm, and in more specific embodiments, the support particles are, less than about 7,5 μm. In most specific embodiments, the support particles are less than about 5 μm. In other embodiments, greater than about 60% of the support particles are within the range of about 1 μm to about 5 μm. In further embodiments, greater than about 75% of the support particles are within the range of about 1 μm to about 5 μm. In additional embodiments, greater than about 80% of the support particles are within the range of about 1 μm to about 5 μm.

[0026] One embodiment of an emission treatment system is schematically depicted in Figure 1. As can be seen in Figure 1, the exhaust containing gaseous pollutants (including unburned hydrocarbons, carbon monoxide and NOx) and particulate matter is conveyed from the engine 15 to an oxidation catalyst 11. In the oxidation catalyst 11, unburned gaseous and non-volatile hydrocarbons (i.e., the VOF) and carbon monoxide are largely combusted to form carbon dioxide and water. Removal of substantial proportions of the VOF using the oxidation catalyst, in particular, helps prevent too great a deposition of particulate matter on the soot filter 12 (i.e., clogging), which is positioned downstream in the system. In addition, a substantial proportion of the NO of the NOx component is oxidized to NO ₂ in the oxidation catalyst.

[0027] The exhaust stream is conveyed to the soot filter 12 which is coated with a catalyst composition. According to one or more embodiments, the particulate matter including the soot fraction and the VOF are also largely removed (greater than 80%) by the soot filter. The particulate matter deposited on the soot filter is combusted through the regeneration of the filter. The temperature at which the soot fraction of the particulate matter combusts is lowered by the presence of the catalyst composition disposed on the soot filter. The catalyzed soot filter 12 may optionally contain an SCR catalyst for converting the NOx in the exhaust gas stream to nitrogen.

[0028] Wall flow substrates useful for supporting the catalyst compositions have a plurality of fine, substantially parallel gas flow passages extending along the longitudinal axis of the substrate. Typically, each passage is blocked at one end of the substrate body, with alternate passages blocked at opposite end-faces. Such monolithic carriers may contain greater than about 250 cell per square inch, and up to about 700 or more flow passages (or "cells") per square inch of cross section, although far fewer may be used. For example, the carrier may have from about 7 to 600, more usually from about 100 to 400, cells per square inch ("cpsi"). The cells can have cross sections that are rectangular, square, circular, oval, triangular, hexagonal, or are of other polygonal shapes. Wall flow substrates typically have a wall thickness in the range of about 0.002 and 0.1 inches. Other embodiments have wall flow substrates with a wall thickness in the range of about 0.002 and 0.025 inches. Detailed embodiments have wall thicknesses in the range of about 0.010 inches to about 0.020 inches.

[0029] Figures 2 and 3 illustrate a wall flow filter substrate 30 which has a plurality of passages 52, The passages are tubularly enclosed by the internal walls 53 of the filter substrate. The substrate has an inlet end 54 and an outlet end 56. Alternate passages are plugged at the inlet end with inlet plugs 58, and at the outlet end with outlet plugs 60 to form opposing checkerboard patterns at the inlet 54 and outlet 56. A gas stream 62 enters through the unplugged channel inlet 64, is stopped by outlet plug 60 and diffuses through channel walls 53 (which are porous) to the outlet side 66. The gas cannot pass back to the inlet side of walls because of inlet plugs 58.

[0030] The support particles of some embodiments is be selected from the group consisting of aluminum compounds, zirconium compounds, cerium compounds, zeolites, silicon compounds, base metal oxides and combinations thereof.

[0031] Wall flow filter substrates, also referred to as wall flow monoliths and wall flow substrates, are composed of ceramic-like materials such as cordierite, α-alumina, silicon carbide, silicon nitride, zirconia, mullite, spodumene, alumina-silica-magnesia or zirconium silicate, or of porous, refractory metal. Wall flow substrates may also be formed of ceramic fiber composite materials. The wall flow monolith of other embodiments is one or more of aluminum titanate, cordierite, silicon carbide, metal oxides and ceramics.

[0032] Various embodiments of the invention comprise an aluminum titanate wall flow monolith, having a porosity in the range of about 40% to about 70% . Further embodiments of this sort have a coefficient of thermal expansion that is less than about 25 x 10 ^"7 /°C when measured at 1000° C. More detailed embodiments have a CTE less than about 15 x 10 ^"7 / ⁰ C when measured at 1000° C. In other embodiments, the wall flow monolith comprises a material selected from aluminum titanate, cordierite and silicon carbide.

[0033] According to some detailed embodiments, the coefficient of thermal expansion of the soot filter is less than about 5 x 10 ^'7 / ⁰ C when measured at 800° C. In other detailed embodiments, the CTE is less than about 2 x 10 ^'7 / ⁰ C when measured at 800° C. In further detailed embodiments, the CTE is less than about 1 x 10 ^"7 / ⁰ C when measured at 800° C.

