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Title:
COGENERATION SYSTEMS AND PROCESSES FOR TREATING HYDROCARBON CONTAINING FORMATIONS
Document Type and Number:
WIPO Patent Application WO/2007/050445
Kind Code:
A1
Abstract:
A system for treating a hydrocarbon containing formation (212) includes a steam and electricity cogeneration facility (218) . At least one injection well (216) is located in a first portion of the formation. The injection well is configured to provide steam from the steam and electricity cogeneration facility to the first portion. At least one production well (206A) is located in the first portion. The production well is configured to produce first hydrocarbons. At least one electrical heater (214) is located in the first portion and/or a second portion of the formation and is configured to be powered by electricity from the steam and electricity cogeneration facility. At least one production well is located in the first portion and/or the second portion. The production well is configured to produce second hydrocarbons. The steam and electricity cogeneration facility is configured to use the first hydrocarbons and/or the second hydrocarbons to generate electricity.

Inventors:
FOWLER THOMAS DAVID (US)
KARANIKAS JOHN MICHAEL (US)
VINEGAR HAROLD J (US)
Application Number:
PCT/US2006/040980
Publication Date:
May 03, 2007
Filing Date:
October 20, 2006
Export Citation:
Click for automatic bibliography generation   Help
Assignee:
SHELL OIL CO (US)
FOWLER THOMAS DAVID (US)
KARANIKAS JOHN MICHAEL (US)
VINEGAR HAROLD J (US)
International Classes:
E21B43/24; E21B36/04
Domestic Patent References:
WO2002085821A22002-10-31
Foreign References:
US4694907A1987-09-22
US4043393A1977-08-23
US4344483A1982-08-17
US20030173080A12003-09-18
US5217076A1993-06-08
GB1501310A1978-02-15
US4444258A1984-04-24
Other References:
None
Attorney, Agent or Firm:
CHRISTENSEN, Del, S. (One Shell Plaza P.o. Box 246, Houston Texas, US)
Download PDF:
Claims:
C L A I M S

1. A system for treating a hydrocarbon containing formation, comprising: a steam and electricity cogeneration facility; at least one injection well located in a first portion of the formation, the injection well configured to provide steam from the steam and electricity cogeneration facility to the first portion of the formation; at least one production well located in the first portion of the formation, the production well configured to produce first hydrocarbons; at least one electrical heater located in the first portion of the formation and/or a second portion of the formation, at least one of the electrical heaters configured to be powered by electricity from the steam and electricity cogeneration facility; at least one production well located in the first portion of the formation and/or the second portion of the formation, the production well configured to produce second hydrocarbons; and the steam and electricity cogeneration facility configured to use the first hydrocarbons and/or the second hydrocarbons to generate electricity.

2. The system of claim 1, wherein the facility is configured to use hydrocarbons to make electricity.

3. The system of any of claims 1-2, wherein the facility is configured to use hydrocarbons to make steam.

4. The system of any of claims 1-3, wherein the first hydrocarbons have an API gravity at most 15°. 5. The system of any of claims 1-4, wherein the second hydrocarbons have an API gravity of at least 20°.

6. The system of any of claims 1-5, wherein the system is configured to mix at least a portion of the first hydrocarbons and at least a portion of the second hydrocarbons.

7. The system of any of claims 1 -6, wherein the system is configured to vary the amount of electricity generated and the amount of steam made to vary the production of the first hydrocarbons and/or the second hydrocarbons.

8. The system of any of claims 1-7, wherein the system further comprises a treatment facility for treating the first hydrocarbons and/or second hydrocarbons before use in the steam and electricity cogeneration facility.

9. The system of any of claims 1-8, wherein the system further comprises at least one injection well located in the second portion of the formation, at least one of the injection wells being configured to provide steam from the steam and electricity cogeneration facility to the second portion.

10. The system of any of claims 1-9, wherein the steam and electricity cogeneration facility is configured to burn both gaseous and liquid hydrocarbons.

11. A method for treating a hydrocarbon containing formation using the system of any of claims 1-10, comprising: providing steam to the first portion of the formation; producing first hydrocarbons from the first portion of the formation; providing heat from one or more electrical heaters to the first portion of the formation and/or the second portion of the formation; allowing the provided heat to transfer from the heaters to the first portion of the formation and/or the second portion of the formation; producing second hydrocarbons from the second portion of the formation; and

usiηg the first hydrocarbon^ and/or the second hydrocarbons in the steam and electricity cogeneration Facility, wnerein ' the facility provides steam to the first portion of the formation and electricity for the heaters. 12. The method of claim 11, further comprising using the first hydrocarbons and/or the second hydrocarbons to make electricity. 13. The method of any of claims 11-12, further comprising using the first hydrocarbons and/or the second hydrocarbons to make steam.

