Title:
DIENE-BASED CARBOXYLATE ANION AND SALT THEREOF, AND POLYMERIZABLE OR CURABLE COMPOSITION THEREOF
Document Type and Number:
WIPO Patent Application WO/2012/046787
Kind Code:
A1
Abstract:
The purpose of the present invention is to provide a diene-based carboxylate anion, and salt thereof, which has a specific structure and is a previously unstudied novel compound, and furthermore to provide a diene-based carboxylate anion and salt thereof, particularly a metal salt thereof, which is readily soluble in commonly used organic solvents, reactive diluents, and resins, can also be in a liquid state at normal temperatures, depending on the structure thereof, and is furthermore highly polymerizable. The anion or salt thereof, when polymerized or cured, becomes a resin having a structure to which many ionic bonds as well as a metal have been introduced, and exhibits hardness, abrasion resistance, fingerprint resistance, gas barrier properties, water vapor barrier properties, oxygen absorbance, ultraviolet blocking, infrared blocking, coloring/coloration, high refractive index, adhesion, various catalytic abilities, fluorescence/luminescence, optical amplification, dispersibility, static prevention, and various other properties. The anion or salt thereof is also useful as a raw material for functional microparticles or as a raw material for a metallic nanoparticle composite, and can further be appropriately used as an MOD material. Also provided is an advantageous method for producing the diene-based carboxylate anion and salt thereof.
Inventors:
KANEKO TOMOMASA (JP)
Application Number:
PCT/JP2011/073019
Publication Date:
April 12, 2012
Filing Date:
October 05, 2011
Export Citation:
Assignee:
NIPPON CATALYTIC CHEM IND (JP)
KANEKO TOMOMASA (JP)
KANEKO TOMOMASA (JP)
International Classes:
C08F20/04; C07C59/60
Foreign References:
| JPS5052027A | 1975-05-09 | |||
| JP2011074068A | 2011-04-14 | |||
| JP2010235546A | 2010-10-21 | |||
| JPH10226669A | 1998-08-25 | |||
| JP2011074068A | 2011-04-14 |
Other References:
WIEST O. ET AL.: "Stabilization of the Transition State of the Chorismate-Prephenate Rearrangement: An ab Initio Study of Enzyme and Antibody Catalysis", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 117, no. 47, 1995, pages 11628 - 11639, XP055085593
GAJEWSKI J.J. ET AL.: "On the mechanism of rearrangement of chorismic acid and related compounds", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 109, no. 4, 1987, pages 1170 - 1186, XP055085594
THOMPSON R.D. ET AL.: "Unusually Facile Cyclopolymerization of a New Allyl Ether Substituted Acrylate and Confirmation of Repeat Unit Structure by INADEQUATE NMR", MACROMOLECULES, vol. 25, 1992, pages 6455 - 6459, XP002690308
URUSHISAKI M. ET AL.: "Cyclopolymerization. 25. Five-Membered Ring Formation through Head- to-Head and Tail-to-Tail Additions in Radical and Anionic Polymerizations of a- (Allyloxymethyl)acrylates", MACROMOLECULES, vol. 32, 1999, pages 322 - 327, XP055085595
ROBERT D. THOMPSON, MACROMOLECULES, vol. 25, 1992, pages 6455 - 6459
MICHIO URUSHIZAKI, MACROMOLECULES, vol. 32, 1999, pages 322 - 327
"Spectrometric identification of organic compounds", TOKYO KAGAKU DOZIN C., LTD., pages: 117
"Spectrometric identification of organic compounds", TOKYO KAGAKU DOZIN C., LTD., pages: 118
"BASIC INORGANIC CHEMISTRY", JOHN WILEY & SONS, pages: 143
"Principles and Applications of Organotransition Metal Chemistry", UNIVERSITY SCIENCE BOOKS, pages: 59
"ADVANCED INORGANIC CHEMISTRY", JOHN WILEY & SONS, pages: 483
"BASIC INORGANIC CHEMISTRY", JOHN WILEY & SONS, pages: 142
GAJEWSKI J.J. ET AL.: "On the mechanism of rearrangement of chorismic acid and related compounds", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 109, no. 4, 1987, pages 1170 - 1186, XP055085594
THOMPSON R.D. ET AL.: "Unusually Facile Cyclopolymerization of a New Allyl Ether Substituted Acrylate and Confirmation of Repeat Unit Structure by INADEQUATE NMR", MACROMOLECULES, vol. 25, 1992, pages 6455 - 6459, XP002690308
URUSHISAKI M. ET AL.: "Cyclopolymerization. 25. Five-Membered Ring Formation through Head- to-Head and Tail-to-Tail Additions in Radical and Anionic Polymerizations of a- (Allyloxymethyl)acrylates", MACROMOLECULES, vol. 32, 1999, pages 322 - 327, XP055085595
ROBERT D. THOMPSON, MACROMOLECULES, vol. 25, 1992, pages 6455 - 6459
MICHIO URUSHIZAKI, MACROMOLECULES, vol. 32, 1999, pages 322 - 327
"Spectrometric identification of organic compounds", TOKYO KAGAKU DOZIN C., LTD., pages: 117
"Spectrometric identification of organic compounds", TOKYO KAGAKU DOZIN C., LTD., pages: 118
"BASIC INORGANIC CHEMISTRY", JOHN WILEY & SONS, pages: 143
"Principles and Applications of Organotransition Metal Chemistry", UNIVERSITY SCIENCE BOOKS, pages: 59
"ADVANCED INORGANIC CHEMISTRY", JOHN WILEY & SONS, pages: 483
"BASIC INORGANIC CHEMISTRY", JOHN WILEY & SONS, pages: 142
Attorney, Agent or Firm:
YASUTOMI & Associates (JP)
Patent business corporation Yasutomi international patent firm (JP)
Patent business corporation Yasutomi international patent firm (JP)
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