[0034] Coating of the wall flow substrates with catalyst composition is achieved by immersing the substrates vertically in a portion of the catalyst slurry such that the top of the substrate is located just above the surface of the slurry. In this manner, slurry contacts the inlet face of each honeycomb wall, but is prevented from contacting the outlet face of each wall. The sample is left in the slurry for about 30 seconds. The substrate is removed from the slurry, and excess slurry is removed from the wall flow substrate first by allowing it to dram from the channels, then by blowing with compressed air (against the direction of slurry penetration ), and then by pulling a vacuum from the direction of slurry penetration. By using this technique, the catalyst slurry permeates the walls of the substrate, yet the pores are not occluded to the extent that undue back pressure will build up in the finished substrate. As used herein, the term "permeate" when used to describe the dispersion of the catalyst slurry on the substrate, means that the catalyst composition is dispersed throughout the wall of the substrate.

[0035] The coated substrates are dried typically at about 100° C and calcined at a higher temperature (e.g., 300° C to 450° C), After calcining, the catalyst loading can determined be through calculation of the coated and uncoated weights of the substrate. As will be apparent to those of skill in the ait, the catalyst loading can be modified by altering the solids content of the coating slurry. Alternatively, repeated immersions of the substrate in the coating slurry can be conducted, followed by removal of the excess slurry as described above.

[0036] The catalyst is dispersed on a suitable support material such as a refractory oxide with high surface area and good thermal stability such as a high surface area aluminum oxide. Also, aluminas stabilized with a second oxide are suitable supports. Lanthana stabilization of alumina provides a suitable support for precious group metal catalysts. Also, mixtures of aluminas are suitable supports. Other aluminas that are doped or treated with oxides such as SiO ₂ , ZrO ₂ , TiO ₂ , etc. to provide stabilization or improved surface chemistries can also be utilized. Other suitable support materials include, but are not limited to, ZrO ₂ and TiO ₂ , can be used, In addition to the support oxides discussed above, it might prove useful to include other catalytically functional oxides to incorporate into the catalytic zone. Examples of these include CeO ₂ , Pr ₆ On,

V ₂ O ₅ , and MnO ₂ and combinations thereof and solid solution oxide mixtures, etc. These oxides can contribute to burning of hydrocarbons, especially heavy fuel derived hydrocarbons, and deposited coke/soot derived from dispropoitination (i.e., dehydrogenation or oxidative dehydrogenation) of the injected fuel and in this way give additional combustion activity to the catalytic zone, plus prevent deactivation of the PGM by the deposition hydrocarbon derived coke.

EXAMPLES

[0037J The following examples further illustrate the present invention, but of course, should not be construed as in any way limiting its scope. For example, while examples are provided for aluminum titanate and cordierite wall flow filters, it is expected that silicon carbide filters would show similar results in accordance with the examples described herein.

SAMPLE PREPARATION

[0038] The filter substrate for the following samples is made of aluminum titanate with a porosity of 51% of the mean pore size between 14 μm and 15 μm, 300 cpsi and a wall thickness of 13 mil. The substrate has a dimension of 2" x 6" round.

Comparative Example A

[0039] The reference example catalyst has the following composition: 33.3 g/ft Pt, 16.7 g/ft ³ Pd, 0.5 g/in ³ Siralox 1.5/100 (1.5% Si on Al ₂ O ₃ ) and O.lg/in ³ beta zeolite. The composition is the same throughout the length of the filter.

[0040] To prepare the catalyst coating slurry, a platinum tetra monoethanolamine hydroxide solution was impregnated onto Siralox powder via the incipient wetness technique in a Planetary mixer. Then, palladium nitrate was applied on the Pt/Siralox powder using the same impregnation technique. The precious metal impregnated powder was then dispersed into water to make a slurry. This slurry was milled using a continuous mill to reduce the particle size to 90% less than 4 micrometers (D ₉₀ < 4 μm). Before the completion of milling, zeolite was added into the slurry. The resulting slurry

was further diluted with water to achieve 19% solids by weight. The final pH of the slurxy was 4.1.

[0041] The slurry was then washcoated by immersing the substrate into the slurry with inlet side of the substrate down and the outlet side just above (about ¹ A inch) the slurry level. The substrate was pulled out of the slurry, and a stream of air was blown from the outlet side until no washcoat slurry was coming out. The coated sample was then dried at 110 ⁰ C for 2 hours and calcined in air at 450 ⁰ C for 1 hour.

Example B

[0042] A Ce/Zr composite (0.3 g/in ³ ) with D ₉₀ < 4 μm was used for this example. The Ce/Zr powder was used without further reducing the particle size. The slurry was washcoated in a similar manner as Example A.