14. The method of any of claims 11-13, wherein the first hydrocarbons have an API gravity at most 10°.

15. The method of any of claims 11-14, wherein the second hydrocarbons have an API gravity of at least 15°.

16. The method of any of claims 11-15, further comprising mixing at least a portion of the first hydrocarbons and at least a portion of the second hydrocarbons.

17. The method of any of claims 11-16, further comprising mixing at least a portion of the first hydrocarbons and at least a portion of the second hydrocarbons to make a fuel for electrical generators.

18. The method of any of claims 11-17, further comprising using at least a portion of the second hydrocarbons as a gas for one or more heaters in the formation. 19. The method of any of claims 11-18, further comprising using all of first hydrocarbons and/or the second hydrocarbons as fuel for generating electricity and/or to make steam.

20. The method of any of claims 11-19, further comprising varying the amount of electricity generated and the amount of steam made to vary the production of the first hydrocarbons and/or the second hydrocarbons.

21. The method of any of claims 11-20, further comprising providing steam to the second portion prior to providing heat from the electrical heaters.

22. The method of any of claims 11-21, further comprising treating the first hydrocarbons and/or second hydrocarbons before using the first hydrocarbons and/or the second hydrocarbons in the steam and electricity cogeneration facility.

23. The method of any of claims 11-22, further comprising providing steam to the second portion of the formation from the steam and electricity cogeneration facility.

Description:

COGENEBAXION SYSTEMS AND PROCESSES FOR TREATING HYDROCARBON CONTAINING FORMATIONS

BACKGROUND 1. Field of the Invention

The present invention relates generally to methods and systems for production of hydrocarbons, hydrogen, and/or other products from various subsurface formations such as hydrocarbon containing formations. In particular, certain embodiments relate to using a steam and electricity cogeneration facility in combination with steam injection recovery and in situ processing of a hydrocarbon containing formation 2. Description of Related Art

Hydrocarbons obtained from subterranean formations are often used as energy resources, as feedstocks, and as consumer products. Concerns over depletion of available hydrocarbon resources and concerns over declining overall quality of produced hydrocarbons have led to development of processes for more efficient recovery, processing and/or use of available hydrocarbon resources. In situ processes may be used to remove hydrocarbon materials from subterranean formations. Chemical and/or physical properties of hydrocarbon material in a subterranean formation may need to be changed to allow hydrocarbon material to be more easily removed from the subterranean formation. The chemical and physical changes may include in situ reactions that produce removable fluids, composition changes, solubility changes, density changes, phase changes, and/or viscosity changes of the hydrocarbon material in the formation. A fluid may be, but is not limited to, a gas, a liquid, an emulsion, a slurry, and/or a stream of solid particles that has flow characteristics similar to liquid flow.

Large deposits of heavy hydrocarbons (heavy oil and/or tar) contained in relatively permeable formations (for example in tar sands) are found in North America, South America, Africa, and Asia. Tar can be surface-mined and upgraded to lighter hydrocarbons such as crude oil, naphtha, kerosene, and/or gas oil. Surface milling processes may further separate the bitumen from sand. The separated bitumen may be converted to light hydrocarbons using conventional refinery methods. Mining and upgrading tar sand is usually substantially more expensive than producing lighter hydrocarbons from conventional oil reservoirs.

In situ production of hydrocarbons from tar sand may be accomplished by heating and/or injecting a gas into the formation. U.S. Patent Nos. 5,211,230 to Ostapovich et al. and 5,339,897 to Leaute describe a horizontal production well located in an oil-bearing reservoir. A vertical conduit may be used to inject an oxidant gas into the reservoir for in situ combustion.

U.S. Patent No. 2,780,450 to Ljungstrom describes heating bituminous geological formations in situ to convert or crack a liquid tar-like substance into oils and gases.

U.S. Patent No. 4,597,441 to Ware et al. describes contacting oil, heat, and hydrogen simultaneously in a reservoir. Hydrogenation may enhance recovery of oil from the reservoir. U.S. Patent No. 5,046,559 to Glandt and 5,060,726 to Glandt et al. describe preheating a portion of a tar sands formation between an injector well and a producer well. Steam may be injected from the injector well into the formation to produce hydrocarbons at the producer well.

