CLEANING AND/OR TREATMENT COMPOSITIONS COMPRISING MALODOR REDUCTION COMPOSITIONS

Title:

CLEANING AND/OR TREATMENT COMPOSITIONS COMPRISING MALODOR REDUCTION COMPOSITIONS

Document Type and Number:

WIPO Patent Application WO/2016/049394

Kind Code:

Abstract:

The present invention relates to cleaning and/or treatment compositions comprising malodor reduction compositions and methods of making and using such cleaning and/or treatment compositions and malodor reduction compositions. As a result, such malodor reduction compositions do not unduely interfere with the scent of the perfumed or unperfumed cleaning and/or treatment compositions that comprise such compositions and the perfumed or unperfumed situs that is treated with such cleaning and/or treatment compositions.

See also references of EP 3197422A1

Attorney, Agent or Firm:

KREBS, Jay A. (Global Patent ServicesOne Procter & Gamble Plaza, C8-22, Cincinnati Ohio, US)

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Claims:

CLAIMS

What is claimed:

1. A cleaning and/or treatment composition having a viscosity of from 10 mPa.s to 50,000 mPa.s, preferably from 50 mPa.s to 2000 mPa.s, most preferably from 75 mPa.s to 400 mPa.s, a pH from 3 to 10, preferably from 4 to 8, most preferably from 5 to 8, said composition comprising, based on total cleaning and/or treatment composition weight,

a) a sum total of from 0.00025% to 0.5%, preferably from 0.0025% to 0.1%, more preferably from 0.005% to 0.075%, most preferably from 0.01% to 0.05% of 1 or more malodor reduction materials, preferably 1 to 20 malodor reduction materials, more preferably 1 to 15 malodor reduction materials, most preferably 1 to 10 malodor reduction materials, each of said malodor reduction materials having a MORV of at least 0.5, preferably from 0.5 to 10, more preferably from 1 to 10, most preferably from 1 to 5, and preferably each of said malodor reduction materials having a Universal MORV, said sum total of malodor reduction materials having a Blocker Index of less than 3, more preferable less than 2.5 even more preferably less than 2 and still more preferably less than 1 and most preferably 0 and/or a Blocker Index average of 3 to 0.001; and

b) from 0.25% to 50%, preferably from 0.5% to 25%, more preferably from 0.75% to 15%, most preferably from 1% to 10% of solublizing agent, preferably said solubilizing agent is selected from the group consisting of solvent, emulsifier, surfactant, fabric softener active and mixtures thereof, preferably said solvent is present in the range of 0.25% to 50%, preferably, 1% to 20% and most preferably 2% to 10%, preferably said emulsifier is present in the range of 0.1% to 10% more preferably in the range of 0.5% to 5%, preferably said surfactant is present in the range of 0.1 to 35%, preferably in the range of 1% to 25%, most preferably in the range of 1.5% to 20%, preferably said fabric softener active is present in the range of 1% to 35%, more preferably in the range of 2% to 20% and most preferably in the range of 3% to 10%.

2. A cleaning and/or treatment composition according to Claim 1 wherein:

a) said surfactant is selected from the group consisting of nonionic surfactants, anionic surfactants, cationic surfactants, ampholytic surfactants, zwitterionic surfactants, semi-polar nonionic surfactants and mixtures thereof; b) said solvent is selected from the group consisting of hydrogenated castor oil, glycols, alcohols, and mixtures thereof

c) said fabric softener active is selected from the group consisting of a quaternary ammonium compound, an amine and mixtures thereof, preferably said quaternary ammonium compound is selected from the group consisting of bis-(2-hydroxypropyl)- dimethylammonium methylsulphate fatty acid ester, l,2-di(acyloxy)-3- trimethylammoniopropane chloride., N, N-bis(stearoyl-oxy-ethyl) N,N-dimethyl ammonium chloride, N,N-bis(tallowoyl-oxy-ethyl) Ν,Ν-dimethyl ammonium chloride, N,N-bis(stearoyl-oxy-ethyl) N-(2 hydroxyethyl) N-methyl ammonium methylsulfate., 1, 2 di (stearoyl-oxy) 3 trimethyl ammoniumpropane chloride, dicanoladimethylammonium chloride, di(hard)tallowdimethylammonium chloride dicanoladimethylammonium methylsulfate, 1-methyl- 1 -stearoylamidoethyl-2- stearoylimidazolinium methylsulfate, 1 -tallowylamidoethyl-2-tallowylimidazoline, Dipalmethyl Hydroxyethylammoinum Methosulfate and mixtures thereof.

3. A cleaning and/or treatment composition according to any preceding claim, wherein said malodor reduction materials have a Fragrance Fidelity Index of less than 3, preferably less than 2, more preferably less than 1 and most preferably 0 and/or a Fragrance Fidelity Index average of 3 to 0.001 Fragrance Fidelity Index.

4. A cleaning and/or treatment composition according to any preceding claim, said cleaning and/or treatment composition comprising a perfume and having a weight ratio of parts of malodor reduction composition to parts of perfume of from 1:20,000 to 3000:1, preferably from 1:10,000 to 1,000:1, more preferably 5,000: 1 to 500:1 and most preferably from 1:15 to 1:1.

5. A cleaning and/or treatment composition according to any preceding claim comprising one or more malodor reduction materials having a log P greater than 3, preferably greater than 3 but less than 8, preferably said one or more malodor reduction materials are selected from the group consisting of 2-ethylhexyl (Z)-3-(4-methoxyphenyl)acrylate; 2,4-dimethyl-2-(5,5,8,8- tetramethyl-5,6,7,8-tetrahydronaphthalen-2-yl)-l,3-dioxolane; l,l-dimethoxynon-2-yne; 3- methoxy-7,7-dimethyl-10-methylenebicyclo[4.3.1]decane; methoxycyclododecane; 1,1- dimethoxycyclododecane; (Z)-tridec-2-enenitrile; (2-hydroxy-4- methoxyphenyl)(phenyl)methanone; 2,4a,5,8a-tetramethyl-l,2,3,4,4a,7,8,8a- octahydronaphthalen-l-yl formate; l,8-dioxacycloheptadecan-9-one; 4-(tert-pentyl)cyclohexan-

1- one; 2-methoxy-l,l'-biphenyl; 3a,5, 6,7,8, 8b-hexahydro-2,2, 6,6,7, 8, 8-heptamethyl-4H- indeno(4,5-d)-l,3-dioxole; 7-isopropyl-8,8-dimethyl-6,10-dioxaspiro[4.5]decane; octyl furan-2- carboxylate; octyl acetate; 2-heptyl-4-methyl-l,3-dioxolane; octanal; 1,1-dimethoxyoctane; 7- methyl-3-methyleneocta-l,6-diene; 2-methyl-6-methyleneoct-7-en-2-yl acetate; tetradecanal; tetradecanenitrile; 2,2,6,8-tetramethyl-l,2,3,4,4a,5,8,8a-octahydronaphthalen-l-ol; 2-((lS,5R)- 6,6-dimethylbicyclo[3.1. l]hept-2-en-2-yl)ethyl acetate; (4R,4aS,6R)-4,4a-dimethyl-6-(prop-l-en-

2- yl)-4,4a,5,6,7,8-hexahydronaphthalen-2(3H)-one; nonan-l-ol; nonanal; 12-methyl-14-tetradec- 9-enolide; N-ethyl-2-isopropyl-5-methylcyclohexane- 1-carboxamide; 2-methoxynaphthalene; (E)-3,7,ll-trimethyldodeca-l,6,10-trien-3-ol; (Z)-3,7-dimethylocta-2,6-dien-l-ol; methyl (E)- non-2-enoate; 10-isopropyl-2,7-dimethyl-l-oxaspiro[4.5]deca-3,6-diene; 2-(2-(4- methylcyclohex-3-en-l-yl)propyl)cyclopentan-l-one; (E)-4-(2,2,3,6-tetramethylcyclohexyl)but-

3- en-2-one; (4-(4-methylpent-3-en-l-yl)cyclohex-3-en-l-yl)methyl acetate; 2-(tert-butyl)-4,5,6- trimethyl-l,3-phenylene dinitrite; l,7-dioxacycloheptadecan-8-one; l-(4-(tert-butyl)-2,6- dimethyl-3,5-dinitrophenyl)ethan-l-one; l-(tert-butyl)-2-methoxy-4-methyl-3,5-dinitrobenzene; 3-methylcyclopentadecan-l-one; (E)-3-methylcyclopentadec-4-en-l-one; l-(4- isopropylcyclohexyl)ethan-l-ol; (E)-dec-5-enoic acid; methyl non-2-ynoate; 2-methyldecanal;

6.6- dimethoxy-2,5,5-trimethylhex-2-ene; methyl stearate; l,l-dimethoxy-2-methylundecane; undecan-2-one; 2-methylundecanal; methyl tetradecanoate; methyl (9Z,12Z)-octadeca-9,12- dienoate; methyl palmitate; l-methyl-2-phenoxybenzene; l-allyl-4-methoxybenzene; 1- (naphthalen-2-yl)ethan-l-one; methyl oct-2-ynoate; methyl 2,6,6-trimethylcyclohex-2-ene-l- carboxylate; 7-isopropyl-10-methyl-l,5-dioxaspiro[5.5]undecan-3-ol; 3-(3-(tert-butyl)phenyl)-2- methylpropanal; (E)-4-(4,8-dimethylnona-3,7-dien-l-yl)pyridine; (E)-trideca-3,12-dienenitrile; 2,2-dimethyl-3-(m-tolyl)propan-l-ol; 8-isopropyl-6-methylbicyclo[2.2.2]oct-5-ene-2- carbaldehyde; (S)-l-methyl-4-(prop-l-en-2-yl)cyclohex-l-ene; 3,7-dimethylocta-l,6-dien-3-yl octanoate; 3,7-dimethylocta-l,6-dien-3-yl isobutyrate; 3,7-dimethylocta-l,6-dien-3-yl benzoate;

3.7- dimethylocta-l,6-dien-3-yl 2-aminobenzoate; (2Z,6E)-3,7-dimethylnona-2,6-dienenitrile; 3- (4-methylcyclohex-3-en-l-yl)butanal; (2,5-dimethyl-l,3-dihydroinden-2-yl)methanol; 3-(4-(tert- butyl)phenyl)-2-methylpropanal; dodecan-l-ol; dodecyl acetate; dodecanoic acid; 5-hexyl-5- methyldihydrofuran-2(3H)-one; dodecanal; 4-(l-ethoxyvinyl)-3,3,5,5-tetramethylcyclohexan-l- one; ((3S,3aR,6R,8aS)-7,7-dimethyl-8-methyleneoctahydro-lH-3a,6-methanoazulen-3- yl)methanol; 5-(sec-butyl)-2-(2,4-dimethylcyclohex-3-en-l-yl)-5-methyl-l,3-dioxane; (1-methyl- 2-((l,2,2-trimethylbicyclo[3.1.0]hexan-3-yl)methyl)cyclopropyl)methanol; 2- propylheptanenitrile; 2-hexylcyclopentan-l-one; 2,6,9,10-tetramethyl-l-oxaspiro(4.5)deca-3,6- diene; isopropyl palmitate; isopropyl tetradecanoate; isopropyl dodecanoate; (E)-cyclohexadec-8- en-l-one; (2S,5S)-2-isopropyl-5-methylcyclohexan-l-one; 2-hexylcyclopent-2-en-l-one;

(2S,5S)-2-isopropyl-5-methylcyclohexan-l-one; 4-(4-methylpent-3-en-l-yl)cyclohex-3-ene-l- carbaldehyde; (Z)-l-(benzyloxy)-2-methoxy-4-(prop-l-en-l-yl)benzene; l-((2S,3S)-2,3,8,8- tetramethyl- 1 ,2,3,4,5, 6,7, 8-octahydronaphthalen-2-yl)ethan- 1-one; 6-(sec-butyl)quinoline; 2- (cyclohexyloxy)-l,7,7-trimethylbicyclo[2.2.1]heptane; (1R,2R,4S)-1,7,7- trimethylbicyclo[2.2.1]heptan-2-yl propionate; (lS,2S,4S)-l,7,7-trimethylbicyclo[2.2.1]heptan-2- yl isobutyrate; 4-((2R)-l,7,7-trimethylbicyclo[2.2.1]heptan-2-yl)cyclohexan-l-ol; (1R,4S)-1,7,7- trimethylbicyclo[2.2.1]heptan-2-yl acetate; 2-(4-isopropylcyclohexa-l,4-dien-l-yl)ethyl formate; isopentyl (E)-undec-6-enoate; isopentyl dodecanoate; (E)-oxacycloheptadec-10-en-2-one; (E)- non-2-enenitrile; (E)-8-(lH-indol-l-yl)-2,6-dimethyloct-7-en-2-ol; 8,8-di(lH-indol-l-yl)-2,6- dimethyloctan-2-ol; 2-cyclododecylpropan-l-ol; 3-methyl-5-phenylpentanenitrile; 2,3-dihydro- 3,3-dimethyl-lH-indene-5-propanal; 3-(3,3-dimethyl-2,3-dihydro-lH-inden-5-yl)propanal; hexyl octanoate; hexyl hexanoate; (Z)-2-benzylideneoctanal; hexyl benzoate; (Z)-hex-l-en-l-yl (Z)-2- methylbut-2-enoate; (E)-3,7-dimethylocta-2,6-dien-l-yl palmitate; oxacycloheptadecan-2-one; ethyl (lR,2R,3R,4R)-3-isopropylbicyclo[2.2. l]hept-5-ene-2-carboxylate; 2-(l-(3,3- dimethylcyclohexyl)ethoxy)-2-methylpropyl propionate; (E)-oxacyclohexadec-13-en-2-one; 6- butyl-2,4-dimethyl-3,6-dihydro-2H-pyran; 2-((3S,5R,8S)-3,8-dimethyl-l,2,3,4,5,6,7,8- octahydroazulen-5-yl)propan-2-ol; l-(2,6,6-trimethylcyclohex-2-en-l-yl)pentan-3-one; ethyl 2- ethyl-6,6-dimethylcyclohex-2-ene-l-carboxylate; (lZ,5Z)-l,5-dimethyl-8-(propan-2- ylidene)cyclodeca-l,5-diene; (lE,6E)-8-isopropyl-l-methyl-5-methylenecyclodeca-l,6-diene; (E)-3,7-dimethylocta-2,6-dien-l-yl 2-phenylacetate; (E)-3,7-dimethylocta-2,6-dien-l-yl 2- phenylacetate; (6E,10E)-3,7,ll,15-tetramethylhexadeca-l,6,10,14-tetraen-3-ol; (E)-2-(3,7- dimethylocta-2,6-dien-l-yl)cyclopentan- 1-one; 5-heptyldihydrofuran-2(3H)-one; l-methyl-4- (propan-2-ylidene)cyclohexyl acetate; l-methyl-4-(propan-2-ylidene)cyclohexan-l-ol;

(lR,4aR,8aS)-l-isopropyl-7-methyl-4-methylene-l,2,3,4,4a,5,6,8a-octahydronaphthalene; (Z)-4- (2,2-dimethyl-6-methylenecyclohexyl)but-3-en-2-one; (4aS,9aR)-3,5,5,9-tetramethyl- 2,4a,5,6,7,9a-hexahydro-lH-benzo[7]annulene; (lR,3aR,4R,7R)-l,4-dimethyl-7-(prop-l-en-2- yl)-l,2,3,3a,4,5,6,7-octahydroazulene; 2-((2R,4aR)-4a,8-dimethyl-l,2,3,4,4a,5,6,7- octahydronaphthalen-2-yl)propan-2-ol; 5-octyldihydrofuran-2(3H)-one; (Z)-l-(2,2-dimethyl-6- methylenecyclohexyl)but-2-en- 1-one; (lR,4aS,8aS)-l-isopropyl-7-methyl-4-methylene- l,2,3,4,4a,5,6,8a-octahydronaphthalene; l-(3,3-dimethylcyclohexyl)pent-4-en- 1-one; 4,6,6,7,8,8- hexamethyl-1, 3,4,6,7, 8-hexahydrocyclopenta[g]isochromene; furan-2-ylmethyl octanoate; furan- 2-ylmethyl hexanoate; furan-2-ylmethyl heptanoate; 2-methyldecanenitrile; 8,8-dimethyl- 3a,4,5,6,7,7a-hexahydro-lH-4,7-methanoinden-6-yl propionate; ethyl (3aR,4S,7R,7aR)- octahydro-3aH-4,7-methanoindene-3a-carboxylate; (6-isopropyl-9-methyl- 1 ,4- dioxaspiro[4.5]decan-2-yl)methanol; undec-10-enenitrile; 3-(2-ethylphenyl)-2,2- dimethylpropanal; (E)-4,8-dimethyldeca-4,9-dienal; (E)-4-((3aR,4R,7R,7aR)-l,3a,4,6,7,7a- hexahydro-5H-4,7-methanoinden-5-ylidene)-3-methylbutan-2-ol; 8, 8-dimethyl-3a,4,5, 6,7,7a- hexahydro-lH-4,7-methanoinden-6-yl acetate; 3-(4-ethylphenyl)-2,2-dimethylpropanenitrile; 2- heptylcyclopentan-l-one; 1-ethoxyethoxy Cyclododecane; 3-cyclohexene-l-carboxylic acid, 2,6,6-trimethyl-, methyl ester; (2E,6E)-3,7,l l-trimethyldodeca-2,6,10-trien-l-yl acetate; (2E,6E)- 3,7,ll-trimethyldodeca-2,6,10-trien-l-ol; oxacyclohexadecan-2-one; (E)-cyclopentadec-4-en-l- one; l-cyclopentadec-4-en-l-one; l,4-dioxacycloheptadecane-5,17-dione; ethyl undec-10-enoate; ethyl palmitate; ethyl nonanoate; ethyl tetradecanoate; (E)-3,7-dimethylnona-l,6-dien-3-ol; ethyl dodecanoate; ethyl decanoate; ethyl 6,6-dimethyl-2-methylenecyclohex-3-ene-l-carboxylate; 6- ethyl-2,10,10-trimethyl-l-oxaspiro[4.5]deca-3,6-diene; 2-((lR,3S,4S)-4-methyl-3-(prop-l-en-2- yl)-4-vinylcyclohexyl)propan-2-ol; (E)-3-methyl-5-(2,2,3-trimethylcyclopent-3-en-l-yl)pent-4- en-2-ol; (E)-4-((3aS,7aS)-octahydro-5H-4,7-methanoinden-5-ylidene)butanal; 1,1- dimethoxydodecane; (R)-l-methyl-4-(prop-l-en-2-yl)cyclohex-l-ene; 7,9- dimethylspiro[5.5]undecan-3-one; oxydibenzene; diphenylmethane; 2-methyl-l-phenylpropan-2- yl butyrate; octahydro-lH-4,7-methanoinden-5-yl acetate; 2-methyl-5-(prop-l-en-2- yl)cyclohexyl acetate; 3,7-dimethyloct-6-en-3-ol; dibutylsulfane; 1,2-diphenylethane; 6- hexyltetrahydro-2H-pyran-2-one; (3R,4R)-l-isopropyl-4-methyl-3-(prop-l-en-2-yl)-4- vinylcyclohex-l-ene; (3S,3aS,5R)-3,8-dimethyl-5-(prop-l-en-2-yl)- 1,2,3, 3a,4, 5,6,7- octahydroazulene; 6-heptyltetrahydro-2H-pyran-2-one; (lS,8aR)-4,7-dimethyl-l-(propan-2-yl)- l,2,3,5,6,8a-hexahydronaphthalene; (Z)-l-((lR,2S)-2,6,6-trimethylcyclohex-3-en-l-yl)but-2-en- 1-one; (lS,8aS)-l-isopropyl-4,7-dimethyl-l,2,3,5,6,8a-hexahydronaphthalene; 3,7,7- trimethylbicyclo[4.1.0]hept-3-ene; dec-9-en-l-ol; decyl propionate; 1,1-diethoxydecane; 1- cyclohexylethyl (E)-but-2-enoate; 3-(4-isopropylphenyl)-2-methylpropanal; cyclotetradecane; cyclopentadecanone; cyclohexyl 2-hydroxybenzoate; 3a,4,5,6,7,7a-hexahydro-lH-4,7- methanoinden-6-yl butyrate; 8,8-dimethyl-l,2,3,4,5,6,7,8-octahydronaphthalene-2-carbaldehyde; 3a,4,5,6,7,7a-hexahydro-lH-4,7-methanoinden-5-yl isobutyrate; (5R,6R)-3,6-dimethyl-5-(prop- l-en-2-yl)-6-vinyl-4,5,6,7-tetrahydrobenzofuran; 2-(3-phenylpropyl)pyridine; dodecanenitrile; (E)-cycloheptadec-9-en-l-one; 3-(4-methylcyclohex-3-en-l-yl)but-3-en-l-yl acetate; 3-(4- methylcyclohex-3-en-l-yl)butan-l-ol; (E)-3-methyl-5-phenylpent-2-enenitrile; (E)-2-(2,6- dimethylhepta- 1 ,5-dien- 1 -yl)-4-methyl- 1 ,3-dioxolane; (E)- 1 , l-dimethoxy-3 ,7-dimethylocta-2,6- diene; (E)-l,l-diethoxy-3,7-dimethylocta-2,6-diene; (E)-3,7-dimethylocta-l,3,6-triene; (E)- oxacycloheptadec-ll-en-2-one; (Z)-dec-4-enal; (E)-hex-3-en-l-yl (E)-hex-3-enoate; (Z)-hex-3- en-l-yl 2-hydroxybenzoate; (Z)-hex-3-en-l-yl benzoate; (Z)-hex-3-en-l-yl 2-methylbutanoate; cinnamyl propionate; cinnamyl isobutyrate; cinnamyl cinnamate; hexadecan-l-ol; (E)-l-(2,6,6- trimethylcyclohex-2-en-l-yl)hepta-l,6-dien-3-one; 2-methyl-4-(2,6,6-trimethylcyclohex-l-en-l- yl)butanal; (3aR,5aR,9aR,9bR)-3a,6,6,9a-tetramethyldodecahydronaphtho[2,l-b]furan; 1,6- dioxacycloheptadecan-7-one; l-(6-(tert-butyl)-l,l-dimethyl-2,3-dihydro-lH-inden-4-yl)ethan-l- one; (3R,3aR,6S,7S,8aS)-6-methoxy-3,6,8,8-tetramethyloctahydro-lH-3a,7-methanoazulene; (3R,3aS,6R,7R,8aS)-3,6,8,8-tetramethyloctahydro-lH-3a,7-methanoazulen-3-yl formate;

(3R,3aS,6R,7R,8aS)-3,6,8,8-tetramethyloctahydro-lH-3a,7-methanoazulen-6-yl acetate; (4Z,8Z)- l,5,9-trimethyl-13-oxabicyclo[10.1.0]trideca-4,8-diene; (3R,3aS,6R,7R,8aS)-3,6,8,8- tetramethyloctahydro-lH-3a,7-methanoazulen-6-ol; 5-methyl-l-(2,2,3-trimethylcyclopent-3-en- l-yl)-6-oxabicyclo[3.2.1]octane; 5-methyl-l-(2,2,3-trimethylcyclopent-3-en-l-yl)-6- oxabicyclo[3.2.1]octane; l,l,2,3,3-pentamethyl-l,2,3,5,6,7-hexahydro-4H-inden-4-one; (Z)- 4,11,1 l-trimethyl-8-methylenebicyclo[7.2.0]undec-3-en-5-yl acetate; (lS,2S,5R,8S)-4,4,8- trimethyltricyclo[6.3.1.02,5]dodecan-l-ol; 2-methyl-5-(prop-l-en-2-yl)cyclohex-2-en-l-yl acetate; octanenitrile; decanoic acid; decanal; 2,2-dimethyl-3-methylenebicyclo[2.2.1]heptane; ethyl 2-methyl-4-oxo-6-pentylcyclohex-2-ene- 1-carboxylate; 2,6-di-tert-butyl-4-methylphenol; butyl stearate; butyl undec-10-enoate; 2-methyl-4-(2,2,3-trimethylcyclopent-3-en-l-yl)butan-l- ol; 3-(4-(tert-butyl)phenyl)propanal; (lS,2S)-l,7,7-trimethylbicyclo[2.2.1]heptan-2-yl isobutyrate; l,7,7-trimethylbicyclo[2.2.1]heptan-2-yl acetate; 2-ethoxy-2,6,6-trimethyl-9- methylenebicyclo[3.3.1]nonane; (ethoxymethoxy)cyclododecane; (E)-l-methyl-4-(6-methylhept- 5-en-2-ylidene)cyclohex-l-ene; 3,3,6,7-tetramethyloctahydro-2H-chromene; (5R,10R)-6,10- dimethyl-2-(propan-2-ylidene)spiro[4.5]dec-6-en-8-one; l-methyl-4-(prop-l-en-2-yl)cyclohexyl acetate; (2Z,6E)-2,6-dimethyl-10-methylenedodeca-2,6,l 1-trienal; (R)-3-methylene-6-((S)-6- methylhept-5-en-2-yl)cyclohex-l-ene; (4aR,7R,8aS)-4a-methyl-l-methylene-7-(prop-l-en-2- yl)decahydronaphthalene; (Z)-2-methyl-5-((lS,2R,4R)-2-methyl-3- methylenebicyclo[2.2.1]heptan-2-yl)pent-2-en-l-ol; 6,6-dimethyl-2- methylenebicyclo [3.1.1 Jheptane; 2-ethoxynaphthalene ; ( 1 S ,4R,7R)- 1 ,4,9 ,9-tetramethyl- 1,2,3,4,5, 6,7, 8-octahydro-4,7-methanoazulene; (laS,5aR,9aR)-la,5,5,7-tetramethyl- la,2,3,4,5,5a,8,9-octahydrobenzo[l,7]cyclohepta[l,2-b]oxirene; (R)-3,5,5,9-tetramethyl- 2,4a,5,6,7,8-hexahydro-lH-benzo[7]annulene; (lS,4S)-l,4-dimethyl-7-(propan-2-ylidene)- 1,2,3,4,5, 6,7, 8-octahydroazulene; (E)-7,ll-dimethyl-3-methylenedodeca-l,6,10-triene;

(lR,2S,6S,7S,8S)-8-isopropyl-l-methyl-3-methylenetricyclo[4.4.0.02,7]decane;

(3R,3aS,7S,8aS)-3,8,8-trimethyl-6-methyleneoctahydro-lH-3a,7-methanoazulene; (1R,9S,Z)- 4,ll,l l-trimethyl-8-methylenebicyclo[7.2.0]undec-4-ene; (S)-4-methyl-l-((S)-6-methylhept-5- en-2-yl)cyclohex-3-en-l-ol; benzyl dodecanoate; benzyl cinnamate; benzyl benzoate; 2'- isopropyl-l,7,7-trimethylspiro[bicyclo[2.2.1]heptane-2,4'-[l,3]dioxane]; 4-(4-methylpent-3-en-l- yl)cyclohex-3-ene-l-carbonitrile; methyl (E)-2-((7-hydroxy-3,7- dimethyloctylidene)amino)benzoate; 4-methoxybenzyl 2-phenylacetate; pentyl (Z)-3- phenylacrylate; (3aR,5aS,9aS,9bR)-3a,6,6,9a-tetramethyldodecahydronaphtho[2,l-b]furan; (4aR,5R,7aS,9R)-2,2,5,8,8,9a-hexamethyloctahydro-4H-4a,9-methanoazuleno[5,6- d][l,3]dioxole; 2,5, 5-trimethyl-l, 2,3,4,5, 6,7, 8-octahydronaphthalen-2-ol; 2,5,5-trimethyl- l,2,3,4,4a,5,6,7-octahydronaphthalen-2-ol; l-((2-(tert-butyl)cyclohexyl)oxy)butan-2-ol;

(3S,5aR,7aS,l laS,l lbR)-3,8,8,lla-tetramethyldodecahydro-5H-3,5a-epoxynaphtho[2,l- cjoxepine; 2,2,6,6,7, 8, 8-heptamethyldecahydro-2H-indeno[4,5-b]furan; 2,2,7,7,8,9,9- heptamethyldecahydroindeno[4,3a-b]furan; 2-(sec-butyl)-l-vinylcyclohexyl acetate; (4R,4aS)- 4,4a-dimethyl-6-(propan-2-ylidene)-4,4a,5,6,7,8-hexahydronaphthalen-2(3H)-one; 2-(4- methylcyclohex-3-en-l-yl)propan-2-yl propionate; (2Z,6E,9E)-2,6,10-trimethyldodeca-2,6,9,l 1- tetraenal; (2R,4aR,8aR)-4a,8-dimethyl-2-(prop-l-en-2-yl)-l,2,3,4,4a,5,6,8a- octahydronaphthalene; l,7-dimethyl-7-(4-methylpent-3-en-l-yl)tricyclo[2.2.1.02,6]heptane; (E)- 5-(2,3-dimethyltricyclo[2.2.1.02,6]heptan-3-yl)-2-methylpent-2-en-l-ol; (lR,3aS,7S,8aR)- l,4,9,9-tetramethyl-2,3,6,7,8,8a-hexahydro-lH-3a,7-methanoazulene; l-(5,5-dimethylcyclohex-

1- en-l-yl)pent-4-en-l-one; (lS,4aS,8aR)-l-isopropyl-4,7-dimethyl-l,2,4a,5,6,8a- hexahydronaphthalene; (R,Z)-l-(2,6,6-trimethylcyclohex-2-en-l-yl)pent-l-en-3-one; l-methyl-4- (prop-l-en-2-yl)cyclohex-l-ene; (Z)-4-(2,5,6,6-tetramethylcyclohex-2-en-l-yl)but-3-en-2-one; (lZ,4E,8Z)-2,6,6,9-tetramethylcycloundeca-l,4,8-triene; (4aR,8S,9aS)-3,5,5,8-tetramethyl-9- methylene-2,4a,5,6,7,8,9,9a-octahydro-lH-benzo[7]annulene; (laR,4R,4aR,7bS)-l, 1,4,7- tetramethyl-la,2,3,4,4a,5,6,7b-octahydro-lH-cyclopropa[e]azulene; l,4-dimethyl-7-(prop-l-en-

2- yl)-l,2,3,4,5,6,7,8-octahydroazulene; (3E,6E)-3,7,l l-trimethyldodeca-l,3,6,10-tetraene; 7,7- dimethyl-2-methylenebicyclo[2.2.1]heptane; 2-((2R,4aR,8aR)-4a,8-dimethyl-l,2,3,4,4a,5,6,8a- octahydronaphthalen-2-yl)propan-2-ol; (R)-l-methyl-4-(6-methylhept-5-en-2-yl)benzene;

(3aR,3bR,4S,7R,7aS)-4-isopropyl-7-methyl-3a,3b,4,5,6,7-hexahydro-lH- cyclopenta[l,3]cyclopropa[l,2]benzene; (laS,2aR,3R,5aS,7R,7aR)-3, 6,6,7a- tetramethyloctahydro-2H-2a,7-methanoazuleno[5,6-b]oxirene; (lR,4S,4aR,8aR)-4-isopropyl-l,6- dimethyl-l,2,3,4,4a,7,8,8a-octahydronaphthalen-l-ol; (lS,4aR,8aR)-l-isopropyl-4,7-dimethyl- l,2,4a,5,6,8a-hexahydronaphthalene; (R)-2-((R)-4-methylcyclohex-3-en-l-yl)hex-5-en-2-ol; (Z)- 1 -methyl-4-(6-methylhepta-2,5 -dien-2-yl)cyclohex- 1 -ene; 2, 6-dimethyl-6-(4-methylpent-3 -en- 1 - yl)bicyclo[3.1.1]hept-2-ene; (E)-2-benzylideneheptan-l-ol; (E)-2-benzylideneheptyl acetate; (Z)- (2-(diethoxymethyl)hept- 1 -en- 1 -yl)benzene; (E)-2-benzylideneheptanal ; ( 1 S ,4aR,8aS)- 1 - isopropyl-4,7-dimethyl-l,2,4a,5,6,8a-hexahydronaphthalene; (3R,5aS,9aR)-2,2,5a,9-tetramethyl- 3,4,5,5a,6,7-hexahydro-2H-3,9a-methanobenzo[b]oxepine; l-methyl-4-(4-methylpent-3-en-l- yl)cyclohex-3-ene-l-carbaldehyde; 3-methyl-l-phenylpentan-3-ol; 2,6,10-trimethylundecanal; allyl 3-cyclohexylpropanoate; (laR,4aS,7R,7aR,7bS)-l,l,7-trimethyl-4-methylenedecahydro-lH- cyclopropa[e]azulene; (E)-undec-9-enal; methyl (E)-2-(((3,5-dimethylcyclohex-3-en-l- yl)methylene)amino)benzoate; 2,6, 10-trimethylundec-9-enal; (7,7,8,8-tetramethyloctahydro- 2,3b-methanocyclopenta[l,3]cyclopropa[l,2]benzen-4-yl)methyl acetate; nonyl acetate; (2-(l- propoxyethoxy)ethyl)benzene; (Z)-2-(4-methylbenzylidene)heptanal; dec-9-enal; (Z)- oxacycloheptadec-8-en-2-one; (2S,4aR,8aR)-4a,8-dimethyl-2-(prop-l-en-2-yl)-l,2,3,4,4a,5,6,8a- octahydronaphthalene; 2-((2S,4aR,8aR)-4a,8-dimethyl-l,2,3,4,4a,5,6,8a-octahydronaphthalen-2- yl)propan-2-ol; l-(3,5,5,6,8,8-hexamethyl-5,6,7,8-tetrahydronaphthalen-2-yl)ethan-l-one; 6- isopropylquinoline; 3-(6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)propanal; 6,10,14- trimethylpentadecan-2-one; (E)-cyclohexadec-5-en-l-one; l-isopropyl-4-methylcyclohex-3-en-l- ol; l-isopropyl-4-methylcyclohex-3-en-l-ol; 3,6-dimethyl-4,5,6,7-tetrahydrobenzofuran;

(laR,2S,4aS)-2,4a,8,8-tetramethyloctahydrocyclopropa[d]naphthalen-3(lH)-one; (Z)-dodec-2- enal; (E)-hex-3-en-l-yl 3-methylbutanoate; 3,6-dimethyloctan-3-yl acetate; 3-(4- isopropylphenyl)propanal; (Z)-undec-2-enenitrile; (E)-undec-2-enal; phenethyl butyrate; (Z)- non-2-enal; nonan-2-ol; nonan-2-one; 2-isobutylquinoline; (E)-2-hexylidenecyclopentan-l-one; 2-heptyltetrahydrofuran; (E)-dec-2-enal; 2,6-dimethyloctanal; decan-l-ol; (E)-hept-l-en-l-yl acetate; undec-10-en-l-ol; undec-10-enal; 2-((2R,4aS)-4a,8-dimethyl-l,2,3,4,4a,5,6,7- octahydronaphthalen-2-yl)propan-2-ol; l-isopropyl-4-methyl-7-thiabicyclo[2.2.1]heptane;

(3E,5Z)-undeca-l,3,5-triene; 3,7-dimethyloct-6-en-3-ol; l,3,3-trimethylbicyclo[2.2.1]heptan-2-yl acetate; 1, 1,2,3, 3-pentamethyl-2,3-dihydro-lH-indene; (Z)-6,10-dimethylundeca-5,9-dien-2-yl acetate; (Z)-dodec-3-enal; (S)-5-heptyldihydrofuran-2(3H)-one; (R)-5-heptyldihydrofuran-2(3H)- one; (E)-6,10-dimethylundeca-5,9-dien-2-yl acetate; (Z)-3-methyl-5-phenylpent-2-enenitrile; (2S,5S,6S)-2,6,10,10-tetramethyl-l-oxaspiro[4.5]decan-6-ol; (2E)-3-methyl-5-phenyl-2- pentenenitrile; (2S,5R)-2-isopropyl-5-methylcyclohexan-l-one; (R,E)-2-methyl-4-(2,2,3- trimethylcyclopent-3-en-l-yl)but-2-en-l-ol; 2-(8-isopropyl-6-methylbicyclo[2.2.2]oct-5-en-2-yl)- 1,3-dioxolane; (E)-4-(2,2-dimethyl-6-methylenecyclohexyl)-3-methylbut-3-en-2-one; 3-(3- isopropylphenyl)butanal; 3-(l-ethoxyethoxy)-3,7-dimethylocta-l,6-diene; 3a,4,5,6,7,7a- hexahydro-lH-4,7-methanoinden-6-yl propionate; 2-((3S,3aS,5R)-3,8-dimethyl-l,2,3,3a,4,5,6,7- octahydroazulen-5-yl)propan-2-ol; benzyl 2-phenylacetate; 3-(6,6-dimethylbicyclo[3.1.1]hept-2- en-2-yl)-2,2-dimethylpropanal; 2-methyl-5-(6-methylhept-5-en-2-yl)bicyclo[3.1.0]hex-2-ene; 1- (1,1,2,3, 3, 6-hexamethyl-2,3-dihydro-lH-inden-5-yl)ethan-l-one; (E)-tridec-2-enal;

(lR,4S,4aS,6R,8aS)-4,8a,9,9-tetramethyloctahydro-l,6-methanonaphthalen-l(2H)-ol; p-tolyl hexanoate; 5-hexyl-4-methyldihydrofuran-2(3H)-one; ethyl (2Z,4E)-deca-2,4-dienoate; 2,4- dimethyl-6-phenyl-3,6-dihydro-2H-pyran; 2-cyclohexylidene-2-phenylacetonitrile; (4-(prop-l- en-2-yl)cyclohex-l-en-l-yl)methyl acetate; (4-(prop-l-en-2-yl)cyclohex-l-en-l-yl)methanol; (2- isopropoxyethyl)benzene; 2-cyclohexylhepta-l,6-dien-3-one; (2-(cyclohexyloxy)ethyl)benzene; phenethyl 2-methylbutanoate; phenethyl 2-phenylacetate; phenyl benzoate; phenethyl benzoate; 2-(6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)acetaldehyde; 3a,4,5,6,7,7a-hexahydro-lH-4,7- methanoinden-6-yl pivalate; (E)-3,3-dimethyl-5-(2,2,3-trimethylcyclopent-3-en-l-yl)pent-4-en-2- ol; l-methyl-4-(4-methylpent-3-en-l-yl)cyclohex-3-ene-l-carbaldehyde; p-tolyl 2-phenylacetate; Ethyl 2,4,7-decatrienoate; 2-benzyl-4,4,6-trimethyl-l,3-dioxane; 2,4-dimethyl-4- phenyltetrahydrofuran; (2R,4a'R,8a'R)-3,7'-dimethyl-3',4',4a',5',8',8a'-hexahydro-l'H- spiro[oxirane-2,2'-[l,4]methanonaphthalene]; (Z)-6-ethylideneoctahydro-2H-5,8- methanochromene; 2-((S)-l-((S)-3,3-dimethylcyclohexyl)ethoxy)-2-oxoethyl propionate; methyl 2,2-dimethyl-6-methylenecyclohexane-l-carboxylate; 4-methyl-2-phenyl-3,6-dihydro-2H-pyran; 2,2,7, 9-tetramethylspiro(5.5)undec-8-en-l-one; 3-methyl-5-(2,2,3-trimethylcyclopent-3-en-l- yl)pentan-2-ol; (Z)-2-ethyl-4-(2,2,3-trimethylcyclopent-3-en-l-yl)but-2-en-l-ol; (E)-2-methyl-4- (2,2,3 -trimethylcyclopent-3 -en- 1 -yl)but-2-en- 1 -ol; 1 -(3-hydroxy-3 -methylpent-4-en- 1-yl)- 2,5,5,8a-tetramethyldecahydronaphthalen-2-ol; (4aR,6aS,10aS,10bR)-3,4a,7,7,10a-pentamethyl- 4a,5,6,6a,7,8,9,10,10a,10b-decahydro-lH-benzo[i]chromene; (4aR,8aR)-4a,8-dimethyl-2- (propan-2-ylidene)-l,2,3,4,4a,5,6,8a-octahydronaphthalene; 2-(l-(3,3- dimethylcyclohexyl)ethoxy)-2-methylpropyl cyclopropanecarboxylate; 3-(4-isobutylphenyl)-2- methylpropanal; ( laR,4aR,7S,7aR,7bR)- 1 , 1 ,7-trimethyl-4-methylenedecahydro- 1H- cyclopropa[e]azulen-7-ol; l-(spiro[4.5]dec-7-en-7-yl)pent-4-en-l-one; (Z)-dodec-4-enal;

(lS,4S,4aR,8aR)-4-isopropyl-l,6-dimethyl-l,2,3,4,4a,7,8,8a-octahydronaphthalen-l-ol;

(lS,4S,4aR,8aS)-4-isopropyl-l,6-dimethyl-l,2,3,4,4a,7,8,8a-octahydronaphthalen-l-ol; 3- methyl-2-pentylcyclopentan-l-one; 2,6,10,10-tetramethyl-l-oxaspiro[4.5]dec-6-ene; (laR,4aS)- 2,4a,8,8-tetramethyl-l,la,4,4a,5,6,7,8-octahydrocyclopropa[d]naphthalene; l-isopropyl-2- methoxy-4-methylbenzene; l-(2,2,6-trimethylcyclohexyl)hexan-3-ol; (2E,6E)-3,7,11- trimethyldodeca-2,6,10-trien-l-ol; (Z)-dec-2-enal; (E)-non-2-enal; (E)-dec-4-enal; (Z)- oxacycloheptadec-8-en-2-one; (Z)-3,7-dimethylocta-l,3,6-triene; (Z)-3,7-dimethylocta- 1,3,6- triene; (E)-3,7-dimethylocta-2,6-dien-l-ol; (lR-(lalpha,3alpha,4aalpha))-2,3,4,4a,5,6-hexahydro- 2,2-dimethyl-l,3-methanonaphthalen-7(lH)-one; tridecan-l-ol; methyl 2-((l-hydroxy-3- phenylbutyl)amino)benzoate; l-((2E,5Z,9Z)-2,6,10-trimethylcyclododeca-2,5,9-trien-l-yl)ethan- 1- one; decahydro-2,6,6,7,8,8-hexamethyl-2h-indeno(4,5-b)furan; pentamethyl octahydroindenodioxane; undecanal; (E)-4-methyldec-3-en-5-ol; (3R,4aS,5R)-4a,5-dimethyl-3- (prop-l-en-2-yl)-l,2,3,4,4a,5,6,7-octahydronaphthalene; 2-((2R,8R,8aS)-8,8a-dimethyl- 1,2,3,4,6,7, 8, 8a-octahydronaphthalen-2-yl)propan-2-ol; (Z)-2-methyl-4-(2,6,6-trimethylcyclohex-

2- en-l-yl)but-2-enal; l-methoxy-3a,4,5,6,7,7a-hexahydro-lH-4,7-methanoindene; methyl (Z)-2- ((3-(4-(tert-butyl)phenyl)-2-methylpropylidene)amino)benzoate; 2,4,6-trimethyl-4-phenyl-l,3- dioxane; l-((3R,3aR,7R,8aS)-3,6,8,8-tetramethyl-2,3,4,7,8,8a-hexahydro-lH-3a,7- methanoazulen-5-yl)ethan- 1-one; methyl (Z)-2-(((2,4-dimethylcyclohex-3-en-l- yl)methylene)amino)benzoate; 4,8-dimethyl-2-(propan-2-ylidene)- 1,2,3, 3a,4,5, 6,8a- octahydroazulen-6-ol; 4,8-dimethyl-2-(propan-2-ylidene)-l,2,3,3a,4,5,6,8a-octahydroazulen-6-yl acetate; decahydro-3H-spiro[furan-2,5'-[4,7]methanoindene] ; (2Z,6E)-nona-2,6-dienenitrile; (laR,4S,4aS,7R,7aS,7bS)-l,l,4,7-tetramethyldecahydro-lH-cyclopropa[e]azulen-4-ol;

3,5,5,6,7,8,8-heptamethyl-5,6,7,8-tetrahydronaphthalene-2-carbonitrile; (lS,2S,3S,5R)-2,6,6- trimethylspiro[bicyclo[3.1.1]heptane-3,l'-cyclohexan]-2'-en-4'-one; Γ,Γ,5',5'- tetramethylhexahydro-2'H,5'H-spiro[[l,3]dioxolane-2,8'-[2,4a]methanonaphthalene];

(2'S,4a'S,8a'S)-l',l',5',5'-tetramethylhexahydro-2'H,5'H-spiro[[l,3]dioxolane-2,8'- [2,4a]methanonaphthalene]; (lR,8aR)-4-isopropyl-l,6-dimethyl- 1,2,3,7, 8,8a- hexahydronaphthalene; (7,7,8,8-tetramethyloctahydro-2,3b- methanocyclopenta[l,3]cyclopropa[l,2]benzen-4-yl)methanol; l-ethoxy-4-(tert- pentyl)cyclohexane; (3Z)-l-(2-buten-l-yloxy)-3-hexene; 4-(2-methoxypropan-2-yl)-l- methylcyclohex-l-ene; 3-methoxy-3,7-dimethylocta-l,6-diene; 3,7-dimethyloctanal; hexyl 2- hydroxybenzoate; hexyl (Z)-but-2-enoate; (Z)-3,7-dimethylocta-2,6-dien-l-yl formate; (Z)-l- (2,6,6-trimethylcyclohex-l-en-l-yl)pent-l-en-3-one; (E)-3,7-dimethylocta-4,6-dien-3-ol; methyl (Z)-3,7-dimethylocta-2,6-dienoate; ((ls,4s)-4-isopropylcyclohexyl)methanol; 3,7-dimethylocta- l,6-dien-3-yl propionate; 3,7-dimethylocta-l,6-dien-3-yl formate; 3,7-dimethylocta-l,6-dien-3-yl butyrate; 3,7-dimethylocta-l,6-dien-3-yl acetate; 3,7-dimethylocta-l,6-dien-3-ol; 2,2-dimethyl-5- phenylhexanenitrile; (Z)-4-(6,6-dimethylcyclohex-2-en- l-yl)-3-methylbut-3-en-2-one; 7- methyloctyl acetate; isopentyl octanoate; hexyl propionate; hexyl butyrate; hexyl 2- methylbutanoate; hexyl furan-2-carboxylate; heptyl acetate; (Z)-3,7-dimethylocta-2,6- dienenitrile; (E)-3,7-dimethylocta-2,6-dien-l-yl formate; (E)-3,7-dimethylocta-2,6-dien-l-yl octanoate; (E)-3,7-dimethylocta-2,6-dien-l-yl benzoate; (E)-3,7-dimethylocta-2,6-dienal; 1- isopropyl-4-methylcyclohexa-l,4-diene; 2-(sec-butyl)cyclohexan- 1-one; 3-(2-ethylphenyl)-2,2- dimethylpropanal; 2-(tert-butyl)cyclohexyl ethyl carbonate; ethyl octanoate; ethyl 2- cyclohexylpropanoate; 4-methyl-2-phenyltetrahydro-2H-pyran; 2,6-dimethyloct-7-en-2-ol; 3- methyl-2-pentylcyclopent-2-en-l-one; 2-(4-methylcyclohexyl)propan-2-yl acetate; 4-(2,6,6- trimethylcyclohex-2-en-l-yl)butan-2-one; (oxybis(methylene))dibenzene; dibutyl phthalate; decyl 2-aminobenzoate; methyl (ls,4s)-l,4-dimethylcyclohexane-l-carboxylate; 2- cyclohexylethyl acetate; (3Z,5Z)-2,6-dimethylocta-l,3,5,7-tetraene; 4-cyclohexyl-2-methylbutan- 2-ol; 2-benzyl-2-methylbut-3-enenitrile; 3,7-dimethyloct-6-enenitrile; 3,7-dimethyloct-6-en-l-yl 2-phenylacetate; 3,7-dimethyloct-6-en-l-yl formate; 3,7-dimethyloct-6-en-l-yl benzoate; 3,7- dimethyloct-6-en-l-ol; 3,7-dimethyloct-6-enal; (E)-3,7-dimethylocta-2,6-dienal; (1R,2S,5R)- 2,6,6-trimethylbicyclo[3.1.1]heptane; (Z)-hex-3-en-l-yl pentanoate; (E)-hex-3-en-l-yl (E)-2- methylbut-2-enoate; (Z)-hex-3-en-l-yl butyrate; 4-chloro-3,5-dimethylphenol; 5-isopropyl-2- methylphenol; (E)-2-methyl-4-(2,6,6-trimethylcyclohex-l-en-l-yl)but-2-enal; 3-isopropyl-6- methylenecyclohex-l-ene; benzyl 2-hydroxybenzoate; benzyl 3-methylbutanoate; l-(3,3- dimethylcyclohexyl)ethyl formate; (Z)-l-methoxy-4-(prop-l-en-l-yl)benzene; pentyl benzoate; 2-(4-methylcyclohex-3-en- l-yl)propan-2-yl acetate; (Z)-3-methyl-4-(2,6,6-trimethylcyclohex-2- en-l-yl)but-3-en-2-one; (2-(allyloxy)ethyl)benzene; allyl heptanoate; 6,8-dimethylnonan-2-ol; 5- methyl-5-phenylhexan-3-one; 3,7-dimethyl-2-methyleneoct-6-enal; 3,7-dimethyloctan-l-ol; 2- pentylcyclopentan-l-ol; (2S,4S)-2-heptyl-2,4-dimethyl-l,3-dioxolane; (E)-2-isopropyl-5- methylhex-2-enal; l-isopropyl-4-methyl-7-oxabicyclo[2.2. ljheptane; (Z)-l-(2,6,6- trimethylcyclohex-2-en-l-yl)but-2-en-l-one; (R)-3,7-dimethylocta-l,6-dien-3-ol; 3,7- dimethyloct-6-enal; (R)-3,7-dimethyloct-6-enal; 3,7-dimethyloct-6-en-l-ol; 3,7-dimethyloct-6- en-l-ol; (lR,5R)-2,6,6-trimethylbicyclo[3.1.1]hept-2-ene; (lS,5S)-2,6,6- trimethylbicyclo[3.1.1]hept-2-ene; hexyl (Z)-2-methylbut-2-enoate; p-cymene; phenethyl isobutyrate; phenethyl (Z)-2-methylbut-2-enoate; phenethyl methacrylate; (2Z,5Z)-5,6,7- trimethylocta-2,5-dien-4-one; l-methoxy-4-propylbenzene; 2-(4-(tert-butyl)phenyl)acetaldehyde; 4-(tert-pentyl)cyclohexan-l-ol; 2,6,6-trimethylbicyclo[3.1.1]hept-2-ene; ethyl (2,3,6- trimethylcyclohexyl) carbonate; l-(3,3-dimethylcyclohexyl)ethyl acetate; (S)-3,7-dimethylocta- l,6-dien-3-ol; l-isopropyl-4-methylenebicyclo[3.1.0]hexane; 3,7-dimethyloctanal; 4-(2,2,6- trimethylcyclohexyl)butan-2-ol; 3,7-dimethyloctan-3-ol; 3,7-dimethyloctan-3-yl acetate; ethyl (lR,6S)-2,2,6-trimethylcyclohexane-l-carboxylate; 2-isopropyl-5-methylphenol; (Z)-l-(2,6,6- trimethylcyclohex-2-en- l-yl)but-2-en- 1-one; (Z)- 1 -methoxy-4-(prop- 1 -en- 1 -yl)benzene; 2,2,2- trichloro-l-phenylethyl acetate; 2,2, 5-trimethyl-5-pentylcyclopentan- 1-one; (4-tert- butylcyclohexyl) acetate; 4-(tert-butyl)cyclohexyl acetate; 4-methyl-4-phenylpentan-2-yl acetate; (Z)-l-((2-methylallyl)oxy)hex-3-ene; 4,5-epoxy-4,l l,ll-trimethyl-8- methylenebicyclo(7.2.0)undecane; 1, 3,4,6,7, 8alpha-hexahydro- 1,1,5, 5-tetramethyl-2H-2,4alpha- methanophtalen-8(5H)-one, more preferably said one or more malodor reduction materials are selected from the group consisting of 2-ethylhexyl (Z)-3-(4-methoxyphenyl)acrylate; 2,4- dimethyl-2-(5,5,8,8-tetramethyl-5,6,7,8-tetrahydronaphthalen-2-yl)-l,3-dioxolane; 1,1- dimethoxynon-2-yne; 3-methoxy-7,7-dimethyl-10-methylenebicyclo[4.3.1]decane;

methoxycyclododecane; 1,1-dimethoxycyclododecane; (Z)-tridec-2-enenitrile; (2-hydroxy-4- methoxyphenyl)(phenyl)methanone; 2,4a,5,8a-tetramethyl-l, 2,3, 4,4a,7, 8,8a- octahydronaphthalen-l-yl formate; l,8-dioxacycloheptadecan-9-one; 4-(tert-pentyl)cyclohexan-