Example C

[0043] The ammonium form of ZSM- 5 (0.3 g/in ³ ) with D ₉₀ < 13 μm was used for this sample. The zeolite powder was used without further reducing the particle size. The slurry was washcoated in a similar manner as Example A.

Example D

[0044] A Siralox 1.5 powder (0.1 g/in ³ ) milled to D ₉₀ < 5 μm was used for this sample. The slurry was washcoated hi a similar manner as Example A.

Example E

[0045] A Siralox 1.5 powder (0.3 g/in ³ ) was used for this sample. The powder was milled to D ₉₀ < 6 μm with tartaric acid added before milling. The slurry was washcoated from both the inlet and outlet sides to get the total washcoat loading of 0.3 g/in ³ .

Example F

J0Q46] A jet milled alumina powder was used, which has a Dp ₀ < 7 μm. This alumina powder was further milled in a continuous mill to D ₉₀ < 5 μm. The slurry was coated from the inlet side to achieve a 0.40 g/in washcoat.

[0047] Figure 4 shows a chart of the coefficient of thermal expansion (CTE) for Examples (Samples) A-F. These measurements were performed at 1000 ⁰ C. A lower CTE is indicative of a more robust catalyzed soot filter. All of the milled samples (Examples B-F) demonstrate CTEs lower than the Comparative Example A. Catalyzed soot filters with CTEs below 15xlO ^"7 / ⁰ C have been observed to be robust. CTEs between 15xlO ^'7 and 25xlO ^~7 / ⁰ C are being investigated for robustness. All of the milled samples have CTEs below 25xlO ^"7 / ⁰ C, with most being below 15xlO ^"7 / ⁰ C.

[0048] Examples G-I

[0049] A jet milled alumina powder, having a D ₉₀ < 7 μm, was further classified mechanically into 3 cuts - fine (Example G), medium (Example H) and coarse (Example I). The particle size distributions (PSD) are shown in Figure 5. Example G, the fine powder, has 10% of the particles with a size less than about 1.1 μm (90% >l.lμm). Example H, the medium powder, has 10% of the particles with a size less than about 1.7 μm (90% >1.7 μm). Example I, the coarse powder, has 10% of the particles with a size less than about 2.0 μm (or 90% >2.0 μm).

[0050] Each cut of the classified powders was used as an alumina support for preparing a catalyzed soot filter. An alumina powder was added in water to make an alumina slurry. Platinum tetramonoethanolamine was added to the slurry drop-wise, and then palladium nitrate was added to the slurry in the same fashion. The slurry was washcoated onto an aluminum titanate substrate. The substrate has a porosity of about 51%, a mean particle size of about 14-15 μm, a cell density of about 300 cpsi, and wall

thickness of about 13 mil. The substrate dimension is 2" x 6" round, The coated filter was dried at 110° C for 2 hours and then calcined at 450° C for 2 hours. The amounts of Pt and Pd are equivalent to 23.3 g/ft ³ Pt and 11.7 g/ft ³ Pd, The amount of alumina was 0.35 g/in ³ . The washeoat loading is same for each of the coated filters.

[0051] The coefficient of thermal expansion (CTE) was measured for each of the coated filters from 25° to 1000° C. The CTE values at 1000° C are summarized in Figure 6. The CTEs are about 20.5, 12.3 and 10.0 for filters coated with "fine", "medium" and "coarse" alumina powder, respectively.

[0052] Comparative Examples J-L

[0053] A platinum tetramonoethanolamine hydroxide solution was impregnated onto Siralox powder via the incipient wetness technique in a Planetary mixer. Acetic acid (5% by weight relative to powder) was added to the powder. The precious metal impregnated powder was then dispersed into water to make a slurry. This slurry was milled using a continuous mill to reduce the particle size to 90% less than 4 micrometer (D ₉₀ < 4 μm). Before the completion of milling, Ce/Zr powder was added into the slurry. The slurry was then washcoated by immersing a filter substrate into the slurry with the inlet side of the substrate down and the outlet side just above (about ¹ A inch) the slurry level. The substrate was pulled out of the slurry, and a stream of air was blown from the outlet side until washeoat slurry stopped coming out. The coated sample was then dried at 110° C for 2 hours and calcined in air at 450° C for 2 hour. Three types of substrates were coated with the same slurry to achieve the following catalyst composition, 5 g/ft ³ , 0.2g/in ³ Siralox, 0.1 g/in ³ Ce/Zr. The properties of the 3 types of substrates are described in Table 1,

Table 1

[0054] Examples M-O

[0055] A dry milled alumina powder was used for the coating. This alumina powder has the following particle size distribution (PSD): 90% of the particles less than <5 μm and 90% of the particles larger than Ll μm. The PSD comparison between the wet milled slurry (from Examples J-L) and the dry milled alumina (this example) is illustrated in Figure 7.