As outlined above, there has been a significant amount of effort to develop methods and systems to economically produce hydrocarbons, hydrogen, and/or other products from hydrocarbon containing formations. Producing hydrocarbons through both steam injection and an in situ heat treatment process may increase the total recovery of hydrocarbons from a hydrocarbon containing formation. Using both processes may be more economical than using either process alone.

SUMMARY

EmBόdlments ' des ' cribe3 " herein generally relate to systems, methods, and heaters for treating a subsurface formation. Embodiments described herein also generally relate to heaters that have novel components therein. Such heaters can be obtained by using the systems and methods described herein. In certain embodiments, the invention provides one or more systems, methods, and/or heaters. In some embodiments, the systems, methods, and/or heaters are used for treating a subsurface formation.

In certain embodiments, the invention provides a system for treating a hydrocarbon containing formation, comprising: a steam and electricity cogeneration facility; at least one injection well located in a first portion of the formation, the injection well configured to provide steam from the steam and electricity cogeneration facility to the first portion of the formation; at least one production well located in the first portion of the formation, the production well configured to produce first hydrocarbons; at least one electrical heater located in the first portion of the formation and/or a second portion of the formation, at least one of the electrical heaters configured to be powered by electricity from the steam and electricity cogeneration facility; at least one production well located in the first portion of the formation and/or the second portion of the formation, the production well configured to produce second hydrocarbons; and the steam and electricity cogeneration facility configured to use the first hydrocarbons and/or the second hydrocarbons to generate electricity.

In some embodiments, the invention provides a method for treating a hydrocarbon containing formation, comprising: providing steam to the first portion of the formation; producing first hydrocarbons from the first portion of the formation; providing heat from one or more electrical heaters to the first portion of the formation and/or the second portion of the formation; allowing the provided heat to transfer from the heaters to the first portion of the formation and/or the second portion of the formation; producing second hydrocarbons from the second portion of the formation; and using the first hydrocarbons and/or the second hydrocarbons in the steam and electricity cogeneration facility, wherein the facility provides steam to the first portion of the formation and electricity for the heaters.

In further embodiments, features from specific embodiments may be combined with features from other embodiments. For example, features from one embodiment may be combined with features from any of the other embodiments.

In further embodiments, treating a subsurface formation is performed using any of the methods, systems, or heaters described herein.

In further embodiments, additional features may be added to the specific embodiments described herein. BRIEF DESCRIPTION OF THE DRAWINGS

Advantages of the present invention may become apparent to those skilled in the art with the benefit of the following detailed description and upon reference to the accompanying drawings in which:

FIG. 1 depicts an illustration of stages of heating a hydrocarbon containing formation.

FIG. 2 shows a schematic view of an embodiment of a portion of an in situ heat treatment system for treating a hydrocarbon containing formation.

FIG. 3 depicts a representation of an embodiment for producing hydrocarbons from a hydrocarbon containing formation.

While the invention is susceptible to various modifications and alternative forms, specific embodiments thereof are shown by way of example in the drawings and may herein be described in detail. The drawings may not be to scale. It should be understood, however, that the drawings and detailed description thereto are not intended to limit the invention to the particular form disclosed, but on the contrary, the intention is to cover all modifications,

equivalents and alternatives falling , within the spirit and scope of the present invention as defined by the appended claims.

DETAILED DESCRIPTION

The following description generally relates to systems and methods for treating hydrocarbons in the formations. Such formations may be treated to yield hydrocarbon products, hydrogen, and other products.

"Hydrocarbons" are generally defined as molecules formed primarily by carbon and hydrogen atoms. Hydrocarbons may also include other elements such as, but not limited to, halogens, metallic elements, nitrogen, oxygen, and/or sulfur. Hydrocarbons may be, but are not limited to, kerogen, bitumen, pyrobitumen, oils, natural mineral waxes, and asphaltites. Hydrocarbons may be located in or adjacent to mineral matrices in the earth. Matrices may include, but are not limited to, sedimentary rock, sands, silicilytes, carbonates, diatomites, and other porous media. "Hydrocarbon fluids" are fluids that include hydrocarbons. Hydrocarbon fluids may include, entrain, or be entrained in non-hydrocarbon fluids such as hydrogen, nitrogen, carbon monoxide, carbon dioxide, hydrogen sulfide, water, and ammonia.

