Title:
DEUTERATION METHOD AND DEUTERATION CATALYST
Document Type and Number:
WIPO Patent Application WO/2015/129813
Kind Code:
A1
Abstract:
The present invention provides: a deuteration method that is both cost effective and has an excellent deuteration rate; a method for selectively replacing a leaving group of an aromatic compound with deuterium; and a deuteration catalyst used in said methods. The present invention relates to a deuteration catalyst that includes a carbene ligand derived from a compound represented by formula (I) and a transition metal, and to a deuteration method using said catalyst.
Inventors:
KURIYAMA MASAMI (JP)
ONOMURA OSAMU (JP)
SATO KANAKO (JP)
YANO GEMBA (JP)
HAMAGUCHI NORIHISA (JP)
KUJIRADA SHOTA (JP)
ONOMURA OSAMU (JP)
SATO KANAKO (JP)
YANO GEMBA (JP)
HAMAGUCHI NORIHISA (JP)
KUJIRADA SHOTA (JP)
Application Number:
PCT/JP2015/055652
Publication Date:
September 03, 2015
Filing Date:
February 26, 2015
Export Citation:
Assignee:
UNIV NAGASAKI (JP)
International Classes:
B01J31/22; C07C41/18; C07C43/205; C07C45/61; C07C49/217; C07C51/347; C07C63/06; C07C67/30; C07C69/738; C07C69/78; C07C201/12; C07C205/06; C07C231/12; C07C233/65; C07C319/20; C07C321/24; C07D209/08; C07D213/64; C07D213/74; C07D215/12; C07D233/58; C07D233/60; C07D233/61; C07D277/64; C07D279/24; C07D301/00; C07D303/22; C07D307/87; C07D307/94; C07D311/30; C07D333/08; C07D333/54; C07F15/00; C07F15/04; C07B59/00; C07B61/00
Foreign References:
| US20110160412A1 | 2011-06-30 | |||
| JP2012214390A | 2012-11-08 |
Other References:
LIU, Q.-X. ET AL.: "Silver(I), palladium(II) and mercury(II) NHC complexes based on bis- benzimidazole salts with mesitylene linker: Synthesis, structural studies and catalytic activity", JOURNAL OF ORGANOMETALLIC CHEMISTRY, vol. 731, 2013, pages 35 - 48, XP055220059, ISSN: 0022-328x
WANG, S. ET AL.: "Two-Dimensional Charge- Separated Metal-Organic Framework for Hysteretic and Modulated Sorption", INORG. CHEM., vol. 52, no. 8, 2013, pages 4198 - 4204, XP055220060, ISSN: 0020-1669
AKKURT, M. ET AL.: "Chlorido[1-phenyl-3- (2,3,5,6-tetramethylbenzyl) benzimidazol-2- ylidene]silver(I", ACTA CRYST., vol. E68, no. sup-1 - sup-8, 2012, pages m590 - m591
HUYNH, H. V. ET AL.: "13C NMR Spectroscopic Determination of Ligand Donor Strengths Using N-Heterocyclic Carbene Complexes of Palladium(II", ORGANOMETALLICS, vol. 28, no. 18, 2009, pages 5395 - 5404, XP055220062, ISSN: 0276-7333
WANG, S. ET AL.: "Two-Dimensional Charge- Separated Metal-Organic Framework for Hysteretic and Modulated Sorption", INORG. CHEM., vol. 52, no. 8, 2013, pages 4198 - 4204, XP055220060, ISSN: 0020-1669
AKKURT, M. ET AL.: "Chlorido[1-phenyl-3- (2,3,5,6-tetramethylbenzyl) benzimidazol-2- ylidene]silver(I", ACTA CRYST., vol. E68, no. sup-1 - sup-8, 2012, pages m590 - m591
HUYNH, H. V. ET AL.: "13C NMR Spectroscopic Determination of Ligand Donor Strengths Using N-Heterocyclic Carbene Complexes of Palladium(II", ORGANOMETALLICS, vol. 28, no. 18, 2009, pages 5395 - 5404, XP055220062, ISSN: 0276-7333
Attorney, Agent or Firm:
TAKASHIMA, HAJIME (JP)
Takashima 1 (JP)
Takashima 1 (JP)
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