(lR,4aR,8aS)-l-isopropyl-7-methyl-4-methylene-l,2,3,4,4a,5,6,8a-octahydronaphthalene; (Z)-4- (2,2-dimethyl-6-methylenecyclohexyl)but-3-en-2-one; (4aS,9aR)-3,5,5,9-tetramethyl- 2,4a,5,6,7,9a-hexahydro-lH-benzo[7]annulene; (lR,3aR,4R,7R)-l,4-dimethyl-7-(prop-l-en-2- yl)-l,2,3,3a,4,5,6,7-octahydroazulene; 2-((2R,4aR)-4a,8-dimethyl-l,2,3,4,4a,5,6,7- octahydronaphthalen-2-yl)propan-2-ol; 5-octyldihydrofuran-2(3H)-one; (Z)-l-(2,2-dimethyl-6- methylenecyclohexyl)but-2-en-l-one; (lR,4aS,8aS)-l-isopropyl-7-methyl-4-methylene- l,2,3,4,4a,5,6,8a-octahydronaphthalene; l-(3,3-dimethylcyclohexyl)pent-4-en-l-one; 4,6,6,7,8,8- hexamethyl-1, 3,4,6,7, 8-hexahydrocyclopenta[g]isochromene; furan-2-ylmethyl octanoate; furan- 2-ylmethyl hexanoate; furan-2-ylmethyl heptanoate; 2-methyldecanenitrile; 8,8-dimethyl- 3a,4,5,6,7,7a-hexahydro-lH-4,7-methanoinden-6-yl propionate; ethyl (3aR,4S,7R,7aR)- octahydro-3aH-4,7-methanoindene-3a-carboxylate; (6-isopropyl-9-methyl- 1 ,4- dioxaspiro[4.5]decan-2-yl)methanol; undec-10-enenitrile; 3-(2-ethylphenyl)-2,2- dimethylpropanal; (E)-4,8-dimethyldeca-4,9-dienal; (E)-4-((3aR,4R,7R,7aR)-l,3a,4,6,7,7a- hexahydro-5H-4,7-methanoinden-5-ylidene)-3-methylbutan-2-ol; 8, 8-dimethyl-3a,4,5, 6,7,7a- hexahydro-lH-4,7-methanoinden-6-yl acetate; 3-(4-ethylphenyl)-2,2-dimethylpropanenitrile; 2- heptylcyclopentan-l-one; 1-ethoxyethoxy Cyclododecane; 3-cyclohexene-l-carboxylic acid, 2,6,6-trimethyl-, methyl ester; (2E,6E)-3,7,l l-trimethyldodeca-2,6,10-trien-l-yl acetate; (2E,6E)- 3,7,ll-trimethyldodeca-2,6,10-trien-l-ol; oxacyclohexadecan-2-one; (E)-cyclopentadec-4-en-l- one; l-cyclopentadec-4-en-l-one ; l,4-dioxacycloheptadecane-5,17-dione; ethyl undec- 10- enoate; ethyl palmitate; ethyl nonanoate; ethyl tetradecanoate; (E)-3,7-dimethylnona-l,6-dien-3- ol; ethyl dodecanoate; ethyl decanoate; ethyl 6,6-dimethyl-2-methylenecyclohex-3-ene-l- carboxylate; 6-ethyl-2,10,10-trimethyl-l-oxaspiro[4.5]deca-3,6-diene; 2-((lR,3S,4S)-4-methyl-3- (prop-l-en-2-yl)-4-vinylcyclohexyl)propan-2-ol; (E)-3-methyl-5-(2,2,3-trimethylcyclopent-3-en- l-yl)pent-4-en-2-ol; (E)-4-((3aS,7aS)-octahydro-5H-4,7-methanoinden-5-ylidene)butanal; 1,1- dimethoxydodecane; (R)-l-methyl-4-(prop-l-en-2-yl)cyclohex-l-ene; 7,9- dimethylspiro[5.5]undecan-3-one; oxydibenzene; diphenylmethane; 2-methyl-l-phenylpropan-2- yl butyrate; octahydro-lH-4,7-methanoinden-5-yl acetate; 2-methyl-5-(prop-l-en-2- yl)cyclohexyl acetate; 3,7-dimethyloct-6-en-3-ol; dibutylsulfane; 1,2-diphenylethane; 6- hexyltetrahydro-2H-pyran-2-one; (3R,4R)-l-isopropyl-4-methyl-3-(prop-l-en-2-yl)-4- vinylcyclohex-l-ene; (3S,3aS,5R)-3,8-dimethyl-5-(prop-l-en-2-yl)- 1,2,3, 3a,4, 5,6,7- octahydroazulene; 6-heptyltetrahydro-2H-pyran-2-one; (lS,8aR)-4,7-dimethyl-l-(propan-2-yl)- l,2,3,5,6,8a-hexahydronaphthalene; (Z)-l-((lR,2S)-2,6,6-trimethylcyclohex-3-en-l-yl)but-2-en- 1-one; (lS,8aS)-l-isopropyl-4,7-dimethyl-l,2,3,5,6,8a-hexahydronaphthalene; 3,7,7- trimethylbicyclo[4.1.0]hept-3-ene; dec-9-en-l-ol; decyl propionate; 1,1-diethoxydecane; 1- cyclohexylethyl (E)-but-2-enoate; 3-(4-isopropylphenyl)-2-methylpropanal; cyclotetradecane; cyclopentadecanone; cyclohexyl 2-hydroxybenzoate; 3a,4,5,6,7,7a-hexahydro-lH-4,7- methanoinden-6-yl butyrate; 8,8-dimethyl-l,2,3,4,5,6,7,8-octahydronaphthalene-2-carbaldehyde; 3a,4,5,6,7,7a-hexahydro-lH-4,7-methanoinden-5-yl isobutyrate; (5R,6R)-3,6-dimethyl-5-(prop- l-en-2-yl)-6-vinyl-4,5,6,7-tetrahydrobenzofuran; 2-(3-phenylpropyl)pyridine; dodecanenitrile; (E)-cycloheptadec-9-en-l-one; 3-(4-methylcyclohex-3-en-l-yl)but-3-en-l-yl acetate; 3-(4- methylcyclohex-3-en-l-yl)butan-l-ol; (E)-3-methyl-5-phenylpent-2-enenitrile; (E)-2-(2,6- dimethylhepta- 1 ,5-dien- 1 -yl)-4-methyl- 1 ,3-dioxolane; (E)- 1 , l-dimethoxy-3 ,7-dimethylocta-2,6- diene; (E)-l,l-diethoxy-3,7-dimethylocta-2,6-diene; (E)-3,7-dimethylocta-l,3,6-triene; (E)- oxacycloheptadec-ll-en-2-one; (Z)-dec-4-enal; (E)-hex-3-en-l-yl (E)-hex-3-enoate; (Z)-hex-3- en-l-yl 2-hydroxybenzoate; (Z)-hex-3-en-l-yl benzoate; (Z)-hex-3-en-l-yl 2-methylbutanoate; cinnamyl propionate; cinnamyl isobutyrate; cinnamyl cinnamate; hexadecan-l-ol; (E)-l-(2,6,6- trimethylcyclohex-2-en-l-yl)hepta-l,6-dien-3-one; 2-methyl-4-(2,6,6-trimethylcyclohex-l-en-l- yl)butanal; (3aR,5aR,9aR,9bR)-3a,6,6,9a-tetramethyldodecahydronaphtho[2,l-b]furan; 1,6- dioxacycloheptadecan-7-one; l-(6-(tert-butyl)-l,l-dimethyl-2,3-dihydro-lH-inden-4-yl)ethan-l- one; (3R,3aR,6S,7S,8aS)-6-methoxy-3,6,8,8-tetramethyloctahydro-lH-3a,7-methanoazulene; (3R,3aS,6R,7R,8aS)-3,6,8,8-tetramethyloctahydro-lH-3a,7-methanoazulen-3-yl formate;

(lR,2S,6S,7S,8S)-8-isopropyl-l-methyl-3-methylenetricyclo[4.4.0.02,7]decane;

2- yl)- 1,2, 3, 4,5, 6,7, 8-octahydroazulene; (3E,6E)-3,7,l l-trimethyldodeca-l,3,6,10-tetraene; 7,7- dimethyl-2-methylenebicyclo[2.2.1]heptane; 2-((2R,4aR,8aR)-4a,8-dimethyl-l,2,3,4,4a,5,6,8a- octahydronaphthalen-2-yl)propan-2-ol; (R)-l-methyl-4-(6-methylhept-5-en-2-yl)benzene;

(3aR,3bR,4S,7R,7aS)-4-isopropyl-7-methyl-3a,3b,4,5,6,7-hexahydro-lH- cyclopenta[l,3]cyclopropa[l,2]benzene; (laS,2aR,3R,5aS,7R,7aR)-3, 6,6,7a- tetramethyloctahydro-2H-2a,7-methanoazuleno[5,6-b]oxirene; (lR,4S,4aR,8aR)-4-isopropyl-l,6- dimethyl-l,2,3,4,4a,7,8,8a-octahydronaphthalen-l-ol; (lS,4aR,8aR)-l-isopropyl-4,7-dimethyl- l,2,4a,5,6,8a-hexahydronaphthalene; (R)-2-((R)-4-methylcyclohex-3-en-l-yl)hex-5-en-2-ol; (Z)- 1 -methyl-4-(6-methylhepta-2,5 -dien-2-yl)cyclohex- 1 -ene; 2, 6-dimethyl-6-(4-methylpent-3 -en- 1 - yl)bicyclo[3.1.1]hept-2-ene; (E)-2-benzylideneheptan-l-ol; (E)-2-benzylideneheptyl acetate; (Z)- (2-(diethoxymethyl)hept- 1 -en- 1 -yl)benzene; (E)-2-benzylideneheptanal ; ( 1 S ,4aR,8aS)- 1 - isopropyl-4,7-dimethyl-l,2,4a,5,6,8a-hexahydronaphthalene; (3R,5aS,9aR)-2,2,5a,9-tetramethyl- 3,4,5,5a,6,7-hexahydro-2H-3,9a-methanobenzo[b]oxepine; l-methyl-4-(4-methylpent-3-en-l- yl)cyclohex-3-ene-l-carbaldehyde; 3-methyl-l-phenylpentan-3-ol; 2,6,10-trimethylundecanal; allyl 3-cyclohexylpropanoate; (laR,4aS,7R,7aR,7bS)-l,l,7-trimethyl-4-methylenedecahydro-lH- cyclopropa[e]azulene; (E)-undec-9-enal; methyl (E)-2-(((3,5-dimethylcyclohex-3-en-l- yl)methylene)amino)benzoate; 2,6, lO-trimethylundec-9-enal; (7,7,8,8-tetramethyloctahydro- 2,3b-methanocyclopenta[l,3]cyclopropa[l,2]benzen-4-yl)methyl acetate; nonyl acetate; (2-(l- propoxyethoxy)ethyl)benzene; (Z)-2-(4-methylbenzylidene)heptanal; dec-9-enal; (Z)- oxacycloheptadec-8-en-2-one; (2S,4aR,8aR)-4a,8-dimethyl-2-(prop-l-en-2-yl)-l,2,3,4,4a,5,6,8a- octahydronaphthalene; 2-((2S,4aR,8aR)-4a,8-dimethyl-l,2,3,4,4a,5,6,8a-octahydronaphthalen-2- yl)propan-2-ol; l-(3,5,5,6,8,8-hexamethyl-5,6,7,8-tetrahydronaphthalen-2-yl)ethan-l-one; 6- isopropylquinoline; 3-(6,6-dimethylbicyclo[3.1. l]hept-2-en-2-yl)propanal; 6, 10, 14- trimethylpentadecan-2-one; (E)-cyclohexadec-5-en-l-one; l-isopropyl-4-methylcyclohex-3-en-l- ol; l-isopropyl-4-methylcyclohex-3-en-l-ol; 3,6-dimethyl-4,5,6,7-tetrahydrobenzofuran;

(lR,4S,4aS,6R,8aS)-4,8a,9,9-tetramethyloctahydro-l,6-methanonaphthalen-l(2H)-ol; p-tolyl hexanoate; 5-hexyl-4-methyldihydrofuran-2(3H)-one; ethyl (2Z,4E)-deca-2,4-dienoate; 2,4- dimethyl-6-phenyl-3,6-dihydro-2H-pyran; 2-cyclohexylidene-2-phenylacetonitrile; (4-(prop-l- en-2-yl)cyclohex-l-en-l-yl)methyl acetate; (4-(prop-l-en-2-yl)cyclohex-l-en-l-yl)methanol; (2- isopropoxyethyl)benzene; 2-cyclohexylhepta-l,6-dien-3-one; (2-(cyclohexyloxy)ethyl)benzene; phenethyl 2-methylbutanoate; phenethyl 2-phenylacetate; phenyl benzoate; phenethyl benzoate; 2-(6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)acetaldehyde; 3a,4,5,6,7,7a-hexahydro-lH-4,7- methanoinden-6-yl pivalate; (E)-3,3-dimethyl-5-(2,2,3-trimethylcyclopent-3-en-l-yl)pent-4-en-2- ol; l-methyl-4-(4-methylpent-3-en-l-yl)cyclohex-3-ene-l-carbaldehyde; p-tolyl 2-phenylacetate; Ethyl 2,4,7-decatrienoate; 2-benzyl-4,4,6-trimethyl-l,3-dioxane; 2,4-dimethyl-4- phenyltetrahydrofuran; (2R,4a'R,8a'R)-3,7'-dimethyl-3',4',4a',5',8',8a'-hexahydro-l'H- spiro[oxirane-2,2'-[l,4]methanonaphthalene]; (Z)-6-ethylideneoctahydro-2H-5,8- methanochromene; 2-((S)-l-((S)-3,3-dimethylcyclohexyl)ethoxy)-2-oxoethyl propionate; methyl 2,2-dimethyl-6-methylenecyclohexane-l-carboxylate; 4-methyl-2-phenyl-3,6-dihydro-2H-pyran; 2,2,7, 9-tetramethylspiro(5.5)undec-8-en-l-one; 3-methyl-5-(2,2,3-trimethylcyclopent-3-en-l- yl)pentan-2-ol; (Z)-2-ethyl-4-(2,2,3-trimethylcyclopent-3-en-l-yl)but-2-en-l-ol; (E)-2-methyl-4- (2,2,3 -trimethylcyclopent-3 -en- 1 -yl)but-2-en- 1 -ol; 1 -(3-hydroxy-3 -methylpent-4-en- 1-yl)- 2,5,5,8a-tetramethyldecahydronaphthalen-2-ol; (4aR,6aS,10aS,10bR)-3,4a,7,7,10a-pentamethyl- 4a,5,6,6a,7,8,9,10,10a,10b-decahydro-lH-benzo[f]chromene; (4aR,8aR)-4a,8-dimethyl-2- (propan-2-ylidene)-l,2,3,4,4a,5,6,8a-octahydronaphthalene; 2-(l-(3,3- dimethylcyclohexyl)ethoxy)-2-methylpropyl cyclopropanecarboxylate; 3-(4-isobutylphenyl)-2- methylpropanal; ( laR,4aR,7S,7aR,7bR)- 1 , 1 ,7-trimethyl-4-methylenedecahydro- 1H- cyclopropa[e]azulen-7-ol; l-(spiro[4.5]dec-7-en-7-yl)pent-4-en-l-one; (Z)-dodec-4-enal;

(lS,4S,4aR,8aR)-4-isopropyl-l,6-dimethyl-l,2,3,4,4a,7,8,8a-octahydronaphthalen-l-ol;

1- one; decahydro-2,6,6,7,8,8-hexamethyl-2h-indeno(4,5-b)furan; pentamethyl

octahydroindenodioxane; undecanal; (E)-4-methyldec-3-en-5-ol; (3R,4aS,5R)-4a,5-dimethyl-3- (prop-l-en-2-yl)-l,2,3,4,4a,5,6,7-octahydronaphthalene; 2-((2R,8R,8aS)-8,8a-dimethyl- 1,2,3,4,6,7, 8, 8a-octahydronaphthalen-2-yl)propan-2-ol; (Z)-2-methyl-4-(2,6,6-trimethylcyclohex-

2- en-l-yl)but-2-enal; l-methoxy-3a,4,5,6,7,7a-hexahydro-lH-4,7-methanoindene; methyl (Z)-2- ((3-(4-(tert-butyl)phenyl)-2-methylpropylidene)amino)benzoate; 2,4,6-trimethyl-4-phenyl-l,3- dioxane; l-((3R,3aR,7R,8aS)-3,6,8,8-tetramethyl-2,3,4,7,8,8a-hexahydro-lH-3a,7- methanoazulen-5-yl)ethan-l-one; methyl (Z)-2-(((2,4-dimethylcyclohex-3-en-l- yl)methylene)amino)benzoate; 4,8-dimethyl-2-(propan-2-ylidene)- 1,2,3, 3a,4,5, 6,8a- octahydroazulen-6-ol; 4,8-dimethyl-2-(propan-2-ylidene)-l,2,3,3a,4,5,6,8a-octahydroazulen-6-yl acetate; decahydro-3H-spiro[furan-2,5'-[4,7]methanoindene] ; (2Z,6E)-nona-2,6-dienenitrile; (laR,4S,4aS,7R,7aS,7bS)-l,l,4,7-tetramethyldecahydro-lH-cyclopropa[e]azulen-4-ol;

(laS,5aR,9aR)-la,5,5,7-tetramethyl-la,2,3,4,5,5a,8,9-octahydrobenzo[l,7]cyclohepta[l,2- bjoxirene; (3R,3aS,7S,8aS)-3,8,8-trimethyl-6-methyleneoctahydro-lH-3a,7-methanoazulene; 4- methoxybenzyl 2-phenylacetate; 2,2,7,7,8,9,9-heptamethyldecahydroindeno[4,3a-b]furan;

(4R,4aS)-4,4a-dimethyl-6-(propan-2-ylidene)-4,4a,5,6,7,8-hexahydronaphthalen-2(3H)-one; (E)- 5-(2,3-dimethyltricyclo[2.2.1.02,6]heptan-3-yl)-2-methylpent-2-en-l-ol; (lR,3aS,7S,8aR)- l,4,9,9-tetramethyl-2,3,6,7,8,8a-hexahydro-lH-3a,7-methanoazulene; (laR,4R,4aR,7bS)-l, 1,4,7- tetramethyl-la,2,3,4,4a,5,6,7b-octahydro-lH-cyclopropa[e]azulene; 2-((2R,4aR,8aR)-4a,8- dimethyl-l,2,3,4,4a,5,6,8a-octahydronaphthalen-2-yl)propan-2-ol; (3aR,3bR,4S,7R,7aS)-4- isopropyl-7-methyl-3a,3b,4,5,6,7-hexahydro-lH-cyclopenta[l,3]cyclopropa[l,2]benzene;

(3R,5aS,9aR)-2,2,5a,9-tetramethyl-3,4,5,5a,6,7-hexahydro-2H-3,9a-methanobenzo[b]oxepine; (laR,4aS,7R,7aR,7bS)-l,l,7-trimethyl-4-methylenedecahydro-lH-cyclopropa[e]azulene; 2- ((2S,4aR,8aR)-4a,8-dimethyl-l,2,3,4,4a,5,6,8a-octahydronaphthalen-2-yl)propan-2-ol; 1- (3,5,5,6,8,8-hexamethyl-5,6,7,8-tetrahydronaphthalen-2-yl)ethan-l-one; (E)-cyclohexadec-5-en- 1-one; (laR,2S,4aS)-2,4a,8,8-tetramethyloctahydrocyclopropa[d]naphthalen-3(lH)-one; 2- ((2R,4aS)-4a,8-dimethyl-l,2,3,4,4a,5,6,7-octahydronaphthalen-2-yl)propan-2-ol; 3a,4,5,6,7,7a- hexahydro-lH-4,7-methanoinden-6-yl propionate; l-(l,l,2,3,3,6-hexamethyl-2,3-dihydro-lH- inden-5-yl)ethan-l-one; (lR,4S,4aS,6R,8aS)-4,8a,9,9-tetramethyloctahydro-l,6- methanonaphthalen-l(2H)-ol; 3a,4,5,6,7,7a-hexahydro-lH-4,7-methanoinden-6-yl pivalate; (2R,4a'R,8a'R)-3,7'-dimethyl-3',4',4a',5',8',8a'-hexahydro-l'H-spiro[oxirane-2,2'- [l,4]methanonaphthalene]; 2,2,7, 9-tetramethylspiro(5.5)undec-8-en-l-one; (Z)-2-ethyl-4-(2,2,3- trimethylcyclopent-3-en-l-yl)but-2-en-l-ol; (4aR,6aS,10aS,10bR)-3,4a,7,7,10a-pentamethyl- 4a,5,6,6a,7,8,9,10,10a,10b-decahydro-lH-benzo[f]chromene; (laR,4aR,7S,7aR,7bR)-l,l,7- trimethyl-4-methylenedecahydro-lH-cyclopropa[e]azulen-7-ol; l-(spiro[4.5]dec-7-en-7-yl)pent- 4-en-l-one; (laR,4aS)-2,4a,8,8-tetramethyl-l,la,4,4a,5, 6,7,8- octahydrocyclopropa[d]naphthalene; (lR-(lalpha,3alpha,4aalpha))-2,3,4,4a,5,6-hexahydro-2,2- dimethyl-l,3-methanonaphthalen-7(lH)-one; 2-((2R,8R,8aS)-8,8a-dimethyl-l,2,3,4,6,7,8,8a- octahydronaphthalen-2-yl)propan-2-ol; l-((3R,3aR,7R,8aS)-3,6,8,8-tetramethyl-2,3,4,7,8,8a- hexahydro- lH-3a,7-methanoazulen-5-yl)ethan- 1-one; methyl (Z)-2-(((2,4-dimethylcyclohex-3- en-l-yl)methylene)amino)benzoate; 4,8-dimethyl-2-(propan-2-ylidene)-l, 2,3, 3a,4,5, 6,8a- octahydroazulen-6-yl acetate; decahydro-3H-spiro[furan-2,5'-[4,7]methanoindene] ;

(laR,4S,4aS,7R,7aS,7bS)-l,l,4,7-tetramethyldecahydro-lH-cyclopropa[e]azulen-4-ol;

(2'S,4a'S,8a'S)-l',l',5',5'-tetramethylhexahydro-2'H,5'H-spiro[[l,3]dioxolane-2,8'- [2,4a]methanonaphthalene]; tetrahydronaphthalen-2-yl)-l,3-dioxolane; 2-(cyclohexyloxy)- 1,7,7- trimethylbicyclo[2.2.1]heptane; 4-((2R)-l,7,7-trimethylbicyclo[2.2.1]heptan-2-yl)cyclohexan-l- ol; 8,8-dimethyl-3a,4,5,6,7,7a-hexahydro-lH-4,7-methanoinden-6-yl propionate;

(laS,2aR,3R,5aS,7R,7aR)-3,6,6,7a-tetramethyloctahydro-2H-2a,7-methanoazuleno[5,6- bjoxirene; 4,5-epoxy-4,ll,l l-trimethyl-8-methylenebicyclo(7.2.0)undecane; 1, 3,4,6,7, 8alpha- hexahydro-l,l,5,5-tetramethyl-2H-2,4alpha-methanophtalen-8(5H)-one, and most preferably said one or more malodor reduction materials are selected from the group consisting of 3-(3,3- dimethyl-2,3-dihydro-lH-inden-5-yl)propanal; 8,8-dimethyl-3a,4,5,6,7,7a-hexahydro-lH-4,7- methanoinden-6-yl acetate; 2,2,7,7,8,9,9-heptamethyldecahydroindeno[4,3a-b]furan; (E)- cyclohexadec-5-en- 1-one; 4,5-epoxy-4,ll,l l-trimethyl-8-methylenebicyclo(7.2.0)undecane; 1, 3,4,6,7, 8alpha-hexahydro- 1,1, 5, 5-tetramethyl-2H-2,4alpha-methanophtalen-8(5H)-one and mixtures thereof.

6. A cleaning and/or treatment composition according to any of Claims 1-4 comprising one or more malodor reduction materials having a vapor pressure of greater than 0.01 torr, preferably, greater than 0.01 torr to 10 torr, preferably said one or more malodor materials are selected from the group consisting of l,l-dimethoxynon-2-yne; 2-(p-tolyl)propan-2-ol; 3- methoxy-7,7-dimethyl- 10-methylenebicyclo[4.3. ljdecane; methoxycyclododecane; 4-(tert- pentyl)cyclohexan- 1-one; 7-isopropyl-8,8-dimethyl-6,10-dioxaspiro[4.5]decane; octyl acetate; 2- heptyl-4-methyl-l,3-dioxolane; octanal; 1,1-dimethoxyoctane; 7-methyl-3-methyleneocta-l,6- diene; 2-methyl-6-methyleneoct-7-en-2-ol; 2-methyl-6-methyleneoct-7-en-2-yl acetate; (E)-2,6- dimethylocta-5,7-dien-2-ol; nonan-l-ol; nonanal; 2-methoxynaphthalene; (Z)-3,7-dimethylocta-

2.6- dien-l-ol; l-ethyl-3-methoxytricyclo[2.2.1.02,6]heptane; methyl (E)-non-2-enoate; 6,6- dimethylbicyclo[3.1.1]hept-2-ene-2-carbaldehyde; methyl non-2-ynoate; 2-methyldecanal; 6,6- dimethoxy-2,5,5-trimethylhex-2-ene; 4-phenylbutan-2-ol; l,l-dimethoxy-2-methylundecane; undecan-2-one; 2-methylundecanal; (Z)-l,2-dimethoxy-4-(prop-l-en-l-yl)benzene; 4-allyl-l,2- dimethoxybenzene; l-methyl-2-phenoxybenzene; methyl cinnamate; l-allyl-4-methoxybenzene; methyl oct-2-ynoate; methyl 2,6,6-trimethylcyclohex-2-ene-l-carboxylate; 7-methoxy-3,7- dimethyloctanal; octahydro- lH-4,7-methanoindene- 1 -carbaldehyde; 8-isopropyl-6- methylbicyclo[2.2.2]oct-5-ene-2-carbaldehyde; (S)-l-methyl-4-(prop-l-en-2-yl)cyclohex-l-ene; (Z)-3-hexen-l-yl-2-cyclopenten-l-one; 3,7-dimethylocta-l,6-dien-3-yl isobutyrate; 2-(5-methyl- 5-vinyltetrahydrofuran-2-yl)propan-2-ol; 3-(4-methylcyclohex-3-en-l-yl)butanal; (E)-l-(l- methoxypropoxy)hex-3-ene; (E)-l-(l-ethoxyethoxy)hex-3-ene; (lS,5R)-2-methyl-5-(prop-l-en- 2-yl)cyclohex-2-en-l-ol; dodecanal; 2-propylheptanenitrile; 2-hexylcyclopentan-l-one; 2- methyl-4-phenyl-l,3-dioxolane; 2,6,9, 10-tetramethyl-l-oxaspiro(4.5)deca-3,6-diene; (1R,2S,5R)- 5-methyl-2-(prop-l-en-2-yl)cyclohexan-l-ol; (2S,5S)-2-isopropyl-5-methylcyclohexan-l-one; 2- hexylcyclopent-2-en-l-one; (2S,5S)-2-isopropyl-5-methylcyclohexan-l-one; 2,5,6- trimethylcyclohex-3-ene-l-carbaldehyde; (lR,2R,4S)-l,7,7-trimethylbicyclo[2.2.1]heptan-2-yl propionate; (lS,2S,4S)-l,7,7-trimethylbicyclo[2.2.1]heptan-2-yl isobutyrate; (1R,4S)-1,7,7- trimethylbicyclo[2.2.1]heptan-2-yl acetate; (E)-non-2-enenitrile; 3-phenylpropan-l-ol; (1,1- dimethoxypropan-2-yl)benzene; 5-ethyl-4-hydroxy-2-methylfuran-3(2H)-one; hexyl hexanoate; (Z)-hex-l-en-l-yl (Z)-2-methylbut-2-enoate; 2-butyl-4,4,6-trimethyl-l,3-dioxane; ethyl

(lR,2R,3R,4R)-3-isopropylbicyclo[2.2.1]hept-5-ene-2-carboxylate; 3a,4,5,6,7,7a-hexahydro-lH-

4.7- methanoinden-6-yl acetate; 6-butyl-2,4-dimethyl-3,6-dihydro-2H-pyran; ethyl 2-ethyl-6,6- dimethylcyclohex-2-ene-l-carboxylate; l-methyl-4-(propan-2-ylidene)cyclohexyl acetate; 1- methyl-4-(propan-2-ylidene)cyclohexan-l-ol; (lR,4aR,8aS)-l-isopropyl-7-methyl-4-methylene- l,2,3,4,4a,5,6,8a-octahydronaphthalene; (4aS,9aR)-3,5,5,9-tetramethyl-2,4a,5,6,7,9a-hexahydro- lH-benzo[7]annulene; (lR,4aS,8aS)-l-isopropyl-7-methyl-4-methylene- 1,2, 3,4,4a,5, 6,8a- octahydronaphthalene; furan-2-ylmethyl hexanoate; 2-methyldecanenitrile; ethyl

(3aR,4S,7R,7aR)-octahydro-3aH-4,7-methanoindene-3a-carboxylate; (E)-4,8-dimethyldeca-4,9- dienal; 2-heptylcyclopentan-l-one; 3-cyclohexene-l-carboxylic acid, 2,6,6-trimethyl-, methyl ester; 4-allyl-2-methoxyphenol; ethyl nonanoate; nonan-3-one; ethyl decanoate; ethyl 6,6- dimethyl-2-methylenecyclohex-3-ene- 1 -carboxylate; (2-( 1 -ethoxyethoxy)ethyl)benzene; 1,1- dimethoxydodecane; (R)- 1 -methyl-4-(prop- 1 -en-2-yl)cyclohex- 1 -ene; oxydibenzene ;

diphenylmethane; 2,6-dimethyloct-7-en-4-one; octahydro-lH-4,7-methanoinden-5-yl acetate; 2- methyl-5-(prop-l-en-2-yl)cyclohexyl acetate; 2-methyl-5-(prop-l-en-2-yl)cyclohexan-l-ol; 3,7- dimethyloct-6-en-3-ol; dibutylsulfane; (3R,4R)-l-isopropyl-4-methyl-3-(prop-l-en-2-yl)-4- vinylcyclohex-l-ene; (Z)-l-((lR,2S)-2,6,6-trimethylcyclohex-3-en-l-yl)but-2-en-l-one; 3,7,7- trimethylbicyclo[4.1.0]hept-3-ene; decyl propionate; 1,1-diethoxydecane; decahydronaphthalen- 2-ol; 1-cyclohexylethyl (E)-but-2-enoate; (4-isopropylphenyl)methanol; (E)-2-(2,6- dimethylhepta- 1 ,5-dien- 1 -yl)-4-methyl- 1 ,3-dioxolane; (E)- 1 , l-dimethoxy-3 ,7-dimethylocta-2,6- diene; (E)-3,7-dimethylocta-l,3,6-triene; (lR,4R,6S)-l-methyl-4-(prop-l-en-2-yl)-7- oxabicyclo[4.1.0]heptane; (Z)-non-6-en-l-ol; (lR,5R)-2-methyl-5-(prop-l-en-2-yl)cyclohex-2- en-l-ol; (Z)-dec-4-enal; (E)-hex-3-en-l-yl (E)-hex-3-enoate; (Z)-hex-3-en-l-yl 2- methylbutanoate; (3Z,6Z)-nona-3,6-dien-l-ol; cinnamyl formate; (E)-3-phenylprop-2-en-l-ol; (3R,3aR,6S,7S,8aS)-6-methoxy-3,6,8,8-tetramethyloctahydro-lH-3a,7-methanoazulene;

octanenitrile; octan-l-ol; octanoic acid; decanal; 3-(4-methoxyphenyl)-2-methylpropanal; 1,7,7- trimethylbicyclo[2.2. l]heptane-2,3-dione; 2,2-dimethyl-3-methylenebicyclo[2.2. ljheptane;

1- en-2-yl)cyclohexyl acetate; l-methyl-4-(prop-l-en-2-yl)cyclohexan-l-ol; (R)-3-methylene-6- ((S)-6-methylhept-5-en-2-yl)cyclohex-l-ene; (4aR,7R,8aS)-4a-methyl-l-methylene-7-(prop-l- en-2-yl)decahydronaphthalene; 6,6-dimethyl-2-methylenebicyclo[3.1. ljheptane; (1S,4R,7R)-

1, 4,9, 9-tetramethyl- 1,2,3,4,5, 6,7, 8-octahydro-4,7-methanoazulene; (2,2-dimethoxyethyl)benzene; (E)-7,ll-dimethyl-3-methylenedodeca-l,6,10-triene; (lR,2S,6S,7S,8S)-8-isopropyl-l-methyl-3- methylenetricyclo[4.4.0.02,7]decane; (3R,3aS,7S,8aS)-3,8,8-trimethyl-6-methyleneoctahydro- lH-3a,7-methanoazulene; (lR,9S,Z)-4,ll,ll-trimethyl-8-methylenebicyclo[7.2.0]undec-4-ene;

2- methyl-4-phenylbutan-2-ol; 2-methyl-l-phenylpropan-2-ol; 2'-isopropyl-l,7,7- trimethylspiro[bicyclo[2.2.1]heptane-2,4'-[l,3]dioxane]; methyl (E)-octa-4,7-dienoate;

(lS,4R,5R)-l-isopropyl-4-methylbicyclo[3.1.0]hexan-3-one; 2-(4-methylcyclohex-3-en-l- yl)propan-2-yl propionate; (2R,4aR,8aR)-4a,8-dimethyl-2-(prop-l-en-2-yl)-l,2,3,4,4a,5,6,8a- octahydronaphthalene; l,7-dimethyl-7-(4-methylpent-3-en-l-yl)tricyclo[2.2.1.02,6]heptane; (lR,3aS,7S,8aR)-l,4,9,9-tetramethyl-2,3,6,7,8,8a-hexahydro-lH-3a,7-methanoazulene;

(lS,4aS,8aR)-l-isopropyl-4,7-dimethyl-l,2,4a,5,6,8a-hexahydronaphthalene; l-methyl-4-(prop- l-en-2-yl)cyclohex-l-ene; (laR,4R,4aR,7bS)-l,l,4,7-tetramethyl-la,2,3,4,4a,5,6,7b-octahydro- lH-cyclopropa[e]azulene; 7,7-dimethyl-2-methylenebicyclo[2.2.1]heptane; (3aR,3bR,4S,7R,7aS)-4-isopropyl-7-methyl-3a,3b,4,5,6,7-hexahydro-lH- cyclopenta[l,3]cyclopropa[l,2]benzene; (laS,2aR,3R,5aS,7R,7aR)-3, 6,6,7a- tetramethyloctahydro-2H-2a,7-methanoazuleno[5,6-b]oxirene; (lS,4aR,8aR)-l-isopropyl-4,7- dimethyl-l,2,4a,5,6,8a-hexahydronaphthalene; 2,6-dimethyl-6-(4-methylpent-3-en-l- yl)bicyclo[3.1.1]hept-2-ene; (lS,4aR,8aS)-l-isopropyl-4,7-dimethyl-l,2,4a,5,6,8a- hexahydronaphthalene; l-phenylpentan-2-ol; trans,Trans-2,4-nonadien-l-al; alpha-4-Dimethyl benzenepropanal; allyl 2-(isopentyloxy)acetate; (laR,4aS,7R,7aR,7bS)-l,l,7-trimethyl-4- methylenedecahydro-lH-cyclopropa[e]azulene; (E)-undec-9-enal; nonyl acetate; (2-(l- propoxyethoxy)ethyl)benzene ; 1 - ( 1 -propoxyethoxy)propane ; (( 1 - (2- methoxyethoxy)ethoxy)methyl)benzene; dec-9-enal; (2S,4aR,8aR)-4a,8-dimethyl-2-(prop- 1-en- 2-yl)-l,2,3,4,4a,5,6,8a-octahydronaphthalene; 6-isopropylquinoline; 3-(6,6- dimethylbicyclo[3.1. l]hept-2-en-2-yl)propanal; 2-methyl-5-(prop-l-en-2-yl)-2- vinyltetrahydrofuran; l-isopropyl-4-methylcyclohex-3-en-l-ol; l-phenylpent-4-en-l-one; 1- isopropyl-4-methylcyclohex-3-en-l-ol; 3,6-dimethyl-4,5,6,7-tetrahydrobenzofuran; (Z)-dodec-2- enal; (E)-hex-3-en-l-yl 3-methylbutanoate; 3,6-dimethyloctan-3-yl acetate; 3-(4- isopropylphenyl)propanal; (Z)-undec-2-enenitrile; (E)-undec-2-enal; (2E,6E)-nona-2,6-dienal; 2- phenoxyethan-l-ol; (Z)-non-2-enal; nonan-2-ol; nonan-2-one; (E)-2-hexylidenecyclopentan-l- one; 2-heptyltetrahydrofuran; (E)-dec-2-enal; (2E,6E)-nona-2,6-dienal; (2E,6E)-nona-2,6-dien-l- ol; 2,6-dimethyloctanal; decan-l-ol; (E)-hept-l-en-l-yl acetate; undec-10-enal; l-isopropyl-4- methyl-7-thiabicyclo[2.2.1]heptane; (3E,5Z)-undeca-l,3,5-triene; 3,7-dimethyloct-6-en-3-ol; l,3,3-trimethylbicyclo[2.2.1]heptan-2-yl acetate; 1, 1,2,3, 3-pentamethyl-2,3-dihydro-lH-indene; (Z)-dodec-3-enal; (lS,2S,5S)-2-methyl-5-(prop-l-en-2-yl)cyclohexan-l-ol; (2S,5R)-2-isopropyl- 5-methylcyclohexan-l-one; 3-(3-isopropylphenyl)butanal; 2-methyl-5-(6-methylhept-5-en-2- yl)bicyclo[3.1.0]hex-2-ene; 2-(m-tolyl)ethan-l-ol; (3E,6E)-nona-3,6-dien-l-ol; p-tolyl isobutyrate; 4-(prop- 1 -en-2-yl)cyclohex- 1 -ene- 1 -carbaldehyde; (4-(prop- 1 -en-2-yl)cyclohex- 1 - en-l-yl)methyl acetate; (2-isopropoxyethyl)benzene; 2-phenylethan-l-ol; 2-benzyl-l,3- dioxolane; 2-(6,6-dimethylbicyclo[3.1. l]hept-2-en-2-yl)acetaldehyde; 6,6-dimethyl-2- methylenebicyclo[3.1.1]heptan-3-ol; 4-isopropyl-l-methylcyclohex-3-en-l-ol; propane- 1,2-diol; 2,4-dimethyl-4-phenyltetrahydrofuran; (Z)-6-ethylideneoctahydro-2H-5,8-methanochromene; methyl 2,2-dimethyl-6-methylenecyclohexane- 1 -carboxylate; 4-methyl-2-phenyl-3 ,6-dihydro- 2H-pyran; (lS,3R,5S)-l-isopropyl-4-methylenebicyclo[3.1.0]hexan-3-ol; 5- allylbenzo[d][l,3]dioxole; (4aR,8aR)-4a,8-dimethyl-2-(propan-2-ylidene)-l,2,3,4,4a,5,6,8a- octahydronaphthalene; 2-methyl- 1 ,5-dioxaspiro[5.5]undecane; 2-(heptan-3-yl)- 1,3-dioxolane; (Z)-dodec-4-enal; 3-methyl-2-pentylcyclopentan-l-one; 2,6,10,10-tetramethyl-l- oxaspiro[4.5]dec-6-ene; (laR,4aS)-2,4a,8,8-tetramethyl-l,la,4,4a,5,6,7,8- octahydrocyclopropa[d]naphthalene; 1 -isopropyl-2-methoxy-4-methylbenzene; (2Z,4E)-nona- 2,4-dienal; (2E,6Z)-nona-2,6-dienal; (Z)-dec-2-enal; (E)-non-2-enal; (3E,6Z)-nona-3,6-dien-l-ol; (E)-dec-4-enal; (Z)-3,7-dimethylocta-l,3,6-triene; (Z)-3,7-dimethylocta-l,3,6-triene; (E)-3,7- dimethylocta-2,6-dien-l-ol; undecanal; (E)-4-methyldec-3-en-5-ol; (3R,4aS,5R)-4a,5-dimethyl- 3-(prop-l-en-2-yl)-l,2,3,4,4a,5,6,7-octahydronaphthalene; l-methoxy-3a,4,5,6,7,7a-hexahydro- lH-4,7-methanoindene; (Z)-hex-3-en-l-yl isobutyrate; decahydro-3H-spiro[furan-2,5'- [4,7]methanoindene]; (2Z,6E)-nona-2,6-dienenitrile; l', ,5',5'-tetramethylhexahydro-2'H,5'H- spiro[[l,3]dioxolane-2,8'-[2,4a]methanonaphthalene]; (2'S,4a'S,8a'S)-l',l',5',5'- tetramethylhexahydro-2Ή,5Ή-spiro[[l,3]dioxolane-2,8'-[2,4a]methanonaphthalene]; l-ethoxy-4- (tert-pentyl)cyclohexane; (3Z)-l-(2-buten-l-yloxy)-3-hexene; 4-(2-methoxypropan-2-yl)-l- methylcyclohex-l-ene; 3-methoxy-3,7-dimethylocta-l,6-diene; 3,7-dimethyloctanal; 3,3- Dimethyl-5(2,2,3-Trimethyl-3-Cyclopenten-lyl)-4-Penten-2-01; hexyl (Z)-but-2-enoate; (Z)-3,7- dimethylocta-2,6-dien-l-yl formate; (E)-2,2-dimethyl-3-(3-methylpenta-2,4-dien-l-yl)oxirane; (E)-3,7-dimethylocta-4,6-dien-3-ol; (Z)-hex-3-en-l-yl cyclopropanecarboxylate; 1-phenylethyl propionate; methyl 2-phenylacetate; methyl (Z)-3,7-dimethylocta-2,6-dienoate; methyl 2- cyclopentylideneacetate; 6-methoxy-2,6-dimethylheptanal; ((ls,4s)-4- isopropylcyclohexyl)methanol; 3,7-dimethylocta-l,6-dien-3-yl propionate; 3,7-dimethylocta-l,6- dien-3-yl formate; 3,7-dimethylocta-l,6-dien-3-yl acetate; 3,7-dimethylocta-l,6-dien-3-ol; (Z)- hex-3-en-l-yl methyl carbonate; 4-methylquinoline; 2-Methyl-5-(l-methylethenyl)-2- cyclohexenone; 4-methylpent-l-en-3-ol; isopropyl 2-methylbutanoate; 4-methylpent-4-en-2-yl isobutyrate; 7-methyloctyl acetate; 7-methyloctan-l-ol; l,7,7-trimethylbicyclo[2.2.1]heptan-2-ol; isopentyl octanoate; isopentyl isobutyrate; 2-phenylpropan-l-ol; hexyl propionate; hexyl butyrate; hexyl 2-methylbutanoate; heptan-l-ol; heptyl acetate; heptanal; benzo[d][l,3]dioxole-5- carbaldehyde; (Z)-3,7-dimethylocta-2,6-dienenitrile; (E)-3,7-dimethylocta-2,6-dien-l-yl formate; (E)-3,7-dimethylocta-2,6-dienal; l-isopropyl-4-methylcyclohexa-l,4-diene; 2-(sec- butyl)cyclohexan- 1-one; 3-(2-ethylphenyl)-2,2-dimethylpropanal; (Z)-5-methylhept-2-en-4-one; l,3,3-trimethylbicyclo[2.2.1]heptan-2-ol; l,3,3-trimethyl-2-oxabicyclo[2.2.2]octane; ethyl octanoate; ethyl 2-cyclohexylpropanoate; (2R,5R)-2-methyl-5-(prop-l-en-2-yl)cyclohexan-l- one; 4-methyl-2-phenyltetrahydro-2H-pyran; 2,6-dimethyloct-7-en-2-ol; 3-methyl-2- pentylcyclopent-2-en- 1-one; 3,3,5-trimethylcyclohexan-l-one; 2-methyl-5-(prop-l-en-2- yl)cyclohexan- 1-one; 2-(4-methylcyclohexyl)propan-2-yl acetate; 4-(2,6,6-trimethylcyclohex-2- en-l-yl)butan-2-one; 2-pentylcyclopentan- 1-one; methyl (ls,4s)-l,4-dimethylcyclohexane-l- carboxylate; 2-cyclohexylethyl acetate; 2-methoxy-4-methylphenol; (3Z,5Z)-2,6-dimethylocta- 1,3,5,7-tetraene; 4-cyclohexyl-2-methylbutan-2-ol; 3,7-dimethyloct-6-enenitrile; 3,7- dimethyloct-6-en-l-yl formate; 3,7-dimethyloct-6-en-l-ol; 3,7-dimethyloct-6-enal; (E)-3,7- dimethylocta-2,6-dienal; (lR,2S,5R)-2,6,6-trimethylbicyclo[3.1.1]heptane; (Z)-hex-3-en-l-yl pentanoate; (E)-hex-3-en-l-yl (E)-2-methylbut-2-enoate; (Z)-hex-3-en-l-yl propionate; (Z)-hex-

3- en-l-yl butyrate; (Z)-hex-3-en-l-ol; (Z)-hex-2-en-l-ol; cinnamonitrile; cinnamaldehyde;

cinnamonitrile; 4-chloro-3,5-dimethylphenol; 5-isopropyl-2-methylphenol; 2-methyl-5-(prop-l- en-2-yl)cyclohex-2-en-l-one; 2-(2-ethoxyethoxy)ethan-l-ol; hexan-l-ol; 2-(2,2,3- trimethylcyclopent-3-en-l-yl)acetonitrile; l,7,7-trimethylbicyclo[2.2.1]heptan-2-one;

(lS,2R,4S)-l,7,7-trimethylbicyclo[2.2.1]heptan-2-ol; 6,6-dimethylspiro[bicyclo[3.1.1]heptane- 2,2'-oxirane]; 3-isopropyl-6-methylenecyclohex-l-ene; 4-phenylbutan-2-one; benzyl 3- methylbutanoate; benzyl isobutyrate; benzyl butyrate; phenylmethanol; l-(3,3- dimethylcyclohexyl)ethyl formate; 4-methoxybenzyl acetate; 4-methoxybenzyl formate; (Z)-l- methoxy-4-(prop-l-en-l-yl)benzene; 2-(4-methylcyclohex-3-en-l-yl)propan-2-yl acetate; 4- cyclohexylbutan-2-ol; (E)-2-methyl-3-phenylacrylaldehyde; 4-methoxy-2,5-dimethylfuran- 3(2H)-one; (2-(allyloxy)ethyl)benzene; allyl heptanoate; 3-hydroxybutan-2-one; l-(4- methoxyphenyl)ethan-l-one; 6-methylquinoline; 6,8-dimethylnonan-2-ol; 5-methylheptan-3-one;

4- vinylphenol; 4-ethyl-2-methoxyphenol; 3-methylcyclopentane-l,2-dione; 3-methoxy-3- methylbutan-l-ol; (E)-hex-3-en-l-ol; 3,7-dimethyl-2-methyleneoct-6-enal; 3,7-dimethyloctan-l- ol; phenethyl acetate; phenethyl propionate; 2-pentylcyclopentan-l-ol; (2S,4S)-2-heptyl-2,4- dimethyl-l,3-dioxolane; 2-(sec-butyl)-3-methoxypyrazine; 2-isopropyl-N,2,3- trimethylbutanamide; (E)-2-isopropyl-5-methylhex-2-enal; 2-isopropyl-4-methylthiazole; (E)- hex-2-en-l-ol; 2-butoxyethan-l-ol; l-isopropyl-4-methyl-7-oxabicyclo[2.2.1]heptane; (Z)-hept- 3-en-l-yl acetate; (lS,5S)-4,6,6-trimethylbicyclo[3.1.1]hept-3-en-2-one; (R)-3,7-dimethylocta-

1.6- dien-3-ol; 3,7-dimethyloct-6-enal; (R)-3,7-dimethyloct-6-enal; 3,7-dimethyloct-6-en-l-ol;

3.7- dimethyloct-6-en-l-ol; (lR,5R)-2,6,6-trimethylbicyclo[3.1.1]hept-2-ene; (S)-2-methyl-5- (prop-l-en-2-yl)cyclohex-2-en-l-one; (lS,5S)-2,6,6-trimethylbicyclo[3.1.1]hept-2-ene; methyl 2- methylbutanoate; hexyl (Z)-2-methylbut-2-enoate; 1-phenylvinyl acetate; p-cymene; phenethyl formate; 2-(4-isopropylphenyl)acetaldehyde; l,2-dimethyl-3-(prop-l-en-2-yl)cyclopentan-l-ol; (2Z,5Z)-5,6,7-trimethylocta-2,5-dien-4-one; l-methoxy-4-propylbenzene; 2-(4-(tert- butyl)phenyl)acetaldehyde; 4-(tert-pentyl)cyclohexan- 1 -ol ; 2,6, 6-trimethylbicyclo [3.1.1 ]hept-2- ene; 3,7-dimethyloct-7-en-l-ol; l-(3,3-dimethylcyclohexyl)ethyl acetate; (S)-3,7-dimethylocta- l,6-dien-3-ol; l-isopropyl-4-methylenebicyclo[3. l.OJhexane; 5-isopropyl-2- methylbicyclo[3.1.0]hexan-2-ol; propyl (S)-2-(tert-pentyloxy)propanoate; l-oxaspiro(4,5)decan- 2-one; (Z)-5-methylheptan-3-one oxime; 1-phenylethyl acetate; 3,7-dimethyloctanal; 3,7- dimethyloctan-3-ol; 3,7-dimethyloctan-3-yl acetate; ethyl (lR,6S)-2,2,6-trimethylcyclohexane-l- carboxylate; 2-isopropyl-5-methylphenol; (E)-hex-2-en-l-ol; (lR,2S)-2-(tert-butyl)cyclohexan-l- ol; (Z)-l-methoxy-4-(prop-l-en-l-yl)benzene; (2R,5R)-2-methyl-5-(prop-l-en-2-yl)cyclohexan-