A "formation" includes one or more hydrocarbon containing layers, one or more non-hydrocarbon layers, an overburden, and/or an underburden. The "overburden" and/or the "underburden" include one or more different types of impermeable materials. For example, the overburden and/or underburden may include rock, shale, mudstone, or wet/tight carbonate. In some embodiments of in situ heat treatment processes, the overburden and/or the underburden may include a hydrocarbon containing layer or hydrocarbon containing layers that are relatively impermeable and are not subjected to temperatures during in situ heat treatment processing that result in significant characteristic changes of the hydrocarbon containing layers of the overburden and/or the underburden. For example, the underburden may contain shale or mudstone, but the underburden is not allowed to heat to pyrolysis temperatures during the in situ heat treatment process. In some cases, the overburden and/or the underburden may be somewhat permeable.

"Formation fluids" refer to fluids present in a formation and may include pyrόlyzation fluid, synthesis gas, mobilized hydrocarbon, and water (steam). Formation fluids may include hydrocarbon fluids as well as non- hydrocarbon fluids. The term "mobilized fluid" refers to fluids in a hydrocarbon containing formation that are able to flow as a result of thermal treatment of the formation. "Visbroken fluid" refers to fluid that has a viscosity that has been reduced as a result of heat treatment of the formation.

"Produced fluids" refer to fluids removed from the formation. A "heat source" is any system for providing heat to at least a portion of a formation substantially by conductive and/or radiative heat transfer. For example, a heat source may include electric heaters such as an insulated conductor, an elongated member, and/or a conductor disposed in a conduit. A heat source may also include systems that generate heat by burning a fuel external to or in a formation. The systems may be surface burners, downhole gas burners, flameless distributed combustors, and natural distributed combustors. In some embodiments, heat provided to or generated in one or more heat sources may be supplied by other sources of energy. The other sources of energy may directly heat a formation, or the energy may be applied to a transfer medium that directly or indirectly heats the formation. It is to be understood that one or more heat sources that are applying heat to a formation may use different sources of energy. Thus, for example, for a given formation some heat sources may supply heat from electric resistance heaters, some heat sources may provide heat from combustion, and some heat sources may provide heat from one or more other energy sources (for example, chemical reactions, solar energy, wind energy, biomass, or other sources of renewable energy). A chemical reaction may include an exothermic

^reaction ^for exampl^ an oxjdatipn reaction). A heat source may also include a heater that provides heat to a zone prbxirnate " arϊd/ό " r surrdurfding a ' h'eafing location such as a heater well.

A "heater" is any system or heat source for generating heat in a well or a near wellbore region. Heaters may be, but are not limited to, electric heaters, burners, combustors that react with material in or produced from a formation, and/or combinations thereof.

An "in situ heat treatment process" refers to a process of heating a hydrocarbon containing formation with heat sources to raise the temperature of at least a portion of the formation above a mobilization, or visbreaking, or pyrolysis temperature so that mobilized fluids, visbroken fluids, or pyrolyzation fluids are produced in the formation.

"Temperature limited heater" generally refers to a heater that regulates heat output (for example, reduces heat output) above a specified temperature without the use of external controls such as temperature controllers, power regulators, rectifiers, or other devices. Temperature limited heaters may be AC (alternating current) or modulated (for example, "chopped") DC (direct current) powered electrical resistance heaters.

The term "wellbore" refers to a hole in a formation made by drilling or insertion of a conduit into the formation. A wellbore may have a substantially circular cross section, or another cross-sectional shape. As used herein, the terms "well" and "opening," when referring to an opening in the formation may be used interchangeably with the term "wellbore."

A "u-shaped wellbore" refers to a wellbore that extends from a first opening in the formation, through at least a portion of the formation, and out through a second opening in the formation. In this context, the wellbore may be only roughly in the shape of a "v" or "u", with the understanding that the "legs" of the "u" do not need to be parallel to each other, or perpendicular to the "bottom" of the "u" for the wellbore to be considered "u-shaped".

"Visbreaking" refers to the untangling of molecules in fluid during heat treatment and/or to the breaking of large molecules into smaller molecules during heat treatment, which results in a reduction of the viscosity of the fluid.

"Pyrolysis" is the breaking of chemical bonds due to the application of heat. For example, pyrolysis may include transforming a compound into one or more other substances by heat alone. Heat may be transferred to a section of the formation to cause pyrolysis.

"Pyrolyzation fluids" or "pyrolysis products" refers to fluid produced substantially during pyrolysis of hydrocarbons. Fluid produced by pyrolysis reactions may mix with other fluids in a formation. The mixture would be considered pyrolyzation fluid or pyrolyzation product. As used herein, "pyrolysis zone" refers to a volume of a formation (for example, a relatively permeable formation such as a tar sands formation) that is reacted or reacting to form a pyrolyzation fluid.