[0056] The alumina powder was added in water to make an alumina slurry. Platinum tetramonoethanolamine was added to the slurry drop-wise, and then palladium nitrate was added to the slurry in the same fashion. The slurry was washcoated onto each of the three filter substrates shown in Table 1. The coated filters were dried at 110° C for 2 hours and then calcined at 450° C for 2 hours. The metal and washcoat loadings are as same as the ones for the reference samples.

[0057] Figure 8 shows a comparison of the CTEs (measured at 800° C) of the reference samples (Examples J-L) and the samples made from the dry milled alumina powder with less fines (Examples M-O). For each filter substrate, the CTE is significantly reduced by using powders with less fine particles.

[0058] Examples P-Q

[0059] The catalyst washcoat for samples P and Q contains the same amount of precious metals (50 g/ft , Pt/Pd=2:l) and base metal components (0.4 g/in support, 0.1 g/in ³ beta zeolite). Both samples were coated on the same type of filter substrate (SiC, 50% porosity, mean pore size ^~ 20 μm, 300 cpsi, 12 mil wall thickness). However, the washcoat slurries were made by different processes. Sample P was made by a process same as Sample A. Sample Q was made by a process same as Sample M.

[0060] The catalyzed soot filters (Samples P and Q) were tested in a flow reactor system with a feed containing 1000 ppm CO, 450 ppm hydrocarbons on a Cl basis, 100 ppm NO ₅ 10% O ₂ , 7% water, 5% CO ₂ with the balance made up with N ₂ . The hydrocarbon makeup was equal portions of propene, toluene and decane, all on Cl basis. The space velocity for the test was 35,000 h ^"1 . The system was equipped with CO, HC, CO ₂ analyzers as well as a FTIR spectrometer and a mass spectrometer, which were used

to determine the conversion efficiency of a catalyst. A catalyst was first saturated with the feed at 90° C for 90 seconds, the temperature was then ramped to 300° C at 20° C/minute. The concentrations of reactants and products were continuously monitored and recorded. The conversions of CO and total hydrocarbons (THC) at various times were calculated as a relative difference between the concentration in feed (without passing the catalyst) and the resulting concentration after passing through the catalyst. Before testing, the samples were aged in an apparatus at 700° C for four hours with flowing air and 10% steam, Samples were then aged in an apparatus at 800 ⁰ C for an additional four hows.

[0061] Figure 9 shows a comparison of the catalytic performance (CO and HC light- off curves) of Samples P and Q. Both CO and HC for Sample Q light-off at much lower temperatures (more active) compared to those of Sample P. The T50 (defined as the temperature at 50% conversion) for CO over Sample Q is 14 ⁰ C lower than that of Sample P, and the difference for HC T50 is 36 ⁰ C. According to one or more embodiments, the catalyzed soot filter exhibits a T50 for carbon monoxide of less than about 130° C when tested according to the procedure described above for Examples P and Q. In other embodiments, the catalyzed soot filter exhibits a T50 for hydrocarbons of less than about 130° C when tested according to the same procedure in Examples P and Q. In other embodiments, the catalyzed soot filter exhibits a T50 for carbon monoxide and hydrocarbons less than about 130° C when tested under these conditions. In yet other embodiments, the catalyzed soot filter exhibits a T70 (70% conversion) for hydrocarbons less than about 180° C, or less than about 160° C, or less than about 140° C or less than about 130° C when measured according to the procedure of Examples P and Q.

[0062] Accordingly, while the present invention has been disclosed in connection with various embodiments thereof, it should be understood that other embodiments might fall within the spirit and scope of the invention, as defined by the following claims.

[0063] Reference throughout this specification to "one embodiment," "certain embodiments," "one or more embodiments" or "an embodiment", means that a particular feature, structure, material, or characteristic described in connection with the embodiment is included in at least one embodiment of the invention. Thus, the appearances of the

phrases such as "in one or more embodiments," "in certain embodiments," "in one embodiment" or "in an embodiment" in various places throughout this specification are not necessarily referring to the same embodiment of the invention. Furthermore, the particular features, structures, materials, or characteristics may be combined in any suitable manner in one or more embodiments.

[0064] Although the invention herein has been described with reference to particular embodiments, it is to be understood that these embodiments are merely illustrative of the principles and applications of the present invention. It will be apparent to those skilled in the art that various modifications and variations can be made to the method and apparatus of the present invention without departing from the spirit and scope of the invention. Thus, it is intended that the present invention include modifications and variations that are within the scope of the appended claims and their equivalents.