1- one; 2-mercapto-2-methylpentan-l-ol; 2,2,5-trimethyl-5-pentylcyclopentan-l-one; (1R,5R)- 4,6,6-trimethylbicyclo[3.1.1]hept-3-en-2-one; 2-(tert-butyl)cyclohexan-l-ol; (4-tert- butylcyclohexyl) acetate; 4-(tert-butyl)cyclohexyl acetate; (Z)-l-((2-methylallyl)oxy)hex-3-ene, more preferably said one or more malodor reduction materials are selected from the group consisting of l,l-dimethoxynon-2-yne; 2-(p-tolyl)propan-2-ol; 3-methoxy-7,7-dimethyl-10- methylenebicyclo[4.3.1]decane; methoxycyclododecane; 4-(tert-pentyl)cyclohexan-l-one; 7- isopropyl-8,8-dimethyl-6,10-dioxaspiro[4.5]decane; octyl acetate; 2-heptyl-4-methyl-l,3- dioxolane; octanal; 1,1-dimethoxyoctane; 7-methyl-3-methyleneocta-l,6-diene; 2-methyl-6- methyleneoct-7-en-2-ol; 2-methyl-6-methyleneoct-7-en-2-yl acetate; (E)-2,6-dimethylocta-5,7- dien-2-ol; nonan-l-ol; nonanal; 2-methoxynaphthalene; (Z)-3,7-dimethylocta-2,6-dien-l-ol; 1- ethyl-3-methoxytricyclo[2.2.1.02,6]heptane; methyl (E)-non-2-enoate; 6,6- dimethylbicyclo[3.1.1]hept-2-ene-2-carbaldehyde; methyl non-2-ynoate; 2-methyldecanal; 6,6- dimethoxy-2,5,5-trimethylhex-2-ene; 4-phenylbutan-2-ol; l,l-dimethoxy-2-methylundecane; undecan-2-one; 2-methylundecanal; (Z)-l,2-dimethoxy-4-(prop-l-en-l-yl)benzene; 4-allyl-l,2- dimethoxybenzene; l-methyl-2-phenoxybenzene; methyl cinnamate; l-allyl-4-methoxybenzene; methyl oct-2-ynoate; methyl 2,6,6-trimethylcyclohex-2-ene-l-carboxylate; 7-methoxy-3,7- dimethyloctanal; octahydro- lH-4,7-methanoindene- 1 -carbaldehyde; 8-isopropyl-6- methylbicyclo[2.2.2]oct-5-ene-2-carbaldehyde; (S)-l-methyl-4-(prop-l-en-2-yl)cyclohex-l-ene; (Z)-3-hexen-l-yl-2-cyclopenten-l-one; 3,7-dimethylocta-l,6-dien-3-yl isobutyrate; 2-(5-methyl- 5-vinyltetrahydrofuran-2-yl)propan-2-ol; 3-(4-methylcyclohex-3-en-l-yl)butanal; (E)-l-(l- methoxypropoxy)hex-3-ene; (E)-l-(l-ethoxyethoxy)hex-3-ene; (lS,5R)-2-methyl-5-(prop-l-en-

2- yl)cyclohex-2-en-l-ol; dodecanal; 2-propylheptanenitrile; 2-hexylcyclopentan-l-one; 2- methyl-4-phenyl-l,3-dioxolane; 2,6,9, 10-tetramethyl-l-oxaspiro(4.5)deca-3,6-diene; (1R,2S,5R)- 5-methyl-2-(prop-l-en-2-yl)cyclohexan-l-ol; (2S,5S)-2-isopropyl-5-methylcyclohexan-l-one; 2- hexylcyclopent-2-en-l-one; (2S,5S)-2-isopropyl-5-methylcyclohexan-l-one; 2,5,6- trimethylcyclohex-3-ene-l-carbaldehyde; (lR,2R,4S)-l,7,7-trimethylbicyclo[2.2.1]heptan-2-yl propionate; (lS,2S,4S)-l,7,7-trimethylbicyclo[2.2.1]heptan-2-yl isobutyrate; (1R,4S)-1,7,7- trimethylbicyclo[2.2.1]heptan-2-yl acetate; (E)-non-2-enenitrile; 3-phenylpropan-l-ol; (1,1- dimethoxypropan-2-yl)benzene; 5-ethyl-4-hydroxy-2-methylfuran-3(2H)-one; hexyl hexanoate; (Z)-hex-l-en-l-yl (Z)-2-methylbut-2-enoate; 2-butyl-4,4,6-trimethyl-l,3-dioxane; ethyl

(lR,2R,3R,4R)-3-isopropylbicyclo[2.2.1]hept-5-ene-2-carboxylate; 3a,4,5,6,7,7a-hexahydro-lH- 4,7-methanoinden-6-yl acetate; 6-butyl-2,4-dimethyl-3,6-dihydro-2H-pyran; ethyl 2-ethyl-6,6- dimethylcyclohex-2-ene-l-carboxylate; l-methyl-4-(propan-2-ylidene)cyclohexyl acetate; 1- methyl-4-(propan-2-ylidene)cyclohexan-l-ol; (lR,4aR,8aS)-l-isopropyl-7-methyl-4-methylene- l,2,3,4,4a,5,6,8a-octahydronaphthalene; (4aS,9aR)-3,5,5,9-tetramethyl-2,4a,5,6,7,9a-hexahydro- lH-benzo[7]annulene; (lR,4aS,8aS)-l-isopropyl-7-methyl-4-methylene- 1,2, 3,4,4a,5, 6,8a- octahydronaphthalene; furan-2-ylmethyl hexanoate; 2-methyldecanenitrile; ethyl

octanenitrile; octan-l-ol; octanoic acid; decanal; 3-(4-methoxyphenyl)-2-methylpropanal; 1,7,7- trimethylbicyclo[2.2. l]heptane-2,3-dione; 2,2-dimethyl-3-methylenebicyclo[2.2. ljheptane;

(lS,2S)-l,7,7-trimethylbicyclo[2.2.1]heptan-2-yl isobutyrate; 1,7,7- trimethylbicyclo[2.2. l]heptan-2-yl acetate; 2-ethoxy-2,6,6-trimethyl-9- methylenebicyclo[3.3. ljnonane; 3,3,6,7-tetramethyloctahydro-2H-chromene; l-methyl-4-(prop- l-en-2-yl)cyclohexyl acetate; l-methyl-4-(prop-l-en-2-yl)cyclohexan-l-ol; (R)-3-methylene-6- ((S)-6-methylhept-5-en-2-yl)cyclohex-l-ene; (4aR,7R,8aS)-4a-methyl-l-methylene-7-(prop-l- en-2-yl)decahydronaphthalene; 6,6-dimethyl-2-methylenebicyclo[3.1. ljheptane; (1S,4R,7R)- 1, 4,9, 9-tetramethyl- 1,2,3,4,5, 6,7, 8-octahydro-4,7-methanoazulene; (2,2-dimethoxyethyl)benzene; (E)-7,ll-dimethyl-3-methylenedodeca-l,6,10-triene; (lR,2S,6S,7S,8S)-8-isopropyl-l-methyl-3- methylenetricyclo[4.4.0.02,7]decane; (3R,3aS,7S,8aS)-3,8,8-trimethyl-6-methyleneoctahydro- lH-3a,7-methanoazulene; (lR,9S,Z)-4,ll,ll-trimethyl-8-methylenebicyclo[7.2.0]undec-4-ene; 2-methyl-4-phenylbutan-2-ol; 2-methyl-l-phenylpropan-2-ol; 2'-isopropyl-l,7,7- trimethylspiro[bicyclo[2.2.1]heptane-2,4'-[l,3]dioxane]; methyl (E)-octa-4,7-dienoate;

(lS,4aS,8aR)-l-isopropyl-4,7-dimethyl-l,2,4a,5,6,8a-hexahydronaphthalene; l-methyl-4-(prop-

1- en-2-yl)cyclohex-l-ene; (laR,4R,4aR,7bS)-l,l,4,7-tetramethyl-la,2,3,4,4a,5,6,7b-octahydro- lH-cyclopropa[e]azulene; 7,7-dimethyl-2-methylenebicyclo[2.2.1]heptane;

2- yl)-l,2,3,4,4a,5,6,8a-octahydronaphthalene; 6-isopropylquinoline; 3-(6,6- dimethylbicyclo[3.1. l]hept-2-en-2-yl)propanal; 2-methyl-5-(prop-l-en-2-yl)-2- vinyltetrahydrofuran; l-isopropyl-4-methylcyclohex-3-en-l-ol; l-phenylpent-4-en-l-one; 1- isopropyl-4-methylcyclohex-3-en-l-ol; 3,6-dimethyl-4,5,6,7-tetrahydrobenzofuran; (Z)-dodec-2- enal; (E)-hex-3-en-l-yl 3-methylbutanoate; 3,6-dimethyloctan-3-yl acetate; 3-(4- isopropylphenyl)propanal; (Z)-undec-2-enenitrile; (E)-undec-2-enal; (2E,6E)-nona-2,6-dienal; 2- phenoxyethan-l-ol; (Z)-non-2-enal; nonan-2-ol; nonan-2-one; (E)-2-hexylidenecyclopentan-l- one; 2-heptyltetrahydrofuran; (E)-dec-2-enal; (2E,6E)-nona-2,6-dienal; (2E,6E)-nona-2,6-dien-l- ol; 2,6-dimethyloctanal; decan-l-ol; (E)-hept-l-en-l-yl acetate; undec-10-enal; l-isopropyl-4- methyl-7-thiabicyclo[2.2.1]heptane; (3E,5Z)-undeca-l,3,5-triene; 3,7-dimethyloct-6-en-3-ol; l,3,3-trimethylbicyclo[2.2.1]heptan-2-yl acetate; 1, 1,2,3, 3-pentamethyl-2,3-dihydro-lH-indene; (Z)-dodec-3-enal; (lS,2S,5S)-2-methyl-5-(prop-l-en-2-yl)cyclohexan-l-ol; (2S,5R)-2-isopropyl- 5-methylcyclohexan-l-one; 3-(3-isopropylphenyl)butanal; 2-methyl-5-(6-methylhept-5-en-2- yl)bicyclo[3.1.0]hex-2-ene; 2-(m-tolyl)ethan-l-ol; (3E,6E)-nona-3,6-dien-l-ol; p-tolyl isobutyrate; 4-(prop- 1 -en-2-yl)cyclohex- 1 -ene- 1 -carbaldehyde; (4-(prop- 1 -en-2-yl)cyclohex- 1 - en-l-yl)methyl acetate; (2-isopropoxyethyl)benzene; 2-phenylethan-l-ol; 2-benzyl-l,3- dioxolane; 2-(6,6-dimethylbicyclo[3.1. l]hept-2-en-2-yl)acetaldehyde; 6,6-dimethyl-2- methylenebicyclo[3.1.1]heptan-3-ol; 4-isopropyl-l-methylcyclohex-3-en-l-ol; propane- 1,2-diol; 2,4-dimethyl-4-phenyltetrahydrofuran; (Z)-6-ethylideneoctahydro-2H-5,8-methanochromene; methyl 2,2-dimethyl-6-methylenecyclohexane- 1 -carboxylate; 4-methyl-2-phenyl-3 ,6-dihydro- 2H-pyran; (lS,3R,5S)-l-isopropyl-4-methylenebicyclo[3.1.0]hexan-3-ol; 5- allylbenzo[d][l,3]dioxole; (4aR,8aR)-4a,8-dimethyl-2-(propan-2-ylidene)-l,2,3,4,4a,5,6,8a- octahydronaphthalene; 2-methyl- 1 ,5-dioxaspiro[5.5]undecane; 2-(heptan-3-yl)- 1,3-dioxolane; (Z)-dodec-4-enal; 3-methyl-2-pentylcyclopentan-l-one; 2,6,10,10-tetramethyl-l- oxaspiro[4.5]dec-6-ene; (laR,4aS)-2,4a,8,8-tetramethyl-l,la,4,4a,5,6,7,8- octahydrocyclopropa[d]naphthalene; 1 -isopropyl-2-methoxy-4-methylbenzene; (2Z,4E)-nona- 2,4-dienal; (2E,6Z)-nona-2,6-dienal; (Z)-dec-2-enal; (E)-non-2-enal; (3E,6Z)-nona-3,6-dien-l-ol; (E)-dec-4-enal; (Z)-3,7-dimethylocta-l,3,6-triene; (Z)-3,7-dimethylocta-l,3,6-triene; (E)-3,7- dimethylocta-2,6-dien-l-ol; undecanal; (E)-4-methyldec-3-en-5-ol; (3R,4aS,5R)-4a,5-dimethyl- 3-(prop-l-en-2-yl)-l,2,3,4,4a,5,6,7-octahydronaphthalene; l-methoxy-3a,4,5,6,7,7a-hexahydro- lH-4,7-methanoindene; (Z)-hex-3-en-l-yl isobutyrate; decahydro-3H-spiro[furan-2,5'- [4,7]methanoindene]; (2Z,6E)-nona-2,6-dienenitrile; , ,5',5'-tetramethylhexahydro-2'H,5'H- spiro[[l,3]dioxolane-2,8'-[2,4a]methanonaphthalene]; (2'S,4a'S,8a'S)-l',l',5',5'- tetramethylhexahydro-2'H,5'H-spiro[[l,3]dioxolane-2,8'-[2,4a]methanonaphthalene], most preferably, said one or more malodor reduction materials are selected from the group consisting of 3-methoxy-7,7-dimethyl-10-methylenebicyclo[4.3.1]decane; (1S,2S,4S)-1,7,7- trimethylbicyclo[2.2. l]heptan-2-yl isobutyrate; 3a,4,5,6,7,7a-hexahydro-lH-4,7-methanoinden-6- yl acetate; octahydro-lH-4,7-methanoinden-5-yl acetate; (1S,2S)-1,7,7- trimethylbicyclo[2.2.1]heptan-2-yl isobutyrate; (lS,4R,7R)-l,4,9,9-tetramethyl-l,2,3,4,5,6,7,8- octahydro-4,7-methanoazulene; (2,2-dimethoxyethyl)benzene; (3R,3aS,7S,8aS)-3,8,8-trimethyl- 6-methyleneoctahydro-lH-3a,7-methanoazulene; (lR,3aS,7S,8aR)-l,4,9,9-tetramethyl- 2,3,6,7,8,8a-hexahydro-lH-3a,7-methanoazulene; (laR,4R,4aR,7bS)-l,l,4,7-tetramethyl- la,2,3,4,4a,5,6,7b-octahydro-lH-cyclopropa[e]azulene; (3aR,3bR,4S,7R,7aS)-4-isopropyl-7- methyl-3a,3b,4,5,6,7-hexahydro-lH-cyclopenta[l,3]cyclopropa[l,2]benzene;

(laR,4aS,7R,7aR,7bS)-l,l,7-trimethyl-4-methylenedecahydro-lH-cyclopropa[e]azulene;

(laR,4aS)-2,4a,8,8-tetramethyl-l,la,4,4a,5,6,7,8-octahydrocyclopropa[d]naphthalene;

decahydro-3H-spiro[furan-2,5'-[4,7]methanoindene]; l', ,5',5'-tetramethylhexahydro-2'H,5'H- spiro[[l,3]dioxolane-2,8'-[2,4a]methanonaphthalene]; (2'S,4a'S,8a'S)-l',l',5',5'- tetramethylhexahydro-2Ή,5Ή-s iro[[l,3]dioxolane-2,8'-[2,4a]methanona hthalene];

(laS,2aR,3R,5aS ,7R,7aR)-3,6,6,7a-tetramethyloctahydro-2H-2a,7-methanoazuleno[5,6-b]oxirene and mixtures thereof.

7. A cleaning and/or treatment composition according to any of Claims 1-4 comprising one or more malodor reduction materials having a log P of 3 or less, preferably a log P from 0.1 to 3, preferably said one or more malodor reduction materials are selected from the group consisting of 2-(p-tolyl)propan-2-ol; 4-methyl-l-oxaspiro[5.5]undecan-4-ol; 7-methyl-2H- benzo[b][l,4]dioxepin-3(4H)-one; 2-methyl-6-methyleneoct-7-en-2-ol; 4-methoxy-6-prop-2- enyl-l,3-benzodioxole; (E)-2,6-dimethylocta-5,7-dien-2-ol; (E)-2,7-dimethylocta-l,5,7-trien-3- ol; l-(3-methylbenzofuran-2-yl)ethan-l-one; l-ethyl-3-methoxytricyclo[2.2.1.02,6]heptane; 6,6- dimethylbicyclo[3.1. l]hept-2-ene-2-carbaldehyde; 3-methyl-4-phenylbutan-2-ol; 4-phenylbutan- 2-ol; l-hydroxydecan-3-one; (Z)-l,2-dimethoxy-4-(prop-l-en-l-yl)benzene; 4-allyl-l,2- dimethoxybenzene; methyl 2-((lR,2R)-3-oxo-2-((Z)-pent-2-en-l-yl)cyclopentyl)acetate; methyl 2-(3-oxo-2-pentylcyclopentyl)acetate; methyl cinnamate; 7-methoxy-3,7-dimethyloctanal;

octahydro-lH-4,7-methanoindene-l-carbaldehyde; 2,4-dimethyl-4,4a,5,9b-tetrahydroindeno[l,2- d][l,3]dioxine; 4-(4-hydroxy-4-methylpentyl)cyclohex-3-ene-l-carbaldehyde; (Z)-3-hexen-l-yl- 2-cyclopenten-l-one; 2-(5-methyl-5-vinyltetrahydrofuran-2-yl)propan-2-ol; 6-methyl-2-(oxiran- 2-yl)hept-5-en-2-ol; (E)-l-(l-methoxypropoxy)hex-3-ene; (E)-l-(l-ethoxyethoxy)hex-3-ene; (lS,5R)-2-methyl-5-(prop-l-en-2-yl)cyclohex-2-en-l-ol; 3,6-dimethylhexahydrobenzofuran- 2(3H)-one; (E)-6-(pent-3-en-l-yl)tetrahydro-2H-pyran-2-one; 2-methyl-4-phenyl-l,3-dioxolane; (lR,2S,5R)-5-methyl-2-(prop-l-en-2-yl)cyclohexan-l-ol; 4,9-dimethoxy-7H-furo[3,2- g]chromen-7-one; 2,5,6-trimethylcyclohex-3-ene-l-carbaldehyde; 4,4a,5,9b- tetrahydroindeno[l,2-d][l,3]dioxine; 3,7-dimethyloctane-l,7-diol; 3-phenylpropan-l-ol; (1,1- dimethoxypropan-2-yl)benzene; 5-ethyl-4-hydroxy-2-methylfuran-3(2H)-one; 2-butyl-4,4,6- trimethyl-l,3-dioxane; 3a,4,5,6,7,7a-hexahydro-lH-4,7-methanoinden-6-yl acetate; 5- (diethoxymethyl)benzo [d] [ 1 , 3 ] dioxole ; 3 - (benzo [d] [ 1 , 3 ] dioxol- 5 -yl) -2-methylpropanal ; 5 - pentyldihydrofuran-2(3H)-one; 5-[(Z)-hex-3-enyl]oxolan-2-one; 5-hexyldihydrofuran-2(3H)-one; diethyl cyclohexane-l,4-dicarboxylate; 2-isobutyl-4-methyltetrahydro-2H-pyran-4-ol; (Z)-6- ethylideneoctahydro-2H-5,8-methanochromen-2-one; 2-methoxy-4-(4-methylenetetrahydro-2H- pyran-2-yl)phenol; 4-allyl-2-methoxyphenyl acetate; 4-allyl-2-methoxyphenol; ethyl 3-methyl-3- phenyloxirane-2-carboxylate; nonan-3-one; ethyl 3-phenyloxirane-2-carboxylate; (2-(l- ethoxyethoxy)ethyl)benzene; (2R,3S,4R)-2,3,4,5-tetrahydroxypentanal; 2-(2- hydroxypropoxy)propan-l-ol; 2,6-dimethyloct-7-en-4-one; 2-methyl-5-(prop-l-en-2- yl)cyclohexan-l-ol; methyl 2-hexyl-3-oxocyclopentane-l-carboxylate; 6-pentyltetrahydro-2H- pyran-2-one; decahydronaphthalen-2-ol; l,4-dioxacyclohexadecane-5,16-dione; (4- isopropylphenyl)methanol; l-(benzofuran-2-yl)ethan-l-one; (lR,4R,6S)-l-methyl-4-(prop-l-en- 2-yl)-7-oxabicyclo[4.1.0]heptane; (Z)-non-6-en-l-ol; (lR,5R)-2-methyl-5-(prop-l-en-2- yl)cyclohex-2-en-l-ol; (3Z,6Z)-nona-3,6-dien-l-ol; cinnamyl formate; cinnamyl acetate; (E)-3- phenylprop-2-en-l-ol; octan-l-ol; octanoic acid; 3-(4-methoxyphenyl)-2-methylpropanal; 1,7,7- trimethylbicyclo[2.2.1]heptane-2,3-dione; l-butoxy-l-oxopropan-2-yl butyrate; l-methyl-4- (prop-l-en-2-yl)cyclohexan-l-ol; (2,2-dimethoxyethyl)benzene; (Z)-4-(2,2,6-trimethyl-7- oxabicyclo[4.1.0]heptan-l-yl)but-3-en-2-one; 4-methoxy-7H-furo[3,2-g]chromen-7-one; 2- methyl-4-phenylbutan-2-ol; 2-methyl-l-phenylpropan-2-ol; benzophenone; 7-isopentyl-2H- benzo[b][l,4]dioxepin-3(4H)-one; methyl (E)-octa-4,7-dienoate; (lS,4R,5R)-l-isopropyl-4- methylbicyclo[3.1.0]hexan-3-one; l-phenylpentan-2-ol; 2,3,4-trimethoxybenzaldehyde; 2,4,5- trimethoxybenzaldehyde; 2,4,6-trimethoxybenzaldehyde; trans,Trans-2,4-Nonadien-l-al; alphas- Dimethyl benzenepropanal; allyl 2-(isopentyloxy)acetate; l-(l-propoxyethoxy)propane; ((l-(2- methoxyethoxy)ethoxy)methyl)benzene; 7-methoxy-2H-chromen-2-one; 2-methyl-5-(prop- 1-en- 2-yl)-2-vinyltetrahydrofuran; l-phenylpent-4-en-l-one; 4-(4-methoxyphenyl)butan-2-one; (E)-3- propylideneisobenzofuran- l(3H)-one; 3-methyl-5-phenylpentanal; 3,4,5- trimethoxybenzaldehyde; (2E,6E)-nona-2,6-dienal; (Z)-3-(furan-2-yl)-2-phenylacrylaldehyde; 2- phenoxyethan-l-ol; (2E,6E)-nona-2,6-dienal; (2E,6E)-nona-2,6-dien-l-ol; (lS,2S,5S)-2-methyl- 5-(prop-l-en-2-yl)cyclohexan-l-ol; 2-hydroxy-l,2-diphenylethan-l-one; (E)-l,2,4-trimethoxy-5- (prop-l-en-l-yl)benzene; 2-(m-tolyl)ethan-l-ol; (3E,6E)-nona-3,6-dien-l-ol; p-tolyl isobutyrate; 4-(prop- 1 -en-2-yl)cyclohex- 1 -ene- 1 -carbaldehyde; 2-phenylethan- 1 -ol; 3 -methyl-5 - phenylpentan-l-ol; 2-benzyl-l,3-dioxolane; 6,6-dimethyl-2-methylenebicyclo[3.1.1]heptan-3-ol; 4-(benzo[d][l,3]dioxol-5-yl)butan-2-one; (4aR,8aS)-7-methyloctahydro-l,4-methanonaphthalen- 6(2H)-one; 4-isopropyl-l-methylcyclohex-3-en-l-ol; propane- 1,2-diol; 2-methyl-5- phenylpentan-l-ol; (lS,3R,5S)-l-isopropyl-4-methylenebicyclo[3.1.0]hexan-3-ol; 5- allylbenzo[d][l,3]dioxole; 5-methoxyoctahydro-lH-4,7-methanoindene-2-carbaldehyde; 5- methoxyoctahydro-lH-4,7-methanoindene-2-carbaldehyde; (lR,3R,6R)-2',2',3,7,7- pentamethylspiro[bicyclo[4.1.0]heptane-2,5'-[l,3]dioxane]; 2-methyl-l,5- dioxaspiro[5.5]undecane; 2-(4-methylthiazol-5-yl)ethan-l-ol; 2-(2-mercaptopropan-2-yl)-5- methylcyclohexan-l-one; (2Z,4E)-nona-2,4-dienal; (2E,6Z)-nona-2,6-dienal; (3E,6Z)-nona-3,6- dien-l-ol; methyl 2-((lS,2S)-3-oxo-2-pentylcyclopentyl)acetate; 7-(l,l-Dimethylethyl)-2H-l,5- benzodioxepin-3(4H)-one; triethyl 2-hydroxypropane-l,2,3-tricarboxylate; 4-formyl-2- methoxyphenyl isobutyrate; methyl 2,4-dihydroxy-3,6-dimethylbenzoate; (Z)-hex-3-en-l-yl isobutyrate; (Z)-cyclooct-4-en-l-yl methyl carbonate; 4-(4-hydroxy-3-methoxyphenyl)butan-2- one; (E)-3-(2-methoxyphenyl)acrylaldehyde; 3,3-Dimethyl-5(2,2,3-Trimethyl-3-Cyclopenten- lyl)-4-Penten-2-01; (E)-2,2-dimethyl-3-(3-methylpenta-2,4-dien-l-yl)oxirane; (Z)-hex-3-en-l-yl cyclopropanecarboxylate; 1-phenylethyl propionate; methyl 2-phenylacetate; 2-methyl-6- oxaspiro[4.5]decan-7-one; 2-ethoxy-4-(methoxymethyl)phenol; methyl 2- cyclopentylideneacetate; 6-methoxy-2,6-dimethylheptanal; (Z)-hex-3-en-l-yl methyl carbonate; 4-methylquinoline; 2-Methyl-5-(l -methylethenyl)-2-cyclohexenone; 4-methylpent- l-en-3-ol; isopropyl 2-methylbutanoate; 4-methylpent-4-en-2-yl isobutyrate; 7-methyloctan-l-ol; (Z)-2- methoxy-4-(prop-l-en-l-yl)phenyl acetate; (Z)-2-methoxy-4-(prop-l-en-l-yl)phenol; 1,7,7- trimethylbicyclo[2.2.1]heptan-2-ol; isopentyl isobutyrate; 3-phenylpropanoic acid; 2- phenylpropan-l-ol; heptan-l-ol; heptanal; benzo[d][l,3]dioxole-5-carbaldehyde; N,2-dimethyl- N-phenylbutanamide; (Z)-5-methylhept-2-en-4-one; l,3,3-trimethylbicyclo[2.2. l]heptan-2-ol; l,3,3-trimethyl-2-oxabicyclo[2.2.2]octane; 2-ethoxy-4-formylphenyl acetate; ethyl cinnamate; (2R, 5R)-2-methyl-5 -(prop- 1 -en-2-yl)cyclohexan- 1 -one ; 3 , 3 ,5 -trimethylcyclohexan- 1 -one; 2- methoxy-4-propylphenol; chroman-2-one; 2-methyl-5-(prop-l-en-2-yl)cyclohexan-l-one; 2- pentylcyclopentan- 1-one; 2-methoxy-4-methylphenol; (Z)-3-methyl-2-(pent-2-en- l-yl)cyclopent- 2-en-l-one; (E)-2-methoxy-4-(prop-l-en-l-yl)phenol; (Z)-hex-3-en-l-yl propionate; (Z)-hex-3- en-l-ol; (Z)-hex-2-en-l-ol; cinnamonitrile; cinnamaldehyde; cinnamonitrile; 2-methyl-5-(prop-l- en-2-yl)cyclohex-2-en- 1-one; 2-(2-ethoxyethoxy)ethan-l-ol; hexan-l-ol; 2-(2,2,3- trimethylcyclopent-3-en-l-yl)acetonitrile; l,7,7-trimethylbicyclo[2.2.1]heptan-2-one;

(lS,2R,4S)-l,7,7-trimethylbicyclo[2.2.1]heptan-2-ol; 6,6-dimethylspiro[bicyclo[3.1.1]heptane- 2,2'-oxirane]; 4-phenylbutan-2-one; benzyl isobutyrate; benzyl butyrate; phenylmethanol; 4- methoxybenzyl acetate; 4-methoxybenzyl formate; 4-cyclohexylbutan-2-ol; (E)-2-methyl-3- phenylacrylaldehyde; 4-methoxy-2,5-dimethylfuran-3(2H)-one; allyl 2-phenoxyacetate; N-ethyl- N-(m-tolyl)propionamide; 3-hydroxybutan-2-one; l-(4-methoxyphenyl)ethan- 1-one; 6- methylquinoline; 5-methylheptan-3-one; 4-vinylphenol; (E)-3-(4-hydroxy-3- methoxyphenyl)acrylaldehyde; 4-ethyl-2-methoxyphenol; 3-methyl-4-phenyl-lH-pyrazole; 3- methylcyclopentane-l,2-dione; 3-methoxy-5-methylphenol; 3-methoxy-3-methylbutan-l-ol; (E)- hex-3-en-l-ol; phenethyl acetate; phenethyl propionate; 2-(sec-butyl)-3-methoxypyrazine; 2- isopropyl-N,2,3-trimethylbutanamide; 2-isopropyl-4-methylthiazole; (E)-hex-2-en-l-ol; 2- butoxyethan-l-ol; (Z)-hept-3-en-l-yl acetate; (lS,5S)-4,6,6-trimethylbicyclo[3.1.1]hept-3-en-2- one; (S)-2-methyl-5-(prop-l-en-2-yl)cyclohex-2-en-l-one; methyl 2-methylbutanoate; allyl 2- (cyclohexyloxy) acetate; l,5-dimethylbicyclo[3.2.1]octan-8-one oxime; 1-phenylvinyl acetate; phenethyl formate; 2-(4-isopropylphenyl)acetaldehyde; l,2-dimethyl-3-(prop-l-en-2- yl)cyclopentan-l-ol; l-(4-methoxyphenyl)propan-2-one; 4-(4-hydroxyphenyl)butan-2-one; 3,7- dimethyloct-7-en-l-ol; 5-isopropyl-2-methylbicyclo[3.1.0]hexan-2-ol; l-oxaspiro(4,5)decan-2- one; (Z)-5-methylheptan-3-one oxime; 1-phenylethyl acetate; (E)-hex-2-en-l-ol; (lR,2S)-2-(tert- butyl)cyclohexan-l-ol; cinnamic acid; (2R,5R)-2-methyl-5-(prop-l-en-2-yl)cyclohexan-l-one; (Z)-2-methoxy-4-(prop- 1-en- l-yl)phenol; 2-mercapto-2-methylpentan- l-ol; 4-formyl-2- methoxyphenyl acetate; (Z)-2-ethoxy-5-(prop-l-en-l-yl)phenol; 3,4-dimethoxybenzaldehyde; (lR,5R)-4,6,6-trimethylbicyclo[3.1.1]hept-3-en-2-one; 2-(tert-butyl)cyclohexan-l-ol; 2,4- diethoxy-5-methylpyrimidine; 2,4-dimethyl-4,4a,5,9b-tetrahydroindeno[l,2-d][l,3]dioxine; isobornylcyclohenxanol, more preferably said one or more malodor reduction materials are selected from the group consisting of 2-(p-tolyl)propan-2-ol; 4-methyl-l-oxaspiro[5.5]undecan- 4-ol; 7-methyl-2H-benzo[b][l,4]dioxepin-3(4H)-one; 2-methyl-6-methyleneoct-7-en-2-ol; 4- methoxy-6-prop-2-enyl-l,3-benzodioxole; (E)-2,6-dimethylocta-5,7-dien-2-ol; (E)-2,7- dimethylocta-l,5,7-trien-3-ol; l-(3-methylbenzofuran-2-yl)ethan-l-one; l-ethyl-3- methoxytricyclo[2.2.1.02,6]heptane; 6,6-dimethylbicyclo[3.1. l]hept-2-ene-2-carbaldehyde; 3- methyl-4-phenylbutan-2-ol; 4-phenylbutan-2-ol; l-hydroxydecan-3-one; (Z)-l,2-dimethoxy-4- (prop-l-en-l-yl)benzene; 4-allyl-l,2-dimethoxybenzene; methyl 2-((lR,2R)-3-oxo-2-((Z)-pent-2- en-l-yl)cyclopentyl)acetate; methyl 2-(3-oxo-2-pentylcyclopentyl)acetate; methyl cinnamate; 7- methoxy-3 ,7-dimethyloctanal; octahydro- lH-4,7-methanoindene- 1 -carbaldehyde; 2,4-dimethyl- 4,4a,5,9b-tetrahydroindeno[l,2-d][l,3]dioxine; 4-(4-hydroxy-4-methylpentyl)cyclohex-3-ene-l- carbaldehyde; (Z)-3-hexen- l-yl-2-cyclopenten- 1-one; 2-(5-methyl-5-vinyltetrahydrofuran-2- yl)propan-2-ol; 6-methyl-2-(oxiran-2-yl)hept-5-en-2-ol; (E)-l-(l-methoxypropoxy)hex-3-ene; (E)-l-(l-ethoxyethoxy)hex-3-ene; (lS,5R)-2-methyl-5-(prop-l-en-2-yl)cyclohex-2-en-l-ol; 3,6- dimethylhexahydrobenzofuran-2(3H)-one; (E)-6-(pent-3-en-l-yl)tetrahydro-2H-pyran-2-one; 2- methyl-4-phenyl-l,3-dioxolane; (lR,2S,5R)-5-methyl-2-(prop-l-en-2-yl)cyclohexan-l-ol; 4,9- dimethoxy-7H-furo[3,2-g]chromen-7-one; 2,5,6-trimethylcyclohex-3-ene-l-carbaldehyde;

4,4a,5,9b-tetrahydroindeno[l,2-d][l,3]dioxine; 3,7-dimethyloctane-l,7-diol; 3-phenylpropan-l- ol; (l,l-dimethoxypropan-2-yl)benzene; 5-ethyl-4-hydroxy-2-methylfuran-3(2H)-one; 2-butyl- 4,4,6-trimethyl-l,3-dioxane; 3a,4,5,6,7,7a-hexahydro-lH-4,7-methanoinden-6-yl acetate; 5- (diethoxymethyl)benzo [d] [ 1 , 3 ] dioxole ; 3 - (benzo [d] [ 1 , 3 ] dioxol- 5 -yl) -2-methylpropanal ; 5 - pentyldihydrofuran-2(3H)-one; 5-[(Z)-hex-3-enyl]oxolan-2-one; 5-hexyldihydrofuran-2(3H)-one; diethyl cyclohexane-l,4-dicarboxylate; 2-isobutyl-4-methyltetrahydro-2H-pyran-4-ol; (Z)-6- ethylideneoctahydro-2H-5,8-methanochromen-2-one; 2-methoxy-4-(4-methylenetetrahydro-2H- pyran-2-yl)phenol; 4-allyl-2-methoxyphenyl acetate; 4-allyl-2-methoxyphenol; ethyl 3-methyl-3- phenyloxirane-2-carboxylate; nonan-3-one; ethyl 3-phenyloxirane-2-carboxylate; (2-(l- ethoxyethoxy)ethyl)benzene; (2R,3S,4R)-2,3,4,5-tetrahydroxypentanal; 2-(2- hydroxypropoxy)propan-l-ol; 2,6-dimethyloct-7-en-4-one; 2-methyl-5-(prop-l-en-2- yl)cyclohexan-l-ol; methyl 2-hexyl-3-oxocyclopentane-l-carboxylate; 6-pentyltetrahydro-2H- pyran-2-one; decahydronaphthalen-2-ol; l,4-dioxacyclohexadecane-5,16-dione; (4- isopropylphenyl)methanol; l-(benzofuran-2-yl)ethan-l-one; (lR,4R,6S)-l-methyl-4-(prop-l-en- 2-yl)-7-oxabicyclo[4.1.0]heptane; (Z)-non-6-en-l-ol; (lR,5R)-2-methyl-5-(prop-l-en-2- yl)cyclohex-2-en-l-ol; (3Z,6Z)-nona-3,6-dien-l-ol; cinnamyl formate; cinnamyl acetate; (E)-3- phenylprop-2-en-l-ol; octan-l-ol; octanoic acid; 3-(4-methoxyphenyl)-2-methylpropanal; 1,7,7- trimethylbicyclo[2.2.1]heptane-2,3-dione; l-butoxy-l-oxopropan-2-yl butyrate; l-methyl-4- (prop-l-en-2-yl)cyclohexan-l-ol; (2,2-dimethoxyethyl)benzene; (Z)-4-(2,2,6-trimethyl-7- oxabicyclo[4.1.0]heptan-l-yl)but-3-en-2-one; 4-methoxy-7H-furo[3,2-g]chromen-7-one; 2- methyl-4-phenylbutan-2-ol; 2-methyl-l-phenylpropan-2-ol; benzophenone; 7-isopentyl-2H- benzo[b][l,4]dioxepin-3(4H)-one; methyl (E)-octa-4,7-dienoate; (lS,4R,5R)-l-isopropyl-4- methylbicyclo[3.1.0]hexan-3-one; l-phenylpentan-2-ol; 2,3,4-trimethoxybenzaldehyde; 2,4,5- trimethoxybenzaldehyde; 2,4,6-trimethoxybenzaldehyde; trans,Trans-2,4-Nonadien-l-al; alphas- Dimethyl benzenepropanal; allyl 2-(isopentyloxy)acetate; l-(l-propoxyethoxy)propane; ((l-(2- methoxyethoxy)ethoxy)methyl)benzene; 7-methoxy-2H-chromen-2-one; 2-methyl-5-(prop- 1-en- 2-yl)-2-vinyltetrahydrofuran; l-phenylpent-4-en-l-one; 4-(4-methoxyphenyl)butan-2-one; (E)-3- propylideneisobenzofuran- l(3H)-one; 3-methyl-5-phenylpentanal; 3,4,5- trimethoxybenzaldehyde; (2E,6E)-nona-2,6-dienal; (Z)-3-(furan-2-yl)-2-phenylacrylaldehyde; 2- phenoxyethan-l-ol; (2E,6E)-nona-2,6-dienal; (2E,6E)-nona-2,6-dien-l-ol; (lS,2S,5S)-2-methyl- 5-(prop-l-en-2-yl)cyclohexan-l-ol; 2-hydroxy-l,2-diphenylethan-l-one; (E)-l,2,4-trimethoxy-5- (prop-l-en-l-yl)benzene; 2-(m-tolyl)ethan-l-ol; (3E,6E)-nona-3,6-dien-l-ol; p-tolyl isobutyrate; 4-(prop- 1 -en-2-yl)cyclohex- 1 -ene- 1 -carbaldehyde; 2-phenylethan- 1 -ol; 3 -methyl-5 - phenylpentan-l-ol; 2-benzyl-l,3-dioxolane; 6,6-dimethyl-2-methylenebicyclo[3.1.1]heptan-3-ol; 4-(benzo[d][l,3]dioxol-5-yl)butan-2-one; (4aR,8aS)-7-methyloctahydro-l,4-methanonaphthalen- 6(2H)-one; 4-isopropyl-l-methylcyclohex-3-en-l-ol; propane- 1,2-diol; 2-methyl-5- phenylpentan-l-ol; (lS,3R,5S)-l-isopropyl-4-methylenebicyclo[3.1.0]hexan-3-ol; 5- allylbenzo[d][l,3]dioxole; 5-methoxyoctahydro-lH-4,7-methanoindene-2-carbaldehyde; 5- methoxyoctahydro-lH-4,7-methanoindene-2-carbaldehyde; (lR,3R,6R)-2',2',3,7,7- pentamethylspiro[bicyclo[4.1.0]heptane-2,5'-[l,3]dioxane]; 2-methyl-l,5- dioxaspiro[5.5]undecane; 2-(4-methylthiazol-5-yl)ethan-l-ol; 2-(2-mercaptopropan-2-yl)-5- methylcyclohexan-l-one; (2Z,4E)-nona-2,4-dienal; (2E,6Z)-nona-2,6-dienal; (3E,6Z)-nona-3,6- dien-l-ol; methyl 2-((lS,2S)-3-oxo-2-pentylcyclopentyl)acetate; 7-(l,l-Dimethylethyl)-2H-l,5- benzodioxepin-3(4H)-one; triethyl 2-hydroxypropane-l,2,3-tricarboxylate; 4-formyl-2- methoxyphenyl isobutyrate; methyl 2,4-dihydroxy-3,6-dimethylbenzoate; (Z)-hex-3-en-l-yl isobutyrate; (Z)-cyclooct-4-en-l-yl methyl carbonate; 4-(4-hydroxy-3-methoxyphenyl)butan-2- one; 2,4-dimethyl-4,4a,5,9b-tetrahydroindeno[l,2-d][l,3]dioxine; isobomylcyclohenxanol, most preferably said one or more malodor reduction materials are selected from the group consisting of 4,9-dimethoxy-7H-furo[3,2-g]chromen-7-one; 3a,4,5,6,7,7a-hexahydro-lH-4,7-methanoinden- 6-yl acetate; (Z)-6-ethylideneoctahydro-2H-5,8-methanochromen-2-one; (2,2- dimethoxyethyl)benzene; 5-methoxyoctahydro- lH-4,7-methanoindene-2-carbaldehyde and mixtures thereof.

8. A cleaning and/or treatment composition according to any preceding claim, wherein said malodor reduction materials are not selected from the group consisting of geranyl nitrile;

helional; nonanal; linalool; (S)-(+)-linalool; (R)-(-)-linalool; nerol; tetrahydrolinalool; 2- phenylethyl acetate; eugenol; ethyl linalool; allyl heptoate; agrumen nitrile; citronitrile; 2,2- dimethyl-3-(m-tolyl)propan-l-ol; 2-methyl-5-phenylpentan-l-ol; dodecanenitrile; 2- heptylcyclopentan-l-one; methyl nonyl acetaldehyde; 3-(2-ethylphenyl)-2,2-dimethylpropanal; (Z)-l-(2,6,6-trimethylcyclohex-2-en-l-yl)but-2-en-l-one; (R,E)-2-methyl-4-(2,2,3- trimethylcyclopent-3-en-l-yl)but-2-en-l-ol; 4-(tert-butyl)cyclohexyl acetate; 1-cyclohexylethyl (E)-but-2-enoate; allyl 2-(cyclohexyloxy)acetate; alpha terpinyl acetate; beta terpinyl acetate; gamma terpinyl acetate; methyl dodecyl ether ; 2,4-dimethyl-4,4a,5,9b-tetrahydroindeno[l,2- d][l,3]dioxine; cinnamyl isobutyrate; (E)-2-methyl-4-(2,6,6-trimethylcyclohex-l-en-l-yl)but-2- enal; gamma methyl ionone; ethyl 2,3,6-trimethyl cyclohexyl carbonate ethyl 2,3,6-trimethyl cyclohexyl carbonate; Citral diethyl acetal; Dimethoxycyclododecane; l-((2S,3S)-2,3,8,8- tetramethyl- 1 ,2,3,4,5, 6,7, 8-octahydronaphthalen-2-yl)ethan- 1-one; oxacyclohexadecan-2-one; 4,6,6,7, 8, 8-hexamethyl-l, 3,4,6,7, 8-hexahydrocyclopenta[g]isochromene; Ethylene brassylate; Methyl (Z)-2-((3-(4-(tert-butyl)phenyl)-2-methylpropylidene)amino)benzoate; 4,7-Methano- 1H- inden-5-ol, 3a,4,5,6,7,7a-hexahydro-, 5-acetate; cedryl methyl ether: vetivert acetate; 1- ((3R,3aR,7R,8aS)-3,6,8,8-tetramethyl-2,3,4,7,8,8a-hexahydro-lH-3a,7-methanoazulen-5- yl)ethan- 1-one; Benzophenone; Farnesol; trans,trans-farnesol; 3-(3-isopropylphenyl)butanal; 2,6, 10-trimethylundec-9-enal; 3-(4-(tert-butyl)phenyl)propanal; 3-(4-isopropylphenyl)-2- methylpropanal; Citronellal (1); Citronellal (d); (E)-4,8-dimethyldeca-4,9-dienal; Pino

Acetaldehyde; 3-(4-(tert-butyl)phenyl)-2-methylpropanal; Cinnamic aldehyde; Citral; Geranial; MethoxyMelonal; o-methoxycinnamaldehyde; (E)-4-((3aS,7aS)-octahydro-5H-4,7- methanoinden-5-ylidene)butanal; Methyl Octyl Acetaldehyde; 3-(4-methoxyphenyl)-2- methylpropanal; 5-methoxyoctahydro-lH-4,7-methanoindene-2-carbaldehyde; Iso Cyclocitral; Octanal; 2-Undecenal; 10-Undecenal; Trans-trans-2,6-Nonadienal; Trans-2,cis-6-nondienal; Heliotropin; Hexyl Cinnamic aldehyde; p-methyl-alpha- pentylcinnamaldehyde; Alpha-methyl cinnamaldehyde; 3,4-dimethoxybenzaldehyde; Myrtenal; Perillaldehyde; Maceal; Methyl palmitate; Methyl iso eugenol and mixtures thereof.

9. A cleaning and/or treatment composition according to any preceding claim, said composition comprising an adjunct ingredient selected from the group consisting of builders, chelating agents, dye transfer inhibiting agents, dispersants, enzymes, and enzyme stabilizers, catalytic materials, bleach activators, hydrogen peroxide, sources of hydrogen peroxide, preformed peracids, polymeric dispersing agents, clay soil removal/anti-redeposition agents, brighteners, suds suppressors, dyes, hueing dyes, perfumes, perfume delivery systems, structure elasticizing agents, carriers, structurants, hydrotropes, processing aids, solvents in addition to said solubilizing agent, a fabric softener active selected from the group consisting of a silicone polymer, a polysaccharide, a clay, a fatty ester, a dispersible polyolefin, a polymer latex and mixtures thereof, pigments, and mixtures thereof, preferably said composition comprises an organic acid, preferably citric acid and/ or lactic acid, hydrogenated castor oil, ethoxylated polyethleneimines, preferably PEI 600 EO 20 and/or PEI 600, an enzyme, preferably a cold water amylase, cold water protease and/ or xylogluconase.

10. A cleaning and/or treatment composition according to any preceding claim, comprising a fabric softener active selected from the group consisting of a quaternary ammonium compound, a silicone polymer, a polysaccharide, a clay, an amine, a fatty ester, a dispersible polyolefin, a polymer latex and mixtures thereof, preferably

a. ) said quaternary ammonium compound comprises an alkyl quaternary ammonium compound, preferably said alkyl quaternary ammonium compound is selected from the group consisting of a monoalkyl quaternary ammonium compound, a dialkyl quaternary ammonium compound, a trialkyl quaternary ammonium compound and mixtures thereof;

b. ) said silicone polymer is selected from the group consisting of cyclic

silicones, polydimethylsiloxanes, aminosilicones, cationic silicones, silicone polyethers, silicone resins, silicone urethanes, and mixtures thereof;

c. ) said polysaccharide comprises a cationic starch; d. ) said clay comprises a smectite clay;

e. ) said dispersible polyolefin is selected from the group consisting of

polyethylene, polypropylene and mixtures thereof; and f. ) said fatty ester is selected from the group consisting of a polyglycerol ester, a sucrose ester, a glycerol ester and mixtures thereof.

11. A cleaning and/or treatment composition according to any preceding claim, comprising a fabric softener active that comprises a material selected from the group consisting of

monoesterquats, diesterquats, triesterquats, and mixtures thereof, preferably, said monoesterquats and diesterquats are selected from the group consisting of bis-(2-hydroxypropyl)- dimethylammonium methylsulfate fatty acid ester and isomers of bis-(2-hydroxypropyl)- dimethylammonium methylsulfate fatty acid ester and/or mixtures thereof, l,2-di(acyloxy)-3- trimethylammoniopropane chloride, N,N-bis(stearoyl-oxy-ethyl)-N,N-dimethyl ammonium chloride, N,N-bis(tallowoyl-oxy-ethyl)-N,N-dimethyl ammonium chloride, N,N-bis(stearoyl- oxy-ethyl)-N-(2-hydroxyethyl)-N-methyl ammonium methylsulfate, N,N-bis-(stearoyl-2- hydroxypropyl)-N,N-dimethylammonium methylsulfate, N,N-bis-(tallowoyl-2-hydroxypropyl)- Ν,Ν-dimethylammonium methylsulfate, N,N-bis-(palmitoyl-2-hydroxypropyl)-N,N- dimethylammonium methylsulfate, N,N-bis-(stearoyl-2-hydroxypropyl)-N,N- dimethylammonium chloride, l,2-di-(stearoyl-oxy)-3-trimethyl ammoniumpropane chloride, dicanoladimethylammonium chloride, di(hard)tallowdimethylammonium chloride,

dicanoladimethylammonium methylsulfate, l-methyl-l-stearoylamidoethyl-2- stearoylimidazolinium methylsulfate, 1 -tallowylamidoethyl-2-tallowylimidazoline,

dipalmylmethyl hydroxyethylammoinum methylsulfate and mixtures thereof.

12. A cleaning and/or treatment composition according to any preceding claim, said composition comprising a quaternary ammonium compound and a silicone polymer, preferably said composition comprises from 0.001% to 10%, from 0.1% to 8%, more preferably from 0.5% to 5%, of said silicone polymer.

13. A cleaning and/or treatment composition according to any preceding claim wherein said fabric softening active has an Iodine Value of between 0-140, preferably 5-100, more preferably 10-80, even more preferably, 15-70, most preferably 18-25 or when said fabric softening active comprises a partially hydrogenated fatty acid quaternary ammonium compound said fabric softening active most preferably has a Iodine Value of 25-60.

14. A cleaning and/or treatment composition according to any preceding claim wherein said cleaning and/or treatment composition is a soluble unit-dose product said soluble unit dose product comprising one or more cleaning and/or treatment compositions contained within one or more chambers said chambers being formed from one or more films, preferably said one or more films comprise PVA film.

15. A method of controlling malodors comprising: contacting a situs comprising a malodor and/or a situs that will become malodorous with a cleaning and/or treatment composition selected from the group consisting of the cleaning and/or treatment composition of Claims 1 to 14 and mixtures thereof, .preferably said situs comprises a fabric and said contacting step comprises contacting said fabric with a sufficient amount of Applicants' cleaning and/or treatment compositions to provide said fabric with a level of malodor reduction material at least 0.0025 mg of malodor reduction material/kg of fabric, preferably from 0.0025 mg of malodor reduction material /kg of fabric to 50mg of malodor reduction material /kg of fabric, more preferably from 0.25mg of malodor reduction material/kg of fabric to 25mg of malodor reduction material/kg of fabric, most preferably from 0.5 of malodor reduction material/kg of fabric to lOmg of malodor reduction material/kg of fabric of said sum of malodor reduction materials.