"Cracking" refers to a process involving decomposition and molecular recombination of organic compounds to produce a greater number of molecules than were initially present. In cracking, a series of reactions take place accompanied by a transfer of hydrogen atoms between molecules. For example, naphtha may undergo a thermal cracking reaction to form ethene and H 2 .

"Superposition of heat" refers to providing heat from two or more heat sources to a selected section of a formation such that the temperature of the formation at least at one location between the heat sources is influenced by the heat sources.

"Fluid pressure" is a pressure generated by a fluid in a formation. "Lithostatic pressure" (sometimes referred to as "lithostatic stress") is a pressure in a formation equal to a weight per unit area of an overlying rock mass. "Hydrostatic pressure" is a pressure in a formation exerted by a column of water.

"API gravity" refers to. API gravity at 15.5 0 C (60 0 F). API gravity is as determined by ASTM Method D6822.

"Thickness" of a layer refers to the thickness of a cross section of the layer, wherein the cross section is normal to a face of the layer. "Heavy hydrocarbons" are viscous hydrocarbon fluids. Heavy hydrocarbons may include highly viscous hydrocarbon fluids such as heavy oil, tar, and/or asphalt. Heavy hydrocarbons may include carbon and hydrogen, as well as smaller concentrations of sulfur, oxygen, and nitrogen. Additional elements may also be present in heavy hydrocarbons in trace amounts. Heavy hydrocarbons may be classified by API gravity. Heavy hydrocarbons generally have an API gravity below about 20°. Heavy oil, for example, generally has an API gravity of about 10- 20°, whereas tar generally has an API gravity below about 10°. The viscosity of heavy hydrocarbons is generally greater than about 100 centipoise at 15 °C. Heavy hydrocarbons may include aromatics or other complex ring hydrocarbons.

Heavy hydrocarbons may be found in a relatively permeable formation. The relatively permeable formation may include heavy hydrocarbons entrained in, for example, sand or carbonate. "Relatively permeable" is defined, with respect to formations or portions thereof, as an average permeability of 10 millidarcy or more (for example, 10 or 100 millidarcy). "Relatively low permeability" is defined, with respect to formations or portions thereof, as an average permeability of less than about 10 millidarcy. One darcy is equal to about 0.99 square micrometers. An impermeable layer generally has a permeability of less than about 0.1 millidarcy.

"Tar" is a viscous hydrocarbon that generally has a viscosity greater than about 10,000 centipoise at 15 0 C. The specific gravity of tar generally is greater than 1.000. Tar may have an API gravity less than 10°.

A "tar sands formation" is a formation in which hydrocarbons are predominantly present in the form of heavy hydrocarbons and/or tar entrained in a mineral grain framework or other host lithology (for example, sand or carbonate). Tar sands formations include formations such as the Athabasca tar sands formation and the Grosmont carbonate formation, both in Alberta, Canada. In some cases, a portion or all of a hydrocarbon portion of a relatively permeable formation may be predominantly heavy hydrocarbons and/or tar with no supporting mineral grain framework and only floating (or no) mineral matter (for example, asphalt lakes).

Certain types of formations that include heavy hydrocarbons may also be, but are not limited to, natural mineral waxes, or natural asphaltites. "Natural mineral waxes" typically occur in substantially tubular veins that may be several meters wide, several kilometers long, and hundreds of meters deep. "Natural asphaltites" include solid hydrocarbons of an aromatic composition and typically occur in large veins. In situ recovery of hydrocarbons from formations such as natural mineral waxes and natural asphaltites may include melting to form liquid hydrocarbons and/or solution mining of hydrocarbons from the formations.

"Upgrade" refers to increasing the quality of hydrocarbons. For example, upgrading heavy hydrocarbons may result in an increase in the API gravity of the heavy hydrocarbons.

Hydrocarbons in formations may be treated in various ways to produce many different products. In certain embodiments, hydrocarbons in formations are treated in stages. FIG. 1 depicts an illustration of stages of heating the hydrocarbon containing formation. FIG. 1 also depicts an example of yield ("Y") in barrels of oil equivalent per ton (y axis) of formation fluids from the formation versus temperature ("T") of the heated formation in degrees Celsius (x axis).