Description:

CLEANING AND/OR TREATMENT COMPOSITIONS COMPRISING MALODOR

REDUCTION COMPOSITIONS

FIELD OF THE INVENTION

BACKGROUND OF THE INVENTION

Unscented or scented products are desired by consumers as they may be considered more natural and discreet than scented products. Manufacturers of unscented or scented products for controlling malodors rely on malodor reduction ingredients or other technologies (e.g. filters) to reduce malodors. However, effectively controlling malodors, for example, amine-based malodors (e.g. fish and urine), thiol and sulfide-based malodors (e.g. garlic and onion), C2-C12 carboxylic acid based malodors (e.g. body and pet odor), indole based malodors (e.g. fecal and bad breath), short chain fatty aldehyde based malodors (e.g. grease) and geosmin based malodors (e.g. mold/mildew) may be difficult, and the time required for a product to noticeably reduce malodors may create consumer doubt as to the product's efficacy on malodors. Often times, manufacturers incorporate scented perfumes to help mask these difficult malodors.

Unfortunately, malodor control technologies typically cover up the malodor with a stronger scent and thus interfere with the scent of the perfumed or unperfumed situs that is treated with the malodor control technology. Thus, limited nature of the current malodor control technologies is extremely constraining. Thus what is needed is a broader palette of malodor control technologies so the perfume community can deliver the desired level of character in a greater number of situations/applications. Surprisingly, Applicants recognized that in addition to blocking a malodor' s access to a sensory cell, in order to achieve the desired goal, a malodor control technology must leave such sensor cell open to other molecules, for example scent molecules. As a result, such malodor reduction compositions do not unduely interfere with the scent of the perfumed or unperfumed cleaning and/or treatment compositions that comprise such compositions and the perfumed or unperfumed situs that is treated with such cleaning and/or treatment compositions. SUMMARY OF THE INVENTION

The present invention relates to cleaning and/or treatment compositions comprising malodor reduction compositions and methods of making and using such cleaning and/or treatment products and malodor reduction compositions. As a result, such malodor reduction compositions do not unduely interfere with the scent of the perfumed or unperfumed cleaning and/or treatment compositions that comprise such compositions and the perfumed or unperfumed situs that is treated with such cleaning and/or treatment compositions.

DETAILED DESCRIPTION OF THE INVENTION

As used herein "MORV" is the calculated malodor reduction value for a subject material.

A material's MORV indicates such material's ability to decrease or even eliminate the perception of one or more malodors. For purposes of the present application, a material's MORV is calculated in accordance with method found in the test methods section of the present application.

As used herein, the term "perfume" does not include malodor reduction materials. Thus, the perfume portion of a composition does not include, when determining the perfume's composition, any malodor reduction materials found in the composition as such malodor reduction materials are described herein. In short, if a material has a malodor reduction value "MORV" that is within the range of the MORV recited in the subject claim, such material is a malodor reduction material for purposes of such claim.

As used herein "cleaning and/or treatment compositions" means products comprising fluid laundry detergents, fabric enhancers, laundry and/or rinse additives, fluid dishwashing detergents, fluid hard surface cleaning and/or treatment compositions, fluid toilet bowl cleaners that may or may not be contained in a unit dose delivery product all for consumer, agricultural, industrial or institutional use.

As used herein, "malodor" refers to compounds generally offensive or unpleasant to most people, such as the complex odors associated with bowel movements.

As used herein, "odor blocking" refers to the ability of a compound to dull the human sense of smell.

As used herein, the terms "a" and "an" mean "at least one".

As used herein, the terms "include", "includes" and "including" are meant to be non- limiting.

Unless otherwise noted, all component or composition levels are in reference to the active portion of that component or composition, and are exclusive of impurities, for example, residual solvents or by-products, which may be present in commercially available sources of such components or compositions.

All percentages and ratios are calculated by weight unless otherwise indicated. All percentages and ratios are calculated based on the total composition unless otherwise indicated.

It should be understood that every maximum numerical limitation given throughout this specification includes every lower numerical limitation, as if such lower numerical limitations were expressly written herein. Every minimum numerical limitation given throughout this specification will include every higher numerical limitation, as if such higher numerical limitations were expressly written herein. Every numerical range given throughout this specification will include every narrower numerical range that falls within such broader numerical range, as if such narrower numerical ranges were all expressly written herein.

Malodor Reduction Materials

A non-limiting set of suitable malodor reduction materials are provided in the tables below. For ease of use, each material in Tables 1-3 is assigned a numerical indentifier which is found in the column for each table that is designated Number. Table 4 is a subset of Table 1, Table 5 is a subset of Table 2 and Table 6 is a subset of Table 3 and there for Tables 4, 5 and 6 each use the same numerical identifier as found, respectively, in Tables 1-3.

Codes

A = Vapor Pressure > 0.1 torr

B = Vapor Pressure is between 0.01 torr and 0.1 torr

C = log P < 3

D = log P > 3

E = Probability of Ingredient Color Instability = 0%

F = Probability of Ingredient Color Instability < 71%

G = Odor Detection Threshold less than p.ol=8

H = Odor Detection Threshold greater than p.ol=8

I = Melamine formaldehyde PMC Headspace Response Ratio greater than or equal to 10 J = Melamine formaldehyde PMC leakage less than or equal to 5%

K = Log of liquid dish neat product liquid-air partition coefficient greater than or equal to - 7

L = Log of liquid dish neat product liquid-air partition coefficient greater than or equal to - 5 Table 1 List of materials with at least one MORV from 1 to 5

Number Material Name CAS Number Comment Code

1 2-ethylhexyl (Z)-3-(4- 5466-77-3

methoxyphenyl)acrylate DEFHJ

2 2,4-dimethyl-2-(5,5,8,8-tetramethyl- 131812-67-4

5,6,7, 8-tetrahydronaphthalen-2-yl)- 1,3-dioxolane DFHJ 1 , 1 -dimethoxynon-2-yne 13257-44-8 ACEFHJK para-Cymen-8-ol 1197-01-9 BCGIJK

3 -methoxy-7 ,7-dimethyl- 10- 216970-21-7

methylenebicyclo[4.3. ljdecane BDEFHJK

Methoxycyclododecane 2986-54-1 DEFHJK

1 , 1 -dimethoxycyclododecane 950-33-4 DEFHJK

(Z)-tridec-2-enenitrile 22629-49-8 DEFHJK

Oxybenzone 131-57-7 DEFGJ

Oxyoctaline formate 65405-72-3 DFHJK

4-methyl-l-oxaspiro[5.5]undecan-4- 57094-40-3

ol CFGIJK

7-methyl-2H-benzo[b] [ 1 ,4]dioxepin- 28940-11-6

3(4H)-one CGIK

1 , 8 -dioxacycloheptadec an-9 -one 1725-01-5 DGJ

4-(tert-pentyl)cyclohexan- 1 -one 16587-71-6 ADFGIJKL o-Phenyl anisol 86-26-0 DEFHJK

3a,5,6,7,8,8b-hexahydro- 823178-41-2

2,2,6,6,7,8,8-heptamethyl-4H- indeno(4,5-d)-l,3-dioxole DEFHJK

7-isopropyl-8,8-dimethyl-6,10- 62406-73-9

dioxaspiro [4.5] decane BDEFHIJK

Octyl 2-furoate 39251-88-2 DEFHJK

Octyl acetate 112-14-1 BDEFHJKL octanal propylene glycol acetal 74094-61-4 BDEFHJKL

Octanal 124-13-0 ACHIKL

Octanal dimethyl acetal 10022-28-3 ACEFGJKL

Myrcene 123-35-3 ADEFGIKL

Myrcenol 543-39-5 BCEFGIJK

Myrcenyl acetate 1118-39-4 ADEFGJK

Myristaldehyde 124-25-4 DFHJK

Myristicine 607-91-0 CGJK

Myristyl nitrile 629-63-0 DEFHJK

2,2,6,8-tetramethyl-l,2,3,4,4a,5,8,8a- 103614-86-4

octahydronaphthalen- 1 -ol DEFHIJK

Ocimenol 5986-38-9 BCHIJK

Ocimenol 28977-58-4 BCHIJK

Nopyl acetate 128-51-8 DEFHJK

Nootkatone 4674-50-4 DHJK

Nonyl alcohol 143-08-8 BDEFGIJKL

Nonaldehyde 124-19-6 ADHIKL

12-methyl- 14-tetradec-9-enolide 223104-61-8 DFHJK

N-ethyl-p-menthane-3-carboxamide 39711-79-0 DEFGIJK l-(3-methylbenzofuran-2-yl)ethan-l- 23911-56-0

one CEFHIK

2-methoxynaphthalene 93-04-9 BDEFHK

Nerolidol 7212-44-4 DEFHJK

Nerol 106-25-2 BCHIK l-ethyl-3- 31996-78-8

methoxytricyclo[2.2.1.02,6]heptane ACEFHIJKL Methyl (E)-non-2-enoate 111-79-5 ADEFHJKL

10-isopropyl-2,7-dimethyl-l- 89079-92-5

oxaspiro[4.5]deca-3,6-diene BDEFHIJK

2-(2-(4-methylcyclohex-3 -en- 1 - 95962-14-4

yl)propyl)cyclopentan- 1 -one DHJK

Myrtenal 564-94-3 ACFHIJKL

(E)-4-(2,2,3,6- 54992-90-4

tetramethylcyclohexyl)but-3-en-2- one BDEFHIJK

Myraldyl acetate 53889-39-7 DHJK

Musk tibetine 145-39-1 DHIJ

1 ,7-dioxacycloheptadecan-8-one 3391-83-1 DGJ

Musk ketone 81-14-1 DHJ

Musk ambrette 83-66-9 DHIJ

3-methylcyclopentadecan- 1-one 541-91-3 DEFHJK

(E)-3-methylcyclopentadec-4-en-l- 82356-51-2

one DHJK

3 -methyl-4-phenylbutan-2-ol 56836-93-2 BCEFHIK

1 -(4-isopropylcyclohexyl)ethan- 1 -ol 63767-86-2 BDEFHIJK

Milk Lactone 72881-27-7 DEFHJK

Methyl octine carbonate 111-80-8 BDEFHKL

Methyl octyl acetaldehyde 19009-56-4 ADFHJKL

6,6-dimethoxy-2,5,5-trimethylhex-2- 67674-46-8

ene ACHIJKL

Methyl phenylethyl carbinol 2344-70-9 BCEFHIK

Methyl stearate 112-61-8 DEFHJ

Methyl nonyl acetaldehyde dimethyl 68141-17-3

acetal BDEFHJK

Methyl nonyl ketone 112-12-9 BDFHJKL

Methyl nonyl acetaldehyde 110-41-8 BDFHJK

Methyl myristate 124-10-7 DEFHJK

Methyl linoleate 112-63-0 DEFHJ

Methyl lavender ketone 67633-95-8 CFHJK

Methyl isoeugenol 93-16-3 ACEFHK

Methyl hexadecanoate 112-39-0 DEFHJK

Methyl eugenol 93-15-2 ACEFHK

Methyl epijasmonate 1211-29-6 CHJK

Methyl dihydrojasmonate 24851-98-7 DFHJK

Methyl diphenyl ether 3586-14-9 DEFHJK

Methyl cinnamate 103-26-4 BCEFHK

Methyl chavicol 140-67-0 ADEFHK

Methyl beta-naphthyl ketone 93-08-3 CEFHK

Methyl 2-octynoate 111-12-6 ACEFHKL

Methyl alpha-cyclogeranate 28043-10-9 ACHIJKL

Methoxycitronellal 3613-30-7 ACFGIJK

Menthone 1,2-glycerol ketal 67785-70-0

(racemic) CEFHJ

Octahydro- lH-4,7-methanoindene- 1- 30772-79-3

carbaldehyde BCFHIJKL 3-(3-(tert-butyl)phenyl)-2- 62518-65-4

methylpropanal BDHJK

(E)-4-(4,8-dimethylnona-3,7-dien-l- 38462-23-6

yl)pyridine DEFHJK

(E)-trideca-3, 12-dienenitrile 134769-33-8 DEFHJK

2,2-dimethyl-3-(m-tolyl)propan-l-ol 103694-68-4 CEFHIJK

2,4-dimethyl-4,4a,5,9b- 27606-09-3

tetrahydroindeno[ 1 ,2-d] [ 1 ,3]dioxine CEFHJK

Maceal 67845-30-1 BDFHJK

4-(4-hydroxy-4- 31906-04-4

methylpentyl)cyclohex-3-ene- 1 - carbaldehyde CHJ

1-Limonene 5989-54-8 ADEFGIJKL

(Z)-3 -hexen- 1 -yl-2-cyclopenten- 1 - 53253-09-1

one BDHK

Linalyl octanoate 10024-64-3 DEFHJ

Linalyl isobutyrate 78-35-3 BDHJK

Linalyl benzoate 126-64-7 DFHJ

Linalyl anthranilate 7149-26-0 DFHJ

Linalool oxide (furanoid) 60047-17-8 BCHIJK linalool oxide 1365-19-1 CGIJK

(2Z,6E)-3,7-dimethylnona-2,6- 61792-11-8

dienenitrile BDEFHJK

3-(4-methylcyclohex-3-en- 1 - 6784-13-0

yl)butanal ACFHIJK

(2,5-dimethyl-l,3-dihydroinden-2- 285977-85-7

yl)methanol CEFHJK

3-(4-(tert-butyl)phenyl)-2- 80-54-6

methylpropanal BDHJK

(E)-l-(l-methoxypropoxy)hex-3-ene 97358-54-8 ACEFGJKL

Leaf acetal 88683-94-7 ACEFGJKL

1-Carveol 2102-58-1 BCHIJK

Lauryl alcohol 112-53-8 DEFGJK

Lauryl acetate 112-66-3 DEFHJK

Laurie acid 143-07-7 DEFHJ

Lactojasmone 7011-83-8 BDEFHIJKL

Lauraldehyde 112-54-9 BDFHJK

3,6-dimethylhexahydrobenzofuran- 92015-65-1

2(3H)-one BCEFHIJKL

4-(l-ethoxyvinyl)-3,3,5,5- 36306-87-3

tetramethylcyclohexan- 1 -one BDFHIJK

Khusimol 16223-63-5 CEFHJK

5-(sec-butyl)-2-(2,4- 117933-89-8

dimethylcyclohex- 3 -en- 1 -yl) - 5 - methyl- 1 , 3 -dioxane DEFHJ

(l-methyl-2-((l,2,2- 198404-98-7

trimethylbicyclo[3.1.0]hexan-3- yl)methyl)cyclopropyl)methanol DEFHJK

2-propylheptanenitrile 208041-98-9 ADEFHIJKL (E)-6-(pent-3-en-l-yl)tetrahydro-2H- 32764-98-0

pyran-2-one BCFHIKL

2-hexylcyclopentan- 1 -one 13074-65-2 BDFHJKL

2-methyl-4-phenyl- 1 ,3 -dioxolane 33941-99-0 BCEFGIK

2,6,9, 10-tetramethyl-l- 71078-31-4

oxaspiro(4.5)deca-3,6-diene BDEFHIJK

Isopulegol 89-79-2 BCEFHIJKL

Isopropyl palmitate 142-91-6 DEFHJ

Isopropyl myristate 110-27-0 DEFHJK

Isopropyl dodecanoate 10233-13-3 DEFHJK

Isopimpinellin 482-27-9 CFGJ

Iso3 -methylcyclopentadecan- 1 -one 3100-36-5 DEFGJK

Isomenthone 491-07-6 ADEFGIJKL

Isojasmone 95-41-0 BDFHJKL

Isomenthone 36977-92-1 ADEFGIJKL

Isohexenyl cyclohexenyl 37677-14-8

carboxaldehyde DFHJK

Isoeugenyl benzyl ether 120-11-6 DFHJ l-((2S,3S)-2,3,8,8-tetramethyl- 54464-57-2

1,2,3,4, 5,6,7, 8-octahydronaphthalen- 2-yl)ethan-l-one DHJK

Isocyclocitral 1335-66-6 ACFHIJKL

Isobutyl quinoline 65442-31-1 DEFHJK

Isobornylcyclohexanol 68877-29-2 DEFHJK

Isobornyl propionate 2756-56-1 BDEFHIJK

Isobornyl isobutyrate 85586-67-0 BDEFHIJK

Isobornyl cyclohexanol 66072-32-0 DEFHJK

Isobornyl acetate 125-12-2 ADEFHIJKL

Isobergamate 68683-20-5 DEFHJK

Isoamyl undecylenate 12262-03-2 DEFHJK

Isoamyl laurate 6309-51-9 DEFHJK

Isoambrettolide 28645-51-4 DGJ

Irisnitrile 29127-83-1 ADEFHKL

Indolene 68527-79-7 DEFHJ

Indol/Hydroxycitronellal Schiff base 67801-36-9 DEFHJ

4 ,4a, 5 , 9b- tetrahydroindeno [1,2- 18096-62-3

d][l,3]dioxine BCEFGJK

Hydroxy-citronellol 107-74-4 CEFGIJK

2-cyclododecylpropan- 1 -ol 118562-73-5 DEFHJK

Hydrocitronitrile 54089-83-7 CEFHJK

Hydrocinnamyl alcohol 122-97-4 BCEFHIK

Hydratropaldehyde dimethyl acetal 90-87-9 ACEFHJK

5-ethyl-4-hydroxy-2-methylfuran- 27538-09-6

3(2H)-one CFGIK

2,3-dihydro-3,3-dimethyl-lH-indene- 173445-44-8

5-propanal DHJK

3-(3,3-dimethyl-2,3-dihydro-lH- 173445-65-3

inden-5 -yl)propanal DHJK

Hexyl octanoate 1117-55-1 DEFHJK Hexyl hexanoate 6378-65-0 DEFHJKL

Hexyl cinnamic aldehyde 101-86-0 DHJ

Hexyl benzoate 6789-88-4 DEFHJK

Hexenyl tiglate 84060-80-0 BDEFHJK

(E)-3 ,7-dimethylocta-2,6-dien- 1 -yl 3681-73-0

palmitate DEFHJ

Hexadecanolide 109-29-5 DEFGJK

2-butyl-4,4,6-trimethyl-l,3-dioxane 54546-26-8 ADEFHIJKL

Ethyl (lR,2R,3R,4R)-3- 116126-82-0

isopropylbicyclo[2.2.1]hept-5-ene-2- carboxylate BDEFHIJK

3a,4,5,6,7,7a-hexahydro-lH-4,7- 5413-60-5

methanoinden-6-yl acetate CEFGJK

2-(l-(3,3- 141773-73-1

dimethylcyclohexyl)ethoxy)-2- methylpropyl propionate DEFHJ

Heliotropine diethyl acetal 40527-42-2 CEFGJ

Helional 1205-17-0 CHJK

(E)-oxacyclohexadec- 13 -en-2-one 111879-80-2 DGJK

Gyrane 24237-00-1 ADEFHIJKL

Guaiol 489-86-1 DEFHJK l-(2,6,6-trimethylcyclohex-2-en-l- 68611-23-4

yl)pentan-3-one DHJK

Ethyl 2-ethyl-6,6-dimethylcyclohex- 57934-97-1

2-ene- 1 -carboxylate BDEFHIJK

Germacrene B 15423-57-1 DEFHJK

Germacrene D 23986-74-5 DEFHJK

Geranyl phenylacetate 102-22-7 DFHJ

Geranyl phenyl acetate 71648-43-6 DFHJ

Geranyl linalool 1113-21-9 DFHJ

Geranyl cyclopentanone 68133-79-9 DHJK gamma-Undecalactone (racemic) 104-67-6 DEFHJKL gamma-Terpinyl acetate 10235-63-9 BDHJK gamma-Terpineol 586-81-2 BCGIJK gamma-Nonalactone 104-61-0 BCEFHIKL gamma- Muurolene 30021-74-0 DEFHJKL gamma-(E)-6-(pent-3-en-l- 63095-33-0

yl)tetrahydro-2H-pyran-2-one BCEFHKL gamma-Ionone 79-76-5 BDEFHIJK gamma-Himachalene 53111-25-4 BDEFHJKL gamma-Gurjunene 22567-17-5 DEFHJKL gamma- Eudesmol 1209-71-8 DFHJK gamma-Dodecalactone 2305-05-7 DEFHJK gamma-Damascone 35087-49-1 BDEFHIJK gamma-Decalactone 706-14-9 BDEFHIJKL gamma-Cadinene 39029-41-9 DEFHJKL

1 -(3 ,3 -dimethylcyclohexyl)pent-4- 56973-87-6

en-l-one BDEFHJK

4,6,6,7,8,8-hexamethyl-l,3,4,6,7,8- 1222-05-5 DEFHJK hexahydrocyclopenta[g]isochromene

Furfuryl octanoate 39252-03-4 DEFHJK

Furfuryl hexanoate 39252-02-3 CEFHJK

Furfuryl heptanoate 39481-28-2 CEFHJK

2-methyldecanenitrile 69300-15-8 BDEFHJKL

8,8-dimethyl-3a,4,5,6,7,7a- 76842-49-4

hexahydro-lH-4,7-methanoinden-6- yl propionate DEFHJK

Ethyl (3aR,4S,7R,7aR)-octahydro- 80657-64-3

3aH-4,7-methanoindene-3a- carboxylate DEFHIJK

Diethyl cyclohexane-1,4- 72903-27-6

dicarboxylate CEFHJK

(6-isopropyl-9-methyl-l,4- 63187-91-7

dioxaspiro[4.5]decan-2-yl)methanol CEFHJ

2-isobutyl-4-methyltetrahydro-2H- 63500-71-0

pyran-4-ol BCEFHIJK

Undec- 10-enenitrile 53179-04-7 BDEFHJK

(Z)-6-ethylideneoctahydro-2H-5,8- 69486-14-2

methanochromen-2-one CEFGJK

3-(2-ethylphenyl)-2,2- 67634-15-5

dimethylpropanal BDHJK

(E)-4,8-dimethyldeca-4,9-dienal 71077-31-1 BDFHJK

(E)-4-((3aR,4R,7R,7aR)- 501929-47-1

l,3a,4,6,7,7a-hexahydro-5H-4,7- methanoinden-5-ylidene)-3- methylbutan-2-ol DEFHJK

8,8-dimethyl-3a,4,5,6,7,7a- 171102-41-3

hexahydro-lH-4,7-methanoinden-6- yl acetate DEFHJK

3-(4-ethylphenyl)-2,2- 134123-93-6

dimethylpropanenitrile DEFHJK

2-heptylcyclopentan- 1 -one 137-03-1 DFHJKL

1-ethoxyethoxy Cyclododecane 389083-83-4 DEFHJK

3-cyclohexene-l-carboxylic acid, 815580-59-7

2,6,6-trimethyl-, methyl ester ACHIJKL

Farnesyl acetate 29548-30-9 DEFHJK

Farnesol 4602-84-0 DEFHJK

Oxacyclohexadecan-2-one 106-02-5 DEFGJK

1 -cyclopentadec-4-en- 1 -one 14595-54-1 DEFGJK

1 -cyclopentadec-4-en- 1 -one 35720-57-1 DEFGJK

2-methoxy-4-(4- 128489-04-3

methylenetetrahydro-2H-pyran-2- yl)phenol CGJ

Eugenyl acetate 93-28-7 CFHJK

Eugenol 97-53-0 CHIK

Ethylmethylphenylglycidate 77-83-8 CFHJK

Ethylene brassylate 105-95-3 DFGJ

Ethyl undecylenate 692-86-4 DEFHJK Ethyl palmitate 628-97-7 DEFHJ

Ethyl nonanoate 123-29-5 BDEFHJKL

Ethyl myristate 124-06-1 DEFHJK

Ethyl linalool 10339-55-6 BCEFHJK

Ethyl laurate 106-33-2 DEFHJK

Ethyl hexyl ketone 925-78-0 ADFHIKL

Ethyl decanoate 110-38-3 BDEFHJK

Ethyl gamma-Safranate 35044-57-6 ADHIJK

Ethyl 3-phenylglycidate 121-39-1 CGJK

6-ethyl-2,10,10-trimethyl-l- 79893-63-3

oxaspiro[4.5]deca-3,6-diene BDEFHIJK

Elemol 639-99-6 DEFHJK

(2-( 1 -ethoxyethoxy)ethyl)benzene 2556-10-7 BCEFHJK

(E)-3-methyl-5-(2,2,3- 67801-20-1

trimethylcyclopent-3 -en- 1 -yl)pent-4- en-2-ol DHJK d-xylose 58-86-6 CGIJ

(E)-4-((3aS,7aS)-octahydro-5H-4,7- 30168-23-1

methanoinden-5-ylidene)butanal DFHJK

Dodecanal dimethyl acetal 14620-52-1 DEFHJK d-Limonene 5989-27-5 ADEFGIJKL

Dipropylene Glycol 25265-71-8 CEFGIK

Dispirone 83863-64-3 BDEFHJK

Diphenyloxide 101-84-8 BDEFHK

Diphenylmethane 101-81-5 DEFGK

Dimethyl benzyl carbinyl butyrate 10094-34-5 DEFHJK

2,6-dimethyloct-7-en-4-one 1879-00-1 ADEFHIJKL

Octahydro-lH-4,7-methanoinden-5- 64001-15-6

yl acetate DEFHJKL

Dihydrocarveol acetate 20777-49-5 BDEFHIJK

Dihydrocarveol 619-01-2 BCEFHIJKL

Dihydro Linalool 18479-51-1 BCEFGIJKL

Dihydro Isojasmonate 37172-53-5 DHJK

Dibutyl sulfide 544-40-1 ADEFHIKL

Dibenzyl 103-29-7 DEFGJK delta- Undecalactone 710-04-3 DEFHJKL delta-Elemene 20307-84-0 BDEFHJK delta-Guaiene 3691-11-0 DEFHJKL delta-Dodecalactone 713-95-1 DEFHJK delta-Decalactone 705-86-2 BDEFHIJKL delta-Cadinene 483-76-1 DEFHJKL delta-damascone 57378-68-4 ADHIJK delta- Amorphene 189165-79-5 DEFHJKL delta-3-Carene 13466-78-9 ADEFGIJKL

Decylenic alcohol 13019-22-2 BDEFHJK

Decyl propionate 5454-19-3 DEFHJK

Decanal diethyl acetal 34764-02-8 DEFHJK

Decahydro-beta-naphthol 825-51-4 B CEFGIK

1-cyclohexylethyl (E)-but-2-enoate 68039-69-0 BDFHJK 3-(4-isopropylphenyl)-2- 103-95-7

methylpropanal BDFHJK

Cyclotetradecane 295-17-0 DEFGJKL

Cyclopentadecanone 502-72-7 DEFGJK

Cyclohexyl salicylate 25485-88-5 DFGJ

3a,4,5,6,7,7a-hexahydro-lH-4,7- 113889-23-9

methanoinden-6-yl butyrate DEFHJK

Cyclic ethylene dodecanedioate 54982-83-1 DFGJ

8,8-dimethyl-l,2,3,4,5,6,7,8- 68991-97-9

octahydronaphthalene-2- carbaldehyde DHJK

3a,4,5,6,7,7a-hexahydro-lH-4,7- 67634-20-2

methanoinden-5-yl isobutyrate DEFHJK

Curzerene 17910-09-7 DHJK

Cumic alcohol 536-60-7 CHIJK

Coumarone 1646-26-0 BCEFHIK

2-(3-phenylpropyl)pyridine 2110-18-1 CEFHJK

Dodecanenitrile 2437-25-4 DEFHJK

(E)-cycloheptadec-9-en- 1 -one 542-46-1 DEFGJ

Citryl acetate 6819-19-8 DFHJK

Citrus Propanol 15760-18-6 CEFHIJK

Citronitrile 93893-89-1 CEFHJK

Citral propylene glycol acetal 10444-50-5 CEFHJK

Citral dimethyl acetal 7549-37-3 B CEFHJK

Citral diethyl acetal 7492-66-2 BDEFHJK cis-Ocimene 3338-55-4 ADGIKL cis-Limonene oxide 13837-75-7 ADEFGIJKL

Cis -iso -ambrettolide 36508-31-3 DGJ cis-6-nonenol 35854-86-5 BCEFHIKL cis-carveol 1197-06-4 BCHIJK cis-4-Decen-l-al 21662-09-9 ADHKL cis-3-hexenyl-cis-3-hexenoate 61444-38-0 BDEFHJK cis-3-Hexenyl salicylate 65405-77-8 DEFGJ

Cis-3-hexenyl Benzoate 25152-85-6 DEFHJK cis-3-Hexenyl 2-methylbutyrate 53398-85-9 ADEFHJKL cis-3, cis-6-nonadienol 53046-97-2 ACEFHK

Cinnamyl propionate 103-56-0 DEFHJK

Cinnamyl isobutyrate 103-59-3 DEFHJK

Cinnamyl formate 104-65-4 BCEFHK

Cinnamyl cinnamate 122-69-0 DHJ

Cinnamyl acetate 103-54-8 BCEFHK

Cinnamic alcohol 104-54-1 BCEFHIK

Cetyl alcohol 36653-82-4 DEFHJ

(E) - 1 - (2 , 6, 6-trimethylcyclohex-2-en- 79-78-7

l-yl)hepta-l,6-dien-3-one DHJK

2-methyl-4-(2,6,6-trimethylcyclohex- 65405-84-7

l-en-l-yl)butanal DFHJK

(3aR,5aR,9aR,9bR)-3a,6,6,9a- 3738-00-9

tetramethy Idodecahydronaphtho [2,1- DEFHJK bjfuran

l,6-dioxacycloheptadecan-7-one 6707-60-4 DGJ l-(6-(tert-butyl)-l,l-dimethyl-2,3- 13171-00-1

dihydro- 1 H-inden-4-yl)ethan- 1 -one DEFHJK

Cedryl methyl ether 19870-74-7 ADEFHJK

Cedryl formate 39900-38-4 BDEFHJK

Cedryl acetate 77-54-3 DEFHJK

(4Z,8Z)-l,5,9-trimethyl-13- 71735-79-0

oxabicyclo[ 10.1.0]trideca-4,8-diene DFHJK

Cedrol 77-53-2 DEFHJK

5-methyl-l-(2,2,3- 139539-66-5

trimethylcyclopent-3-en-l-yl)-6- oxabicyclo[3.2.1]octane DEFHJK

5-methyl-l-(2,2,3- 426218-78-2

trimethylcyclopent-3-en-l-yl)-6- oxabicyclo[3.2.1]octane DFHJ

1,1, 2,3, 3-pentamethyl- 1,2,3, 5,6,7- 33704-61-9

hexahydro-4H-inden-4-one BDEFHIJK

Caryophyllene alcohol acetate 32214-91-8 DEFHJK

Caryolan-l-ol 472-97-9 DEFHJK

Carvyl acetate 97-42-7 BDHIJK

Caprylnitrile 124-12-9 ACEFGIKL

Caprylic alcohol 111-87-5 ACEFGIKL

Caprylic acid 124-07-2 BCEFHIK

Capric acid 334-48-5 DEFHJK

Capraldehyde 112-31-2 ADHKL

3-(4-methoxyphenyl)-2- 5462-06-6

methylpropanal BCHJK

Camphorquinone 10373-78-1 ACEFGIJK

Camphene 79-92-5 ADEFGIJKL

Ethyl 2-methyl-4-oxo-6- 59151-19-8

pentylcyclohex-2-ene-l-carboxylate DHJ

Butylated hydroxytoluene 128-37-0 DEFGIJK

Butyl stearate 123-95-5 DEFHJ

Butyl butyryl lactate 7492-70-8 CEFGJK

Butyl 10-undecenoate 109-42-2 DEFHJK

2-methyl-4-(2,2,3- 72089-08-8

trimethy Icy clopent- 3 -en- 1 -yl)butan- l-ol DEFHJK

3-(4-(tert-butyl)phenyl)propanal 18127-01-0 BDHJK

Bornyl isobutyrate 24717-86-0 BDEFHIJK

Bornyl acetate 76-49-3 ADEFHIJKL

2-ethoxy-2,6,6-trimethyl-9- 68845-00-1

methylenebicyclo [3.3.1 Jnonane BDEFHJK

(ethoxymethoxy)cyclododecane 58567-11-6 DEFHJK

Bisabolene 495-62-5 DEFHJK

Bigarade oxide 72429-08-4 ADEFHJKL beta-Vetivone 18444-79-6 DHJK beta-Terpinyl acetate 10198-23-9 BDHJK beta-Terpineol 138-87-4 BCGIJK beta-Sinensal 60066-88-8 DHJK beta-Sesquiphellandrene 20307-83-9 DEFHJK beta-Selinene 17066-67-0 BDEFGJK beta-Santalol 77-42-9 DEFHJK beta-Pinene 127-91-3 ADEFGIJKL beta-Naphthyl ethyl ether 93-18-5 BDEFHJK beta-Patchoulline 514-51-2 BDEFGJKL beta-Himachalene Oxide 57819-73-5 BDFHJK beta-Himachalene 1461-03-6 DEFHJKL beta-Guaiene 88-84-6 DEFHJKL

(2,2-dimethoxyethyl)benzene 101-48-4 DHJK beta-Farnesene 18794-84-8 DEFHJK beta-Copaene 18252-44-3 BDEFHJKL beta-Cedrene 546-28-1 BDEFGJKL beta- Caryophy llene 87-44-5 DEFHJKL beta-Bisabolol 15352-77-9 DFHJK

Beta ionone epoxide 23267-57-4 BDEFHIJK

Bergaptene 484-20-8 CGJ

Benzyl-tert-butanol 103-05-9 CEFGJK

Benzyl laurate 140-25-0 DEFHJ

Benzyl dimethyl carbinol 100-86-7 BCEFGIK

Benzyl cinnamate 103-41-3 DHJ

Benzyl benzoate 120-51-4 DHJ

Benzophenone 119-61-9 DEFHK

7-isopentyl-2H- 362467-67-2

benzo [b] [ 1 ,4]dioxepin-3 (4H)-one DHJ

2'-isopropyl-l,7,7- 188199-50-0

trimethylspiro[bicyclo[2.2.1]heptane- 2,4'-[l,3]dioxane] DEFHJK

4-(4-methylpent-3-en-l-yl)cyclohex- 21690-43-7

3 -ene- 1 -carbonitrile DEFHJK

Aurantiol 89-43-0 DEFHJ

Anisyl phenylacetate 102-17-0 DFHJ

Methyl (E)-octa-4,7-dienoate 189440-77-5 ACEFHKL

Amyl Cinnamate 3487-99-8 DEFHJK

(3aR,5aS,9aS,9bR)-3a,6,6,9a- 6790-58-5

tetramethy Idodecahydronaphtho [2,1- b]furan DEFHJK

(4aR,5R,7aS,9R)-2,2,5,8,8,9a- 211299-54-6

hexamethyloctahydro-4H-4a,9- methanoazuleno[5,6-d] [1 ,3]dioxole DEFHJK

2,5,5-trimethyl-l,2,3,4,5,6,7,8- 71832-76-3

octahydronaphthalen-2-ol DEFHJK

2,5,5-trimethyl-l,2,3,4,5,6,7,8- 41199-19-3

octahydronaphthalen-2-ol DEFHJK l-((2-(tert- 139504-68-0

butyl)cyclohexyl)oxy)butan-2-ol DEFHJK

(3S,5aR,7aS,l laS,llbR)-3,8,8,l la- 57345-19-4 DEFHJ tetramethyldodecahydro-5H-3 ,5a- epoxynaphtho[2, l-c]oxepine

2,2, 6,6,7,8, 8-heptamethyldecahydro- 476332-65-7

2H-indeno [4 , 5 -b] furan ADEFHJK

2,2, 6,6,7,8, 8-heptamethyldecahydro- 647828-16-8

2H-indeno [4 , 5 -b] furan ADEFHJK

Amber acetate 37172-02-4 BDEFHJK

Alpinofix ^® 811436-82-5 DEFHJ alpha- Thuj one 546-80-5 ADEFGIJKL alpha- Vetivone 15764-04-2 DHJK alpha- Terpinyl propionate 80-27-3 BDEFHJK alpha-Sinensal 17909-77-2 DHJK alpha-Selinene 473-13-2 BDEFHJK alpha- Santalene 512-61-8 ADEFHJKL alpha-Santalol 115-71-9 DEFHJK alpha- Patchoulene 560-32-7 ADEFHJKL alpha-neobutenone 56973-85-4 BDHJK alpha-Muurolene 10208-80-7 DEFHJKL alpha-methyl ionone 127-42-4 BDHJK alpha-Limonene 138-86-3 ADEFGIJKL alpha-Irone 79-69-6 BDHJK alpha-Humulene 6753-98-6 DEFHJK alpha-Himachalene 186538-22-7 BDEFHJK alpha- Gurj unene 489-40-7 BDEFHJKL alpha- Guaiene 3691-12-1 DEFHJKL alpha-Farnesene 502-61-4 DEFHJK alpha-Fenchene 471-84-1 ADEFGIJKL alpha-Eudesmol 473-16-5 DEFHJK alpha- Curcumene 4176-17-4 DEFHJK alpha- Cubebene 17699-14-8 ADEFHJKL alpha- Cedrene epoxide 13567-39-0 ADEFHJK alpha- Cadinol 481-34-5 DEFHJK alpha-Cadinene 24406-05-1 DEFHJKL alpha-Bisabolol 515-69-5 DFHJK alpha-bisabolene 17627-44-0 DEFHJK alpha-Bergamotene 17699-05-7 BDEFHJKL alpha- Amylcinnamyl alcohol 101-85-9 DEFHJ alpha- Amylcinnamyl acetate 7493-78-9 DEFHJ alpha- Amylcinnamaldehyde diethyl 60763-41-9

acetal DEFHJ alpha- Amylcinnamaldehyde 122-40-7 DHJK alpha- Amorphene 23515-88-0 DEFHJKL alpha- Agarofuran 5956-12-7 BDEFHJK

1 -methyl-4-(4-methyl-3 -penten- 1 - 52475-86-2

yl)-3-Cyclohexene- 1 -carboxaldehyde DFHJK l-Phenyl-2-pentanol 705-73-7 CEFHK l-Phenyl-3-methyl-3-pentanol 10415-87-9 CEFHJK

2,3,4-trimethoxy-benzaldehyde 2103-57-3 BCGI

2,4,5-trimethoxy-benzaldehyde 4460-86-0 BCG 2,4, 6- trimethoxybenzaldehyde 830-79-5 BCGI

2,4-Nonadienal 6750-03-4 ACHKL

2,6,10-Trimethylundecanal 105-88-4 BDFGJK alpha,4-Dimethyl benzenepropanal 41496-43-9 ACHJK

Allyl cyclohexyl propionate 2705-87-5 BDEFHJK

Allyl amyl glycolate 67634-00-8 BCEFGJK

Alio- aromadendrene 25246-27-9 BDEFHJKL

Aldehyde C- 11 143-14-6 ADHJK

Methyl (E)-2-(((3,5- 94022-83-0

dimethylcyclohex-3-en- 1- yl)methylene)amino)benzoate DEFHJ

2,6, 10-trimethylundec-9-enal 141-13-9 BDFHJK

Acetoxymethyl-isolongifolene 59056-62-1

(isomers) BDEFHJK

Acetate C9 143-13-5 BDEFHJKL

Acetarolle ^® 744266-61-3 DFHJK

Acetaldehyde phenylethyl propyl 7493-57-4

acetal CEFHJK

Acetaldehyde dipropyl acetal 105-82-8 ACEFGIKL

Acetaldehyde benzyl 2-methoxyethyl 7492-39-9

acetal B CEFHJK

(Z)-2-(4-methylbenzylidene)heptanal 84697-09-6 DHJ

9-decenal 39770-05-3 ADHKL

8-Hexadecenolide 123-69-3 DGJ

7-Methoxycoumarin 531-59-9 CHK

7 -epi- alpha- Selinene 123123-37-5 BDEFHJK

7-eip-alpha-Eudesmol 123123-38-6 DEFHJK

7-Acetyl-l, 1,3,4,4,6- 1506-02-1

hexamethyltetralin DEFHJ

6-Isopropylquinoline 135-79-5 CEFHJK

6,6-dimethyl-2-norpinene-2- 33885-51-7

propionaldehyde BCFHJK

6,10, 14-trimethyl-2-Pentadecanone 502-69-2 DEFHJK

5-Isopropenyl-2-methyl-2- 13679-86-2

vinyltetrahydrofuran ACGIJKL

5 - Cy clohexadecenone 37609-25-9 DEFGJK

4-Terpinenol 562-74-3 BCHIJK

4-Pentenophenone 3240-29-7 BCEFHIK

4-Carvomenthenol 28219-82-1 BCHIJK

4,5,6,7-Tetrahydro-3,6- 494-90-6

dimethylbenzofuran BCEFHIJKL

4-(p-Methoxyphenyl)-2-butanone 104-20-1 B CEFHJK

3-Thujopsanone 25966-79-4 BDEFHJK

3 -Propylidenephthalide 17369-59-4 CEFHK

3-Nonylacrolein 20407-84-5 BDFHJK

3 -Methyl- 5 -phenyl- 1 -pentanal 55066-49-4 BDFHJK

3-Hexenyl isovalerate 10032-11-8 ADEFHJKL

3,6-Dimethyl-3-octanyl acetate 60763-42-0 ADEFHIJKL

3,4,5 -trimethoxybenzaldehyde 86-81-7 BCGIK 3-(p- 7775-00-0

Isopropylphenyl)propionaldehyde BDFHJK

2-Undecenenitrile 22629-48-7 BDEFHJK

2-Undecenal 2463-77-6 ADHJK

2-trans-6-trans-Nonadienal 17587-33-6 ACHKL

2-Phenylethyl butyrate 103-52-6 DEFHJK

2-Phenyl-3-(2-furyl)prop-2-enal 57568-60-2 CHJ

2-Phenoxyethanol 122-99-6 BCEFGIK

2-Nonen-l-al 2463-53-8 ADHKL

2-Nonanol 628-99-9 BDEFGIKL

2-Nonanone 821-55-6 ADFHIKL

2-Isobutyl quinoline 93-19-6 CEFHJK

2-Hexylidene cyclopentanone 17373-89-6 DFHJKL

2-Heptyl tetrahydrofuran 2435-16-7 BDEFHJKL

2-Decenal 3913-71-1 ADHKL

2,6-Nonadienal 26370-28-5 ACHKL

2,6-Nonadien-l-ol 7786-44-9 ACEFHK

2,6-dimethyl-octanal 7779-07-9 ADFGIJKL

1-Decanol 112-30-1 BDEFGJK

1-Hepten-l-ol, 1-acetate 35468-97-4 ACEFHKL

10-Undecen-l-ol 112-43-6 DEFHJK

10-Undecenal 112-45-8 ADHJK

10-epi-gamma-Eudesmol 15051-81-7 DFHJK

1,8-Thiocineol 68391-28-6 ADEFHIJKL

1 ,3 ,5 -undecatriene 16356-11-9 ADEFHJKL

1 ,2-Dihydrolinalool 2270-57-7 BCEFGIJKL l,3,3-trimethyl-2-norbornanyl 13851-11-1

acetate ADEFHIJKL

1,1 ,2,3,3-Pentamethylindan 1203-17-4 ADHIJKL

(Z)-6,10-dimethylundeca-5,9-dien-2- 3239-37-0

yl acetate DEFHJK

(Z)-3-Dodecenal 68141-15-1 BCFHJK

(S)-gamma-Undecalactone 74568-05-1 DEFHJKL

(R)-gamma-Undecalactone 74568-06-2 DEFHJKL

(E)-6,10-dimethylundeca-5,9-dien-2- 3239-35-8

yl acetat DEFHJK

(2Z)-3-methyl-5-phenyl-2- 53243-59-7

Pentenenitrile DEFHJK

(2S,5S,6S)-2,6,10,10-tetramethyl-l- 65620-50-0

oxaspiro[4_5]decan-6-ol DFHIJK

(2E)-3-methyl-5-phenyl-2- 53243-60-0

pentenenitrile CEFHJK

(+)-Dihydrocarveol 22567-21-1 BCEFHIJKL

Menthone 89-80-5 ADEFGIJKL

(R,E)-2-methyl-4-(2,2,3- 185068-69-3

trimethylcyclopent-3-en-l-yl)but-2- en-l-ol CHJK

2-(8-isopropyl-6- 68901-32-6

methylbicyclo[2.2.2]oct-5-en-2-yl)- DEFHJK 1,3-dioxolane

gamma-methyl ionone 7388-22-9 BDHIJK

3 - (3 -isopropylphenyl)butanal 125109-85-5 BDHJK

3-(l-ethoxyethoxy)-3,7- 40910-49-4

dimethylocta- 1 ,6-diene BDEFHJK

3a,4,5,6,7,7a-hexahydro-lH-4,7- 17511-60-3

methanoinden-6-yl propionate CEFHJK

Bulnesol 22451-73-6 DEFHJK

Benzyl phenylacetate 102-16-9 DHJ

Benzoin 119-53-9 CEFHJ

(E)- 1 ,2,4-trimethoxy-5-(prop- 1-en- 1 - 2883-98-9

yl)benzene BCFGJK alpha, alpha, 6, 6-tetramethyl 33885-52-8

bicyclo [3.1.1 ]hept-2-ene-propanal BDFHJK

7-epi-sesquithujene 159407-35-9 DEFHJKL

5-Acetyl-l, 1,2,3,3,6- 15323-35-0

hexamethylindan DEFHJK

3-Methylphenethyl alcohol 1875-89-4 BCEFHIK

3,6-Nonadien-l-ol 76649-25-7 ACEFHK

2-Tridecenal 7774-82-5 BDFHJK

Patchouli alcohol 5986-55-0 DEFHIJK p-Cresyl isobutyrate 103-93-5 BDHJK p-Cresyl n-hexanoate 68141-11-7 DEFHJK

5-hexyl-4-methyldihydrofuran- 67663-01-8

2(3H)-one BDEFHIJKL

Ethyl (2Z,4E)-deca-2,4-dienoate 3025-30-7 BDEFHJK

Pelargene 68039-40-7 DEFHJK

2-cyclohexylidene-2- 10461-98-0

phenylacetonitrile DFHJK

Perillaldehyde 2111-75-3 ACHIJK

Perillyl acetate 15111-96-3 DFHJK

Perillyl alcohol 536-59-4 CHIJK

(2-isopropoxyethyl)benzene 68039-47-4 ACEFHJKL

Ethyl (2Z,4E)-deca-2,4-dienoate 313973-37-4 BDEFHJK

(2-(cyclohexyloxy)ethyl)benzene 80858-47-5 DEFHJK

Phenethyl 2-methylbutyrate 24817-51-4 DEFHJK

Phenethyl alcohol 60-12-8 BCEFGIK

Phenethyl phenylacetate 102-20-5 DHJ

Phenoxanol 55066-48-3 DEFHJK

Phenyl benzoate 93-99-2 DFHJK

Phenyl ethyl benzoate 94-47-3 DHJ

Phenylacetaldehyde ethyleneglycol 101-49-5

acetal BCEFGIK

2-(6,6-dimethylbicyclo[3.1.1]hept-2- 30897-75-7

en-2-yl)acetaldehyde ACFHIJKL

Pinocarveol 5947-36-4 BCEFGIJKL

Piperonyl acetone 55418-52-5 CEFGJ

3a,4,5,6,7,7a-hexahydro-lH-4,7- 68039-44-1

methanoinden-6-yl pivalate DEFHJK 980 (4aR,8aS)-7-methyloctahydro-l,4- 41724-19-0

methanonaphthalen-6(2H)-one CEFGJKL

982 p-Menth-3-en-l-ol 586-82-3 BCGIJK

985 (E)-3,3-dimethyl-5-(2,2,3- 107898-54-4

trimethylcyclopent-3 -en- 1 -yl)pent-4- en-2-ol DHJK

988 1 -methyl-4-(4-methylpent-3 -en- 1 - 52474-60-9

yl)cyclohex-3-ene-l-carbaldehyde DFHJK

993 Propylene glycol 57-55-6 ACEFGIKL

998 p-Tolyl phenylacetate 101-94-0 DFHJ

1000 Ethyl 2,4,7-decatrienoate 78417-28-4 BDEFHJK

1003 2-benzyl-4 ,4 , 6- trimethyl- 1 , 3 -dioxane 67633-94-7 DEFHJK

1006 2,4-dimethyl-4- 82461-14-1

phenyltetrahydrofuran BDEFHJK

1007 (2R,4a'R,8a'R)-3,7'-dimethyl- 41816-03-9

3 ' ,4' ,4a' ,5 ' ,8 ' ,8a' -hexahydro- 1 ' H- spiro[oxirane-2,2' - [ 1 ,4]methanonaphthalene] DEFHJK

1008 (Z)-6-ethylideneoctahydro-2H-5,8- 93939-86-7

methanochromene BCEFHJKL

1009 2-((S)-l-((S)-3,3- 236391-76-7

dimethylcyclohexyl)ethoxy)-2- oxoethyl propionate DFHJ

1010 Methyl 2,2-dimethyl-6- 81752-87-6

methylenecyclohexane- 1 -carboxylate ADHIJKL

1012 2-methyl-5-phenylpentan- l-ol 25634-93-9 DEFHJK

1016 4-methyl-2-phenyl-3,6-dihydro-2H- 60335-71-9

pyran BCEFGJK

1020 Sabinol 471-16-9 BCEFHIJKL

1021 Safrole 94-59-7 BCEFHK

1022 2,2,7, 9-tetramethylspiro(5.5)undec- 502847-01-0

8-en-l-one DHIJK

1023 3-methyl-5-(2,2,3- 65113-99-7

trimethylcyclopent-3-en- 1 -yl)pentan- 2-ol DEFHJK

1024 (Z)-2-ethyl-4-(2,2,3- 28219-61-6

trimethylcyclopent-3-en- 1 -yl)but-2- en-l-ol DEFHJK

1025 (E)-2-methyl-4-(2,2,3- 28219-60-5

trimethylcyclopent-3-en- 1 -yl)but-2- en-l-ol CHJK

1026 5-methoxyoctahydro- lH-4,7- 86803-90-9

methanoindene-2-carbaldehyde CHJK

1027 5-methoxyoctahydro- lH-4,7- 193425-86-4

methanoindene-2-carbaldehyde CHJK

1028 Sclareol 515-03-7 DEFHJ

1029 Sclareol oxide 5153-92-4 DEFHJK

1031 Selina-3,7(1 l)-diene 6813-21-4 DEFHJKL

1032 2-(l-(3,3- 477218-42-1

dimethylcyclohexyl)ethoxy)-2- DEFHJ methylpropyl

cyclopropanecarboxylate

1033 3-(4-isobutylphenyl)-2- 6658-48-6

methylpropanal DHJK

1035 Spathulenol 6750-60-3 DEFHJK

1036 Spirambrene 533925-08-5 BCEFHJK

1037 Spirodecane 6413-26-9 BCEFGIJKL

1038 l-(spiro[4.5]dec-7-en-7-yl)pent-4-en- 224031-70-3

1-one DGJK

1042 2-(4-methylthiazol-5-yl)ethan-l-ol 137-00-8 CGIKL

1043 2-(heptan-3-yl)- 1 ,3-dioxolane 4359-47-1 ACEFHIJKL

1045 (Z)-dodec-4-enal 21944-98-9 BDFHJK

1046 tau-Cadinol 5937-11-1 DEFHJK

1047 tau-Muurolol 19912-62-0 DEFHJK

1053 Tetrahydroj asmone 13074-63-0 BDFHIJKL

1057 2,6,10, 10-tetramethyl- 1 - 36431-72-8

oxaspiro [4.5] dec- 6-ene BDFHIJKL

1059 Thiomenthone 38462-22-5 BDEFHIJKL

1060 Thujopsene 470-40-6 BDEFGJKL

1062 Thymol methyl ether 1076-56-8 ADHIJKL

1063 l-(2,2,6-trimethylcyclohexyl)hexan- 70788-30-6

3-ol DEFHJK

1064 trans ,trans-2,4-Nonadienal 5910-87-2 ACHKL

1065 trans,trans-Farnesol 106-28-5 DEFHJK

1066 trans-2,cis-6-Nonadienal 557-48-2 ACHKL

1067 trans-2-Decenal 3913-81-3 ADHKL

1070 trans-2-Nonen- 1-al 18829-56-6 ADHKL

1072 trans-3, cis-6-nonadienol 56805-23-3 ACEFHK

1073 trans-4-Decen-l-al 65405-70-1 ADHKL

1075 trans-ambrettolide 51155-12-5 DGJ

1077 trans-beta-ocimene 13877-91-3 ADGIKL

1078 trans-beta-Ocimene 3779-61-1 ADGIKL

1082 trans-Geraniol 106-24-1 BCHIK

1083 trans-Hedione 2570-03-8 DFHJK

1085 7-(l , 1-Dimethylethyl)-2H- 1,5- 195251-91-3

benzodioxepin- 3 (4H) -one CEFHJ

1089 Tricyclone 68433-81-8 DEFHJK

1090 Tridecyl alcohol 112-70-9 DEFGJK

1091 Triethyl citrate 77-93-0 CEFGJ

1093 Methyl 2-((l-hydroxy-3- 144761-91-1

phenylbutyl)amino)benzoate DFHJ

1095 1-((2E,5Z,9Z)-2,6,10- 28371-99-5

trimethylcyclododeca-2 ,5,9 -trien- 1 - yl)ethan-l-one DHJK

1097 Decahydro-2,6, 6,7,8, 8-hexamethyl- 338735-71-0

2h-indeno(4,5-b)furan BDEFHJK

1099 13 -methyl oxacyclopentadec- 10-en- 365411-50-3

2-one DEFHJK

1102 Undecanal 112-44-7 BDHJK 1104 (E)-4-methyldec-3-en-5-ol 81782-77-6 BDEFHIJK

1105 Valencene 4630-07-3 BDEFHJK

1107 Valerianol 20489-45-6 DEFHJK

1111 Vanillin isobutyrate 20665-85-4 CHJ

1113 Vaniwhite ^® 5533-03-9 CGIK

1116 (Z)-2-methyl-4-(2,6,6- 68555-62-4

trimethylcyclohex-2-en-l-yl)but-2- enal BDFHJK

1117 Methyl 2,4-dihydroxy-3,6- 4707-47-5

dimethylbenzoate CGIJ

1120 l-methoxy-3a,4,5,6,7,7a-hexahydro- 27135-90-6

lH-4,7-methanoindene ACEFHJKL

1121 Methyl (Z)-2-((3-(4-(tert- 91-51-0

butyl)phenyl)-2- methylpropylidene)amino)benzoate DFHJ

1125 (Z)-hex-3-en-l-yl isobutyrate 41519-23-7 ADEFHJKL

1126 Vertacetal 5182-36-5 BCFHJK

1129 l-((3R,3aR,7R,8aS)-3,6,8,8- 32388-55-9

tetr amethy 1- 2 , 3 ,4 , 7 , 8 , 8 a-hexahy dro - lH-3a,7-methanoazulen-5-yl)ethan- 1-one DHJK

1131 Methyl (Z)-2-(((2,4- 68738-99-8

dimethylcyclohex-3-en- 1- yl)methylene)amino)benzoate DEFHJ

1135 Vetiverol 89-88-3 CEFHIJK

1136 Vetivert Acetate 117-98-6 DEFHJK

1137 Decahydro-3H-spiro[furan-2,5'- 68480-11-5

[4,7]methanoindene] DEFGJKL

1138 (2Z,6E) -nona-2 , 6-dienenitrile 67019-89-0 ACEFHKL

1139 (Z)-cyclooct-4-en-l-yl methyl 87731-18-8

carbonate BCHJKL

1140 (laR,4S,4aS,7R,7aS,7bS)-l, 1,4,7- 552-02-3

tetramethyldecahydro- 1 H- cyclopropa[e]azulen-4-ol DEFHJK

1142 3, 5,5, 6,7,8, 8-heptamethyl-5, 6,7,8- 127459-79-4

tetrahydronaphthalene-2-carbonitrile DHJ

1143 (lS,2S,3S,5R)-2,6,6- 133636-82-5

trimethylspiro [bicyclo[3.1.1 Jheptane- 3,1' -cyclohexan] -2 ' -en-4 ' -one DEFHJK

1144 1 ' , 1 ' ,5 ' ,5 ' -tetramethylhexahydro- 154171-76-3

2'H,5'H-spiro[[l,3]dioxolane-2,8'- [2,4a]methanonaphthalene] DEFHJK

1145 1 ' , 1 ' ,5 ' ,5 ' -tetramethylhexahydro- 154171-77-4

2'H,5'H-spiro[[l,3]dioxolane-2,8'- [2,4a]methanonaphthalene] K DEFHJK

1146 4-(4-hydroxy-3- 122-48-5

methoxyphenyl)butan-2-one CEFGJ

1147 (lR,8aR)-4-isopropyl-l,6-dimethyl- 41929-05-9

1,2,3,7,8 , 8a-hexahydronaphthalene DEFHJKL

1148 4,5-epoxy-4,l 1,1 l-trimethyl-8- 1139-30-6 DEFHJK methylenebicyclo(7.2.0)undecane

1149 1, 3,4,6,7, 8alpha-hexahydro-l, 1,5,5- 23787-90-8

tetramethyl-2H-2,4alpha- methanophtalen-8(5H)-one DEFHIJK

Table 2 List of materials with at least one MORV greater than 5 to 10

Number Material Name CAS Number Comment Code

2,4-dimethyl-2-(5,5,8,8-tetramethyl- 5,6,7,8-tetrahydronaphthalen-2-yl)-

2 1,3-dioxolane 131812-67-4 DFHJ

3a,5, 6,7,8, 8b-hexahydro- 2,2,6,6,7,8,8-heptamethyl-4H-

23 indeno(4,5-d)-l,3-dioxole 823178-41-2 DEFHJK

2,4-dimethyl-4,4a,5,9b-

141 tetrahydroindeno[l ,2-d] [1 ,3]dioxine 27606-09-3 CEFHJK

(l-methyl-2-((l,2,2- trimethylbicyclo[3.1.0]hexan-3-

185 yl)methyl)cyclopropyl)methanol 198404-98-7 DEFHJK

227 Isobornylcyclohexanol 68877-29-2 DEFHJK

230 Isobornyl cyclohexanol 66072-32-0 DEFHJK

246 Indol/Hydroxycitronellal Schiff base 67801-36-9 DEFHJ

248 Hydroxymethyl isolongifolene 59056-64-3 DEFHJK

8,8-dimethyl-3a,4,5,6,7,7a- hexahydro-lH-4,7-methanoinden-6-

343 yl propionate 76842-49-4 DEFHJK

(E)-4-((3aR,4R,7R,7aR)- l,3a,4,6,7,7a-hexahydro-5H-4,7- methanoinden-5-ylidene)-3-

359 methylbutan-2-ol 501929-47-1 DEFHJK

565 Cedryl methyl ether 19870-74-7 BDEFHJK

631 beta-Copaene 18252-44-3 BDEFHJKL

2'-isopropyl-l,7,7- trimethylspiro[bicyclo[2.2.1]heptane-

659 2,4'-[l,3]dioxane] 869292-93-3 BDEFHJK

(4aR,5R,7aS,9R)-2,2,5,8,8,9a- hexamethyloctahydro-4H-4a,9-

674 methanoazuleno [5 , 6-d] [ 1 , 3 ] dioxole 211299-54-6 DEFHJK

(3S,5aR,7aS,llaS,l lbR)-3,8,8,lla- tetramethyldodecahydro- 5H- 3,5 a-

678 epoxynaphtho[2, 1 -cjoxepine 57345-19-4 DEFHJ

2,2,6,6,7, 8,8-heptamethyldecahydro-

679 2H-indeno[4,5-b]furan 476332-65-7 DEFHJK

715 alpha- Cedrene epoxide 13567-39-0 BDEFHJK

Acetoxymethyl-isolongifolene

758 (isomers) 59056-62-1 DEFHJK

1028 Sclareol 515-03-7 DEFHJ

Decahydro-2,6,6,7,8,8-hexamethyl-

1097 2h-indeno(4,5-b)furan 338735-71-0 DEFHJK Table 3 List of materials with at least one MORV from 0.5 to less than 1

Number Material Name CAS Number Comment Code

l-ethoxy-4-(tert-

12 pentyl)cyclohexane 181258-89-9 ADEFHJK

(3Z)- 1 -(2-buten- 1 -yloxy)-3 -

19 hexene 888744-18-1 ADEFHJKL

4-(2-methoxypropan-2-yl)- 1-

20 methylcyclohex- 1 -ene 14576-08-0 ADHIJKL

24 O-Methyl linalool 60763-44-2 ADHIJKL

26 o-Methoxycinnamaldehyde 1504-74-1 ACHK

27 Octanal, 3,7-dimethyl- 25795-46-4 ADGIJKL

3,3-Dimethyl-5(2,2,3- Trimethyl- 3 - Cyclopenten-

53 lyl)-4-Penten-2-ol 329925-33-9 CEFHJ

54 n-Hexyl salicylate 6259-76-3 DEFHJ

55 n-Hexyl 2-butenoate 19089-92-0 ADEFHJKL

59 Neryl Formate 2142-94-1 BCEFHJK

72 Methyl-beta-ionone 127-43-5 DHJK

73 Myroxide 28977-57-3 ADGIJKL

(E)-3,7-dimethylocta-4,6-

81 dien-3-ol 18479-54-4 BCEFGIJK

(Z)-hex-3-en-l-yl

84 cyclopropanecarboxylate 188570-78-7 BCEFHIKL

Methyl phenyl carbinyl

96 propionate 120-45-6 BCHJK

97 Methyl phenylacetate 101-41-7 ACEFHIKL

2-methyl-6-

107 oxaspiro [4.5] decan-7 -one 91069-37-3 BCEFGIKL

111 Methyl geraniate 2349-14-6 BCHJKL

2-ethoxy-4-

115 (methoxymethyl)phenol 5595-79-9 CFGK

Methyl

116 cyclopentylideneacetate 40203-73-4 ACEFHIKL

125 Methoxymelonal 62439-41-2 ACGIJK

((ls,4s)-4-

133 isopropylcyclohexyl)methanol 13828-37-0 BDEFHIJK

147 Linalyl propionate 144-39-8 BDFHJK

150 Linalyl formate 115-99-1 ACFHJK

151 Linalyl butyrate 78-36-4 BDEFHJK

154 Linalyl acetate 115-95-7 BDHJK

157 Linalool 78-70-6 BCEFGIJK

(Z)-hex-3-en-l-yl methyl

163 carbonate 67633-96-9 ACEFGKL

166 Lepidine 491-35-0 BCEFHIKL

169 L-Carvone 6485-40-1 ACGIJKL 181 Khusinil 75490-39-0 DHJK

191 Isoraldeine 1335-46-2 BDHIJK

194 Isopropylvinylcarbinol 4798-45-2 ACGIKL

198 Isopropyl 2-methylbutyrate 66576-71-4 ACEFGIJKL

201 Isopentyrate 80118-06-5 ADEFGIJKL

204 Isononyl acetate 40379-24-6 BDEFHJKL

205 Isononanol 27458-94-2 BDEFGIKL

213 Isoeugenyl acetate 93-29-8 CFHJK

214 Isoeugenol 97-54-1 CEFHIK

232 Isoborneol 124-76-5 ACEFHIJKL

237 Isoamyl octanoate 2035-99-6 DEFHJK

239 Isoamyl isobutyrate 2050-01-3 ACEFGIJKL

255 Hydrocinnamic acid 501-52-0 CEFHIK

258 Hydratopic alcohol 1123-85-9 B CEFHIK

264 Hexyl propanoate 2445-76-3 ADEFHIKL

270 Hexyl butyrate 2639-63-6 BDEFHJKL

273 Hexyl 2-methylbutanoate 10032-15-2 BDEFHJKL

275 Hexyl 2-furoate 39251-86-0 DEFHJK

282 Heptyl alcohol 111-70-6 ACEFGIKL

283 Heptyl acetate 112-06-1 ADEFHKL

284 Heptaldehyde 111-71-7 ACHIKL

287 Heliotropin 120-57-0 BCGIK

302 Geranyl nitrile 5146-66-7 BCEFHKL

306 Geranyl formate 105-86-2 BCEFHJK

308 Geranyl caprylate 51532-26-4 DEFHJ

310 Geranyl benzoate 94-48-4 DFHJ

312 Geranial 141-27-5 ACHIKL

N,2-dimethyl-N-

314 phenylbutanamide 84434-18-4 BCEFHJK

319 gamma-Terpinene 99-85-4 ADEFGIJKL

2-(sec-butyl)cyclohexan- 1-

346 one 14765-30-1 ADFHIKL

3-(2-ethylphenyl)-2,2-

354 dimethylpropanal 67634-14-4 BDHJK

2-(tert-butyl)cyclohexyl ethyl

355 carbonate 67801-64-3 BDFHJK

2-(tert-butyl)cyclohexyl ethyl

365 carbonate 81925-81-7 ACFHIKL

366 Fenchyl alcohol 1632-73-1 ACGIJKL

376 Eucalyptol 470-82-6 ADEFGIJKL

379 Ethyl vanillin acetate 72207-94-4 CHJ

387 Ethyl octanoate 106-32-1 BDEFHJKL

400 Ethyl cinnamate 103-36-6 BCEFHK

Ethyl 2-

412 (cyclohexyl)propionate 2511-00-4 BDFHIJKL

419 d-p-8(9)-Menthen-2-one 5524-05-0 ACGIJKL

4-methyl-2-phenyltetrahydro-

420 2H-pyran 94201-73-7 BDEFHJK

437 Dihydromyrcenol 18479-58-8 ADEFGIJK Dihydroj asmone 1128-08-1 BCFHIJKL

Dihydroisophorone 873-94-9 ACEFGIJKL

Dihydroeugenol 2785-87-7 CEFHIJK

Dihydrocoumarin 119-84-6 BCGIKL

Dihydrocarvone 7764-50-3 ACGIJKL

Dihydro-alpha-terpinyl

acetate 80-25-1 BDEFHIJKL

Dihydro-alpha-ionone 31499-72-6 BDHIJK

Dibenzyl ether 103-50-4 DEFHJK

Dibutyl o-phthalate 84-74-2 DEFHJ

2-pentylcyclopentan- 1 -one 4819-67-4 BDFHIKL

Decyl anthranilate 18189-07-6 DEFHJ

Methyl (ls,4s)-l,4- dimethylcyclohexane- 1 - carboxylate 23059-38-3 ADEFHIJKL

Cyclohexylethyl acetate 21722-83-8 BDEFHJKL

Creosol 93-51-6 BCHIK

Cosmene 460-01-5 ADEFGIKL

4-cyclohexyl-2-methylbutan- 2-ol 83926-73-2 BDEFGIJK

2-benzyl-2-methylbut-3 - enenitrile 97384-48-0 BDHJK

Citronellyl nitrile 51566-62-2 BCEFGIKL

Citronellyl phenylacetate 139-70-8 DFHJ

Citronellyl formate 105-85-1 BCEFGJKL

Citronellyl benzoate 10482-77-6 DFHJ

Citronellol 106-22-9 BCHIJKL

Citronellal 106-23-0 ACHIJKL

Citral 5392-40-5 ACHIKL cis-Pinane 6876-13-7 ADEFGIJKL

(Z)-3-methyl-2-(pent-2-en-l- yl)cyclopent-2-en- 1 -one 488-10-8 BCHIJKL cis-iso-Eugenol 5912-86-7 CEFHIK cis-3-Hexenyl valerate 35852-46-1 BDEFHJKL cis-3-Hexenyl tiglate 67883-79-8 BDEFHJK cis-3-Hexenyl propionate 33467-74-2 ACEFHIKL cis-3-Hexenyl butyrate 16491-36-4 ADEFHJKL cis-3-Hexen-l-ol 928-96-1 ACEFHIKL cis-2-Hexenol 928-94-9 ACEFHIKL

Cinnamyl nitrile 4360-47-8 ACEFGIK

Cinnamic aldehyde 104-55-2 ACHIK

Cinnamyl nitrile 1885-38-7 ACEFGIK

Chloroxylenol 88-04-0 BCHIJK

Carvacrol 499-75-2 DHIJK

Carvone 99-49-0 ACGIJKL

Carbitol 111-90-0 BCEFGIK

Caproyl alcohol 111-27-3 ACEFGIKL-(2,2,3-trimethylcyclopent-3- en- 1 -yl)acetonitrile 15373-31-6 ACGIJKL Camphor 76-22-2 ACEFGIJKL

(E)-2-methyl-4-(2,6,6- trimethylcyclohex- 1 -en- 1 - yl)but-2-enal 3155-71-3 DHJK

Borneol 507-70-0 ACEFHIJKL beta-Pinene epoxide 6931-54-0 ACEFGIJKL beta-Phellandrene 555-10-2 ADEFGIJKL

Benzylacetone 2550-26-7 ACEFGIK

Benzyl salicylate 118-58-1 DFGJ

Benzyl isovalerate 103-38-8 BDEFHJK

Benzyl isobutyrate 103-28-6 BCHJK

Benzyl butyrate 103-37-7 BCEFHJK

Benzyl alcohol 100-51-6 ACEFGIKL l-(3,3- dimethylcyclohexyl)ethyl

formate 25225-08-5 ADEFHIJKL

Anisyl acetate 104-21-2 BCEFGK

Anisyl formate 122-91-8 BCEFGK

Anethole 104-46-1 ACEFHK

Amyl benzoate 2049-96-9 DEFHJK alpha-Terpinyl acetate 80-26-2 BDHJK alpha-methyl- cyclohexanepropanol 10528-67-3 BDEFHIK alpha-methyl cinnamaldehyde 101-39-3 ACHIK alpha-Isomethylionone 127-51-5 BDHIJK

2,5-Dimethyl-4-methoxy- 3(2H)-furanone 4077-47-8 ACEFGIJKL

Allyl phenoxyacetate 7493-74-5 BCGK

Allyl Phenethyl ether 14289-65-7 ACEFHK

Allyl heptanoate 142-19-8 ADEFHJKL

N-ethyl-N-(m- tolyl)propionamide 179911-08-1 CEFHJK

3-hydroxybutan-2-one 513-86-0 ACEFGIKL

Acetoanisole 100-06-1 BCEFHIK

6-Methylquinoline 91-62-3 BCEFHIKL

6,8-Diethyl-2-nonanol 70214-77-6 BDEFGIJKL

5 -Methyl- 3 -heptanone 541-85-5 ACFGIKL

4-Vinylphenol 2628-17-3 BCHIK

4-hydroxy-3-methoxy- cinnamaldehyde 458-36-6 CH

4-Ethylguaiacol 2785-89-9 CEFHIK

4-Damascol 4927-36-0 BDFHJK

3-methyl-4-phenylpyrazole 13788-84-6 CEFHK

3-Methyl-l,2- cyclopentanedione 765-70-8 ACEFGIKL

3 -Methoxy- 5 -methylphenol 3209-13-0 BCHIK

3-Methoxy-3-Methyl Butanol 56539-66-3 ACGIKL

3-Hexenol 544-12-7 ACEFHIKL

3,7-dimethyl-2-methylene-6- 22418-66-2 ADFHIJK octenal

3 ,7-dimethyl- 1 -octanol 106-21-8 BDEFGIJKL

2-Phenylethyl acetate 103-45-7 BCEFHK

2-Phenethyl propionate 122-70-3 BCEFHJK

2-Pentylcyclopentan- 1 -ol 84560-00-9 DEFHIKL

2-nonanone propylene glycol

acetal 165191-91-3 BDEFHJK

2-Methoxy-3-(l- methylpropyl)pyrazine 24168-70-5 BCEFGIK

2-isopropyl-N,2,3- trimethylbutyramide 51115-67-4 ACEFGIJK

2-Isopropyl-5-methyl-2- hexenal 35158-25-9 ADFGIJKL

2-Isopropyl-4-methylthiazole 15679-13-7 ACHIJKL

2-Hexen-l-ol 2305-21-7 ACEFHIKL

2-Butoxyethanol 111-76-2 ACEFGIKL

1,4-Cineole 470-67-7 ADGIJKL l-(2,6,6-Trimethyl-2- cyclohexen- 1 -yl)-2-buten- 1 - one 43052-87-5 BDHIJK

(Z)-3-hepten-l-yl acetate 1576-78-9 ACEFHKL

(S)-(lR,5R)-4,6,6- trimethylbicyclo[3.1.1 ]hept-3- en-2-one 1196-01-6 ACEFGIJKL

(R)-(-)-Linalool 126-91-0 BCEFGIJK

(l)-Citronellal 5949-05-3 ACHIJKL

(d)-Citronellal 2385-77-5 ACHIJKL

(+)-Citronellol 1117-61-9 BCHIJKL

(-)-Citronellol 7540-51-4 BCHIJKL

(+)-alpha-Pinene 7785-70-8 ADEFGIJKL

(+)-Carvone 2244-16-8 ACGIJKL

(-)-alpha-Pinene 7785-26-4 ADEFGIJKL

Methyl 2-methylbutyrate 868-57-5 ACEFGIKL

Hexyl tiglate 16930-96-4 BDEFHJKL

Allyl 2- (cyclohexyloxy)acetate 68901-15-5 CHJK

1,5- dimethylbicyclo[3.2. ljoctan- 8 -one oxime 75147-23-8 CFHIJK alpha-acetoxystyrene 2206-94-2 ACEFHIK p-Cymene 99-87-6 ADGIJKL

Phenethyl formate 104-62-1 ACEFHK

Phenethyl isobutyrate 103-48-0 DHJK

Phenethyl tiglate 55719-85-2 DHJK

Phenylethyl methacrylate 3683-12-3 DHJK p-

Isopropylphenylacetaldehyde 4395-92-0 BDFHK

1 ,2-dimethyl-3-(prop- 1 -en-2- yl)cyclopentan- 1 -ol 72402-00-7 BCEFGIJKL 983 p-Methoxyphenylacetone 122-84-9 BCEFHK

(2Z,5Z)-5,6,7-trimethylocta-

986 2,5-dien-4-one 358331-95-0 ADHIJKL

987 p-Propyl anisole 104-45-0 ADEFHKL

994 p-t-butyl phenyl acetaldehyde 109347-45-7 BDHJK

995 p-tert-Amyl cyclohexanol 5349-51-9 BDEFHIJK

1001 Racemic alpha-Pinene 80-56-8 ADEFGIJKL

4-(4-hydroxyphenyl)butan-2-

1002 one 5471-51-2 CEFGIK

1004 Rhodinol 141-25-3 BCHIJKL

Ethyl (2,3,6- trimethylcyclohexyl)

1005 carbonate 93981-50-1 BDEFHJKL l-(3,3- dimethylcyclohexyl)ethyl

1011 acetate 25225-10-9 ADHIJKL

1017 S)-(+)-Linalool 126-90-9 BCEFGIJK

1018 Sabinene 3387-41-5 ADEFGIJKL

1019 Sabinene hydrate 546-79-2 ADEFGIJKL

Propyl (S)-2-(tert-

1030 pentyloxy)propanoate 319002-92-1 BDEFHJK

1039 Spirolide 699-61-6 BCGIKL

(Z)-5-methylheptan-3-one

1040 oxime 22457-23-4 BCEFGIJKL

1041 1-phenylethyl acetate 93-92-5 ACEFHIK

1051 Tetrahydrogeranial 5988-91-0 ADGIJKL

1052 Tetrahydroionol 4361-23-3 BDEFHIJK

1054 Tetrahydrolinalool 78-69-3 BDEFGIJKL

1055 Tetrahydrolinalyl acetate 20780-48-7 ADEFHJKL

Ethyl (lR,6S)-2,2,6- trimethylcyclohexane- 1 -

1058 carboxylate 22471-55-2 ADEFHIJKL

1061 Thymol 89-83-8 BDHIJK

1069 trans-2-Hexenol 928-95-0 ACEFHIKL trans-2-tert-

1071 Butylcyclohexanol 5448-22-6 ACGIJKL

1074 trans-alpha-Damascone 24720-09-0 BDHIJK

1076 trans -Anethole 4180-23-8 ACEFHK

1079 trans-Cinnamic acid 140-10-3 CEFHK

1081 trans -Dihydroc arvone 5948-04-9 ACGIJKL

1084 trans-Isoeugenol 5932-68-3 CEFHIK

Trichloromethyl phenyl

1088 carbinyl acetate 90-17-5 BDEFGJ

2-mercapto-2-methylpentan-

1098 l-ol 258823-39-1 ACEFHIJKL

1110 Vanillin acetate 881-68-5 CH

1112 Vanitrope 94-86-0 CEFHK

2,2,5-trimethyl-5-

1115 pentylcyclopentan- 1 -one 65443-14-3 BDFGIJKL 1118 Veratraldehyde 120-14-9 BCGIK

(lR,5R)-4,6,6- trimethylbicyclo[3.1.1 ]hept-3-

1119 en-2-one 18309-32-5 ACEFGIJKL

1122 Verdol 13491-79-7 ACGIJKL

4-(tert-butyl)cyclohexyl

1127 acetate 10411-92-4 BDEFHJK

4-(tert-butyl)cyclohexyl

1128 acetate 32210-23-4 BDEFHJK

1133 Vethymine 7193-87-5 CEFGK

4-methyl-4-phenylpentan-2-yl

1134 acetate 68083-58-9 BDFHJK

(Z)-l-((2-

1141 methylallyl)oxy )hex- 3 -ene 292605-05-1 ADEFHKL

Table 4 List of materials with ALL MORVs from 1 to 5

Number Material Name CAS Number Comment Code

3-methoxy-7,7-dimethyl- 10-

7 methylenebicyclo [4.3.1] decane 216970-21-7 BDEFHJK

14 Oxyoctaline formate 65405-72-3 DFHJK

2,2,6,8-tetramethyl-l, 2,3, 4,4a,5, 8,8a-

39 octahydronaphthalen- 1 -ol 103614-86-4 DEFHIJK

48 Nootkatone 4674-50-4 DHJK

183 Khusimol 16223-63-5 CEFHJK

199 Isopimpinellin 482-27-9 CFGJ

206 Iso3-methylcyclopentadecan-l-one 3100-36-5 DEFGJK

212 Isoeugenyl benzyl ether 120-11-6 DFHJ l-((2S,3S)-2,3,8,8-tetramethyl- 1,2,3, 4,5, 6,7, 8-octahydronaphthalen-

215 2-yl)ethan-l-one 54464-57-2 DHJK

229 Isobornyl isobutyrate 85586-67-0 BDEFHIJK

2,3-dihydro-3,3-dimethyl-lH-indene-

260 5-propanal 173445-44-8 DHJK

3-(3,3-dimethyl-2,3-dihydro-lH-

261 inden-5 -yl)propanal 173445-65-3 DHJK

3a,4,5,6,7,7a-hexahydro-lH-4,7-

281 methanoinden-6-yl acetate 5413-60-5 CEFGJK

329 gamma-Eudesmol 1209-71-8 DFHJK

4,6,6,7,8,8-hexamethyl-l,3,4,6,7,8-

335 hexahydrocyclopenta[g]isochromene 1222-05-5 DEFHJK

(Z)-6-ethylideneoctahydro-2H-5,8-

353 methanochromen-2-one 69486-14-2 CEFGJK

8,8-dimethyl-3a,4,5,6,7,7a- hexahydro-lH-4,7-methanoinden-6-

360 yl acetate 171102-41-3 DEFHJK

Octahydro-lH-4,7-methanoinden-5-

441 yl acetate 64001-15-6 DEFHJKL

3a,4,5,6,7,7a-hexahydro-lH-4,7-

484 methanoinden-6-yl butyrate 113889-23-9 DEFHJK 3a,4,5,6,7,7a-hexahydro-lH-4,7-

487 methanoinden-5-yl isobutyrate 67634-20-2 DEFHJK

488 Curzerene 17910-09-7 DHJK

501 (E) -cycloheptadec -9 -en- 1 -one 542-46-1 DEFGJ

566 Cedryl formate 39900-38-4 BDEFHJK

567 Cedryl acetate 77-54-3 DEFHJK

569 Cedrol 77-53-2 DEFHJK

5-methyl-l-(2,2,3- trimethylcyclopent-3 -en- 1 -yl)-6-

570 oxabicyclo[3.2.1]octane 139539-66-5 DEFHJK

573 Caryophyllene alcohol acetate 32214-91-8 DEFHJK

574 Caryolan-l-ol 472-97-9 DEFHJK

603 Bornyl isobutyrate 24717-86-0 BDEFHIJK

616 beta-Santalol 77-42-9 DEFHJK

621 beta-Patchoulline 514-51-2 BDEFGJKL

624 beta-Himachalene Oxide 57819-73-5 BDFHJK

627 (2,2-dimethoxyethyl)benzene 101-48-4 DHJK

632 beta-Cedrene 546-28-1 BDEFGJKL

663 Anisyl phenylacetate 102-17-0 DFHJ

2,2,6,6,7, 8, 8-heptamethyldecahydro-

680 2H-indeno [4 , 5 -b] furan 647828-16-8 ADEFHJK

684 alpha- Vetivone 15764-04-2 DHJK

694 alpha-Santalol 115-71-9 DEFHJK

696 alpha- Patchoulene 560-32-7 ADEFHJKL

708 alpha-Gurjunene 489-40-7 BDEFHJKL

712 alpha-Eudesmol 473-16-5 DEFHJK

714 alpha-Cubebene 17699-14-8 ADEFHJKL

726 alpha- Agarofuran 5956-12-7 BDEFHJK

750 Alio- aromadendrene 25246-27-9 BDEFHJKL

764 Acetarolle 744266-61-3 DFHJK

775 7-eip-alpha-Eudesmol 123123-38-6 DEFHJK

7-Acetyl-l, 1,3,4,4,6-

776 hexamethyltetralin 1506-02-1 DEFHJ

788 5 -Cyclohexadecenone 37609-25-9 DEFGJK

804 3-Thujopsanone 25966-79-4 BDEFHJK

872 10-epi-gamma-Eudesmol 15051-81-7 DFHJK

3a,4,5,6,7,7a-hexahydro-lH-4,7-

919 methanoinden-6-yl propionate 17511-60-3 CEFHJK

5-Acetyl-l, 1,2,3,3,6-

927 hexamethylindan 15323-35-0 DEFHJK

933 Patchouli alcohol 5986-55-0 DEFHIJK

3a,4,5,6,7,7a-hexahydro-lH-4,7-

978 methanoinden-6-yl pivalate 68039-44-1 DEFHJK

(2R,4a'R,8a'R)-3,7'-dimethyl-

3 ' ,4' ,4a' ,5 ' ,8' ,8a' -hexahydro- 1 ' H- spiro[oxirane-2,2'-

1007 [ 1 ,4]methanonaphthalene] 41816-03-9 DEFHJK

2,2,7,9-tetramethylspiro(5.5)undec-

1022 8-en-l-one 502847-01-0 DHIJK (Z)-2-ethyl-4-(2,2,3- trimethylcyclopent-3 -en- 1 -yl)but-2-

1024 en-l-ol 28219-61-6 DEFHJK

5-methoxyoctahydro-lH-4,7-

1027 methanoindene-2-carbaldehyde 193425-86-4 CHJK

1029 Sclareol oxide 5153-92-4 DEFHJK

1035 Spathulenol 6750-60-3 DEFHJK l-(spiro[4.5]dec-7-en-7-yl)pent-4-en-

1038 1-one 224031-70-3 DGJK

1060 Thujopsene 470-40-6 BDEFGJKL

1089 Tricyclone 68433-81-8 DEFHJK

1107 Valerianol 20489-45-6 DEFHJK l-((3R,3aR,7R,8aS)-3,6,8,8- tetramethyl-2,3,4,7,8,8a-hexahydro- 1 H- 3 a,7-methanoazulen- 5 -yl)ethan-

1129 1-one 32388-55-9 DHJK

Methyl (Z)-2-(((2,4- dimethylcyclohex- 3 -en- 1 -

1131 yl)methylene)amino)benzoate 68738-99-8 DEFHJ

1136 Vetivert Acetate 117-98-6 DEFHJK

Decahydro-3H-spiro[furan-2,5'-

1137 [4,7]methanoindene] 68480-11-5 DEFGJKL

(laR,4S,4aS,7R,7aS,7bS)-l, 1,4,7- tetramethyldecahydro- 1H-

1140 cyclopropa[e]azulen-4-ol 552-02-3 DEFHJK

3,5, 5, 6,7,8, 8-heptamethyl-5, 6,7,8-

1142 tetrahydronaphthalene-2-carbonitrile 127459-79-4 DHJ

(lS,2S,3S,5R)-2,6,6- trimethylspiro [bicyclo[3.1.1 Jheptane-

1143 3,1' -cyclohexan] -2' -en-4 ' -one 133636-82-5 DEFHJK

1 ' , 1 ' ,5 ' ,5 ' -tetramethylhexahydro- 2'H,5'H-spiro[[l,3]dioxolane-2,8'-

1144 [2,4a]methanonaphthalene] 154171-76-3 DEFHJK

1 ' , 1 ' ,5 ' ,5 ' -tetramethylhexahydro- 2'H,5'H-spiro[[l,3]dioxolane-2,8'-

1145 [2,4a]methanonaphthalene] K 154171-77-4 DEFHJK

1148 4,5-epoxy-4, 11,1 l-trimethyl-8- 1139-30-6

methylenebicyclo(7.2.0)undecane DEFHJK

1149 l,3,4,6,7,8alpha-hexahydro-l,l,5,5- 23787-90-8

tetramethyl-2H-2,4alpha- methanophtalen- 8(5 H) -one DEFHIJK

Table 5 List of materials with ALL MORVs greater than 5 to 10

Table 6 List of materials with ALL MORVs from 0.5 to less than 1 Number Material Name CAS Number Comment Code

472 Decyl anthranilate 18189-07-6 DEFHJ

(Z)-3-methyl-2-(pent- 2-en- 1 -yl)cyclopent-

526 2-en-l-one 488-10-8 BCHIJKL

The materials in Tables 1-6 can be supplied by one or more of the following:

Firmenich Inc. of Plainsboro NJ USA; International Flavor and Fragrance Inc. New York, NY USA; Takasago Corp. Teterboro, NJ USA; Symrise Inc. Teterboro, NJ USA; Sigma- Aldrich/SAFC Inc. Carlsbad, CA USA; and Bedoukian Research Inc. Danbury, CT USA.

Actual MORV values for each material listed in Tables 1-6 above are as follows:

Material MORV value for MORV Value MORV Value MORV value for

No. Equation a.) for Equation b.) for Equation c.) Equation d.)

1 0.548223914 0.876283261 1.22018588 -0.41901144

2 1.520311929 3.493450446 2.70657265 5.11342862

3 2.267801995 -0.81712657 0.43218875 1.595983683

4 -0.591063369 -0.48283571 0.16199804 1.210497701

7 1.437444636 2.131822996 3.81633465 1.318339345

9 2.151445882 -0.46189495 0.56090469 1.206360803

10 2.5733592 -0.58780849 1.39751471 1.258361951

11 3.052627325 1.008519135 -0.30475953 0.076323462

12 0.683776599 -0.01157903 0.82853231 0.326169402

13 1.549643217 1.809183231 0.70864531 2.22799611

14 2.82111224 2.339505033 1.240818 2.502429355

16 -0.31551128 -0.06816599 -0.04371934 2.76742389

17 -1.334904153 -0.5773313 1.75644798 1.898455724

18 -1.34154226 -2.63596666 0.06885109 1.001431671

19 0.15532384 0.09866097 0.64214585 -0.33330779

20 0.640261783 0.693213268 0.54637273 -0.97556029

21 0.936895364 -0.01521118 1.1697513 -0.63510809

22 1.158981042 1.115900089 -0.25859776 1.318200884

23 3.702361074 1.399942641 5.23954766 7.089933671

24 0.773874141 0.146848137 -1.05705847 -0.36193173

25 -1.016103969 -1.18967936 0.78064625 2.944710012

26 0.615085491 -0.00096877 -0.35697252 -0.18121401

27 0.70261974 -0.22197386 0.19710806 -2.37196477

28 1.366472597 -0.42546942 -0.59394241 -0.01417395

29 1.096043453 -1.02972898 -1.42167356 -0.63817943

30 1.143415203 -0.85945441 -0.41416913 2.499807942

31 1.138642907 -0.19595476 -0.54547769 -0.98828898 1.914414495 -0.64487788 0.63212987 1.166699371

0.314847366 1.848003955 -1.3905032 -0.62848261

-0.113542761 0.981530917 0.32824239 1.126524277

0.472382903 1.494882467 -0.07201236 -0.64589543

3.158513795 1.084094934 -0.00328981 -0.17786385

-1.055631982 2.240172964 0.92596118 2.105391988

3.158513795 0.592820874 -0.49326241 0.212867212

1.083800659 2.069727985 2.48170879 3.205630609

-0.103134861 0.267726008 -0.65350189 1.125952363

0.323961628 1.469295081 -0.52991193 0.797908251

1.703678841 1.348737095 2.00634162 -0.16505407

2.370955056 2.783472865 2.68240273 1.221864405

1.670680003 -0.41866107 -0.9173849 1.181929544

1.670680003 0.076369374 -0.49915943 -0.85392575

0.464485039 0.057512869 1.31230219 -0.11170276

0.626671823 -0.46954947 -0.33383736 0.277079201

0.666149043 0.009549925 -0.36226343 0.197224432

0.723473579 -1.50916383 -0.3848989 -0.71458778

0.381273227 1.192994109 1.65593321 -1.65739236

0.561360663 -0.17793966 -1.63250554 -0.7564969

0.146473611 -0.01535544 -0.16339658 1.738656146

1.20162032 -0.3576095 -0.10695443 1.322155191

1.084291915 2.258720158 -1.01245416 1.688283974

0.744770665 0.155243763 -1.8029919 1.023503542

0.972835178 2.797151284 1.53453579 0.857051645

2.069410561 0.021831924 0.37855159 -0.67235457

0.527636614 0.590831983 1.02843762 2.208655795

2.133965691 2.088998449 2.05751412 -0.9433713

0.327378959 0.996844599 1.23648533 -1.25138371

1.40093669 0.778222691 0.70401172 -0.24075444

0.617697349 -0.29503359 0.52404847 0.816184656

0.617792473 0.888976061 -0.45289639 0.615659244

1.437359024 1.548292147 0.10314807 -0.48982286

-1.970885622 3.398008325 4.08025266 -0.89948156

-1.32746934 -2.65365233 0.10272816 1.001614125

-2.541686116 3.295534192 3.75284227 0.404837808

-2.110794 2.109874746 3.13350902 -0.3880285

1.641162056 -0.28533994 1.53676145 0.652696023

1.594400214 0.283682865 2.23140233 1.111682021

0.176566806 -2.0786518 -2.13986952 0.981126964

0.980373758 -0.28813159 0.19404501 1.252564677

0.941833098 0.317310013 1.17606727 0.72992237

0.774237336 -0.27140727 0.72461427 -1.56415746

2.092976965 0.810644229 0.82999192 -0.62861806

2.061595915 -0.79930338 -0.18285395 -0.66898499 2.068748434 -0.24299896 0.07214682 -1.11758276

-0.08984279 -1.06025959 -0.05068694 1.560050105

0.927758203 -0.44129515 0.89190422 0.744284978

0.658667572 -0.68771072 0.46051026 -0.53120883

0.853222693 -0.2037738 -0.21414441 1.119784962

1.654535066 0.995056228 2.35139085 0.543654824

2.173663649 -0.11491477 1.48285148 1.698527571

2.066679492 -0.16785146 -0.84780149 0.12159477

2.335152618 -0.02866585 0.16993375 -0.98254522

2.760588276 0.459513599 1.35310241 0.000336976

1.654535066 3.654489674 3.13033965 0.544225478

1.750588169 -0.55853348 0.50257773 1.630011313

0.896789863 0.73615897 0.53011623 -0.54697747

0.532375207 0.826537134 1.21040312 0.690230716

2.407655187 0.742651426 1.80322099 0.271832856

0.54830833 2.916795026 1.40126098 0.690230716

0.939597126 -0.3750368 -1.23479972 -0.89366351

1.398518854 1.265740274 4.19618377 -0.12762692

1.415726941 0.086297006 3.43559555 -0.12964168

-1.557729423 -0.44113526 0.86330536 0.590708892

0.193562268 -1.58091165 0.83247813 -0.70978039

1.353510875 -0.59062398 -0.31776345 -0.3050158

0.830052725 2.28725579 0.38409695 0.219336109

1.261997955 -0.22622961 -1.04772194 2.028504137

1.505653628 -1.14748206 -0.19760084 -0.81373045

-0.658721962 -0.21299878 1.01439841 -0.76731016

0.749676998 -1.0761601 0.99563924 -1.15409002

0.931054384 -0.35067079 1.06050832 -1.62171794

-1.344832644 -0.09451199 1.19145467 1.621274257

1.153249538 1.605070708 2.38047907 -0.93842293

0.840066046 0.2323025 0.19054023 -0.26588341

0.522267541 0.824106618 1.83479545 0.364403434

2.142817887 2.142411243 -0.93830995 0.696522652

3.052627325 3.606270166 0.50445208 0.076323462

-0.153437637 0.246303216 0.76565758 1.800968868

2.067620311 1.424830396 2.33536931 7.644025075

0.98353103 1.950251373 2.50851828 -0.24499521

1.736969725 0.991537809 2.5691601 1.227191656

-0.211768579 1.46336231 -0.93580247 -1.48749449

1.912710035 0.926306508 1.81253333 0.494121361

0.675736703 0.99202385 -0.66034472 -0.66302669

0.757176542 1.83006252 0.16210659 0.243674851

0.438772371 1.091438092 -0.1560319 -0.61711642

0.84399938 0.675302022 -1.69771411 -0.73841711

0.633570539 0.988413715 -0.54991825 -0.43550324 0.911582356 1.974700218 -0.92267786 0.628660087

0.319053885 2.531735341 -0.39139184 0.734629224

0.714814512 0.690769753 -2.06588692 -0.73356628

-0.161798388 0.032135767 -0.13802086 1.734928461

-0.571799976 -1.32834264 -1.65346017 1.856689553

0.131224024 0.21510779 -1.70996346 0.964902175

1.201616145 -0.21158932 -0.8501176 -0.33330779

0.811289908 1.606645397 0.25352447 -1.83775117

0.475184006 1.99305646 1.90910177 3.288337059

0.833030517 0.487189028 1.76798642 0.104378164

0.58993703 -0.46431772 0.74883588 -0.81090824

-0.121286831 -0.84664528 -0.32625341 0.778055656

0.846400186 -0.25922232 0.69248774 1.183696217

-0.310930833 -0.81048493 0.08527131 1.61831109

-0.2346025 0.890438419 -0.13206526 -0.83961838

-0.169223695 1.172917966 -0.11306441 0.099121666

2.863652137 0.236674094 -0.69038707 1.610215283

1.789769228 -0.31740428 -0.89529921 -0.09686469

2.625947334 0.083548191 0.30634559 -0.35925728

1.674319352 -0.22179044 0.42093738 -0.23683577

2.863652137 0.727069168 -0.26724686 -0.44888613

0.070511885 0.365852864 1.35327505 -0.03748038

0.976254543 0.691638796 0.51371978 -0.02503945

-1.842503751 -0.12688474 2.56277877 0.111744488

3.195758563 3.886545621 4.29482769 3.829845293

0.333889534 -0.67236766 2.21605977 4.254612125

5.61162203 1.40458529 2.86231343 1.035135749

1.068190511 -0.65969343 -0.63104765 -1.36962992

1.396358739 0.249705611 0.81449499 -0.15353102

1.544466636 -0.33742685 0.8096674 -0.44483677

-0.210918777 -1.04086063 0.02614862 3.362615492

0.715897301 0.666316436 -0.41719538 0.400723176

0.65612864 1.231196814 0.75462061 1.514581532

-0.394884432 1.129269425 -0.3157071 -0.61478944

-2.111794245 -0.71010521 0.53077207 0.59302222

1.18880856 0.704463775 1.99312777 1.419709023

1.885714606 0.436434665 1.44657532 1.145809063

2.174580668 0.133070149 0.99814905 0.871658496

-0.533922573 -2.16213117 0.5812107 -0.92280453

1.493919434 1.45125612 1.95141371 4.403441058

-0.005520296 -0.83362523 0.65480762 -0.38894276

0.732981164 -0.97494758 -0.91192246 -1.00034323

0.991838899 -0.60053505 -0.49983634 0.674468753

2.147983695 1.291351958 1.64553247 1.626455601 -0.386224123 -0.24799559 1.19406353 -1.61243489

1.447075297 0.122626462 1.08021156 0.473154634

-0.386224123 -0.24799559 1.19406353 -1.61243489

2.186118467 1.873949371 0.64852028 -0.59205851

1.367811201 1.689658923 1.8017376 2.525531645

0.925016223 0.875610609 0.31462609 0.847028648

-0.239873321 1.808823425 -0.36105512 -0.07650286

2.264275088 1.360001278 3.25759951 2.147928282

-0.509585598 -0.93428643 1.63030386 -0.79436377

1.876297063 0.026873469 0.45442758 1.538486988

5.317676982 2.824566654 1.73360625 3.103310061

3.323728685 1.554268023 1.8883835 0.957527434

3.218950175 1.464118271 2.47512497 1.214429025

5.242356467 3.482206715 3.50441556 1.614847073

2.710087358 1.517756148 0.35088855 0.603171932

0.703604481 0.42129186 0.39567696 0.41729786

1.312921486 0.816597603 2.17066283 0.472801294

0.874145958 0.741410502 1.71105733 -0.47289415

0.778921491 -1.02119303 0.4612164 -0.8881184

0.681403734 -0.342052 1.27750286 -0.3383341

-0.870637933 -2.58292907 0.79173772 -1.27888846

0.910211214 0.374558101 1.01712685 1.001043471

1.670680003 0.104780951 -0.6545574 -0.46985154

1.140332181 0.116513028 1.61110902 3.713305291

-0.634992987 0.548746912 4.62542427 7.660969857

-1.739729444 -0.91508372 1.18693162 3.108631198

5.81821686 6.320330665 6.14379552 5.214046447

0.348188924 -0.95333461 -0.08432225 1.866717393

2.456287983 -0.02516176 0.76814124 1.756087132

1.76915226 0.226389981 -0.18115009 -0.62385199

0.658956861 -0.39322197 -0.67153044 1.416053304

0.892122738 -0.46985097 0.42813903 -0.46752753

0.625043963 -0.65111806 1.4319541 2.110656697

-0.187789327 -0.85870492 -0.21766971 0.931521178

-1.261365139 -2.33099427 1.33595129 0.43644676

2.4020693 2.669351733 2.36395771 1.910609499

1.978618006 2.732613301 2.19594212 1.683156477

1.350274014 -0.59210334 0.14780643 -0.13113746

0.526085484 -1.54983116 -0.17497208 -0.8204696

1.175997006 -1.03507906 -0.11004734 -0.50564806

2.367197222 0.457286256 0.02211231 0.497925297

0.711734628 -1.45058685 -0.17018094 -0.71795736

1.073564668 -0.47951936 -0.80269361 0.136837431 0.663835001 -1.5674675 0.28509522 -1.12959038

1.628173498 -0.58892922 -0.3892777 -0.66728139

0.935336765 -0.9522644 -0.87000279 -0.29365972

-5.989155804 1.722071272 3.31094703 1.273171428

0.904631703 -1.02628534 0.49274649 1.000655271

0.293923493 -0.82335619 0.13147975 2.730914048

-0.284822555 0.322094188 3.2184015 0.383213731

2.201373139 2.228820089 2.03455575 1.720697243

0.505189899 -1.01844885 -0.98499144 0.912195522

0.775002479 -1.29876341 -1.52162214 -0.77292581

0.505189899 -0.57830662 -0.55673047 -1.09870665

-0.987611415 0.908212704 2.59089199 1.311154128

-2.635687733 -1.53554173 0.68132558 4.350511118

-1.890800496 -0.9175912 -0.84177071 0.615422874

-0.417807714 -0.27643667 1.06515025 0.958812195

1.078763544 0.263281029 1.00763749 0.866949263

0.733561298 -0.47493387 0.17088582 1.536463653

1.2252731 0.720498276 4.33362953 2.202084022

0.947860369 0.93449449 1.85056304 0.355024738

-1.051634009 0.136579632 2.17918871 -0.01949057

1.039790111 0.81471915 -0.94326824 0.887662055

1.009509413 1.364418947 1.42805339 0.429992055

0.246930208 1.113809101 0.25540773 0.528760053

0.697198045 -0.41500676 -2.35076003 -0.60639529

0.10667178 3.580489288 0.25893587 2.329367856

0.561360663 -0.17793966 -1.63250554 -0.7564969

1.583243229 1.398558046 0.152423 -0.13988304

-0.067380931 0.74278658 0.29217479 0.180866298

0.238202662 0.926241567 -0.66649303 0.508184193

0.714965519 -0.45511207 -2.34849436 -0.9953911

0.736369931 -0.52068396 0.53882253 -0.7059813

2.314558863 -0.25458611 0.22080129 -0.04142716

1.095005005 0.057439852 -1.20728654 0.035895107

-0.111714595 -0.61079351 -1.16010053 1.102488007

-0.264829849 0.540388888 0.10729709 -0.57215449

1.243861203 -0.75229123 0.05515858 -0.34659253

0.956379568 2.838565742 2.7997689 0.805938034

1.884902746 0.813499245 0.86344403 -0.1241887

0.189037208 1.105600415 0.48460989 0.285938173

0.791400443 2.454239197 1.54315324 1.416449646

1.22836182 2.190068443 2.48751772 0.126982574

1.800767509 1.372656013 2.09551175 2.849728342

2.688999059 0.017422444 0.34929031 0.108155361

-0.223648429 0.873635097 1.78683863 0.126324441 1.884902746 -0.46695445 0.1761545 -0.11026722