Desorption of methane and vaporization of water occurs during stage 1 heating. Heating of the formation through stage 1 may be performed as quickly as possible. For example, when the hydrocarbon containing formation

isjnitially , heated^, hydrocarbons jn the formation desorb adsorbed methane. The desorbed methane may be produced ' from the Formation! If the hydrocarbon containing formation is heated further, water in the hydrocarbon containing formation is vaporized. Water may occupy, in some hydrocarbon containing formations, between 10% and 50% of the pore volume in the formation. In other formations, water occupies larger or smaller portions of the pore volume. Water typically is vaporized in a formation between 160 0 C and 285 0 C at pressures of 600 kPa absolute to 7000 kPa absolute. In some embodiments, the vaporized water produces wettability changes in the formation and/or increased formation pressure. The wettability changes and/or increased pressure may affect pyrolysis reactions or other reactions in the formation. In certain embodiments, the vaporized water is produced from the formation. In other embodiments, the vaporized water is used for steam extraction and/or distillation in the formation or outside the formation. Removing the water from and increasing the pore volume in the formation increases the storage space for hydrocarbons in the pore volume.

In certain embodiments, after stage 1 heating, the formation is heated further, such that a temperature in the formation reaches (at least) an initial pyrolyzation temperature (such as a temperature at the lower end of the temperature range shown as stage 2). Hydrocarbons in the formation may be pyrolyzed throughout stage 2. A pyrolysis temperature range varies depending on the types of hydrocarbons in the formation. The pyrolysis temperature range may include temperatures between 250 0 C and 900 °C. The pyrolysis temperature range for producing desired products may extend through only a portion of the total pyrolysis temperature range. In some embodiments, the pyrolysis temperature range for producing desired products may include temperatures between 250 0 C and 400 °C or temperatures between 270 °C and 350 0 C. If a temperature of hydrocarbons in the formation is slowly raised through the temperature range from 250 0 C to 400 0 C, production of pyrolysis products may be substantially complete when the temperature approaches 400 0 C. Average temperature of the hydrocarbons may be raised at a rate of less than 5 0 C per day, less than 2 0 C per day, less than 1 0 C per day, or less than 0.5 °C per day through the pyrolysis temperature range for producing desired products. Heating the hydrocarbon containing formation with a plurality of heat sources may establish thermal gradients around the heat sources that slowly raise the temperature of hydrocarbons in the formation through the pyrolysis temperature range.

The rate of temperature increase through the pyrolysis temperature range for desired products may affect the quality and quantity of the formation fluids produced from the hydrocarbon containing formation. Raising the temperature slowly through the pyrolysis temperature range for desired products may inhibit mobilization of large chain molecules in the formation. Raising the temperature slowly through the pyrolysis temperature range for desired products may limit reactions between mobilized hydrocarbons that produce undesired products. Slowly raising the temperature of the formation through the pyrolysis temperature range for desired products may allow for the production of high quality, high API gravity hydrocarbons from the formation. Slowly raising the temperature of the formation through the pyrolysis temperature range for desired products may allow for the removal of a large amount of the hydrocarbons present in the formation as hydrocarbon product. In some in situ heat treatment embodiments, a portion of the formation is heated to a desired temperature instead of slowly heating the temperature through a temperature range. In some embodiments, the desired temperature is 300 0 C, 325 0 C, or 350 0 C. Other temperatures may be selected as the desired temperature. Superposition of heat from heat sources allows the desired temperature to be relatively quickly and efficiently established in the formation. Energy input into the formation from the heat sources may be adjusted to maintain the temperature in the formation substantially at the desired temperature. The heated portion of the formation is maintained substantially at the desired temperature until pyrolysis declines such that production of desired formation

fluids from the formation becomes uneconomical. Parts of the formation that are subjected to pyrolysis may include regions brought into a pyrolysis temperature range by heat transfer from only one heat source.

In certain embodiments, formation fluids including pyrolyzation fluids are produced from the formation. As the temperature of the formation increases, the amount of condensable hydrocarbons in the produced formation fluid may decrease. At high temperatures, the formation may produce mostly methane and/or hydrogen. If the hydrocarbon containing formation is heated throughout an entire pyrolysis range, the formation may produce only " small amounts of hydrogen towards an upper limit of the pyrolysis range. After all of the available hydrogen is depleted, a minimal amount of fluid production from the formation will typically occur.

After pyrolysis of hydrocarbons, a large amount of carbon and some hydrogen may still be present in the formation. A significant portion of carbon remaining in the formation can be produced from the formation in the form of synthesis gas. Synthesis gas generation may take place during stage 3 heating depicted in FIG. 1. Stage 3 may include heating a hydrocarbon containing formation to a temperature sufficient to allow synthesis gas generation. For example, synthesis gas may be produced in a temperature range from about 400 0 C to about 1200 0 C, about 500 0 C to about 1100 0 C, or about 550 0 C to about 1000 °C. The temperature of the heated portion of the formation when the synthesis gas generating fluid is introduced to the formation determines the composition of synthesis gas produced in the formation. The generated synthesis gas may be removed from the formation through a production well or production wells.