0.956379568 2.838565742 2.7997689 0.805938034

0.569368001 2.811464091 1.88866785 -0.16122533

1.931053264 2.306571877 4.45651797 4.474221307

1.355107839 -0.49142588 0.83879083 0.18350392

1.025467157 -0.99345477 0.57780149 -0.19101275

1.216559787 -0.68632827 0.71921804 0.140021721

2.073599715 -0.19777074 -0.44964804 -0.71885866

3.375840967 3.294907583 5.0378352 4.14804591

0.926453735 1.336260845 2.20088072 0.226359561

-0.133453942 -0.27276578 0.95852923 -0.88404805

-0.414858428 -0.94736055 1.9452074 -1.32753709

0.011110326 0.415952358 1.08076289 2.638925816

-1.366284701 -1.3912958 -0.0683659 1.205395618

2.592229701 2.014162407 -0.56599991 -0.19676404

2.347680291 1.432589328 3.81650185 2.28664738

-0.094599823 0.704257624 0.8494127 -0.05632553

-0.534528735 -0.26820008 0.69328667 0.63557685

0.71431796 0.568464069 1.14931631 0.32594963

1.637857828 1.932629993 0.68535871 -1.06298922

3.169264285 2.326146291 5.44251947 3.621423972

2.824830639 3.29829616 3.43870859 3.771256974

0.772183137 0.62924397 1.14549597 0.743423792

2.158106604 -0.08901432 0.85035629 -0.37323677

1.485114303 -0.85819594 0.70929196 4.132013298

-0.661168364 -0.30270875 2.49237859 -0.7675819

-0.518303431 -2.08665423 0.5658944 -1.10451499

-0.501301831 0.561788544 0.14113617 0.610082057

-0.106125097 1.092782715 -0.89571841 -0.08594454

1.43532227 1.656262941 -1.09448841 1.674272267

1.064083705 -1.08482967 0.35640283 0.866246621

1.933819902 0.975863726 1.62799441 1.492919426

0.274120553 2.246646022 2.93946992 2.617412085

0.940949346 2.935858163 0.52084392 0.847114052

0.177236108 2.745061961 0.76268843 0.373809692

-0.999571921 0.579320229 -0.06019938 -0.94280945

0.521811983 -0.8476641 0.7732327 1.729406547

-0.532701772 -2.17823188 1.26760147 0.815211357

-0.684994963 0.018353057 -0.8170018 0.582030709

1.592237677 1.373054134 0.60184939 -0.30300485

0.967501839 0.136172137 1.3645564 0.374341215

1.247138794 -0.97883463 0.03688288 -0.57321578

0.785485559 -1.23629818 -0.07759084 -0.71795736 1.503632155 -0.13455265 0.86630165 0.102845335

1.503632155 -0.13455265 0.86630165 0.102845335

0.811363694 0.872605919 -0.17445198 1.358866557

1.653006495 -0.44095837 0.46475017 -0.16817306

1.043989895 -0.82625074 0.40893134 -0.10417542

1.430046723 -0.79407262 0.15684862 -0.4384694

-1.401723491 0.271079592 1.35530191 -0.63550333

0.762211626 -1.06778628 -0.93642574 -0.13193338

0.591198428 -0.8943503 1.41392426 2.694863328

-0.067309295 -0.21963004 0.57788677 -1.22740398

0.630456164 1.538096427 2.10994563 2.45668637

0.460631327 3.678501689 1.18326431 1.28320952

0.060485009 -1.37776759 -0.22689728 2.328813337

1.864088631 0.2451067 1.63260125 1.855346924

-0.747017264 -2.60335412 0.85092701 3.525229717

3.678359573 3.437930194 4.42449746 0.716864637

-0.131519393 0.731836014 0.81604919 -1.29993979

0.11276779 -0.13029453 0.19422843 0.853490939

2.819997124 0.193567405 1.15903162 1.748390255

-0.211768579 1.46336231 -0.93580247 -1.48749449

-1.467980751 -2.41196874 -0.34454968 2.161517022

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-0.233400992 -1.15488444 0.83051343 -1.85751897

-0.631135606 0.037691556 0.57903451 -0.9926

1.707541313 0.010345383 0.48581606 1.513341091

1.447075297 0.022864201 0.99130501 0.473154634

-0.24632881 -0.23975349 -0.01449288 0.574861147

1.176028423 -0.85747031 -0.72464089 0.30542841

2.237616041 0.345329597 -0.60597063 -0.71581056

-1.47960224 -2.5770536 -1.03619781 0.847300104

1.670680003 1.284791101 0.14864516 -0.84985664

1.670680003 1.916382859 0.6998144 1.124089601

1.024819853 -0.7521596 0.35073152 -2.14193241

2.237616041 -0.17986241 -0.86317199 1.325805381

1.747776963 -0.25802105 -1.11614995 -0.77093434

2.592229701 2.030913569 -0.50618719 1.463926567

2.592229701 2.510587108 -0.07540594 -0.58371481

1.800767509 1.372656013 2.09551175 2.849728342 1.849432484 4.556065495 -0.39732139 -0.67726477

0.201768224 0.618509503 -0.39732139 -0.67726477

2.237616041 1.553468488 -0.72864242 -0.33330779

0.323968221 -1.00428076 -1.65151616 1.031096548

0.783570663 2.023288951 -0.03975252 0.474038265

1.187592149 1.464239711 0.67009263 1.103774764

-0.192632911 0.142411101 0.79310676 0.125548041

1.071875228 0.911734331 -1.50008456 0.185176261

0.798806784 -0.1516478 -0.64900063 -0.77199025

-0.671908804 -0.65984824 0.5238174 -0.85314111

2.863652137 1.896850773 0.06443558 -0.44689505

2.314558863 -0.25458637 0.22080129 -0.04142716

0.131224024 0.21510779 -1.70996346 0.964902175

0.742030255 0.281479436 -1.4156326 -1.91369695

1.071875228 0.911734331 -1.50008456 0.185176261

0.742030255 0.281479436 -1.4156326 -1.91369695

1.749446006 0.076054765 -0.59137073 0.291488011

0.869958847 0.843158237 0.61532515 3.158279932

1.749446006 0.076054765 -0.59137073 0.291488011

-0.047486491 1.045012945 -0.25220201 -0.31982826

0.784181146 -0.20530019 -1.89414748 0.152726109

-0.440378333 0.918089245 0.03050609 -1.62235977

-0.2346025 0.890438419 -0.13206526 -0.83961838

-0.440378333 0.918089245 0.03050609 -1.62235977

-1.320466583 -2.49763118 0.9787365 -1.85867969

-0.386224123 -0.24799559 1.19406353 -1.61243489

1.878331515 1.287303121 0.11530502 1.132065786

0.614968453 -1.61827184 -0.80789799 -0.66927285

0.530707518 0.774109528 3.0396125 4.394775258

0.337020095 1.531840025 0.10544973 0.347450471

0.774589061 1.224705331 1.87994281 -0.11684579

-0.363201351 0.35600238 -1.20673542 2.056973054

0.153047955 0.702054562 0.76757802 0.096096862

2.891894151 2.295157633 3.54101626 1.984030826

1.292959895 0.808281618 2.92956952 2.204248324

-0.465333775 0.862817284 0.1439546 0.64701735

1.54265003 0.291977233 0.79089158 0.801314068

1.340862559 0.503169303 0.53213093 3.164832031

0.158497146 1.507280765 2.25315926 1.173977914

1.23162703 1.671882685 3.1838372 -0.22917041

2.608734063 3.080604939 -0.69726361 -0.36219702

1.879182741 3.409153142 2.48473663 3.409954437

-0.093106169 0.019939108 0.15932154 1.229749745 1.670680003 1.94609957 0.19633838 1.14825764

3.052627325 0.956834107 -0.29721209 -0.31007607

0.367631287 0.501274945 -1.31074554 -0.39331005

3.702965303 3.03402795 4.33630831 4.238503729

0.570011387 0.097928934 1.03350455 -0.13392581

1.801474588 0.770314085 0.70188154 0.22333959

-0.412950838 -0.1781887 0.50649275 -0.57215449

1.691004766 -0.42331992 0.66279648 0.0318465

1.451782586 -0.565439 -0.32447381 -0.43378383

1.188491672 0.120632811 0.20106994 3.078484746

1.214814941 0.806987609 0.47605587 1.372949466

0.561732094 1.21448402 0.35542793 -1.03704442

0.956565856 1.505997176 0.88115653 -0.60583691

0.592575441 1.383482681 0.93567635 1.058669028

0.343657562 -0.85471906 -0.21125904 1.184648122

1.236659334 3.828926809 1.57729777 -0.31942874

1.836389049 0.755753735 -0.36014522 1.262853393

1.001653875 -0.85635082 0.89224781 -0.39245818

-0.122918652 -0.846489 -0.63367729 1.182912962

0.589766639 -0.9783487 -0.67638264 -0.38772225

0.715082397 -0.90020686 0.86817768 0.030652004

1.609198886 0.500797943 0.795571 0.908389449

0.952787327 -0.90555475 -0.17381408 0.06786323

1.836429446 0.208275147 -0.14300625 1.067462181

1.9158432 0.35211823 -1.02174589 0.625657932

1.383869627 0.274520494 -0.11659267 0.840327437

-0.445579934 -1.68867059 -0.5241276 2.233793943

0.736419048 0.409875189 -0.63140848 0.034514594

1.073465817 2.18418874 2.01361447 -0.93754437

0.130904221 1.882440008 1.85101055 0.112524893

-0.236681385 -0.09745533 0.1779313 2.08923366

0.904402612 0.936956925 0.87731788 0.102346515

2.201759817 2.123549573 3.7881607 2.358768953

1.784266982 1.845281076 3.42873622 -0.31098233

-0.225023329 0.087962898 -0.29053012 0.514272787

-0.231175318 -0.0159671 1.27391892 1.090487158

0.889215441 0.24321159 0.06877629 0.816247177

1.864634345 0.133647536 1.29803755 1.951226654

0.511450274 -2.33512445 -0.56246315 -0.42184152

0.847260813 0.368638185 0.4114346 0.219336109

1.596170102 1.592158381 0.30052357 0.283467897

-3.549941097 -2.6847861 -0.17502622 1.41034664

0.445802042 0.899738574 0.61059602 0.323194673

0.949498724 0.357111159 0.28371155 -0.14156488 998 2.197271885 1.578871826 0.90563334 1.056619658

998 2.197271885 1.578871826 0.90563334 1.056619658

1000 1.456120673 0.626173572 0.07683183 -0.43324035

1001 -0.440378333 0.918089245 0.03050609 -1.62235977

1002 0.819929066 0.459101825 -0.09227583 0.324342063

1003 1.64412453 -0.09343399 0.70197344 3.710273595

1004 0.796928207 0.459954079 -0.88538616 0.152000937

1005 0.044923203 -0.19994963 0.60082875 0.258347835

1006 -0.320452673 -0.33232662 -0.52315783 1.406273663

1007 4.040291133 3.474551355 3.57146797 3.565985043

1008 0.764519082 0.917635102 2.88258762 2.319622474

1009 -0.071112206 0.539362906 2.98048732 0.580423329

1010 -0.689737481 0.547928768 1.98805626 -0.76653376

1011 0.343668917 0.931501008 -0.05483722 0.395369857

1012 1.926713131 0.124849138 -0.09654906 1.126499382

1016 0.124247716 0.193102712 0.39003599 1.737670628

1017 0.131224136 0.21510779 -1.70996346 0.964902175

1018 0.499624069 0.962843507 0.77617619 -1.15296947

1019 0.813491983 0.322635656 0.02800396 0.599500927

1020 0.715468114 1.015469049 1.45994989 0.352548581

1021 -1.176339404 1.539767848 -0.14427147 1.389902738

1022 1.364966718 1.690570939 2.05914194 2.364375484

1023 2.154641091 0.800066339 0.85365652 0.965810338

1024 2.302280068 1.252164308 1.73414439 1.549538352

1025 1.878331515 1.287303121 0.11530502 1.132065786

1026 2.97722987 2.096441965 3.87172868 0.550274831

1027 2.474381478 1.950326182 3.81861867 1.366897355

1028 1.778414353 3.114931059 4.47690731 6.054314034

1029 3.672910795 2.760483725 3.26915034 3.042677588

1030 -0.604959715 -2.13584086 0.8687855 0.024144016

1031 2.012732245 2.293857161 0.54405555 1.261882121

1032 -1.086688867 0.953083194 2.92177054 0.876865185

1033 1.617520676 1.008017006 2.21183536 -0.1288484

1035 2.506372295 3.419954592 4.58206882 4.134341651

1036 -0.675805062 -0.15357004 0.94597719 3.966016669

1037 -0.275092569 -0.67687665 -0.52763797 1.489972106

1038 2.753559643 3.81185814 2.71344734 2.243351472

1039 0.65087433 0.026885305 -0.0153558 0.011870127

1040 0.141526548 -1.65455278 0.50170705 -1.90794

1041 0.458680435 -0.69730218 -0.48806249 0.586073092

1042 -0.513264812 -0.22001961 0.36339519 1.03208599

1043 -1.497887014 -1.76116109 -0.76634926 1.137002742

1045 2.863652137 1.96790869 0.43661485 -0.44756897

1046 0.981194248 1.73892162 2.21166953 2.738129365

1047 0.981194248 1.73892162 2.21166953 2.738129365 1051 0.70261974 -0.22197386 0.19710806 -2.37196477

1052 0.662126832 0.741436531 0.61672724 0.289359903

1053 0.87463644 -0.19717783 1.2664131 -0.4187507

1054 0.284558077 -1.46754925 -0.03124571 0.587227244

1055 0.885837831 -0.91907796 -0.45817355 -1.1936897

1057 0.790964847 1.387925398 -0.18370692 1.302393792

1058 -1.052897931 -0.85226912 0.90324527 -1.09684959

1059 -0.871565421 -0.17856476 1.51267137 -1.52734367

1060 3.311161199 3.074783921 2.10199297 1.822541682

1061 -0.655128061 0.497032417 0.92381279 -0.56348341

1062 -0.443129049 0.96200606 1.51641349 -0.22974864

1063 1.385675542 0.738759296 1.1677069 0.501211562

1064 1.670680003 -0.20756775 -0.73755051 -0.84924056

1065 1.43532227 1.656262941 -1.09448841 1.674272267

1066 1.670680003 1.284791101 0.14864516 -0.84985664

1067 2.237616041 0.345329863 -0.60597063 -0.71581056

1069 -0.24632881 -0.23975349 -0.01449288 0.574861147

1070 1.670680003 0.070165381 -0.64700996 -0.85055617

1071 -1.02687397 -0.36244273 0.13010074 0.535909448

1072 1.670680003 1.94609957 0.19633838 1.14825764

1073 2.237616041 1.438074134 0.31117554 -0.71786492

1074 -0.192632911 0.142411101 0.79310676 0.125548041

1075 0.909356011 0.368597887 1.03689838 1.001198751

1076 0.812238101 0.195908668 0.21564664 0.219336109

1077 0.325255266 1.131242708 -2.79377204 -0.62848261

1078 0.325255266 1.131242708 -2.79377204 -0.62848261

1079 0.85330799 -0.6855194 -0.90046979 -0.46415796

1081 -0.131519393 0.731836014 0.81604919 -1.29993979

1082 0.744770665 0.155243763 -1.8029919 1.023503542

1083 1.415726941 0.086297223 3.43559555 -0.12964168

1084 0.161304111 0.66712144 0.58401752 0.373809692

1085 -0.72863532 -0.2873027 2.21251376 3.003873022

1088 -1.1773616 -0.23258175 0.40529195 0.994988969

1089 2.769817302 1.661618789 3.97585272 1.059236597

1090 3.052627325 0.420821685 -0.57080756 1.751222205

1091 -3.379896722 -3.71174986 2.53586709 0.644702886

1093 0.72304265 1.667011476 2.53982093 2.7903213

1095 0.744219765 1.372184572 0.15852396 1.126053442

1097 4.407270402 2.670641491 5.02636153 5.361271976

1098 -1.85804837 -2.59071226 -0.46522239 0.655734646

1099 0.745797788 -0.20547378 4.27836342 4.646390386

1102 2.068748434 -0.24299896 0.07214682 -1.11758276

1104 1.018876287 0.025163067 -0.1106021 0.838914654

1105 2.387326861 3.865456674 2.2251199 0.728667998

1107 2.352582059 2.595496601 3.20492728 2.844590737 1110 0.302703712 0.599942142 -0.25637571 -0.03195517

1111 0.750930333 0.656784751 1.68326413 0.329846578

1112 -0.205527848 0.287622624 -0.00340777 0.59203719

1115 0.999825037 0.662221152 0.43571192 0.342558518

1116 0.873381263 1.544324176 0.13703728 -0.38172701

1117 -0.682983903 1.798204302 2.42110319 -0.39173951

1118 0.069769623 0.496895599 0.67857133 -0.14954441

1119 -0.671908804 -0.65984824 0.5238174 -0.85314111

1120 0.953790113 1.106552668 3.00006904 1.585038764

1121 -1.184630973 2.476138312 4.80971952 2.450646806

1122 -1.02687397 -0.36244273 0.13010074 0.535909448

1125 0.387315524 -0.36101406 1.14153708 -0.75303953

1126 1.021783831 -0.0070257 -0.14327539 3.954381426

1127 0.990592079 0.305612583 0.14155512 -0.29526854

1128 0.990592079 0.305612583 0.14155512 -0.29526854

1129 3.18966648 3.284362987 4.49398568 3.950809104

1131 1.650621055 1.545704806 2.37535081 1.259373143

1133 -1.519747805 -0.60804324 0.02746106 0.590708892

1134 0.815942067 -0.16126019 -0.54117238 0.613093526

1135 0.626973385 1.998305877 2.61706075 1.570404253

1136 2.812199484 1.353198146 2.05618426 1.869204406

1137 2.208307057 1.387136198 3.21521374 2.069795393

1138 1.670680003 1.316442078 0.14822999 -0.46985154

1139 1.408517438 0.890457374 1.24524408 0.685687797

1140 2.765860952 2.525539595 4.12464228 3.833744077

1141 -0.484394663 0.677713073 -0.22783646 -0.37267608

1142 2.54335679 4.298105601 3.36234238 2.684404542

1143 4.204367611 3.062126931 3.4234313 2.072899554

1144 2.479165229 3.226545885 4.65897152 4.952127235

1145 2.479158921 3.226545885 4.65897152 4.952127235

1146 0.774334025 1.075800774 1.06893156 1.011113116

1147 0.844648531 1.21935371 2.59138595 0.805938034

1148 2.906236436 1.550674121 3.56959167 2.832126896

1149 2.837627443 3.707154326 4.53384262 2.625871865

Cleaning and/or Treatment Composition and Methods

A cleaning and/or treatment composition having a viscosity of from about 10 mPa.s to about 50,000 mPa.s, preferably from about 50 mPa.s to about 2000 mPa.s, most preferably from about 75 mPa.s to about 400 mPa.s, a pH from about 3 to about 10, preferably from about 4 to about 8, most preferably from about 5 to about 8, said composition comprising, based on total cleaning and/or treatment composition weight, a) a sum total of from about 0.00025% to about 0.5%, preferably from about 0.0025% to about 0.1%, more preferably from about 0.005% to about 0.075%, most preferably from about 0.01% to about 0.05% of 1 or more malodor reduction materials, preferably 1 to about 20 malodor reduction materials, more preferably 1 to about 15 malodor reduction materials, most preferably 1 to about 10 malodor reduction materials, each of said malodor reduction materials having a MORV of at least 0.5, preferably from 0.5 to 10, more preferably from 1 to 10, most preferably from 1 to 5, and preferably each of said malodor reduction materials having a Universal MORV, said sum total of malodor reduction materials having a Blocker Index of less than 3, more preferable less than about 2.5 even more preferably less than about 2 and still more preferably less than about 1 and most preferably 0 and/or a Blocker Index average of 3 to about 0.001; and

b) from about 0.25% to about 50%, preferably from about 0.5% to about 25%, more preferably from about 0.75% to about 15%, most preferably from about 1% to about 10% of solublizing agent, preferably said solubilizing agent is selected from the group consisting of solvent, emulsifier, surfactant, fabric softener active and mixtures thereof, preferably said solvent is present in the range of 0.25% to 50%, preferably, 1% to 20% and most preferably 2% ot 10%, preferably said emulsifier is present in the range of 0.1% to 10% more preferably in the range of 0.5% to 5%, preferably said surfactant is present in the range of 0.1 to 35%, preferably in the range of 1% to 25%, most preferably in the range of 1.5% to 20%, preferably said fabric softener active is present in the range of 1% to 35%, more preferably in the range of 2% to 20% and most preferably in the range of 3% to 10%

is disclosed. As the viscosity range of the cleaning and/or treatment composition is tightened, it is easier to suspend certain such as polymers and waxes. As the pH range of the cleaning and/or treatment composition is tightened, the malodor reduction materials' stability increases in the cleaning and/or treatment composition. As the other ranges above are tightened, the malodor reduction material(s) provide less and less of a scent impact, while continuing to counteract malodors.

In one aspect of Applicants' cleaning and/or treatment composition:

a) said surfactant is selected from the group consisting of selected from nonionic surfactants, anionic surfactants, cationic surfactants, ampholytic surfactants, zwitterionic surfactants, semi-polar nonionic surfactants and mixtures thereof, nonionic surfactants are preferred as they provide excellent cleaning and delivery of malodor reduction materials without interacting negative with other charged surfactants/materials;

b) said solvent is selected from the group consisting of hydrogenated castor oil, glycols, alcohols, and mixtures thereof

c) said fabric softener active is selected from the group consisting of a quaternary ammonium compound, an amine and mixtures thereof, preferably said quaternary ammonium compound is selected from the group consisting of bis-(2-hydroxypropyl)- dimethylammonium methylsulphate fatty acid ester, l,2-di(acyloxy)-3- trimethylammoniopropane chloride., N, N-bis(stearoyl-oxy-ethyl) N,N-dimethyl ammonium chloride, N,N-bis(tallowoyl-oxy-ethyl) Ν,Ν-dimethyl ammonium chloride, N,N-bis(stearoyl-oxy-ethyl) N-(2 hydroxyethyl) N-methyl ammonium methylsulfate., 1, 2 di (stearoyl-oxy) 3 trimethyl ammoniumpropane chloride, dicanoladimethylammonium chloride, di(hard)tallowdimethylammonium chloride dicanoladimethylammonium methylsulfate, 1 -methyl- 1 -stearoylamidoethyl-2- stearoylimidazolinium methylsulfate, 1 -tallowylamidoethyl-2-tallowylimidazoline, Dipalmethyl Hydroxyethylammoinum Methosulfate and mixtures thereof.

In one aspect of Applicants' cleaning and/or treatment composition, said malodor reduction materials have a Fragrance Fidelity Index of less than 3, preferably less than 2, more preferably less than 1 and most preferably 0 and/or a Fragrance Fidelity Index average of 3 to about 0.001 Fragrance Fidelity Index. As the Fragrance Fidelity Index decreases, the malodor reduction material(s) provide less and less of a scent impact, while continuing to counteract malodor s.

In one aspect of Applicants' cleaning and/or treatment composition, said cleaning and/or treatment composition comprises a perfume and has a weight ratio of parts of malodor reduction composition to parts of perfume of from about 1:20,000 to about 3000:1, preferably from about 1:10,000 to about 1,000:1, more preferably 5,000: 1 to about 500:1 and most preferably from about 1:15 to about 1:1. As the ratio of malodor reduction composition to parts of perfume is tightened, the malodor reduction material(s) provide less and less of a scent impact, while continuing to counteract malodors.

In one aspect of said cleaning and/or treatment composition, said cleaning and/or treatment composition comprises one or more malodor reduction materials having a log P greater than 3, preferably greater than 3 but less than 8, preferably said one or more malodor reduction materials are selected from the group consisting of Table 1 materials 1; 2; 3; 7; 9; 10; 11; 13; 14; 18; 21; 22; 23; 25; 28; 29; 30; 31; 32; 33; 35; 36; 38; 39; 47; 48; 49; 50; 52; 57; 62; 63; 64; 67; 68; 69; 71; 74; 75; 76; 77; 78 79; 80; 83; 85 91; 92; 93; 100; 101; 102; 103; 104; 105; 109; 114

119; 120; 122; 123; 128; 134; 135; 137; 140; 142; 145; 148; 149; 152; 153; 158; 159; 161; 162;

174; 175; 176; 177; 178; 182; 183; 184; 185; 186; 189; 192; 195; 196; 197; 206; 208; 209; 210;

211; 212; 215; 221; 227; 228; 229; 230; 231; 233; 234; 238; 242; 243; 244; 246; 252; 253; 260;

261; 263; 267; 269; 271; 274; 276; 277; 280; 285; 289; 290; 292; 293; 294; 295; 296; 300; 301;

303; 307; 316; 317; 318; 322; 324; 325; 328; 329; 330; 331; 333; 334; 335; 336; 338; 339; 342;

343; 344; 349; 352; 356; 358; 359; 360; 361; 362; 363; 364; 368; 369; 370; 371; 372; 378; 381;

385; 386; 388; 390; 391; 397; 398; 413; 414; 416; 418; 421; 424; 426; 428; 429; 432; 441; 444;

449; 453; 457; 459; 461; 462; 463; 465; 466; 467; 468; 470; 471; 473; 475; 478; 479; 480; 482;

484; 486; 487; 488; 497; 498; 501; 502; 503; 505; 519; 520; 521; 524; 529; 532; 534; 537; 541;

544; 548; 550; 552; 558; 559; 560; 561; 562; 563; 565; 566; 567; 568; 569; 570; 571; 572; 573;

574; 577; 578; 582; 584; 589; 591; 592; 594; 599; 600; 601; 603; 604; 606; 607; 608; 609; 610;

611; 613; 614; 615; 616; 618; 620; 621; 624; 625; 626; 628; 631; 632; 633; 635; 644; 650; 653;

659; 660; 661; 663; 671; 673; 674; 675; 676; 677; 678; 679; 680; 681; 684; 686; 691; 692; 693;

694; 696; 697; 698; 700; 702; 704; 706; 707; 708; 709; 710; 711; 712; 713; 714; 715; 716; 717;

718; 719; 720; 721; 722; 723; 724; 725; 726; 727; 731; 741; 746; 750; 752; 754; 757; 758; 763;

766; 769; 770; 771; 774; 775; 776; 778; 781; 782; 788; 791; 800; 802; 804; 806; 814; 821; 826;

827; 828; 831; 837; 839; 840; 849; 850; 852; 856; 866; 868; 869; 870; 871; 872; 873; 876; 877;

878; 879; 881; 884; 885; 886; 890; 892; 893; 894; 905; 908; 912; 913; 914; 916; 919; 920; 922;

925; 926; 927; 930; 933; 939; 941; 942; 943; 945; 947; 948; 950; 951; 953; 954; 959; 965; 967;

973; 978; 985; 988; 998; 1000; 1003; 1006; 1007; 1008; 1009; 1010; 1016; 1022; 1023; 1024;

1025; 1028; 1029; 1031 1032; 1033; 1035; 1038 1045; 1046; 1047; 1053 1057; 1060; 1062 1063; 1065; 1067; 1070 1073; 1075; 1077; 1078 1082; 1089; 1090; 1093 1095; 1097; 1099 1102; 1104; 1105; 1107 1116; 1120; 1121; 1126 1129; 1131; 1135; 1136 1137; 1138; 1140 1142; 1143; 1144; 1145 1147; 1148; 1149; Table 2 materials 2; 23; 185; 227; 230; 246; 248; 343; 359; 565; 631; 659 674; 678; 679; 715; 758; 1028; 1097; Table 3 materials 1; 9; 12; 13; 19; 20; 21; 24; 25; 27; 32; 38; 54; 55; 59; 64; 68; 71; 72; 79; 81; 83; 85; 100; 105; 109; 111; 114; 119; 133; 134; 135; 137; 140; 142; 147; 148; 150; 151; 152; 153; 154; 157; 159; 162; 178; 181 189; 191; 192; 195; 197; 204; 211; 228; 231; 233; 234; 237; 238; 242; 246; 252; 264; 270; 273 275; 277; 283; 285; 289; 290; 292; 293; 295; 300; 301; 302; 306; 308; 310; 312; 319; 322; 325 331; 333; 334; 336; 338; 339; 344; 346; 354; 355; 356; 358; 361; 362; 363; 370; 371; 372; 378 381; 385; 387; 388; 390; 412; 413; 418; 420; 428; 429; 432; 437; 438; 444; 447; 448; 454; 455 457; 461; 465; 467; 472; 477; 478; 479; 480; 481; 482; 495; 496; 497; 502; 503; 504; 509; 510 512; 515; 517; 518; 522; 525; 529; 535; 536; 537; 540; 541; 544; 550; 557; 558; 559; 560; 561 568; 571; 572; 575; 589; 592; 594; 599; 600; 602; 604; 609; 619 620; 625; 626; 633; 641; 644 645; 650; 653; 662; 667; 672; 673; 675; 676; 681; 686; 687; 693 697; 698; 700; 703; 704; 706 707; 716; 717; 718; 722; 725; 744; 745; 746; 757; 769; 771; 779 782; 799; 806; 819; 820; 827 828; 836; 838; 839; 847; 850; 875; 878; 879; 880; 881; 888 890; 891; 893; 899; 900; 901 903; 909; 912; 914; 920; 922; 930; 939; 940; 941; 945; 947 948 953; 954; 958; 959; 960; 965 967; 971; 986; 987; 994; 995; 998; 1000; 1001; 1003; 1005 1008; 1009; 1010; 1011; 1017; 1018; 1023; 1031; 1032; 1046; 1047; 1051; 1052; 1053; 1054; 1055; 1057; 1058; 1061; 1062; 1063; 1074; 1075; 1076; 1082; 1088; 1093; 1095; 1099; 1102; 1104; 1105; 1115; 1116; 1120; 1127; 1128; 1134; 1135; 1141; 1147;1148, 1149, and mixtures thereof; preferably said malodor reduction materials are selected from the group consisting of Table 1 materials 1; 2; 3; 7; 9; 10;

1023; 1024; 1025; 1028 1029; 1031; 1032; 1033; 1035; 1038; 1045; 1046; 1047; 1053; 1057; 1060; 1062; 1063; 1065 1067; 1070; 1073; 1075; 1077; 1078; 1082; 1089; 1090; 1093; 1095; 1097; 1099; 1102; 1104; 1105; 1107; 1116; 1120; 1121; 1126; 1129; 1131; 1135; 1136; 1137;

1138; 1140; 1142; 1143; 1144; 1145; 1147; 1148; 1149; Table 2 materials 2; 23; 185; 227; 230;

246; 248; 343; 359; 565; 631; 659; 674; 678; 679; 715; 758; 1028; 1097 and mixtures thereof; more preferably said malodor reduction materials are selected from the group consisting of Table 4 materials 7; 14; 39; 48; 183; 206; 212; 215; 229; 260; 261; 329; 335; 360; 441; 484; 487; 488;

501; 566; 567; 569; 570; 573; 574; 603; 616; 621; 624; 632; 663; 680; 684; 694; 696; 708; 712;

714; 726; 750; 775; 776; 788; 804; 872; 919; 927; 933; 978; 1007; 1022; 1024; 1029; 1035;

1038; 1060; 1089; 1107; 1129; 1131; 1136; 1137; 1140; 1142; 1143; 1144; 1145; 1148, 1149

Table 5 material 248 and mixtures thereof, most preferably said material is selected from the group consisting of Table 4 materials 261; 680; 788;1129, 1148, 1149 and mixtures thereof. All of the aforementioned materials have a log P that is equal to or greater than 3, thus they deposit through the wash especially well. The more preferred and most preferred of the aforementioned material are particularly preferred as they are effective at counteracting all of the key malodors.

In one aspect of said cleaning and/or treatment composition, said cleaning and/or treatment composition comprises one or more malodor reduction materials having a vapor pressure of greater than 0.01 torr, preferably, greater than 0.01 torr to 10 torr, preferably said one or more malodor materials are selected from the group consisting of Table 1 materials 3; 4; 7; 9;

21; 25; 29; 30 31; 32; 33; 34; 35; 42; 49; 50; 62; 64; 65; 67; 70; 91; 92; 93; 98; 101; 102; 103;

108 110 114 117 119 122 123 126 130; 142 145; 146; 149 155; 159; 167; 168

186 189 190 192 193 208 209 210 218; 228 229; 231; 243 254; 256; 259; 267

280 281 290 294 317 318 322 325 333; 338 342; 344; 358 362; 364; 375; 38

398 415 421 424 428 429 436 441 444; 445 449; 453; 461 466; 468; 471; 473

491 519 520 524 527 530 531 532 534; 544 546; 551; 555 565; 578; 580; 581

587 589 603 604 606 609 611 612 614; 615 618; 621; 627 628; 631; 632; 633

659 668 683 686 692 693 696 698 702; 708 711; 714; 715 717; 720; 725; 73

748 750 752 763 766 767 768 770 774; 778 781; 786; 791 792; 800; 802; 80

826 827 828 829 834 837 839 840 850; 852 856; 864; 865 866; 868; 869; 871

877 878 879 884 897 905 914 926 928; 929 937; 946; 947 950; 955; 969; 973

993 1006; 1008; 1010; 1016; 1020; 1021; 1031; 1037; 1043; 1045; 1053; 1057; 1060; 1062; 1064; 1066; 1067; 1070; 1072; 1073; 1077; 1078; 1082; 1102; 1104; 1105; 1120; 1125; 1137; 1138; 1144; 1145 Table 2 materials 565; 631; 659; 715 Table 3 materials 9; 12; 19; 20; 21; 24; 25; 27; 32; 34; 53; 55; 59; 64; 65; 70; 73; 81; 84; 96; 97; 98; 108; 110; 111; 114; 116; 119; 125 126; 133; 142; 146; 147; 150; 154; 157; 159; 163; 166; 167; 169; 178; 189; 192; 194; 198; 201 204; 205; 228; 231; 232; 237; 239; 254; 256; 258; 264; 270; 273; 282; 283; 284; 287; 290; 302 306; 312; 319; 322; 325; 333; 338; 344; 346; 354; 358; 362; 365; 366; 375; 376; 387; 412; 419; 420; 428; 429; 437; 438; 439; 443; 444; 447; 448; 461; 469; 474; 477; 481; 491; 492; 495; 496; 509; 512; 517; 518; 522; 525; 530; 535; 536; 538; 540; 542; 544; 547; 549; 554; 555; 556; 557; 575; 576; 579; 583; 585; 588; 589; 604; 605; 609; 617; 619; 633; 640; 645; 647; 651; 652; 662; 664; 665; 667; 683; 686; 687; 693; 698; 699; 701; 717; 725; 730; 740; 742; 744; 745; 760; 761; 777; 779; 784; 789; 792; 797; 806; 810; 812; 817; 819; 820; 827; 828; 832; 835; 836; 838; 839; 845; 846; 847; 848; 850; 851; 858; 865; 875; 878; 879; 882; 883; 888; 889; 891; 899; 900; 901; 902; 903; 904; 909; 914; 931; 937; 940; 946; 947; 956; 977; 981; 986; 987; 994; 995; 1001; 1004; 1008; 1010; 1011; 1017; 1018; 1019; 1020; 1030; 1031; 1039; 1040; 1041; 1051; 1053; 1054; 1055; 1057; 1058; 1061; 1062; 1069; 1071; 1076; 1081; 1082; 1098; 1102; 1104; 1105; 1115; 1119; 1120; 1122; 1127; 1128; 1141 and mixtures thereof, more preferably said malodor reduction materials are selected from the group consisting of Table 1 materials 3; 4; 7; 9; 21; 25; 29; 30; 31; 32; 33; 34; 35; 42; 49; 50; 62; 64; 65; 67; 70; 91; 92; 93; 98; 101; 102; 103; 108; 110;

1008; 1010; 1016; 1020; 1021; 1031; 1037; 1043; 1045; 1053; 1057; 1060; 1062; 1064; 1066; 1067; 1070; 1072; 1073; 1077; 1078; 1082; 1102; 1104; 1105; 1120; 1125; 1137; 1138; 1144; 1145 Table 2 materials 565; 631; 659; 715, most preferably said malodor reduction materials are selected from the group consisting of Table 4 materials 7; 229; 281; 441; 603; 621; 627; 632; 696; 708; 714; 750; 1060; 1137; 1144; 1145 and mixtures thereof. All of the aforementioned materials have a vapor pressure that is greater than 0.01 torr, thus they effectively saturate the head space of a cleaning and/or treatment composition, wash solutions comprising same and a treated situs which leads to malodor blocking of any malodors in the cleaning and/or treatment composition, wash solutions comprising same and a treated situs.. The more preferred and most preferred of the aforementioned material are particularly preferred as they are effective at counteracting all of the key malodors. In one aspect of said cleaning and/or treatment composition, said cleaning and/or treatment composition comprises a malodor reduction material comprising one or more malodor reduction materials having a log P of 3 or less, preferably a log P from 0.1 to 3, preferably said one or more malodor reduction materials are selected from the group consisting of Table 1 materials 4; 16; 17; 34; 37; 42; 43; 61; 65; 70; 82; 98; 106; 108; 110; 112; 113; 117; 126; 130;

141; 143; 146; 155; 156; 167; 168; 170; 179; 187; 190; 193; 199; 218; 247; 249; 254; 256; 259;

278; 281; 286; 288; 321; 323; 332; 347; 350; 353; 373; 374; 375; 377; 394; 407; 415; 417; 425;

436; 445; 450; 464; 474; 485; 491; 493; 527; 530; 531; 546; 551; 553; 555; 580; 581; 586; 587;

595; 612; 627; 636; 638; 639; 649; 655; 658; 668; 683; 730; 733; 735; 736; 738; 742; 748; 767; 768; 772; 786; 792; 803; 805; 807; 824; 829; 833; 834; 864; 865; 897; 923; 924; 928; 929; 937;

946; 955; 962; 969; 974; 976; 980; 982; 993; 1012; 1020; 1021; 1026; 1027; 1036; 1037; 1042;

1059; 1064; 1066; 1072; 1083; 1085; 1091; 1111; 1117; 1125; 1139; 1146 Table 2 material 141;

Table 3 materials 26; 34; 37; 43; 53; 65; 70; 73; 82; 84; 96; 97; 98; 106; 107; 108; 110; 115; 116;

125; 126; 143; 146; 163; 166; 167; 169; 187; 194; 198; 201; 205; 213; 214; 232; 239; 254; 255; 256; 258; 282; 284; 286; 287; 288; 314; 323; 365; 366; 374; 375; 376; 377; 379; 400; 407; 417;

419; 439; 440; 442; 443; 469; 474; 485; 491; 492; 526; 528; 530; 538; 542; 547; 549; 554; 555;

556; 576; 579; 583; 585; 588; 605; 617; 636; 638; 640; 647; 651; 652; 664; 665; 683; 699; 701;

730; 740; 742; 743; 755; 760; 761; 772; 777; 784; 789; 792; 796; 797; 803; 805; 807; 808; 810;

811; 812; 817; 832; 833; 835; 845; 846; 848; 851; 858; 865; 882; 883; 902; 904; 918; 921; 923; 931; 937; 946; 956; 977; 981; 983; 1002; 1004; 1019; 1020; 1026; 1036; 1039; 1040; 1041;

1069; 1071; 1079; 1081; 1084; 1091; 1098; 1110; 1111; 1112; 1118; 1119; 1122; 1133; 1139;

1146; and mixtures thereof, more preferably said malodor reduction materials are selected from the group consisting of Table 1 materials 4; 16; 17; 34; 37; 42; 43; 61; 65; 70; 82; 98; 106; 108;

110; 112; 113; 117; 126; 130; 141; 143; 146; 155; 156; 167; 168; 170; 179; 187; 190; 193; 199; 218; 247; 249; 254; 256; 259; 278; 281; 286; 288; 321; 323; 332; 347; 350; 353; 373; 374; 375;

377; 394; 407; 415; 417; 425; 436; 445; 450; 464; 474; 485; 491; 493; 527; 530; 531; 546; 551;

553; 555; 580; 581; 586; 587; 595; 612; 627; 636; 638; 639; 649; 655; 658; 668; 683; 730; 733;

735; 736; 738; 742; 748; 767; 768; 772; 786; 792; 803; 805; 807; 824; 829; 833; 834; 864; 865;

897; 923; 924; 928; 929; 937; 946; 955; 962; 969; 974; 976; 980; 982; 993; 1012; 1020; 1021; 1026; 1027; 1036; 1037; 1042; 1059; 1064; 1066; 1072; 1083; 1085; 1091; 1111; 1117; 1125;

1139; 1146 Table 2 material 141 and mixtures thereof, most preferably said malodor reduction material is selected from the group consisting of Table 4 materials 199; 281; 353; 627; 1027 and mixtures thereof. All of the aforementioned materials have a log P that is less than 3, thus they remain in the water phase of a cleaning and/or treatment composition, wash solutions longer and are good treating hard surfaces. The more preferred and most preferred of the aforementioned material are particularly preferred as they are effective at counteracting all of the key malodors.

In one aspect of said cleaning and/or treatment composition, said malodor reduction materials are not selected from the group consisting of Table 1-3 malodor reduction materials 302; 288; 50; 157; 1017; 888; 64; 1054; 832; 375; 390; 745; 504; 505; 140; 1012; 498; 362; 103; 356; 1074; 908; 1127; 475; 918; 687; 611; 317; 9; 141; 550; 602; 913; 1005; 521; 10; 215; 370; 335; 378; 1121; 360; 565; 1136; 1129; 655; 369; 1065; 914; 757; 601; 478; 889; 891; 358; 973; 162; 554; 522; 312; 125; 26; 418; 92; 586; 1026; 218; 31; 828; 871; 829; 1066; 287; 269; 769; 701; 1118; 70; 946; 142; 109; 108 or mixtures thereof.

In one aspect of Applicants' cleaning and/or treatment composition, said composition comprises an adjunct ingredient selected from the group consisting of builders, chelating agents, dye transfer inhibiting agents, dispersants, enzymes, and enzyme stabilizers, catalytic materials, bleach activators, hydrogen peroxide, sources of hydrogen peroxide, preformed peracids, polymeric dispersing agents, clay soil removal/anti-redeposition agents, brighteners, suds suppressors, dyes, hueing dyes, perfumes, perfume delivery systems, structure elasticizing agents, carriers, structurants, hydrotropes, processing aids, solvents in addition to said solubilizing agent, a fabric softener active selected from the group consisting of a silicone polymer, a polysaccharide, a clay, a fatty ester, a dispersible polyolefin, a polymer latex and mixtures thereof, pigments, and mixtures thereof, preferably said composition comprises an organic acid, preferably citric acid and/ or lactic acid, hydrogenated castor oil, ethoxylated polyethleneimines, preferably PEI 600 EO 20 and/or PEI 600, an enzyme, preferably a cold water amylase, cold water protease and/ or xylogluconase.

In one aspect of Applicants' cleaning and/or treatment composition, said cleaning and/or treatment composition comprises a fabric softener active is selected from the group consisting of a quaternary ammonium compound, a silicone polymer, a polysaccharide, a clay, an amine, a fatty ester, a dispersible polyolefin, a polymer latex and mixtures thereof, preferably

b. ) said silicone polymer is selected from the group consisting of cyclic

silicones, polydimethylsiloxanes, aminosilicones, cationic silicones, silicone polyethers, silicone resins, silicone urethanes, and mixtures

thereof;

c. ) said polysaccharide comprises a cationic starch;

d. ) said clay comprises a smectite clay;

e.) said dispersible polyolefin is selected from the group consisting of

polyethylene, polypropylene and mixtures thereof; and f.) said fatty ester is selected from the group consisting of a poly glycerol ester, a sucrose ester, a glycerol ester and mixtures thereof.

In one aspect of Applicants' cleaning and/or treatment composition, said cleaning and/or treatment composition comprises a fabric softener active comprising a material selected from the group consisting of monoesterquats, diesterquats, triesterquats, and mixtures thereof, preferably, said monoesterquats and diesterquats are selected from the group consisting of bis-(2- hydroxypropyl)-dimethylammonium methylsulfate fatty acid ester and isomers of bis-(2- hydroxypropyl)-dimethylammonium methylsulfate fatty acid ester and/or mixtures thereof, 1,2- di(acyloxy)-3-trimethylammoniopropane chloride, N,N-bis(stearoyl-oxy-ethyl)-N,N-dimethyl ammonium chloride, N,N-bis(tallowoyl-oxy-ethyl)-N,N-dimethyl ammonium chloride, N,N- bis(stearoyl-oxy-ethyl)-N-(2-hydroxyethyl)-N-methyl ammonium methylsulfate, N,N-bis- (stearoyl-2-hydroxypropyl)-N,N-dimethylammonium methylsulfate, N,N-bis-(tallowoyl-2- hydroxypropyl)-N,N-dimethylammonium methylsulfate, N,N-bis-(palmitoyl-2-hydroxypropyl)- Ν,Ν-dimethylammonium methylsulfate, N,N-bis-(stearoyl-2-hydroxypropyl)-N,N- dimethylammonium chloride, l,2-di-(stearoyl-oxy)-3-trimethyl ammoniumpropane chloride, dicanoladimethylammonium chloride, di(hard)tallowdimethylammonium chloride,

dicanoladimethylammonium methylsulfate, l-methyl-l-stearoylamidoethyl-2- stearoylimidazolinium methylsulfate, 1 -tallowylamidoethyl-2-tallowylimidazoline,

dipalmylmethyl hydroxyethylammoinum methylsulfate and mixtures thereof.

In one aspect of Applicants' cleaning and/or treatment composition, said composition comprises a quaternary ammonium compound and a silicone polymer, preferably said composition comprises from 0.001% to 10%, from 0.1% to 8%, more preferably from 0.5% to 5%, of said silicone polymer.

In one aspect of Applicants' cleaning and/or treatment composition, said fabric softening active has an Iodine Value of between 0-140, preferably 5-100, more preferably 10-80, even more preferably, 15-70, most preferably 18-25 or when said fabric softening active comprises a partially hydrogenated fatty acid quaternary ammonium compound said fabric softening active most preferably has a Iodine Value of 25-60. In one aspect of Applicants' cleaning and/or treatment composition, said cleaning and/or treatment composition is a soluble unit-dose product said soluble unit dose product comprising one or more cleaning and/or treatment compositions contained within one or more chambers said chambers being formed from one or more films, preferably said one or more films comprise PVA film.

Adjunct Materials

While not essential for the purposes of the present invention, the non-limiting list of adjuncts illustrated hereinafter are suitable for use in the instant compositions and may be desirably incorporated in certain aspects of the invention, for example to assist or enhance cleaning performance, for treatment of the substrate to be cleaned, or to modify the aesthetics of the composition as is the case with perfumes, colorants, dyes or the like. The precise nature of these additional components, and levels of incorporation thereof, will depend on the physical form of the composition and the nature of the fabric treatment operation for which it is to be used. Suitable adjunct materials include, but are not limited to, surfactants, builders, chelating agents, dye transfer inhibiting agents, dispersants, enzymes, and enzyme stabilizers, catalytic materials, bleach activators, hydrogen peroxide, sources of hydrogen peroxide, preformed peracids, polymeric dispersing agents, clay soil removal/anti-redeposition agents, brighteners, suds suppressors, dyes, hueing dyes, perfumes, perfume delivery systems, structure elasticizing agents, carriers, structurants, hydrotropes, processing aids, solvents, pigments and/or fabric softener actives and clothes softening agents compatible with detergents, anti-bacterials, antimicrobials, and anti-fungals.

As stated, the adjunct ingredients are not essential to Applicants' compositions. Thus, certain aspects of Applicants' compositions do not contain one or more of the following adjuncts materials: surfactants, builders, chelating agents, dye transfer inhibiting agents, dispersants, enzymes, and enzyme stabilizers, catalytic materials, bleach activators, hydrogen peroxide, sources of hydrogen peroxide, preformed peracids, polymeric dispersing agents, clay soil removal/anti-redeposition agents, brighteners, suds suppressors, dyes, hueing dyes, perfumes, perfume delivery systems structure elasticizing agents, carriers, hydrotropes, processing aids, solvents, pigments and/or fabric softener actives, anti-bacterial/ microbial. However, when one or more adjuncts are present, such one or more adjuncts may be present as detailed below.

Hueing Dye - The liquid laundry detergent composition may comprise a hueing dye. The hueing dyes employed in the present laundry care compositions may comprise polymeric or non- polymeric dyes, organic or inorganic pigments, or mixtures thereof. Preferably the hueing dye comprises a polymeric dye, comprising a chromophore constituent and a polymeric constituent. The chromophore constituent is characterized in that it absorbs light in the wavelength range of blue, red, violet, purple, or combinations thereof upon exposure to light. In one aspect, the chromophore constituent exhibits an absorbance spectrum maximum from about 520 nanometers to about 640 nanometers in water and/or methanol, and in another aspect, from about 560 nanometers to about 610 nanometers in water and/or methanol.

Although any suitable chromophore may be used, the dye chromophore is preferably selected from benzodifuranes, methine, triphenylmethanes, napthalimides, pyrazole,

napthoquinone, anthraquinone, azo, oxazine, azine, xanthene, triphenodioxazine and

phthalocyanine dye chromophores. Mono and di-azo dye chromophores are may be preferred.

The hueing dye may comprise a dye polymer comprising a chromophore covalently bound to one or more of at least three consecutive repeat units. It should be understood that the repeat units themselves do not need to comprise a chromophore. The dye polymer may comprise at least 5, or at least 10, or even at least 20 consecutive repeat units.

The repeat unit can be derived from an organic ester such as phenyl dicarboxylate in combination with an oxyalkyleneoxy and a polyoxyalkyleneoxy. Repeat units can be derived from alkenes, epoxides, aziridine, carbohydrate including the units that comprise modified celluloses such as hydroxyalkylcellulose; hydroxypropyl cellulose; hydroxypropyl methylcellulose; hydroxybutyl cellulose; and, hydroxybutyl methylcellulose or mixtures thereof. The repeat units may be derived from alkenes, or epoxides or mixtures thereof. The repeat units may be C2-C4 alkyleneoxy groups, sometimes called alkoxy groups, preferably derived from C ₂- C ₄ alkylene oxide. The repeat units may be C2-C4 alkoxy groups, preferably ethoxy groups.

For the purposes of the present invention, the at least three consecutive repeat units form a polymeric constituent. The polymeric constituent may be covalently bound to the chromophore group, directly or indirectly via a linking group. Examples of suitable polymeric constituents include poly oxy alkylene chains having multiple repeating units. In one aspect, the polymeric constituents include polyoxyalkylene chains having from 2 to about 30 repeating units, from 2 to about 20 repeating units, from 2 to about 10 repeating units or even from about 3 or 4 to about 6 repeating units. Non-limiting examples of polyoxyalkylene chains include ethylene oxide, propylene oxide, glycidol oxide, butylene oxide and mixtures thereof. Surfactants - The compositions according to the present invention may comprise a surfactant or surfactant system wherein the surfactant can be selected from nonionic surfactants, anionic surfactants, cationic surfactants, ampholytic surfactants, zwitterionic surfactants, semi- polar nonionic surfactants and mixtures thereof.

The surfactant is typically present at a level of from about 0.1% to about 60%, from about

1% to about 50% or even from about 5% to about 40% by weight of the subject composition.

Chelating Agents - The compositions herein may contain a chelating agent. Suitable chelating agents include copper, iron and/or manganese chelating agents and mixtures thereof. When a chelating agent is used, the composition may comprise from about 0.1% to about 15% or even from about 3.0% to about 10% chelating agent by weight of the subject composition.

Dye Transfer Inhibiting Agents - The compositions of the present invention may also include one or more dye transfer inhibiting agents. Suitable polymeric dye transfer inhibiting agents include, but are not limited to, polyvinylpyrrolidone polymers, polyamine N-oxide polymers, copolymers of N-vinylpyrrolidone and N-vinylimidazole, polyvinyloxazolidones and polyvinylimidazoles or mixtures thereof.

When present in a subject composition, the dye transfer inhibiting agents may be present at levels from about 0.0001% to about 10%, from about 0.01% to about 5% or even from about 0.1% to about 3% by weight of the composition.

Dispersants - The compositions of the present invention can also contain dispersants. Suitable water-soluble organic materials include the homo- or co-polymeric acids or their salts, in which the polycarboxylic acid comprises at least two carboxyl radicals separated from each other by not more than two carbon atoms.

Perfumes - The dispersed phase may comprise a perfume that may include materials selected from the group consisting of perfumes such as 3-(4-i-butylphenyl)-2-methyl propanal, 3- (4-i-butylphenyl)-propanal, 3-(4-isopropylphenyl)-2-methylpropanal, 3-(3,4- methylenedioxyphenyl)-2-methylpropanal, and 2,6-dimethyl-5-heptenal, oc-damascone, β- damascone, δ-damascone, β-damascenone, 6,7-dihydro-l,l,2,3,3-pentamethyl-4(5H)-indanone, methyl-7,3-dihydro-2H-l,5-benzodioxepine-3-one, 2-[2-(4-methyl-3-cyclohexenyl-l- yl)propyl]cyclopentan-2-one, 2-sec-butylcyclohexanone, and β-dihydro ionone, linalool, ethyllinalool, tetrahydrolinalool, and dihydromyrcenol.

Perfume Delivery Technologies The compositions of the present invention may comprise one or more perfume delivery technologies that stabilize and enhance the deposition and release of perfume ingredients from treated substrate. Such perfume delivery technologies can also be used to increase the longevity of perfume release from the treated substrate. Perfume delivery technologies, methods of making certain perfume delivery technologies and the uses of such perfume delivery technologies are disclosed in US 2007/0275866 Al.

In one aspect, the compositions of the present invention may comprise from about 0.001% to about 20%, or from about 0.01% to about 10%, or from about 0.05% to about 5%, or even from about 0.1% to about 0.5% by weight of the perfume delivery technology. In one aspect, said perfume delivery technologies may be selected from the group consisting of:

perfume microcapsules, pro-perfumes, polymer particles, functionalized silicones, polymer assisted delivery, molecule assisted delivery, fiber assisted delivery, amine assisted delivery, cyclodextrins, starch encapsulated accord, zeolite and inorganic carrier, and mixtures thereof:

In one aspect, said perfume delivery technology may comprise encapsulated perfume such as perfume microcapsules formed by at least partially surrounding a benefit agent with a wall material. Said benefit agent may include materials selected from the group consisting of perfumes such as 3-(4-i-butylphenyl)-2-methyl propanal, 3-(4-i-butylphenyl)-propanal, 3-(4- isopropylphenyl)-2-methylpropanal, 3-(3,4-methylenedioxyphenyl)-2-methylpropanal, and 2,6- dimethyl-5-heptenal, oc-damascone, β-damascone, δ-damascone, β-damascenone, 6,7-dihydro- l,l,2,3,3-pentamethyl-4(5H)-indanone, methyl-7,3-dihydro-2H-l,5-benzodioxepine-3-one, 2-[2- (4-methyl-3-cyclohexenyl-l-yl)propyl]cyclopentan-2-one, 2-sec-butylcyclohexanone, and β- dihydro ionone, linalool, ethyllinalool, tetrahydrolinalool, and dihydromyrcenol. Suitable perfume materials can be obtained from Givaudan Corp. of Mount Olive, New Jersey, USA, International Flavors & Fragrances Corp. of South Brunswick, New Jersey, USA, or Quest Corp. of Naarden, Netherlands. In one aspect, the microcapsule wall material may comprise: melamine, polyacrylamide, silicones, silica, polystyrene, polyurea, polyurethanes, polyacrylate based materials, gelatin, styrene malic anhydride, polyamides, and mixtures thereof. In one aspect, said melamine wall material may comprise melamine crosslinked with formaldehyde, melamine-dimethoxyethanol crosslinked with formaldehyde, and mixtures thereof. In one aspect, said polystyrene wall material may comprise polyestyrene cross-linked with divinylbenzene. In one aspect, said polyurea wall material may comprise urea crosslinked with formaldehyde, urea crosslinked with gluteraldehyde, and mixtures thereof. In one aspect, said polyacrylate based materials may comprise polyacrylate formed from methylmethacrylate/dimethylaminomethyl methacrylate, polyacrylate formed from amine acrylate and/or methacrylate and strong acid, polyacrylate formed from carboxylic acid acrylate and/or methacrylate monomer and strong base, polyacrylate formed from an amine acrylate and/or methacrylate monomer and a carboxylic acid acrylate and/or carboxylic acid methacrylate monomer, and mixtures thereof. In one aspect, the perfume microcapsule may be coated with a deposition aid, a cationic polymer, a non-ionic polymer, an anionic polymer, or mixtures thereof. Suitable polymers may be selected from the group consisting of: polyvinylformaldehyde, partially hydroxylated polyvinylformaldehyde, polyvinylamine, polyethyleneimine, ethoxylated polyethyleneimine, polyvinylalcohol, polyacrylates, and combinations thereof. In one aspect, the microcapsule may be a perfume microcapsule. In one aspect, one or more types of microcapsules, for example two microcapsules types having different benefit agents may be used.

In one aspect, said perfume delivery technology may comprise an amine reaction product (ARP) or a thio reaction product. One may also use "reactive" polymeric amines and or polymeric thiols in which the amine and/or thiol functionality is pre-reacted with one or more PRMs to form a reaction product. Typically the reactive amines are primary and/or secondary amines, and may be part of a polymer or a monomer (non-polymer). Such ARPs may also be mixed with additional PRMs to provide benefits of polymer-assisted delivery and/or amine - assisted delivery. Nonlimiting examples of polymeric amines include polymers based on poly alky limines, such as polyethyleneimine (PEI), or polyvinylamine (PVAm). Nonlimiting examples of monomeric (non-polymeric) amines include hydroxyl amines, such as 2- aminoethanol and its alkyl substituted derivatives, and aromatic amines such as anthranilates. The ARPs may be premixed with perfume or added separately in leave-on or rinse-off applications. In another aspect, a material that contains a heteroatom other than nitrogen and/or sulfur, for example oxygen, phosphorus or selenium, may be used as an alternative to amine compounds. In yet another aspect, the aforementioned alternative compounds can be used in combination with amine compounds. In yet another aspect, a single molecule may comprise an amine moiety and one or more of the alternative heteroatom moieties, for example, thiols, phosphines and selenols. The benefit may include improved delivery of perfume as well as controlled perfume release. Suitable ARPs as well as methods of making same can be found in USPA 2005/0003980 Al and USP 6,413,920 Bl.

Suitable Fabric Softening Actives

The fluid fabric enhancer compositions disclosed herein comprise a fabric softening active ("FSA"). Suitable fabric softening actives, include, but are not limited to, materials selected from the group consisting of quaternary ammonium compounds, amines, fatty esters, sucrose esters, silicones, dispersible polyolefins, clays, polysaccharides, fatty acids, softening oils, polymer latexes and mixtures thereof.

Non-limiting examples of water insoluble fabric care benefit agents include dispersible polyethylene and polymer latexes. These agents can be in the form of emulsions, latexes, dispersions, suspensions, and the like. In one aspect, they are in the form of an emulsion or a latex. Dispersible polyethylenes and polymer latexes can have a wide range of particle size diameters (xso) including but not limited to from about 1 nm to about 100 μιη; alternatively from about 10 nm to about 10 μιη. As such, the particle sizes of dispersible polyethylenes and polymer latexes are generally, but without limitation, smaller than silicones or other fatty oils.

Generally, any surfactant suitable for making polymer emulsions or emulsion polymerizations of polymer latexes can be used to make the water insoluble fabric care benefit agents of the present invention. Suitable surfactants consist of emulsifiers for polymer emulsions and latexes, dispersing agents for polymer dispersions and suspension agents for polymer suspensions. Suitable surfactants include anionic, cationic, and nonionic surfactants, or combinations thereof. In one aspect, such surfactants are nonionic and/or anionic surfactants. In one aspect, the ratio of surfactant to polymer in the water insoluble fabric care benefit agent is about 1:100 to about 1:2; alternatively from about 1:50 to about 1:5, respectively. Suitable water insoluble fabric care benefit agents include but are not limited to the examples described below.

Quats - Suitable quats include but are not limited to, materials selected from the group consisting of ester quats, amide quats, imidazoline quats, alkyl quats, amidoester quats and mixtures thereof. Suitable ester quats include but are not limited to, materials selected from the group consisting of monoester quats, diester quats, triester quats and mixtures thereof. In one aspect, a suitable ester quat is bis-(2-hydroxypropyl)-dimethylammonium methylsulfate fatty acid ester having a molar ratio of fatty acid moieties to amine moieties of from 1.85 to 1.99, an average chain length of the fatty acid moieties of from 16 to 18 carbon atoms and an iodine value of the fatty acid moieties, calculated for the free fatty acid, which has an Iodine Value of between 0-140, preferably 5-100, more preferably 10-80, even more preferably 15-70, even more preferably 18-55, most preferably 18-25. When a soft tallow quaternary ammonium compound softener is used, most preferably range is 25-60. In one aspect, the cis-trans-ratio of double bonds of unsaturated fatty acid moieties of the bis (2 hydroxypropyl)-dimethylammonium methylsulfate fatty acid ester is from 55:45 to 75:25, respectively. Suitable amide quats include but are not limited to, materials selected from the group consisting of monoamide quats, diamide quats and mixtures thereof. Suitable alkyl quats include but are not limited to, materials selected from the group consisting of mono alkyl quats, dialkyl quats quats, trialkyl quats, tetraalkyl quats and mixtures thereof.

Amines - Suitable amines include but are not limited to, materials selected from the group consisting of amidoesteramines, amidoamines, imidazoline amines, alkyl amines, amidoester amines and mixtures thereof. Suitable ester amines include but are not limited to, materials selected from the group consisting of monoester amines, diester amines, triester amines and mixtures thereof. Suitable amido quats include but are not limited to, materials selected from the group consisting of monoamido amines, diamido amines and mixtures thereof. Suitable alkyl amines include but are not limited to, materials selected from the group consisting of mono alkylamines, dialkyl amines quats, trialkyl amines, and mixtures thereof.

In one embodiment, the fabric softening active is a quaternary ammonium compound suitable for softening fabric in a rinse step. In one embodiment, the fabric softening active is formed from a reaction product of a fatty acid and an aminoalcohol obtaining mixtures of mono-, di-, and in one embodiment, tri-ester compounds. In another embodiment, the fabric softening active comprises one or more softener quaternary ammonium compounds such, but not limited to, as a monoalky quaternary ammonium compound, dialkylquaternary ammonium compound, a diamido quaternary compound, a diester quaternary ammonium compound, or a combination thereof.

In one aspect, the fabric softening active comprises a diester quaternary ammonium or protonated diester ammonium (hereinafter "DQA") compound composition. In certain embodiments of the present invention, the DQA compound compositions also encompass diamido fabric softening actives and fabric softening actives with mixed amido and ester linkages as well as the aforementioned diester linkages, all herein referred to as DQA.

In one aspect, said fabric softening active may comprise, as the principal active, compounds of the following formula:

{R ₄-m - N+ - [X - Y - Rl] _m} X ^" (!) wherein each R comprises either hydrogen, a short chain C _j-C ₆, in one aspect a C _j-C ₃ alkyl or hydroxyalkyl group, for example methyl, ethyl, propyl, hydroxyethyl, and the like, poly(C ₂_ ₃ alkoxy), polyethoxy, benzyl, or mixtures thereof; each X is independently (CH ₂)n, CH ₂- CH(CH ₃)- or CH-(CH ₃)-CH ₂-; each Y may comprise -0-(0)C-, -C(0)-0-, -NR-C(O)-, or -C(O)- NR-; each m is 2 or 3; each n is from 1 to about 4, in one aspect 2; the sum of carbons in each

R1, plus one when Y is -0-(0)C- or -NR-C(O) -, may be C ₁₂-C ₂₂, or C ₁₄-C ₂₀, with each R ¹ being a hydrocarbyl, or substituted hydrocarbyl group; and X ^" may comprise any softener-compatible anion. In one aspect, the softener-compatible anion may comprise chloride, bromide, methylsulfate, ethylsulfate, sulfate, and nitrate. In another aspect, the softener-compatible anion may comprise chloride or methyl sulfate.

In another aspect, the fabric softening active may comprise the general formula:

[R ₃N+CH ₂CH(YR ¹)(CH ₂YR ¹)] X ^" wherein each Y, R, R^, and X ^" have the same meanings as before. Such compounds include those having the formula: [CH ₃] ₃ NWfCH _jCHCCH _jOCOJCR^OCOJCR ¹] Cl^ wherein each R may comprise a methyl or ethyl group. In one aspect, each R^ may comprise a C ₁₅ to C ₁₉ group. As ^used herein, when the diester is specified, it can include the monoester that is present.

These types of agents and general methods of making them are disclosed in U. S.P.N. 4,137,180. An example of a suitable DEQA (2) is the "propyl" ester quaternary ammonium fabric softener active comprising the formula l,2-di(acyloxy)-3-trimethylammoniopropane chloride.

A third type of useful fabric softening active has the formula:

[R ₄-m - + - R ¹™] X- (3) wherein each R, R^, m and X ^" have the same meanings as before.

In a further aspect, the fabric softening active may comprise the formula: N CE,

O C

N -— CH„

c - -G— \

R (4) wherein each R, R^, and A ^" have the definitions given above; R ² may comprise a C _{1 6} alkylene group, in one aspect an ethylene group; and G may comprise an oxygen atom or an -NR- group;

In a yet further aspect, the fabric softening active may comprise the formula:

wherein R1, R ² and G are defined as above.

In a further aspect, the fabric softening active may comprise condensation reaction products of fatty acids with dialkylenetriamines in, e.g., a molecular ratio of about 2:1, said reaction products containing compounds of the formula: R ¹— C(O)— NH— R ²— NH— R ³— NH— C(O)— R ¹ ( ⁶) wherein R1, R ² are defined as above, and R ³ may comprise a C^_ alkylene group, in one aspect, an ethylene group and wherein the reaction products may optionally be quatemized by the additional of an alkylating agent such as dimethyl sulfate. Such quatemized reaction products are described in additional detail in U.S. P.N. 5,296,622. In a yet further aspect, the fabric softening active may comprise the formula:

[R ¹— C(O)— NR— R ²— N(R)2— R ³— NR— C(O)— R!]+ A ^" ( ⁷) wherein R, R1, R ², R ³ and A ^" are defined as above;

In a yet further aspect, the fabric softening active may comprise reaction products of fatty acid with hydroxyalkylalkylenediamines in a molecular ratio of about 2:1, said reaction products containing compounds of the formula: wherein Ri, R^ and R3 are defined as above;

In a yet further aspect, the fabric softening active may comprise the formula:

wherein R, Ri, R^, and A ^" are defined as above.

In yet a further aspect, the fabric softening active may comprise the formula:

(10)

wherein;

Xi is a C ₂-3 alkyl group, in one aspect, an ethyl group;

X ₂ and X3 are independently Ci_6 linear or branched alkyl or alkenyl groups, in one aspect, methyl, ethyl or isopropyl groups;

Ri and R ₂ are independently Cs- ₂₂ linear or branched alkyl or alkenyl groups;

characterized in that;

A and B are independently selected from the group comprising -0-(C=0)-, -(C=0)-0-, or mixtures thereof, in one aspect, -0-(C=0)-

Non- limiting examples of fabric softening actives comprising formula (1) are N,N- bis(stearoyl-oxy-ethyl)-N,N-dimethylammonium chloride, N,N-bis(tallowoyl-oxy-ethyl)-N,N- dimethylammonium chloride, N,N-bis(stearoyl-oxy-ethyl)-N-(2 hydroxyethyl)-N- methylammonium methylsulfate.

Non- limiting examples of fabric softening actives comprising formula (2) is 1,2-di- (stearoyl-oxy)-3-trimethyl ammoniumpropane chloride. Non-limiting examples of fabric softening actives comprising formula (3) include dialkylenedimethylammonium salts such as dicanoladimethylammonium chloride, di(hard)tallowdimethylammonium chloride, dicanoladimethylammonium methylsulfate, and mixtures thereof. An example of commercially available dialkylenedimethylammonium salts usable in the present invention is dioleyldimethylammonium chloride available from Witco Corporation under the trade name Adogen® 472 and dihardtallow dimethylammonium chloride available from Akzo Nobel Arquad 2HT75.

A non-limiting example of fabric softening actives comprising formula (4) is 1 -methyl- 1- stearoylamidoethyl-2-stearoylimidazolinium methylsulfate wherein R1 is an acyclic aliphatic C15-C1 hydrocarbon group, is an ethylene group, G is a NH group, is a methyl group and A ^" is a methyl sulfate anion, available commercially from the Witco Corporation under the trade name Varisoft®.

A non- limiting example of fabric softening actives comprising formula (5) is 1- tallowylamidoethyl-2-tallowylimidazoline wherein R1 is an acyclic aliphatic C15-C17 hydrocarbon group, R^ is an ethylene group, and G is a NH group. A non-limiting example of a fabric softening active comprising formula (6) is the reaction products of fatty acids with diethylenetriamine in a molecular ratio of about 2:1, said reaction product mixture containing N,N"-dialkyldiethylenetriamine with the formula:

R ¹-C(0)-NH-CH ₂CH2-NH-CH ₂CH2-NH-C(0)-R ¹ wherein R1 is an alkyl group of a commercially available fatty acid derived from a vegetable or animal source, such as Emersol® 223LL or Emersol® 7021, available from Henkel Corporation, and R2 and R^ are divalent ethylene groups. In one aspect, said fatty acid may be obtained, in whole or in part, from a renewable source, via extraction from plant material, fermentation from plant material, and/or obtained via genetically modified organisms such as algae or yeast.

A non-limiting example of Compound (7) is a di-fatty amidoamine based softener having the formula:

[R ¹-C(0)-NH-CH ₂CH2-N(CH3)(CH2CH20H)-CH2CH2-NH-C(0)-R ¹]+ CH3SO4- wherein R1 is an alkyl group. An example of such compound is that commercially available from the Witco Corporation e.g. under the trade name Varisoft® 222LT.

An example of a fabric softening active comprising formula (8) is the reaction products of fatty acids with N-2-hydroxyethylethylenediamine in a molecular ratio of about 2:1, said reaction product mixture containing a compound of the formula:

R ¹-C(0)-NH-CH ₂CH2-N(CH2CH ₂OH)-C(0)-R ¹ wherein R!-C(O) is an alkyl group of a commercially available fatty acid derived from a vegetable or animal source, such as Emersol® 223LL or Emersol® 7021, available from Henkel Corporation.

An example of a fabric softening active comprising formula (9) is the diquaternary compound having the formula:

wherein R1 is derived from fatty acid. Such compound is available from Witco Company.

A non-limiting example of a fabric softening active comprising formula (10) is a dialkyl imidazoline diester compound, where the compound is the reaction product of N-(2- hydroxyethyl)-l,2-ethylenediamine or N-(2-hydroxyisopropyl)-l,2-ethylenediamine with glycolic acid, esterified with fatty acid, where the fatty acid is (hydrogenated) tallow fatty acid, palm fatty acid, hydrogenated palm fatty acid, oleic acid, rapeseed fatty acid, hydrogenated rapeseed fatty acid or a mixture of the above.

It will be understood that combinations of softener actives disclosed above are suitable for use in this invention. Anion A

In the cationic nitrogenous salts herein, the anion A ^", which comprises any softener compatible anion, provides electrical neutrality. Most often, the anion used to provide electrical neutrality in these salts is from a strong acid, especially a halide, such as chloride, bromide, or iodide. However, other anions can be used, such as methylsulfate, ethylsulfate, acetate, formate, sulfate, carbonate, fatty acid anions and the like. In one aspect, the anion A may comprise chloride or methylsulfate. The anion, in some aspects, may carry a double charge. In this aspect,

A ^" represents half a group.

In one embodiment, the fabric softening agent is chosen from at least one of the following: ditallowoyloxyethyl dimethyl ammonium chloride, dihydrogenated-tallowoyloxyethyl dimethyl ammonium chloride, ditallow dimethyl ammonium chloride, dihydrogenatedtallow dimethyl ammonium chloride, ditallowoyloxyethyl methylhydroxyethylammonium methyl sulfate, dihydrogenated-tallowoyloxyethyl methyl hydroxyethylammonium chloride, or combinations thereof.

Polvssacharides

One aspect of the invention provides a fabric enhancer composition comprising a cationic starch as a fabric softening active. In one embodiment, the fabric care compositions of the present invention generally comprise cationic starch at a level of from about 0.1% to about 7%, alternatively from about 0.1% to about 5%, alternatively from about 0.3% to about 3%, and alternatively from about 0.5% to about 2.0%, by weight of the composition. Suitable cationic starches for use in the present compositions are commercially-available from Cerestar under the trade name C*BOND ^® and from National Starch and Chemical Company under the trade name CATO ^® 2A.

Sucrose esters

Nonionic fabric care benefit agents can comprise sucrose esters, and are typically derived from sucrose and fatty acids. Sucrose ester is composed of a sucrose moiety having one or more of its hydroxyl groups esterified.

Sucrose is a disaccharide having the following formula:

Alternatively, the sucrose molecule can be represented by the formula: M(OH) ₈, wherein M is the disaccharide backbone and there are total of 8 hydroxyl groups in the molecule.

Thus, sucrose esters can be represented by the following formula:

M(OH) ₈. _x(OC(0)R ¹) _x

wherein x is the number of hydroxyl groups that are esterified, whereas (8-x) is the hydroxyl groups that remain unchanged; x is an integer selected from 1 to 8, alternatively from 2 to 8, alternatively from 3 to 8, or from 4 to 8; and R ¹ moieties are independently selected from C1-C22 alkyl or C1-C30 alkoxy, linear or branched, cyclic or acyclic, saturated or unsaturated, substituted or unsubstituted.

In one embodiment, the R ¹ moieties comprise linear alkyl or alkoxy moieties having independently selected and varying chain length. For example, R ¹ may comprise a mixture of linear alkyl or alkoxy moieties wherein greater than about 20% of the linear chains are C ₁₈, alternatively greater than about 50% of the linear chains are C ₁₈, alternatively greater than about 80% of the linear chains are C ₁₈.

In another embodiment, the R ¹ moieties comprise a mixture of saturate and unsaturated alkyl or alkoxy moieties; the degree of unsaturation can be measured by "Iodine Value" (hereinafter referred as "IV", as measured by the standard AOCS method). The IV of the sucrose esters suitable for use herein ranges from about 1 to about 150, or from about 2 to about 100, or from about 5 to about 85. The R ¹ moieties may be hydrogenated to reduce the degree of unsaturation. In the case where a higher IV is preferred, such as from about 40 to about 95, then oleic acid and fatty acids derived from soybean oil and canola oil are the starting materials.

In a further embodiment, the unsaturated R ¹ moieties may comprise a mixture of "cis" and

"trans" forms about the unsaturated sites. The "cis" / "trans" ratios may range from about 1: 1 to about 50:1, or from about 2:1 to about 40:1, or from about 3:1 to about 30:1, or from about 4:1 to about 20:1.

Dispersible Polyolefins

Generally, all dispersible polyolefins that provide fabric care benefits can be used as water insoluble fabric care benefit agents in the present invention. The polyolefins can be in the format of waxes, emulsions, dispersions or suspensions. Non-limiting examples are discussed below.

In one embodiment, the polyolefin is chosen from a polyethylene, polypropylene, or a combination thereof. The polyolefin may be at least partially modified to contain various functional groups, such as carboxyl, alkylamide, sulfonic acid or amide groups. In another embodiment, the polyolefin is at least partially carboxyl modified or, in other words, oxidized.

For ease of formulation, the dispersible polyolefin may be introduced as a suspension or an emulsion of polyolefin dispersed by use of an emulsifying agent. The polyolefin suspension or emulsion may comprise from about 1% to about 60%, alternatively from about 10% to about 55%, alternatively from about 20% to about 50% by weight of polyolefin. The polyolefin may have a wax dropping point (see ASTM D3954- 94, volume 15.04— "Standard Test Method for Dropping Point of Waxes") from about 20° to about 170°C, alternatively from about 50° to about 140°C. Suitable polyethylene waxes are available commercially from suppliers including but not limited to Honeywell (A-C polyethylene), Clariant (Velustrol ^® emulsion), and BASF (LUWAX ^®).

When an emulsion is employed with the dispersible polyolefin, the emulsifier may be any suitable emulsification agent. Non-limiting examples include an anionic, cationic, nonionic surfactant, or a combination thereof. However, almost any suitable surfactant or suspending agent may be employed as the emulsification agent. The dispersible polyolefin is dispersed by use of an emulsification agent in a ratio to polyolefin wax of about 1:100 to about 1:2, alternatively from about 1:50 to about 1:5, respectively.

Polymer Latexes

Polymer latex is made by an emulsion polymerization which includes one or more monomers, one or more emulsifiers, an initiator, and other components familiar to those of ordinary skill in the art. Generally, all polymer latexes that provide fabric care benefits can be used as water insoluble fabric care benefit agents of the present invention. Additional non- limiting examples include the monomers used in producing polymer latexes such as: (1) 100% or pure butylacrylate; (2) butylacrylate and butadiene mixtures with at least 20% (weight monomer ratio) of butylacrylate; (3) butylacrylate and less than 20% (weight monomer ratio) of other monomers excluding butadiene; (4) alkylacrylate with an alkyl carbon chain at or greater than C ₆; (5) alkylacrylate with an alkyl carbon chain at or greater than C ₆ and less than 50% (weight monomer ratio) of other monomers; (6) a third monomer (less than 20% weight monomer ratio) added into an aforementioned monomer systems; and (7) combinations thereof.

Polymer latexes that are suitable fabric care benefit agents in the present invention may include those having a glass transition temperature of from about -120°C to about 120°C, alternatively from about -80°C to about 60°C. Suitable emulsifiers include anionic, cationic, nonionic and amphoteric surfactants. Suitable initiators include initiators that are suitable for emulsion polymerization of polymer latexes. The particle size diameter (xso) of the polymer latexes can be from about 1 nm to about 10 μιη, alternatively from about 10 nm to about 1 μιη, or even from about 10 nm to about 20 nm. Fatty Acid

One aspect of the invention provides a fabric softening composition comprising a fatty acid, such as a free fatty acid. The term "fatty acid" is used herein in the broadest sense to include unprotonated or protonated forms of a fatty acid; and includes fatty acid that is bound or unbound to another chemical moiety as well as the various combinations of these species of fatty acid. One skilled in the art will readily appreciate that the pH of an aqueous composition will dictate, in part, whether a fatty acid is protonated or unprotonated. In another embodiment, the fatty acid is in its unprotonated, or salt form, together with a counter ion, such as, but not limited to, calcium, magnesium, sodium, potassium and the like. The term "free fatty acid" means a fatty acid that is not bound to another chemical moiety (covalently or otherwise) to another chemical moiety.

In one embodiment, the fatty acid may include those containing from about 12 to about 25, from about 13 to about 22, or even from about 16 to about 20, total carbon atoms, with the fatty moiety containing from about 10 to about 22, from about 12 to about 18, or even from about 14 (mid-cut) to about 18 carbon atoms.

The fatty acids of the present invention may be derived from (1) an animal fat, and/or a partially hydrogenated animal fat, such as beef tallow, lard, etc.; (2) a vegetable oil, and/or a partially hydrogenated vegetable oil such as canola oil, safflower oil, peanut oil, sunflower oil, sesame seed oil, rapeseed oil, cottonseed oil, corn oil, soybean oil, tall oil, rice bran oil, palm oil, palm kernel oil, coconut oil, other tropical palm oils, linseed oil, tung oil, etc.; (3) processed and/or bodied oils, such as linseed oil or tung oil via thermal, pressure, alkali-isomerization and catalytic treatments; (4) a mixture thereof, to yield saturated (e.g. stearic acid), unsaturated (e.g. oleic acid), polyunsaturated (linoleic acid), branched (e.g. isostearic acid) or cyclic (e.g. saturated or unsaturated oc-disubstituted cyclopentyl or cyclohexyl derivatives of polyunsaturated acids) fatty acids.

Mixtures of fatty acids from different fat sources can be used.

In one aspect, at least a majority of the fatty acid that is present in the fabric softening composition of the present invention is unsaturated, e.g., from about 40% to 100%, from about 55% to about 99%, or even from about 60% to about 98%, by weight of the total weight of the fatty acid present in the composition, although fully saturated and partially saturated fatty acids can be used. As such, the total level of polyunsaturated fatty acids (TPU) of the total fatty acid of the inventive composition may be from about 0% to about 75% by weight of the total weight of the fatty acid present in the composition.

The cis/trans ratio for the unsaturated fatty acids may be important, with the cis/trans ratio

(of the C18:l material) being from at least about 1:1, at least about 3:1, from about 4: lor even from about 9:1 or higher.

Branched fatty acids such as isostearic acid are also suitable since they may be more stable with respect to oxidation and the resulting degradation of color and odor quality.

The Iodine Value or "IV" measures the degree of unsaturation in the fatty acid. In one embodiment of the invention, the fatty acid has an IV from about 10 to about 140, from about 15 to about 100 or even from about 15 to about 60. Another class of fatty ester fabric care actives is softening oils, which include but are not limited to, vegetable oils (such as soybean, sunflower, and canola), hydrocarbon based oils (natural and synthetic petroleum lubricants, in one aspect polyolefins, isoparaffins, and cyclic paraffins), triolein, fatty esters, fatty alcohols, fatty amines, fatty amides, and fatty ester amines. Oils can be combined with fatty acid softening agents, clays, and silicones.

Clays

In one embodiment of the invention, the fabric care composition may comprise a clay as a fabric care active. In one embodiment clay can be a softener or co-softeners with another softening active, for example, silicone. Suitable clays include those materials classified geologically smectites.

Silicone

In one embodiment, the fabric softening composition comprises a silicone. Suitable levels of silicone may comprise from about 0.1% to about 70%, alternatively from about 0.3% to about 40%, alternatively from about 0.5% to about 30%, alternatively from about 1% to about 20% by weight of the composition. Useful silicones can be any silicone comprising compound. In one embodiment, the silicone polymer is selected from the group consisting of cyclic silicones, polydimethylsiloxanes, aminosilicones, cationic silicones, silicone polyethers, silicone resins, silicone urethanes, and mixtures thereof. In one embodiment, the silicone is a polydialkylsilicone, alternatively a polydimethyl silicone (polydimethyl siloxane or "PDMS"), or a derivative thereof. In another embodiment, the silicone is chosen from an aminofunctional silicone, amino-polyether silicone, alkyloxylated silicone, cationic silicone, ethoxylated silicone, propoxylated silicone, ethoxylated/propoxylated silicone, quaternary silicone, or combinations thereof.

In another embodiment, the silicone may be chosen from a random or blocky organosilicone polymer having the following formula:

[R ₁R ₂R3Si0 _1/2] _(j+2)[(R4Si(X-Z)0 _2/2] _k[R4R4Si0 _2/2] _m[R ₄Si03/ ₂]j wherein: j is an integer from 0 to about 98; in one aspect j is an integer from 0 to about 48; in one aspect, j is 0; is an integer from 0 to about 200, in one aspect k is an integer from 0 to about 50; when k = 0, at least one of Ri _, R ₂ or R3 is -X— Z;

is an integer from 4 to about 5,000; in one aspect m is an integer from about 10 to about 4,000; in another aspect m is an integer from about 50 to about 2,000;

Ri, R ₂ and R3 are each independently selected from the group consisting of H, OH, Ci-C ₃₂ alkyl, C C ₃₂ substituted alkyl, C ₅-C ₃₂ or C ₆-C ₃₂ aryl, C ₅- C ₃₂ or C ₆-C ₃₂ substituted aryl, C ₆-C ₃₂ alkylaryl, C ₆-C ₃₂ substituted alkylaryl, Ci-C ₃₂ alkoxy, Ci-C ₃₂ substituted alkoxy and X-Z;

each R ₄ is independently selected from the group consisting of H, OH, Q- C ₃₂ alkyl, Ci-C ₃₂ substituted alkyl, Cs-C ₃₂ or C ₆-C ₃₂ aryl, Cs-C ₃₂ or C ₆-C ₃₂ substituted aryl, C ₆-C ₃₂ alkylaryl, C ₆-C ₃₂ substituted alkylaryl, Ci-C ₃₂ alkoxy and C]-C ₃₂ substituted alkoxy;

each X in said alkyl siloxane polymer comprises a substituted or unsubsitituted divalent alkylene radical comprising 2-12 carbon atoms, in one aspect each divalent alkylene radical is independently selected from the group consisting of -(CH ₂) _S- wherein s is an integer from about 2 to about 8, from about 2 to about 4; in one aspect, each X in said alkyl siloxane polymer comprises a substituted divalent alkylene radical selected from the group consisting of: -CH ₂-CH(OH)-CH ₂-; -CH ₂-CH ₂-CH(OH)-

CH ₃

; and ^CH2 CH CH ₂ ·

each Z is selected independently from the group consisting of Q ₅

+1 Q Q

n + 1

-N-Q (A ^n") _1/n Q Q —N-X-N-Q 2(A ⁿ-)i _/n

I I Q N— X— N- Q Q

- and

with the proviso that when Z is a quat, Q cannot be an amide, imine, or urea moiety and if Q is an amide, imine, or urea moiety, then any additional Q bonded to the same nitrogen as said amide, imine, or urea moiety must be H or a Ci-C ₆ alkyl, in one aspect, said additional Q is H; for Z A ^n" is a suitable charge balancing anion. In one aspect A ^n" is selected from the group consisting of CI ^", ΒΓ ,Γ, methylsulfate, toluene sulfonate, carboxylate and phosphate; and at least one Q in said organosilicone is independently selected from

each additional Q in said organosilicone is independently selected from the group comprising of H, Ci-C ₃₂ alkyl, Ci-C ₃₂ substituted alkyl, Cs-C ₃₂ or C ₆- C ₃₂ aryl, Cs-C ₃₂ or C ₆-C ₃₂ substituted aryl, -C ₃₂ alkylaryl, C ₆-C ₃₂ substituted alkylaryl, -CH ₂-CH(OH)-CH ₂-R ₅;

—

⁰ S

/ ^R5 ⁵ ° II — P II— o R ₅ N " .. M II

= — P-R ₅ I — P- ₅ — S-R ₅

R I O R, I

⁵ : s : ; 5 : O οτ CHoOT

f I \ Y ^{12 J±} OT

-CH ₂— CH-CH ₂-0 -R ₅ , I I

v . - CH CH ₉— ° ^")Τ~ ^R5- — CH ₂— CH-

CH OT

and ^{CH CH}2 ^R5

wherein each R5 is independently selected from the group consisting of H,

C1-C32 alkyl, C1-C32 substituted alkyl, C5-C32 or C6-C32 aryl, C5-C32 or C ₆-

C ₃2 substituted aryl, C6-C ₃2 alkylaryl, C6-C ₃2 substituted alkylaryl, -(CHR ₆-

CHR ₆-0-) _w-L and a siloxyl residue;

each R ₆ is independently selected from H, Ci-Cis alkyl each L is independently selected from -C(0)-R ₇ or

R ₇;

w is an integer from 0 to about 500, in one aspect w is an integer from about 1 to about 200; in one aspect w is an integer from about 1 to about 50;

each R7 is selected independently from the group consisting of H; C1-C ₃2 alkyl; C1-C32 substituted alkyl, C5-C32 or C6-C32 aryl, C5-C32 or C6-C32 substituted aryl, C6-C ₃2 alkylaryl; C6-C ₃2 substituted alkylaryl and a siloxyl residue;

each T is independently selected from H, and 2_ _{R5 AND}

wherein each v in said organosilicone is an integer from 1 to about 10, in one aspect, v is an integer from 1 to about 5 and the sum of all v indices in each Q in the said organosilicone is an integer from 1 to about 30 or from 1 to about 20 or even from 1 to about 10.

In another embodiment, the silicone may be chosen from a random or blocky organosilicone polymer having the following formula:

[R ₁R2R3Si0 _1/2]( _j+2)[(R4Si(X-Z)02/2]k[R4R4Si0 ₂/2]m[R4Si03/2]j wherein j is an integer from 0 to about 98; in one aspect j is an integer from 0 to about 48; in one aspect, j is 0;

is an integer from 0 to about 200; when k = 0, at least one of Ri _, R ₂ or R ₃= -X-Z, in one aspect, k is an integer from 0 to about 50 m is an integer from 4 to about 5,000; in one aspect m is an integer from about 10 to about 4,000; in another aspect m is an integer from about 50 to about 2,000;

Ri, R ₂ and R ₃ are each independently selected from the group consisting of H, OH, Ci-C3 ₂ alkyl, Ci-C3 ₂ substituted alkyl, Cs-C3 ₂ or C ₆-C ₃₂ aryl, Cs-C3 ₂ or C ₆-C ₃₂ substituted aryl, C ₆-C ₃₂ alkylaryl, C ₆-C ₃₂ substituted alkylaryl, Ci-C3 ₂ alkoxy, Ci-C3 ₂ substituted alkoxy and X-Z;

each R ₄ is independently selected from the group consisting of H, OH, C C ₃₂ alkyl, C C ₃₂ substituted alkyl, C ₅-C ₃₂ or C ₆-C ₃₂ aryl, C5-C3 ₂ or C ₆-C ₃₂ substituted aryl, C ₆-C ₃₂ alkylaryl, C ₆-C ₃₂ substituted alkylaryl, Ci-C ₃₂ alkoxy and Ci-C3 ₂ substituted alkoxy; each X comprises of a substituted or unsubstituted divalent alkylene radical comprising 2-12 carbon atoms; in one aspect each X is independently selected from the group consisting of -(CH ₂) _S-

-; CH ₂-CH-CH ₂ wherein each s independently is an integer from about 2 to about 8, in one aspect s is an integer from about 2 to about 4;

At least one Z in the said organosiloxane is selected from the group

OT CH ₂OT O

— CH ₂— CH-CH ₂-R _5; CH— CH ₂— R _{5 ;}

O II

— S- R ₅

II ⁵

O provided that when

-N— R, wherein A ^" is a suitable charge balancing anion. In one aspect A ^" is selected from the group consisting of CI ^", Br ^",

Γ, methylsulfate, toluene sulfonate, carboxylate and phosphate and each additional Z in said organosilicone is independently selected

10 from the group comprising of H, C1-C32 alkyl, C1-C32 substituted alkyl, C5-C32 or C6-C32 aryl, C5-C32 or C6-C32 substituted aryl, C ₆- C32 alkylaryl, C6-C32 substituted alkylaryl, R ₅,

O Rs O O H o

II I II -OR ₅

15 — C— CH-C-R5; -C N R ₅ -

C(R ₅) ₂0-R ₅— C(R ₅) ₂S-R _{5 and} provided that when

— N— R ₅ each R5 is independently selected from the group consisting of H; C - C32 alkyl; C1-C32 substituted alkyl, C5-C32 or C6-C32 aryl, C5-C32 or C6-C ₃2 substituted aryl or C6-C ₃2 alkylaryl, or C6-C ₃2 substituted alkylaryl,

-(CHR ₆-CHR6-0-) _w-CHR6-CHR ₆-L and siloxyl residue wherein each L is independently -0-C(0)-R7 or -O-R7;

N— R _{7 ;} H H and

w is an integer from 0 to about 500, in one aspect w is an integer from 0 to about 200, one aspect w is an integer from 0 to about 50; each R ₆ is independently selected from H or Ci-Cis alkyl;

each R7 is independently selected from the group consisting of H; Cr

C32 alkyl; C1-C32 substituted alkyl, C5-C32 or C6-C32 aryl, C5-C32 or C6-C ₃2 substituted aryl, C6-C ₃2 alkylaryl, and C6-C ₃2 substituted aryl, and a siloxyl residue;

each T is independently selected from H;

wherein each v in said organosilicone is an integer from 1 to about 10, in one aspect, v is an integer from 1 to about 5 and the sum of all v indices in each Z in the said organosilicone is an integer from 1 to about 30 or from 1 to about 20 or even from 1 to about 10.

In one embodiment, the silicone is one comprising a relatively high molecular weight. A suitable way to describe the molecular weight of a silicone includes describing its viscosity. A high molecular weight silicone is one having a viscosity of from about 10 cSt to about 3,000,000 cSt, or from aboutlOO cSt to about 1,000,000 cSt, or from about 1,000 cSt to about 600,000 cSt, or even from about 6,000 cSt to about 300,000 cSt. In one embodiment, the silicone comprises a blocky cationic organopolysiloxane having the formula:

M _wD _xT _yQ _z

wherein:

M = [S1R1R2R3O1/2], [S1R1R2G1O1/2], [S1R1G1G2O1/2], [S1G1G2G3O1/2], or combinations thereof; D = [S1R1R2O2/2], [S1R1G1O2/2], [S1G1G2O2/2] or combinations thereof;

T = [S1R1O _3/2], [S1G1O _3/2] or combinations thereof;

Q = [Si0 _{4 2}]; w = is an integer from 1 to (2+y+2z);

x = is an integer from 5 to 15,000;

y = is an integer from 0 to 98;

z = is an integer from 0 to 98;

Ri, R2 and R ₃ are each independently selected from the group consisting of H, OH, C1-C ₃2 alkyl, C1-C ₃2 substituted alkyl, C5-C ₃2 or C6-C ₃2 aryl, C5-C ₃2 or C6-C ₃2 substituted aryl, C6-C ₃2 alkylaryl, C6-C ₃2 substituted alkylaryl, C1-C ₃2 alkoxy, C1-C ₃2 substituted alkoxy, C1-C ₃2 alkylamino, and C1-C ₃2 substituted alkylamino; at least one of M, D, or T incorporates at least one moiety Gi, G2 or G _3; and Gi, G2, and G ₃ are each independently selected from the formula:

wherein:

X comprises a divalent radical selected from the group consisting of C1-C ₃2 alkylene, C1-C ₃2 substituted alkylene, C5-C ₃2 or C6-C ₃2 arylene, C5-C ₃2 or C6-C ₃2 substituted arylene, C6-C ₃2 arylalkylene, C6-C ₃2 substituted arylalkylene, C1-C ₃2 alkoxy, C1-C ₃2 substituted alkoxy, C1-C ₃2 alkyleneamino, C1-C ₃2 substituted alkyleneamino, ring-opened epoxide, and ring-opened glycidyl, with the proviso that if X does not comprise a repeating alkylene oxide moiety then X can further comprise a heteroatom selected from the group consisting of P, N and O; each R ₄ comprises identical or different monovalent radicals selected from the group consisting of H, C1-C ₃2 alkyl, C1-C ₃2 substituted alkyl, C5-C ₃2 or C6-C ₃2 aryl, C5-C ₃2 or C6-C ₃2 substituted aryl, C6-C ₃2 alkylaryl, and C6-C ₃2 substituted alkylaryl;

E comprises a divalent radical selected from the group consisting of C1-C ₃2 alkylene, C1-C ₃2 substituted alkylene, C5-C ₃2 or C6-C ₃2 arylene, C5-C ₃2 or C6-C ₃2 substituted arylene, C6-C ₃2 arylalkylene, C6-C ₃2 substituted arylalkylene, C1-C ₃2 alkoxy, C1-C ₃2 substituted alkoxy, C1-C ₃2 alkyleneamino, C1-C ₃2 substituted alkyleneamino, ring-opened epoxide and ring-opened glycidyl, with the proviso that if E does not comprise a repeating alkylene oxide moiety then E can further comprise a heteroatom selected from the group consisting of P, N, and O; E' comprises a divalent radical selected from the group consisting of C1-C ₃2 alkylene, C1-C ₃2 substituted alkylene, C5-C ₃2 or C6-C ₃2 arylene, C5-C ₃2 or C6-C ₃2 substituted arylene, C6-C ₃2 arylalkylene, C6-C ₃2 substituted arylalkylene, C1-C ₃2 alkoxy, C1-C ₃2 substituted alkoxy, C1-C ₃2 alkyleneamino, C1-C ₃2 substituted alkyleneamino, ring-opened epoxide and ring-opened glycidyl, with the proviso that if E' does not comprise a repeating alkylene oxide moiety then E' can further comprise a heteroatom selected from the group consisting of P, N, and O; p is an integer independently selected from 1 to 50;

n is an integer independently selected from 1 or 2; when at least one of Gi, G2, or G ₃ is positively charged, A ^_t is a suitable charge balancing anion or anions such that the total charge, k, of the charge-balancing anion or anions is equal to and opposite from the net charge on the moiety Gi, G2 or G _3; wherein t is an integer independently selected from 1, 2, or 3; and k < (p*2/t) + 1; such that the total number of cationic charges balances the total number of anionic charges in the organopolysiloxane molecule;

and wherein at least one E does not comprise an ethylene moiety.

Method of Use

The compositions of the present invention may be used in any conventional manner. In short, they may be used in the same manner as products that are designed and produced by conventional methods and processes. For example, compositions of the present invention can be used to treat a situs inter alia a surface or fabric. Typically at least a portion of the situs is contacted with an aspect of Applicants' composition, in neat form or diluted in a wash liquor, and then the situs is optionally washed and/or rinsed. For purposes of the present invention, washing includes but is not limited to, scrubbing, and mechanical agitation. The fabric may comprise any fabric capable of being laundered in normal consumer use conditions. When the wash solvent is water, the water temperature typically ranges from about 5 °C to about 90 °C and, when the situs comprises a fabric, the water to fabric mass ratio is typically from about 1:1 to about 100:1.

The cleaning and/or treatment compositions of the present invention may be used as liquid fabric enhancers wherein they are applied to a fabric and the fabric is then dried via line drying and/or drying the an automatic dryer.

In one aspect, a method of controlling malodors comprising: contacting a situs comprising a malodor and/or a situs that will become malodorous with a cleaning and/or treatment composition selected from the group consisting of Applicants' cleaning and/or treatment compositions and mixtures thereof, is disclosed.

In one aspect of Applicants' method, said situs comprises a fabric and said contacting step comprises contacting said fabric with a sufficient amount of Applicants' cleaning and/or treatment compositions to provide said fabric with a level of malodor reduction material at least 0.0025 mg of malodor reduction material/kg of fabric, preferably from about 0.0025 mg of malodor reduction material/kg of fabric to about 50mg of malodor reduction material /kg of fabric, more preferably from about 0.25mg of malodor reduction material kg of fabric to about 25mg of malodor reduction material kg of fabric, most preferably from about 0.5 of malodor reduction material/kg of fabric to about lOmg of malodor reduction material/kg of fabric of said sum of malodor reduction materials.

TEST METHODS

Malodor reduction materials may be separated from mixtures, including but not limited to finished products such as consumer products and indentified, by analytical methods that include GC-MS and/or NMR.

Viscosity Test Method

Viscosity is measured using an AR 550 rheometer / viscometer from TA instruments (New Castle, DE, USA), using parallel steel plates of 40 mm diameter and a gap size of 500 μιη. The high shear viscosity at 20 s ^"1 is obtained from a logarithmic shear rate sweep from 0.1 s ^"1 to 25 s ^"1 in 3 minutes time at 21 °C.

Test Method for Determining Saturation Vapour Pressure (VP)

The saturation Vapour Pressure (VP) values are computed for each PRM in the perfume mixture being tested. The VP of an individual PRM is calculated using the VP Computational Model, version 14.02 (Linux) available from Advanced Chemistry Development Inc.

(ACD/Labs) (Toronto, Canada) to provide the VP value at 25 °C expressed in units of torr. The ACD/Labs' Vapor Pressure model is part of the ACD/Labs model suite. Test Method for Determining the Logarithm of the Octanol/Water Partition Coefficient (logP) The value of the log of the Octanol/Water Partition Coefficient (logP) is computed for each PRM in the perfume mixture being tested. The logP of an individual PRM is calculated using the Consensus logP Computational Model, version 14.02 (Linux) available from

Advanced Chemistry Development Inc. (ACD/Labs) (Toronto, Canada) to provide the unitless logP value. The ACD/Labs' Consensus logP Computational Model is part of the ACD/Labs model suite.

Test Method for the Generation of Molecular Descriptors

In order to conduct the calculations involved in the computed-value test methods described herein, the starting information required includes the identity, weight percent, and molar percent of each PRM in the perfume being tested, as a proportion of that perfume, wherein all PRMs in the perfume composition are included in the calculations. Additionally for each of those PRMs, the molecular structure, and the values of various computationally-derived molecular descriptors are also required, as determined in accordance with the Test Method for the Generation of Molecular Descriptors described herein.

For each PRM in a perfume mixture or composition, its molecular structure is used to compute various molecular descriptors. The molecular structure is determined by the graphic molecular structure representations provided by the Chemical Abstract Service ("CAS"), a division of the American Chemical Society, Columbus, Ohio, U.S.A.. These molecular structures may be obtained from the CAS Chemical Registry System database by looking up the index name or CAS number of each PRM. For PRMs, which at the time of their testing are not yet listed in the CAS Chemical Registry System database, other databases or information sources may be used to determine their structures. For a PRM which has potentially more than one isomer present, the molecular descriptor computations are conducted using the molecular structure of only one of the isomers, which is selected to represent that PRM. The selection of isomer is determined by the relative amount of extension in the molecular structures of the isomers. Of all the isomers of a given PRM, it is the isomer whose molecular structure that is the most prevalent which is the one that is selected to represent that PRM. The structures for other potential isomers of that PRM are excluded from the computations. The molecular structure of the isomer that is the most prevalent is paired with the concentration of that PRM, where the concentration reflects the presence of all the isomers of that PRM that are present.

A molecule editor or molecular sketching software program, such as ChemDraw (CambridgeSoft / PerkinElmer Inc., Waltham, Massachusetts, U.S.A.), is used to duplicate the 2- dimensional molecular structure representing each PRM. Molecular structures should be represented as neutral species (quaternary nitrogen atoms are allowed) with no disconnected fragments (e.g., single structures with no counter ions). The winMolconn program described below can convert any deprotonated functional groups to the neutral form by adding the appropriate number of hydrogen atoms and will discard the counter ion.