Total energy content of fluids produced from the hydrocarbon containing formation may stay relatively constant throughout pyrolysis and synthesis gas generation. During pyrolysis at relatively low formation temperatures, a significant portion of the produced fluid may be condensable hydrocarbons that have a high energy content. At higher pyrolysis temperatures, however, less of the formation fluid may include condensable hydrocarbons. More non-condensable formation fluids may be produced from the formation. Energy content per unit volume of the produced fluid may decline slightly during generation of predominantly non-condensable formation fluids. During synthesis gas generation, energy content per unit volume of produced synthesis gas declines significantly compared to energy content of pyrolyzation fluid. The volume of the produced synthesis gas, however, will in many instances increase substantially, thereby compensating for the decreased energy content. FIG. 2 depicts a schematic view of an embodiment of a portion of the in situ heat treatment system for treating the hydrocarbon containing formation. The in situ heat treatment system may include barrier wells 200. Barrier wells are used to form a barrier around a treatment area. The barrier inhibits fluid flow into and/or out of the treatment area. Barrier wells include, but are not limited to, dewatering wells, vacuum wells, capture wells, injection wells, grout wells, freeze wells, or combinations thereof. In some embodiments, barrier wells 200 are dewatering wells. Dewatering wells may remove liquid water and/or inhibit liquid water from entering a portion of the formation to be heated, or to the formation being heated. In the embodiment depicted in FIG. 2, the barrier wells 200 are shown extending only along one side of heat sources 202, but the barrier wells typically encircle all heat sources 202 used, or to be used, to heat a treatment area of the formation.

Heat sources 202 are placed in at least a portion of the formation. Heat sources 202 may include heaters such as insulated conductors, conductor-in-conduit heaters, surface burners, flameless distributed combustors, and/or natural distributed combustors. Heat sources 202 may also include other types of heaters. Heat sources 202 provide heat to at least a portion of the formation to heat hydrocarbons in the formation. Energy may be supplied to heat sources 202 through supply lines 204. Supply lines 204 may be structurally different depending on the type of heat source or heat sources used to heat the formation. Supply lines 204 for heat sources may transmit electricity for

electric heaters, may transport fuel for combustors, or may transport heat exchange fluid that is circulated in the forrnatϊδhT "" '""" ' " '

Production wells 206 are used to remove formation fluid from the formation. In some embodiments, production well 206 includes a heat source. The heat source in the production well may heat one or more portions of the formation at or near the production well. In some in situ heat treatment process embodiments, the amount of heat supplied to the formation from the production well per meter of the production well is less than the amount of heat applied to the formation from a heat source that heats the formation per meter of the heat source.

Formation fluid produced from production wells 206 may be transported through collection piping 208 to treatment facilities 210. Formation fluids may also be produced from heat sources 202. For example, fluid may be produced from heat sources 202 to control pressure in the formation adjacent to the heat sources. Fluid produced from heat sources 202 may be transported through tubing or piping to collection piping 208 or the produced fluid may be transported through tubing or piping directly to treatment facilities 210. Treatment facilities 210 may include separation units, reaction units, upgrading units, fuel cells, turbines, storage vessels, and/or other systems and units for processing produced formation fluids. The treatment facilities may form transportation fuel from at least a portion of the hydrocarbons produced from the formation. In some embodiments, the transportation fuel may be jet fuel, such as JP-8.

FIG. 3 depicts a representation of an embodiment for producing hydrocarbons from a hydrocarbon containing formation (for example, a tar sands formation). Hydrocarbon layer 212 includes one or more portions with heavy hydrocarbons. Hydrocarbons may be produced from hydrocarbon layer 212 using more than one process. In certain embodiments, hydrocarbons are produced from a first portion of hydrocarbon layer 212 using a steam injection process (for example, cyclic steam injection or steam-assisted gravity drainage) and a second portion of the hydrocarbon layer using an in situ heat treatment process. In the steam injection process, steam is injected into the first portion of hydrocarbon layer 212 through injection well 216. First hydrocarbons are produced from the first portion through production well 206A. The first hydrocarbons include hydrocarbons mobilized by the injection of steam. In certain embodiments, the first hydrocarbons have an API gravity of at most 15°, at most 10°, at most 8°, or at most 6°.