For each PRM, the molecular sketching software is used to generate a file which describes the molecular structure of the PRM. The file(s) describing the molecular structures of the PRMs is subsequently submitted to the computer software program winMolconn, version 1.0.1.3 (Hall Associates Consulting, Quincy, Massachusetts, U.S.A., www.molconn.com), in order to derive various molecular descriptors for each PRM. As such, it is the winMolconn software program which dictates the structure notations and file formats that are acceptable options. These options include either a MACCS SDF formatted file (i.e., a Structure-Data File); or a Simplified Molecular Input Line Entry Specification (i.e., a SMILES string structure line notation) which is commonly used within a simple text file, often with a ".smi" or ".txt" file name extension. The SDF file represents each molecular structure in the format of a multi-line record, while the syntax for a SMILES structure is a single line of text with no white space. A structure name or identifier can be added to the SMILES string by including it on the same line following the SMILES string and separated by a space, e.g.: C1=CC=CC=C1 benzene.

The winMolconn software program is used to generate numerous molecular descriptors for each PRM, which are then output in a table format. Specific molecular descriptors derived by winMolconn are subsequently used as inputs (i.e., as variable terms in mathematical equations) for a variety of computer model test methods in order to calculate values such as: saturation Vapour Pressure (VP); Boiling Point (BP); logarithm of the OctanolAVater Partition Coefficient (logP); Odour Detection Threshold (ODT); Malodour Reduction Value (MORV); and/or Universal Malodour Reduction Value (Universal MORV) for each PRM. The molecular descriptor labels used in the models' test method computations are the same labels reported by the winMolconn program, and their descriptions and definitions can be found listed in the winMolconn documentation. The following is a generic description of how to execute the winMolconn software program and generate the required molecular structure descriptors for each PRM in a composition.

Computing Molecular Structure Descriptors using winMolconn:

1) Assemble the molecular structure for one or more perfume ingredients in the form of a MACCS Structure-Data File, also called an SDF file, or as a SMILES file.

2) Using version 1.0.1.3 of the winMolconn program, running on an appropriate computer, compute the full complement of molecular descriptors that are available from the program, using the SDF or SMILES file described above as input.

a. The output of winMolconn is in the form of an ASCII text file, typically space delimited, containing the structure identifiers in the first column and respective molecular descriptors in the remaining columns for each structure in the input file.

3) Parse the text file into columns using a spreadsheet software program or some other appropriate technique. The molecular descriptor labels are found on the first row of the resulting table.

4) Find and extract the descriptor columns, identified by the molecular descriptor label, corresponding to the inputs required for each model.

a. Note that the winMolconn molecular descriptor labels are case-sensitive.

MORV and Universal MORV calculation

1.) Input Molecular Descriptor values as determined via the method above into the following four equations: a) MORV = -8.5096 + 2.8597x(dxp9) + 1.1253x(knotpv) - 0.34484x(elC2O2) - 0.0004623 lx(idw) + 3.3509x(idcbar) + 0.11158x(n2pag22) b) MORV = -5.2917 + 2.1741x(dxvp5) - 2.6595x(dxvp8) + 0.45297x(elC2C2d) - 0.6202x(clC2O2) + 1.3542x(CdCH2) + 0.68105x(CaasC) + 1.7129x(idcbar) c) MORV = -0.0035 + 0.8028x(SHCsatu) + 2.1673x(xvp7) - 1.3507x(clClC3d) + 0.61496x(clClO2) + 0.00403x(idc) - 0.23286x(nd2). d) MORV = -0.9926 - 0.03882x(SdO) + 0.1869x(Ssp3OH) + 2.1847x(xp7) + 0.34344x(elC3O2) - 0.45767x(clC2C3) + 0.7684x(CKetone)

Equation a) relates a material's effectiveness in reducing the malodor trans-3-methyl-2-hexenoic acid (carboxylic acid based malodors)

Equation b) relates a material's effectiveness in reducing the malodor trimethylamine (amine based malodors)

Equation c) relates a material's effectiveness in reducing the malodor 3-mercapto-3- methylhexan-l-ol (thiol based malodors)

Equation d) relates a material's effectiveness in reducing the malodor skatole (indole based malodors)

2. ) For purpose of the present application, a material's MORV is the highest MORV value from equations l.)a) through l.)d).

3. ) If all MORVvalues from equations l.)a) through l.)d) above are greater than 0.5, the subject material has a Universal MORV.

Method for assigning Fragrance Fidelity Index (FFI) and the Blocker Index (BI) for a Malodor Reduction Compound

Blocker materials suitable for use in cleaning and/or treatment compositions of the present invention are chosen for their ability to decrease malodor, while not interfering with perception of a fragrance. Material selection is done by assigning two indices to a test sample material from two reference scales in order to rank odor strengths. The two reference scales are the Fragrance Fidelity Index (FFI) scale and the Blocker Index (BI) scale. The FFI ranks the ability of the test sample material to impart a perceivable odor which could cause interference when combined with another fragrance and the BI ranks the ability of the test sample material to reduce malodor perception. The two methods for assigning the indices to a test sample on the FFI and the BI reference scales are given below.

Method for assigning the FFI to test samples The first step in the method for assigning an FFI to the test samples on the FFI reference scale is to create the FFI reference swatches. The swatches for the scale are created by treating clean fabrics swatches with a known amount of a known concentration of an ethyl vanillin solution. Fabric swatches for this test are white knit polycotton (4 inch X 4 inch) swatches from EMC ordered as PC 50/50. The supplier is instructed to strip the swatches first, stripping involves washing twice with a fragrance-free detergent and rinsing three times.

Making the FFI reference swatches

Make three solutions of ethyl vanillin using a 50%/ 50% EtOH/water as the diluent at the following concentrations: 25 ppm, 120 ppm and 1000 ppm. Pipette 13 μΕ of each of the three solutions into the middle of a clean swatch resulting in about a 1 cm diameter of the solution in the middle of the swatch. This will create a sensory scale of three swatches with three different odor levels based on the concentration of the solution pipetted onto the swatch. After drying for 30 minutes in a vented hood, the swatches are wrapped in aluminum foil to prevent odor contamination to the treated swatch. A clean untreated swatch is also included as the lowest anchor point of reference for odor strength on the FFI scale. The FFI reference scale swatches should be used within 0.5 to 12 hours and discarded after 12 hours. The swatches are used as scale anchor points when graders evaluate a test sample(s) and are assigned a Fragrance Fidelity Index (FFI) as show in Table 7.

At least four perfumers/ expert graders are used to rank the ethyl vanillin swatches in the FFI scale. The perfumer/ expert grader needs to demonstrate adequate discrimination on the scale. The perfumer/ expert panel is asked to rank order swatches according to a scale between 0 and 3. The panel must demonstrate statistical differences between the swatches as seen in Table 7.

Table 7 Results FFI of reference swatches from six perfumers/ expert graders.

FFI Swatch Expert Grader Ave Std Dev.

1 2 3 4 5 6

Control: stripped swatch NIL

0 0 0 0.5 0 0 0 0.08 0.2 ethyl vanillin

Stripped swatch with 13 μΕ 25

1 0.5 0.5 0.5 1.5 0.5 1.0 0.75 0.4 ppm ethyl vanillin

2 Stripped swatch with 13 μΕ 2.0 1.5 1.5 2.0 2.0 2.0 1.8 0.2 120 ppm ethyl vanillin

Stripped swatch with 13 μL·

3 3.0 2.0 3.0 3.0 3.0 3.0 2.8 0.4 1000 ppm ethyl vanillin

The expert graders must demonstrate a full range of 2.5 over the 4 swatches to be acceptably discriminating. Grader 2 in table 1 has a range of only 2 and is eliminated from the panel. The panel of expert graders must also demonstrated the ability to statistically discriminate between swatches in the scale.

Table 8 This table demonstrates acceptable expert graders with an acceptable range and the panel meets the requirement for discriminating statistics.

The reference swatches represent the 0, 1, 2, and 3 FFIs on the FFI reference scale, Table 9. The expert grader should familiarize them self with the strength of the odor on the FFI reference swatches by sniffing each one starting at 0 (the lowest odor strength) and ending at 3 (the highest odor strength). This should be done prior to evaluating the test sample material treated swatch. Table 9 Swatch treatments comprising the Fragrance Fidelity Index (FFI) reference scale

Swatch treatment Cone, of ethyl vanillin FFI

Clean fabric swatch w/ 13 μL· ethyl vanillin 1000 ppm ethyl vanillin 3

Clean fabric swatch w/ 13 μL· ethyl vanillin 120 ppm ethyl vanillin 2

Clean fabric swatch w/ 13 μL· ethyl vanillin 25 ppm ethyl vanillin 1

Clean fabric swatch NIL ethyl vanillin NIL ethyl vanillin 0 Making swatches treated with the test material

A clean swatch is treated with 13 of a known concentration of a test sample material resulting in an about 1 cm of the solution on the clean swatch. Just like the reference swatches, the test sample material swatch is dried in a vented hood for 30 minutes and then wrapped in aluminum foil to prevent contamination. The test material swatches and the FFI reference swatches should be made within 2 hrs of each other. The test material swatch must be used within 0.5 to 12 hours and discarded after 12 hours.

Assigning the FFI to the test material

At least two perfumers/ expert graders are used to assign an FFI grade to a test sample. The perfumer/ expert grader smells the test sample swatch by holding that swatch 1 inch from their nose with their nose centered over the area where the test sample was pipetted on to the fabric and then assigns the test sample an FFI grade using the FFI reference scale anchor swatches as references. The test sample swatch is assigned an FFI grade at or between numbers on the FFI scale shown in Table 9. In cases where the test sample material is graded greater than 3, the test material is not a blocker material or the concentration of the material needs to be lowered and reevaluated to determine if a lower level has a malodor blocker functionality.

Method for assigning the BI to test sample

The first step in the method for assigning a BI to a test sample material on the BI reference scale is to create the BI reference swatches. The swatches for the scale are created by treating clean fabrics swatches with a known amount of a known volume of isovaleric acid solution at a known concentration. Fabric swatches for this test are white knit polycotton (4 inch X 4 inch) swatches from EMC ordered as PC 50/50. The supplier is instructed to strip the swatches first, stripping involves washing twice with a fragrance-free detergent and rinsing three times.

Making the BI reference swatches

Make one solution of 0.08% isovaleric acid using 50%/ 50% EtOH/water as the diluent. The BI scale contains one clean swatch with no malodor applied. Three other swatches each have a different volume of the 0.08% isovaleric acid applied. Pipette 2 μΕ of the 0.08% isovaleric acid solution to one clean swatch, 5 μΕ of the 0.08% isovaleric acid solution to the next swatch and 20 μΕ of isovaleric acid to the final clean swatch. These solutions are pipetted to the middle of the swatches. This will create a sensory scale of three swatches with three different odor levels based on the volume of the 0.08% isovaleric acid solution pipetted onto the swatch. After drying for 30 minutes in a vented hood, the swatches are wrapped in aluminum foil to prevent odor contamination to the treated swatch. A clean untreated swatch is also included as the lowest anchor point of reference for malodor strength on the BI scale. The BI reference scale swatches should be used within 0.5 to 12 hours and discarded after 12 hours. The swatches are used as scale anchor points when graders evaluate a test sample(s) and are assigned a Blocker Index (BI) as show in Table 12.

At least four perfumers/ expert graders are used to rank the isovaleric acid swatches in the BI scale. The perfumer/ expert grader needs to demonstrate adequate discrimination on the scale. The perfumer/ expert grader is asked to rank order swatches according to a scale between 0 and 3. The panel of graders must demonstrate statistical differences between the swatches as seen in Table 10. Table 10 Results from six perfumers/ expert graders to create the BI scale.

The expert graders must demonstrate a full range of 2.5 over the 4 swatches to be acceptably discriminating. The panel of expert graders must also demonstrated the ability to statistically discriminate between swatches in the scale. Expert grader #2 did not demonstrate the ability to discriminate between the swatches and is eliminated from the panel, see Table 11.

Table 11 This table demonstrates acceptable expert graders with an acceptable range and the panel meets the requirement for discriminating statistics. BI Swatch Expert Grader Ave Std Dev.

1 3 4 5

Control: stripped swatch NIL isovaleric

0 0 0 0 0 0 0 acid

Stripped swatch with 2 μΐ. 0.08%

1 0.5 1.0 1.0 0.5 0.8 0.3 isovaleric acid

Stripped swatch with 5 μL· 0.08%

2 2.0 2.0 2.0 2.0 2.0 0 isovaleric acid

Stripped swatch with 20 μΐ. 0.08%

3 3.0 3.0 3.0 2.5 2.9 0.2 isovaleric acid

The reference swatches represent the 0, 1, 2, and 3 Bis on the BI reference scale, Table 12. The expert grader should familiarizes him/herself with the strength of the odor on the BI reference swatches by sniffing each one starting at 0 (the lowest odor strength) and ending at 3 (the highest odor strength). This should be done prior to evaluating the swatch treated with the test material.

Table 12 Swatch treatments comprising the Blocker Index (BI) reference scale.

To evaluate the BI, the test material is applied to a malodorous swatch to determine how well the test material blocks the malodor. The malodorous swatch is made by treating a clean swatch with 20 μL· of a 0.08% solution of isovaleric acid. Dry the malodorous swatch treated with isovaleric acid in a vented hood for 30 minutes. After drying the malodorous swatch a known concentration of test material solution, between 1 ppm and 100 ppm is pipetted onto the malodorous swatch. Apply the test material solution right on top of the spot where the isovaleric acid solution was applied making an about 1 cm diameter spot. Just like the BI reference swatches, the isovaleric acid + test material swatch is dried in a vented hood for 30 minutes and then wrapped in aluminum foil to prevent contamination. The isovaleric acid + test material swatches and the BI reference swatches should be made within 2 hours of each other. The isovaleric acid + test material swatch must be used between 1-12 hours just like the reference swatches. It is sometimes necessary to evaluate several levels of the test material between about 1 and about 100 ppm to determine the BI. Assigning the BI to the test material

At least two perfumers/ expert graders are used to assign the BI to the test sample. The expert grader smells the isovaleric acid + test material swatch by holding that swatch one inch from their nose with their nose centered over the area where the test sample was pipetted on to the fabric and then assigns the isovaleric acid + test material swatch a BI based on ranking its odor strength against the odor strength of the swatches in the BI reference scale. The test sample swatch is assigned a BI at or between numbers on the BI in table. In cases where the isovaleric acid + test material swatch odor is greater than 3 on the BI reference scale, this indicates the material is not a blocker or the concentration of the test material needs to be lowered to achieve its blocker functionality.

Malodor Reduction Compounds with FFI and BI Grades based on the aforementioned

Table

CAS# log P Name Cone FFI BI Ref #

3a,4,5,6,7,7a- hexahydro-4,7- 10 ppm 0 2.0

54830-99-8

281 3.11 methano-lH-indenyl acetate 50 ppm 0.5 2.0

10 ppm 0 2.3

677 139504-68-0 3.75 l-((2-(tert-

50 ppm 1.8 2.0 butyl)cyclohexyl)oxy)butan-2-ol

10 ppm 0 2.3

962 55066-48-3 3-methyl-5-phenylpentan- l-ol

3.17 50 ppm 0.5 1.7

3 -(3 ,3 -dimethyl-2,3 -dihydro- 1 H- 10 ppm 0 1.8

261 173445-65-3

3.29 inden-5-yl)propanal 50 ppm 1.3 1.3

(Z)-cyclooct-4-en-l-yl methyl 10 ppm 0 2.0

1139 87731-18-8

2.11 carbonate 50 ppm 1.0 2.7

3,4,4a,5, 6,7,8, 8a-octahydrochromen- 10 ppm 0 2.0

4430-31-3

1.43 2-one 50 ppm 0 2.0

10 ppm 0 2.0

204 40379-24-6 3.89 7-methyloctyl acetate

50 ppm 0 2.7 ethyl (2,3,6-trimethylcyclohexyl)

1005 93981-50-1 50 ppm 0.5 2.6

5.59 carbonate

391 106-33-2 5.73 Ethyl laurate 50 ppm 0.3 2.2

1148 1139-30-6 4.06 Caryophyllene Oxide 50 ppm 0.5 2.3

13877-91-3 3,7-Dimethyl-l,3,6-Octatriene(cis-

524 50 ppm 0 2.8

3338-55-4 4.31 ocimene 70%)

1, 3,4,6,7, 8alpha- hexahydro- 10 ppm 0 1.5

1149 23787-90-8 1 , l,5,5-tetramethyl-2H-2,4alpha-

50 ppm 0.8 2.3

4 methanophtalen-8(5H)-one

112-42-5 4.62 Undecanol 50 ppm 0.8 2.3

174 112-53-8 5.17 1-dodecanol 50 ppm 0.5 2.3

10 ppm 0 2.0

98-52-2 4-tert-butyl cyclohexane

2.78 50 ppm 0.3 2.0

109 112-39-0 6.41 Methyl palmitate 10 ppm 2.0

Malodor control compounds with improved performance at lower levels.

Below are some non-limiting examples of preferred behavior by which the malodor control compound gives improved malodor control at lower concentration. These nonlimiting data

provide additional compelling data that malodor is being blocked, not masked.

Retesting malodor reduction compounds at lower levels.

The example below demonstrates that while a malodor control compound could fail to

demonstrate odor blocking (BI > 2.5) at a higher concentration it should be retested at a

concentration to determine if it passes.

Table CAS # Name Cone FFI BI Ref #

10 ppm 0 1.5

N/A 173445-65-3 lH-Indene-5-propanal, 2,3-dihydro-3,3-dimethyl-

50 ppm 0.5 2.7

Example 1 Compositions comprising malodor reduction compounds.

In the present invention blends enable more potent malodor reduction because blends are useful at a higher % of the product composition before becoming olfactively noticeable. Below are non-limiting examples of malodor reduction compounds.

Component CAS# % wt Active

A B C D E

2,2,8,8-tetramethyl-octahydro-lH-

29461-14-1 35-45 15-25 5-20 10 -30 15-25 2,4a-methanonapthalene-10-one

lH-Indene-ar-propanal,2,3-

300371-33-9 10-20 1-30 NIL 5 - 10 1-5 dihydro- 1 , 1 -dimethyl-

Hexadecanoic acid, (2E)-3,7-

35-45 10-25 NIL 30 -40 35-50 dimethyl-2,6-octadien-l-yl ester 3681-73-0

l-Pentanol-3-methyl-5-phenyl 55066-48-3 10-20 10-25 2-10 5 - 17 10

4,7-Methano- lH-inden-5-ol, 171102-41-3

0-5 10-25 NIL 1 - 6 1-5 3a,4,5,6,7,7a-hexahydro-, 5-acetate

4,8 -dimethyl- 1 -(methylethyl) -7 -

N/A 0-5 NIL NIL NIL 1-5 oxybiciclo [4.3.0]nonane

(3Z)-3,7-dimethylocta-l,3,6-triene 3338-55-4 NIL NIL 10-20 2 -5 NIL lH-Indene-5-propanal, 2,3- 7.5 -

173445-65-3 NIL NIL NIL 1-15 dihydro-3,3-dimethyl- 16

3,4,4a,5,6,7,8,8a-

4430-31-3 NIL NIL NIL 3 - 7 1-15 octahydrochromen-2-one

l-(2-tert- 0.25 -

139504-68-0 NIL NIL NIL NIL butylcyclohexyl)oxybutan-2-ol 1.5

ethyl (2,3, 6- trimethy lcyclohexyl)

93981-50-1 NIL NIL 15 - 30 NIL 2 carbonate

benzyl 2-hydroxypropanoate 2051-96-9 NIL NIL 2-5 NIL NIL (3,5-dimethylcyclohex-3-en-l-

67634-16-6 NIL NIL 5-30 NIL NIL yl)methanol

2-Dodecanol 10203-28-8 NIL 0.25-1 NIL 0.5-3 NIL

EXAMPLE 2 Compositions comprising malodor reduction compounds.

% wt Active

Ingredient CAS # A B C B D E

(E)-l-(2,6,6-trimethyl-l- cyclohex-2-enyl)pent- 1 -en-3 - 127-42-4 4 8 2 8 3 2 one ethyl dodecanoate 106-33-2 NIL 1 NIL 3 NIL NIL

3a,4,5,6,7,7a-hexahydro-lH- 4,7-methanoinden- 1 -yl 68912-13-0 8 30 1 4 1 3.5 propanoate

[1R-(1R*,4R*,6R*,10S*)]-

4,12,12-trimethyl-9- methylene-5- 1139-30-6 NIL 0.3 2 0.5 NIL 0.5 oxatricyclo[8.2.0.04,6]dodeca

(8E)-cyclohexadec-8-en- 1 -one 3100-36-5 NIL 5 NIL 7 NIL NIL

3,5,5-trimethylhexyl acetate 58430-94-7 25 15 50 35 60 56 ethyl (2,3,6- trimethylcyclohexyl) 93981-50-1 NIL 1 NIL 5 NIL NIL carbonate 2,4-dimethyl-4,4a,5,9b- tetrahydroindeno[ 1 ,2- 27606-09-3 25 10 15 15 16 15 d][l,3]dioxine

2,2,7,7- tetramethyltricyclo[6.2.1.01,6] 23787-90-8 8 9 5 7 5 5 undecan-5-one

(3,5-dimethylcyclohex-3-en-

67634-16-6 NIL 0.7 NIL 0.5 NIL NIL l-yl)methanol

3-(7,7-dimethyl-4- bicyclo [3.1.1 ]hept-3-enyl)- 33885-52-8 30 20 25 15 15 18 2,2-dimethylpropanal

Total 100 100 100 100 100 100

EXAMPLE 3 Malodor reduction composition.

% wt Active

Ingredient CAS # A B c

5-Cyclohexadecen-l-One 37609-25-9 15.0 2.00 2.00 decahydro-2,2,7,7,8,9,9-

476332-65-7 0.005 0.01 0.01 heptamethylindeno(4, 3 a-b)furan

2,3-Dihydro-5,6-dimethoxy-2-(4-

33704-61-9 0.3 0.5 0.5 piperidinylmethylene)- IH-inden- 1 -one

Cedryl Methyl Ether 19870-74-7 6.0 10.0 4.0

Trans-4-Decenal 65405-70-1 0.005 0.002 0.002

Decyl Aldehyde 112-31-2 3.74 2.0 2.0

3- methyl cyclopentadecenone 63314-79-4 0.4 1.0 1.0

Diphenyl Oxide 101-84-8 0.5 1.0 1.0

3a,4, 5, 6,7,7a- hexahydro-4,7-methano-

54830-99-8 5.0 8.0 8.0 lH-indenyl acetate

3a,4,5,6,7,7a-hexahydro-lH-4,7-

68912-13-0 6.0 8.0 8.0 methanoinden-l-yl propanoate

2-(5-methyl-2-propan-2-yl-8- 68901-32-6 10.0 15.0 15.0 bicyclo[2.2.2]oct-5-enyl)-l,3-dioxolane

(E)-3,7-dimethyl-2,6-

3681-73-0 10.0 10.0 16.0 octadienylhexadecanoate

Iso Nonyl Acetate 58430-94-7 6.65 8.0 3.0

2,2,7,7- tetramethyltricyclo[6.2.1.01,6]undecan-5- 23787-90-8 10.0 8.0 8.0 one

(l-Methyl-2-( 1,2,2- trimethylbicyclo[3.1.0]-hex-3- 198404-98-7 0.1 0.3 0.3 ylmethyl)cyclopropyl)methanol

Laurie Aldehyde 112-54-9 0.625 1.0 0.7

Methyl Iso Eugenol 93-16-3 18.000 10.0 13.0

Methyl hexadecanoate 112-39-0 3.000 10.0 12.0

2,3-dihydro- 1,1- lH-dimethyl-indene-ar- 0.0

300371-33-9 0.400 0.3 propanal

4-tert-butylcyclohexanol 98-52-2 0.400 0.1 0.1

2-isobutyl-4-hydroxy-4-

63500-71-0 1.600 2.0 2.0 methyltetrahydropyran

Undecyl Aldehyde 112-44-7 1.725 2.888 1.888

Undecylenic Aldehyde 112-45-8 0.550 0.2 1.2

Total 100 100.0 100.0

EXAMPLE 4 Liquid Composition w/ Perfume and Malodor Control

An example of liquid composition for very light cleaning or additive to the laundry process is prepared with malodor reduction composition, according to the compositions shown in Example 3.

Ingredients % wt Active

Nonionic Surfactant (1) 0-10

Emulsifier (2) 0-10

Cationic surfactant 0-10

Anti-bac 0-5

Free (Neat) Perfume 0-10 Malodor reducing composition 0 - 0.5

Perfume (encapsulated) 0 - 10

Malodor Reducing Composition (encapsulated) 0 - 10

Perfume + malodor reducing composition (encapsulated) 0 - 10

Structurant 0 - 0.3

Aesthetics Dye 0.015

Water Balance

1. Alkyl ethoxylate with alkyl chain length between C8 and C18, preferably C12 to C16 and mixtures thereof with 3 to 12 ethoxylate groups, preferably 5 to 9.

2. Emulsifier description, including Cremophor, Basophor, Spans and Tweens, etc.

3. PMC is a friable PMC with a urea-formaldehyde shell from Appvion-Encapsys. About 50% water by weight of the PMC (including encapsulated perfume) is assumed.

4. Encapsulated perfume (within PMC) assumes about 32% active.

EXAMPLES 5 Liquid detergent compositions.

A HDL-Heavy Duty Liquid composition is prepared with malodor reduction composition, according to the compositions shown below. The exemplified space is meant to represent dilute to concentrated detergent products.

Ingredient % wt Active

Alkyl (ethoxy) sulfate (1) 0-30

Linear alkyl benzene sulfonic acid (2) 0-30

HSAS (3) 0-30

Nonionic Surfactant (4) 0-15

Amine Oxide 0-8

Citric Acid 0-10

Lactic Acid 0-10

C12-C1 ₈ Fatty Acid 0-5

Protease (55.3 mg/g) 0-3

Amylase (25.4mg/g) 0-2

Borax 0-5

Calcium Formate 0-0.5 Polyethyleneimine 600, EO20 (5) 0-5

Polyethyleneimine 600, E024, P016 (6) 0-5

DTP A (7) 0-5

Optical Brightener (8) 0-1

NaOH As needed

Na Cumene Sulfonate 0-5

Na Formate 0-1

MEA hydrogenated castor oil 0-0.5

Aesthetics Dye 0 - 1.0

Free (Neat) Perfume 0 - 3.0

Malodor Reducing Composition 0 - 0.5

Perfume encasulated (9) 0-5

Malodor reducing composition (encapsulated) (9) 0-5

Perfume + malodor reducing composition (encapsulated) (9) 0-2

Water and Solvent To 100

pH 3.5 - 8.5

1. Typically the alkyl group has about 12 to about 18 carbons and with 0 to about 3 ethoxylate groups.

2. Typically the alkyl group has about 10 to about 16 carbons.

3. HSAS is secondary alkyl sulfate, acid form

4. Alkyl ethoxylate with about 12 to about 18 carbons and about 5 to about 9 moles ethoxylation.

5. Polyethyleneimine at about 600 molecular weight reacted with about 20 moles of ethylene oxide.

6. Polyethyleneimine at about 600 molecular weight reacted with about 24 moles of ethylene oxide and about 16 moles of propylene oxide.

7. Select optical brighteners from one or more of the following, Brightener 14, Brightener 36, Brightener 49.

8. Select chelant from one or a combination of the following non-limiting list DTPA is diethylene triamine pentaacetic acid, Tiron® is 4,5-Dihydroxy-l,3-benzenedisulfonic acid disodium salt monohydrate, EDTA ethylene diamine tetra acetate, HEDP 1- Hydroxyethylidene-l,l-diphosphonic Acid, Octapirox l-Hydroxy-4-methyl-6-(2,4,4- trimethylpentyl)-2(lH)-pyridone Ethanolamine, EDDS Ethylenediamine-N,N'-disuccinic acid.

9. Encapsulated perfume and encapsulated malodor reducing composition in a slurry. One non-limiting example of an encapsulate is a friable microcapsule with a urea- formaldehyde shell from Appvion-Encapsys. About 50% water by weight of the PMC

(including encapsulated perfume) is assumed. About 30% of the internal phase is either perfume, malodor control compound or composition or a combination thereof.

The resulting detergent liquid product when used to wash articles of clothing is effective at reducing malodor on the washed clothing.

EXAMPLE 6 - Liquid fabric enhancer composition

Examples of liquid fabric enhancer compositions prepared with malodor reduction materials, according to the compositions shown in Examples l through 3.

% wt Active

ingredient 4 B c D

FSA ¹ 12 21 18 14

Low MW alcohol 1.95 3.0 3.0 2.28

Stracturant 1.25 ² NIL 0.2 ³ NIL

Free (Neat) Perfume 1.50 1.8 2.0 1.50

Free (Neat) malodor reducing composition 0.3 0.7 NIL NIL

Perfume/ malodor reducing NIL 1.85 1.85 3.7 composition (encapsulated) ⁵

Calcium Chloride 0.10 0.12 0.1 0.45

DTP A ⁶ 0.005 0.005 0.005 0.005

Preservative (ρρτ ^η) ' 5 5 5 5

Antifoam ⁸ 0.015 0.15 0.1 1 0.01 1

Polyethylene imines ⁹ 0.15 0.05 NIL 0.1

Delivery enhancing 0.1 0.1 0.2 0.05

PDMS emulsion ³⁰ NIL 0.5 1 2.0

Dispersant ⁿ NIL NIL 0.5 0.2 Organosiloxane ¹" 5 NIL NIL NIL

Front- end Stability Aid 0.06" 0.63 ¹⁴ 0.36 ¹³ 0.14 ¹⁴

Dye (parts per million ppm) 40 11 30 40

Ammonium Chloride 0-0.1 0-0.1 0-0.1 0.10

Hydrochloric Acid 0.010 0.01 0.10 0.010

Water Balance Balance Balance Balance

1. N,N-di(tallowoyloxyet yl)-N,N-dimethylammonium chloride.

2. Cationic high amylose maize starch-available from National Starch under the trade name HYLON VII ®.

3. Cationic polymer available from BASF ® under the name Rheovis ® CDE.

4. Encapsulated perfume and encapsulated malodor reducing composition (within PMC) assumes about 32% active

5. PMC is a friable PMC with a urea-formaldehyde shell from Appleton. About 50% water by weight of the PMC (including encapsulated perfume and/ or malodor reducing composition) is assumed.

6. Diethylene triamine pentaacetic acid

7. 19% active aqueous solution of 1,2 Benzisothiazolin-3-one (BIT) in dipropylene glycol and water available from Dow Chemical under the trade name oralone B-l 19

8. Silicone antifoam agent available from Dow Corning ® under the trade name I H 2310.

9. Polyethylene imines available from BASF under the trade name Lupasol ®.

12. Qrganosiloxane polymer condensate made by reacting hexamethylenediisocyanate (HDI), and a, w silicone diol and 1,3-propanediamine, N'-(3-(dimethylamino)propyl)- N,N-dimethyl- Jeffcat Z130) or N-(3-diraethylaramopropyl)-N,Ndiisopropaiio1amine (Jef cat ZR50) commercially available from Wacker Silicones, Munich, Germany.

14. Isofol ® 16 from Sasol.

**For example PGE

Liquid fabric enhancer compositions in EXAMPLE 6 are made by combining the molten fabric softener active with the front-end stability agent to form a first mixture. This first mixture is combined with water and hydrochloric acid using a high shear mixing device to form a second mixture. The adjunct ingredients are combined with the second mixture using low shear mixing to form the fabric enhancing formula.

Liquid fabric enhancer compositions in EXAMPLE 6 are used by dosing 10 to 60 g of the

5 formula into the rinse liquor for example via dispensing into a clothes washing machine. Clothes

are dried on a line or in an automated clothes dryer. The fabrics treated with these formulas have improved feel and scent and are effective at reducing malodor on the clothing

EXAMPLE 7 - Liquid Fabric Enhancer Composition

Examples of a Liquid Fabric Enhancer composition prepared with malodor reduction materials, according to the compositions shown in Examples 1-3

% wt Active

Ingredients A B C D E F G H I

DEEDMAC ¹ 16 9 9 12 4 NIL NIL NIL NIL

Dialkyl esterdimethyl NIL NIL NIL NIL NIL 7 2.5 9 11 ammonium methyl sulfate ²

HC1 0.02 0.01 0.01 0.01 NIL 0.01 NIL 0.01 0.01

Fromic Acid 0.05 0.05 0.05 0.05 0.05 0.05 0.025 0.05 0.05

Proxel ® ^J 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02

CaC12 1 0.3 0.3 0.4 NIL 0.3 NIL 0.1 0.1

Antifoam MP10 ⁴ 0.2 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1

Rheovis CDE® ⁵ 0.1 NIL NIL NIL 0.4 0.1 0.2 NIL 0.2

Flosoft ® ^b NIL 0.1 0.1 0.05 NIL NIL NIL 0.3 NIL

Bardac 2250 ® ⁷ NIL NIL 0.5 NIL NIL NIL NIL NIL 0.5

NaHEDP ⁸ 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03

Genapol T680® ^y NIL NIL NIL NIL NIL NIL NIL 0.6 0.8

CAE10 ^1U NIL 0.6 NIL NIL NIL NIL NIL NIL NIL

Glycerol NIL 10 NIL NIL NIL NIL NIL NIL 5

Perfume 0-2 0-1 0-1.5 0-3 0-2.3 0-1.5 0-3 0-0.8 0-0.5

Malodor reducing 0-0.1 0-0.5 0-0.3 0-0.2 0-0.05 0-0.25 0- 0-0.1 0-1 composition 0.003

0- 0-0.5 0-1 0-0.6 0-1.5 0-3 0-0.5 0-1 0-5

Encapsulated perfume

0.25 Encapsulated malodor 0- 0- 0-5 0-0.25 0-0.5 0-1 0-0.6 0-1 0-1.5 reducing composition 0.25 0.003

Encapsulated perfume + 0.3 0-5 0-5 0-0.25 0- 0-0.1 0-1 0- 0-1 malodor reducing 0.003 0.0025 composition

To To To To 100 To 100 To To To To

Water

100 100 100 100 100 100 100

1. 91% activity, 9% isopropanol, supplied by Evonik

2. Reaction product of triethanolamine and alkyl and/or fatty acids followed by

methylation.

3. Proxel GXL, 20% activity, supplied by Lonza

4. MP10, 8% activity, supplied by Dow Corning

5. Rheovis CDE, supplied by BASF

6. Flosoft 222, supplied by SNF

7. Bardac 2250, 50% activity, supplied by Lonza

8. 20% activity

9. 30% activity

10. Genapol T680, supplied by Clariant

11. C12-14 ALCOHOL ETHOXYLATE AE 10 (24E10)

EXAMPLE 8 - Soluble Uni-dose Heavy Duty Liquid Composition

An example for a Soluble Uni-dose heavy duty liquid composition prepared with malodor 5 reduction composition, according to the compositions shown in Examples 7 a-f.

A B C D E 3 compartments

pouched product

Form liquid liquid liquid liquid gel liq liq liq

Compartment # 1 1 1 1 1 1 2 3

Dosage (g) 36.0 38.0 32.0 36.0 40.0 34.0 25 35

Alkylbenzene sulfonic

14.5 13.8 16.0 14.5 13.5 14.5 20.0 NIL acid

C12-14 alkyl ethoxy 3 8.5 16.4 10.0 8.5 15.0 8.5 NIL NIL sulfate

C12-13 alkyl 3-

NIL NIL NIL 13.0 NIL NIL NIL NIL ethoxylate

C12-14 alkyl 7-

12.5 9.0 14.0 NIL 4.0 12.5 17.0 NIL ethoxylate

C12-18 Fatty acid 14.5 8.5 16.0 15.0 7.2 14.5 13.0 NIL

Citric acid NIL NIL NIL 2.0 4.1 NIL NIL NIL

Enzymes 0-3 0-3 0-3 NIL 0-3 0-3 0-3 NIL

PAP granule ¹ NIL NIL NIL NIL NIL NIL NIL 50.0

Ethoxysulfated

Hexamethylene

NIL 3.0 NIL NIL NIL NIL 2.2 NIL Diamine Dimethyl

Quat

Ethoxylated

4.0 1.0 NIL 4.0 3.0 2.0 NIL NIL Polyethylenimine

Hydroxyethane

1.0 1.0 NIL NIL 1.6 0.6 0.6 NIL diphosphonic acid

Ethylene diamine

tetra(methylene NIL NIL NIL 1.0 NIL NIL NIL NIL phosphonic) acid

Brightener 0.2 0.2 0.3 0.3 0.2 0.2 0.2 NIL

Polydimethyl Siloxane NIL NIL 3.0 NIL NIL NIL NIL NIL

Hueing dye NIL NIL NIL NIL NIL NIL 0.05 NIL

Perfume 0-3.0 0-3.0 0-3.0 0-3.0 0-3.0 0-3.0 NIL NIL

Malodor reducing 0- 0- 0- 0-

0-0.05 0-0.05 NIL NIL composition 0.05 0.05 0.05 0.05

Perfume (encapsulated) 0-5 0-5 0-5 0-5 0-5 0-5 NIL NIL

Malodor reducing

composition 0-5 0-5 0-5 0-5 0-5 0-5 NIL NIL

(encapsulated)

Perfume + malodor

reducing composition 0-5 0-5 0-5 0-5 0-5 0-5 NIL NIL (encapsulated) Water and minors To 100%

Buffers (sodium To pH 8.0

carbonate,

monoethanolamine)

Solvents (1,2 To 100%

propanediol, ethanol),

Sulfate

1. ε-Phthalimido-peroxy-hexanoic acid particles made by Solvay Chemicals International, Brussels, Belgium. The resulting Unidose pouch product when used to wash articles of clothing is effective at reducing malodor on the washed clothing.

EXAMPLES 9 Dish cleansing composition examples with Malodor reducing composition.

An example of Dish cleaning compositions prepared with malodor reduction composition, according to the compositions shown in Examples 9a-e.

% wt Active

EXAMPLES 9 A B C D E F G

Alkyl Cio-14 Ethoxy Sulphate

26.9 NIL NIL 25.7 NIL 11.1 21.0 (AE0.6S)

Alkyl Cio-14 Ethoxy Sulphate

NIL 18.7 26.9 NIL 18.7 NIL NIL (AE2S)

Sodium alkyl benzene sulfonate NIL 8.0 NIL NIL NIL NIL NIL

Sodium paraffin sulfonate NIL NIL NIL NIL 8.0 NIL NIL

C12-14 dimethyl amine oxide 6.1 NIL NIL 4.1 NIL 3.7 10.0

Cocamido propyl betaine NIL 4.5 6.8 3.2 6.0 NIL NIL

C12-13 E07 nonionic NIL NIL NIL NIL NIL 1.0 2.0

Branched Nonionic: 3 -propyl

1.0 0.8 NIL NIL NIL NIL 1.0 heptanol E08

PEI600-EO10-PO7 block polymer NIL NIL 0.8 NIL NIL 0.4 0.8

Perfume 0-2 0-2 0-2 0-2 0-2 0-2 0-2 Malodor Reducing Composition 0-1 0-0.5 0-0.5 0-01.5 0-0.5 0-0.3 0-2

Perfume micro capsule 0-1 0-0.5 0-0.5 0-1.5 0-0.5 0-0.8 0-2

Encapsulated perfume 0-0.5 0-0.3 0-1 0-0.5 0-0.5 0-0.7

0.45

Encapsulated malodor control

0-0.6 0-0.9 0-1 0-0.5 0-0.5 0-03 0-1 composition

Encapsulated perfume + malodor

0-0.5 0-0.3 0-0.2 0-0.6 0-0.5 0-03 0-1 composition

Ethanol 4.0 5.0 3.0 3.0 2.0 NIL 3.0

Polypropylene glycol MW2000 1.1 0.8 1.1 1.1 1.1 0.5 1.1

Sodium Chloride 1.3 0.8 1.3 0.5 0.8 1.3 1.3

Minors* and water to ba ance up to 100%

EXAMPLE 10 Compositions for use in cleaning in an automatic dishwashing machine.

Nonlimiting automatic dish washing compositions acceptable are shown below. Some aspects of the present invention have at least one water soluble compartment, preferably composed of Monosol 660 mm M8630K Water Soluble Film. In other aspects of the present invention the unit dose composition has more than one compartment and at least one of the compartments comprises powder as in EXAMPLE 10 A.

% wt Active

A B C

Ingredients

POWDER LIOUID LIOUID

Sodium sulfate 0-15 2-7 NIL

Soda ash 20-50 NIL NIL

Zinc carbonate NIL 0.1-0.2 NIL

Zinc sulfate NIL NIL 0.3-0.7

Sodium silicate 0-2 3-15 1-2

Sodium bicarbonate NIL NIL 15-25

Glutamic acid-N,N-diacetic acid, tetra

NIL NIL 3-7 sodium salt.

Citric acid NIL NIL 1-2 NaOH NIL 0-1.5

Carboxylate polymer, GT101 2.5-7 NIL 1.25

Plurafac SLF 180 0.2-1.5 NIL 0.25-0.6

MDGA 5-15 NIL NIL

Polyacrylate thickener Polygel DKP NIL 0.7-2.3 NIL

Acrylic/ sulfonic dispersant Acusol 588 2-10 NIL NIL

Acrylic acid polymer Acusol 425 N NIL 1-3 NIL

Sodium hypochlorite bleach 0-30 0.3-1.5 NIL

Ultimase 0-2 NIL NIL

Stainzyme 0-1 NIL NIL

Savinase Ultra 16XL NIL NIL 0.2-0.5

Termamyl Ultra 300 L NIL NIL 0.1-0.15

Calcium Chloride NIL NIL 0.3-0.4

Dipropylene Glycol NIL NIL NIL

Nonionic Surfactant NIL 9-50 NIL

Plurafac SLF 180 NIL 25-60 NIL

Glycerine NIL 0-1 NIL

Dye NIL 0-0.1 NIL

Nitric acid NIL 0.005-0.05 NIL

Preservative sodium benzoate NIL 0.25-0.8 0.2-0.8

Perfume 0-1 0-1 0-1

Malodor reducing composition 0-0.3 0-0.3 0-0.3

Encapsulated perfume 0-2 0-2 0-2

Encapsulated malodor reduction

0-2 0-2 0-2 composition

Encapsulated perfume + malodor

0 - 1.5 0 - 1.5 0 - 1.5 reduction composition Balance Water To 100 To 100 To 100

Fatty acid has C12 to C14 alkyl groups and mixtures thereof

Caustic soda is preferably low iron.

Rheovis® AT 120 is a methacrylate/ acrylic acid copolymer. EXAMPLE 11 Spray for cleaning hard surfaces.

Method for evaluating the through-the-wash malodor reducing efficacy of a malodor reduction compound or composition incorporated into a detergent. This method is intended to evaluate the ability of a malodor control compound to deposit on fabric TTW and reduce the impact of the smell of the malodor without contributing a high level of fragrance odor at the end of the wash process and at the end of the drying process. Make the Malodorous Soil Composition. The malodorous soil composition comprises bacon grease purchased from EMC (Empirical Manufacturing Group, Cincinnati, OH) as well as squalene and Skatole, both purchased from Sigma Aldrich. Bacon grease and squalene comprise malodor models (aldehydes and acids similar to residual body and food odors) and also contributes to the substantivity similar to the role residual body soil is believed to play on consumer garments. Skatole is a good model material for potent body odors. The malodorous soil composition comprises 1.15% of Skatole in a 50%/50% by weight matrix of bacon grease and squalene. To make the malodorous melt bacon grease and weight an aliquot into a beaker. Add an equal weight aliquot of squalene to the bacon grease and stir to combine. For every 98.85 g of bacon grease + squalene mixture add 1.15 g of solid Skatole and stir until the Skatole dissolves. Store the malodorous soil in refrigerator below 10 C to preserve it. Warm the malodorous soil gently to room temperature prior to adding it to swatches to create the malodorous soiled swatches.

Make the Malodorous Soiled Swatches: Purchase white knit polycotton (4 inch X 4 inch) swatches from EMC. Order PC 50/50 with instructions to EMC to strip fabrics with Downy. Gently warm the malodorous soil composition and pipet 13 uL of the malodorous soil composition onto the polycotton swatches. Stack malodorous soiled swatches with tin foil separating the swatches and seal the stack of swatches in a Mylar bag. Let the swatches treated with the malodorous soil sit at least 16 hours before proceeding to the next step. Use swatches within 60 hours of making.

Wash the Malodorous Stained Swatch to Create a Residual Malodor Stain.

Prepare the ballast used in washing the malodorous stained swatches. Purchase terry towel ballast is from Standard Textile Cincinnati, OH Inc. Strip the ballast using a Kenmore 600 North American top load washing machine by running the ballast twice through the wash/ rinse cycles at 60°C and 7 gpg water (2) with a 1562.5 ppm dose of AATCC Regular Detergent (purchased from American Assoc. of Textile Chemists and Colorists, Research Triangle Park, NC) and then 3X wash/ rinse cycles at 60°C 7 gpg with NIL detergent. Run a test where malodorous soiled swatches are washed with AATCC comprising a malodor reducing compositions that fall within the boundaries of EXAMPLES 1-3 above. Include a control product which has NIL perfume and NIL malodor control compound or composition. Also run a test where the same detergent formulation comprises a malodor control compound or composition. Wash 2 of the malodorous swatches in each test leg and wrap these in aluminum foil. Dry the rest of the ballast and swatches. After drying extract 2 each of the malodorous swatches from each test leg. A perfumer/ expert grader smells both the wet swatches and the dry swatches for malodor and perfume and grades these on a 100 pt scale with a higher number representing stronger intensity. The desired outcome is to lower both the intensity of malodor, while still maintaining a lower fragrance intensity.

Results of Throu2h-the-Wash Test to Determine Efficacy of

In the table below, zeros for the dry fabric perfume level shows that the malodor reduction composition delivered no fragrance of its own to the dry fabrics, indicating it is very unlikely to shift the character or raise the intensity of any fragrance added to a detergent having that malodor reducing composition. On the other hand, these compositions did lower the impression of the residual malodor on the malodor stained swatches. This futher demonstrates that malodor reducing compositions having at least one component with log P >3 will deposit though the wash of their own accord and without the need for an additional delivery agent to bring these to the surface of the soiled fabric.

In one aspect of the invention it is preferred that the malodor reduction compound or composition be surface active enough to deposition on fabric through the wash without the aid of a deposition agent. This is achieved by selecting a malodor reducing component with log P >3 or making a malodor reducing composition comprising at least one malodor reducing component with log P >3. The following analytical method demonstrates that Amber Core, a malodor reducing component of the present invention with log P > can deposit through the wash. MS Method to detect Ambercore in the headspace above fabrics

This method is used to identify the presence of ambercore in the headspace above fabrics using the analytical chromatography technique of Gas Chromatography Mass Spectrometry equipped with a Dynamic Headspace DHS / Thermal Desorption Unit TDU/ Cooled Injection System CIS, using a non-polar or slightly-polar column. This procedure is suitable for the qualitative presence of ambercore above fabrics treated with liquid laundry formulations containing ambercore.

Suitable instruments for conducting these GC-MS analyses includes equipment such as: Hewlett Packard/Agilent Gas Chromatograph model 7890 series GC (Hewlett Packard/Agilent Technologies Inc., Santa Clara, California, U.S.A.); Hewlett Packard/Agilent Model 5977N Mass Selective Detector (MSD) transmission quadrupole mass spectrometer (Hewlett Packard/ Agilent Technologies Inc., Santa Clara, California, U.S.A.); Multipurpose AutoSampler MPS2 equipped with an Automated Dynamic Headspace DHS / Thermal Desorption Unit TDU/ Cooled Injection System CIS. (GERSTEL Inc., Linthicum, Maryland, U.S.A); and 5% -Phenyl -methylpolysiloxane Column J&W DB-5 (30 m length x 0.25 mm internal diameter x 0.25 μιη film thickness) (J&W Scientific/Agilent Technologies Inc., Santa Clara, California, U.S.A.).

One skilled in the art will understand that in order to detect ambercore in the headspace, the analytical steps may involve the use of external ambercore reference standards to verify retention times and mass spectrum of the four isomers of ambercore.

Sample Preparation:

Fabrics are treated with laundry formulas containing ambercore.

A 2g piece of fabric is placed in a 10 mL headspace vial with a screw cap ( Gerstel part # 093640-038-00) with a metal screw cap (Gerstel part # 093640-040-00)

Instrument Parameters:

The 10 mL vial is analyzed by headspace GC/MS via an Automated Dynamic Headspace Analyzer DHS / Thermal Desorption Unit TDU/ Cooled Injection System CIS

Conditions:

The DHS parameters are set as follows: incubation is 75 C incubation for 15 minutes; trapping phase settings are 200 ml collection @ 20 ml/min, Incubation 75 C, Transfer Temp 150 C, and Trap Temperature 25 C. The TDU parameters are set as follows TDU parameters: Initial Temperature 35 C, purge for 5 minutes @ 50 ml/min, heat to 280 C @ 720 C/min, hold 5.0 min, solvent venting with vent time to 5.0 min. CIS parameters are set to cyro focused @ -70, heat to 280 C @ 12 C/sec, hold 4.0 min. The GC/MS parameters are set to: column J&W DB -5MS 30m x250umx0.25um (direct to MS no FID), PTV solvent vent, 1.6 ml/min, initial temperature 40 C, rate 16 C/min, and hold 280 C for 3 min. Also note the following conditions for the analysis

Column: J&W DB-5, 30 m length x 0.25 mm internal diameter x 0.25 μιη film thickness Pneumatics: He, constant flow, 1.5mL/min

Oven: 50C (Omin), 12C/min, 280C (2min)

MSD: Full Scan mode with a minimum range of 40 to 300 m/z (a wider range may be used). It is important that the final temperature of the system is selected such that it is sufficient to elute all of the perfume materials present in the test sample ethanol filtrate.

Data Analysis:

The results from the analysing a reference standard of ambercore is used to verify the presence of ambercore in the headspace above fabric. This is required to detected and correctly identify, by comparing the data. When a fabric is treated with a detergent containing 0.3% Amber Core, Amber Core is analytically detectable in the head space over the fabric demonstrating that this C log P > 3 deposits even through the wash without requiring the aid of a delivery technology. The dimensions and values disclosed herein are not to be understood as being strictly limited to the exact numerical values recited. Instead, unless otherwise specified, each such dimension is intended to mean both the recited value and a functionally equivalent range surrounding that value. For example, a dimension disclosed as "40 mm" is intended to mean "about 40 mm." Every document cited herein, including any cross referenced or related patent or application is hereby incorporated herein by reference in its entirety unless expressly excluded or otherwise limited. The citation of any document is not an admission that it is prior art with respect to any invention disclosed or claimed herein or that it alone, or in any combination with any other reference or references, teaches, suggests, or discloses any such invention. Further, to the extent that any meaning or definition of a term in this document conflicts with any meaning or definition of the same term in a document incorporated by reference, the meaning or definition assigned to that term in this document shall govern. While particular embodiments of the present invention have been illustrated and described, it would be obvious to those skilled in the art that various other changes and modifications can be made without departing from the spirit and scope of the invention. It is, therefore, intended to cover in the appended claims all such changes and modifications that are within the scope of this invention.

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