Heaters 214 are used to heat the second portion of hydrocarbon layer 212 to mobilization, visbreaking, and/or pyrolysis temperatures. Second hydrocarbons are produced from the second portion through production well 206B. In some embodiments, the second hydrocarbons include at least some pyrolyzed hydrocarbons. In certain embodiments, the second hydrocarbons have an API gravity of at least 15°, at least 20°, or at least 25°.

In some embodiments, the first portion of hydrocarbon layer 212 is treated using heaters after the steam injection process. Heaters may be used to increase the temperature of the first portion and/or treat the first portion using an in situ heat treatment process. Second hydrocarbons (including at least some pyrolyzed hydrocarbons) may be produced from the first portion through production well 206A. In some embodiments, the second portion of hydrocarbon layer 212 is treated using the steam injection process before using heaters 214 to treat the second portion. The steam injection process may be used to produce some fluids (for example, first hydrocarbons or hydrocarbons mobilized by the steam injection) through production well 206B from the second portion and/or preheat the second portion before using heaters 214. In some embodiments, the steam injection process may be used after using heaters 214 to treat the first portion and/or the second portion.

Producing hydrocarbons through both processes increases the total recovery of hydrocarbons from hydrocarbon layer 212 and may be more economical than using either process alone. In some embodiments, the first

^portion is^ treated with the in π situ heat treatment process after the steam injection process is completed. For example, after the steam injection process riδ longer produces viable amounts of hydrocarbon from the first portion, the in situ heat treatment process may be used on the first portion.

Steam is provided to injection well 216 from facility 218. Facility 218 is a steam and electricity cogeneration facility. Facility 218 may burn hydrocarbons in generators to make electricity. Facility 218 may burn gaseous and/or liquid hydrocarbons to make electricity. The electricity generated is used to provide electrical power for heaters 214. Waste heat from the generators is used to make steam. In some embodiments, some of the hydrocarbons produced from the formation are used to provide gas for heaters 214, if the heaters utilize gas to provide heat to the formation. The amount of electricity and steam generated by facility 218 may be controlled to vary the production rate and/or quality of hydrocarbons produced from the first portion and/or the second portion of hydrocarbon layer 212. The production rate and/or quality of hydrocarbons produced from the first portion and/or the second portion may be varied to produce a selected API gravity in a mixture made by blending the first hydrocarbons with the second hydrocarbons. The first hydrocarbon and the second hydrocarbons may be blended after production to produce the selected API gravity. The production from the first portion and/or the second portion may be varied in response to changes in the marketplace for either first hydrocarbons, second hydrocarbons, and/or a mixture of the first and second hydrocarbons.

First hydrocarbons produced from production well 206A and/or second hydrocarbons produced from production well 206B may be used as fuel for facility 218. In some embodiments, first hydrocarbons and/or second hydrocarbons are treated (for example, removing undesirable products) before being used as fuel for facility 218. The amount of first hydrocarbons and second hydrocarbons used as fuel for facility 218 may be determined, for example, by economics for the overall process, the marketplace for either first or second hydrocarbons, availability of treatment facilities for either first or second hydrocarbons, and/or transportation facilities available for either first or second hydrocarbons. In some embodiments, most or all the hydrocarbon gas produced from hydrocarbon layer 212 is used as fuel for facility 218. Burning all the hydrocarbon gas in facility 218 eliminates the need for treatment and/or transportation of gases produced from hydrocarbon layer 212.

The produced first hydrocarbons and the second hydrocarbons may be treated and/or blended in facility 220. In some embodiments, the first and second hydrocarbons are blended to make a mixture that is transportable through a pipeline. In some embodiments, the first and second hydrocarbons are blended to make a mixture that is useable as a feedstock for a refinery. The amount of first and second hydrocarbons produced may be varied based on changes in the requirements for treatment and/or blending of the hydrocarbons. In some embodiments, treated hydrocarbons are used in facility 218.

Further modifications and alternative embodiments of various aspects of the invention may be apparent to those skilled in the art in view of this description. Accordingly, this description is to be construed as illustrative only and is for the purpose of teaching those skilled in the art the general manner of carrying out the invention. It is to be understood that the forms of the invention shown and described herein are to be taken as the presently preferred embodiments. Elements and materials may be substituted for those illustrated and described herein, parts and processes may be reversed, and certain features of the invention may be utilized independently, all as would be apparent to one skilled in the art after having the benefit of this description of the invention. Changes may be made in the elements described herein without departing from the spirit and scope of the invention as described in the following claims. In addition, it is to be understood that features described herein independently may, in certain embodiments, be combined.