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Title:
DIETHYL ZINC COMPOSITION, METHOD FOR THERMAL STABILIZATION AND COMPOUND FOR THERMAL STABILIZATION
Document Type and Number:
WIPO Patent Application WO/2012/081254
Kind Code:
A1
Abstract:
[Problem] To provide a diethyl zinc composition that improves the heat stability of the diethyl zinc used for a polymerization catalyst, a reagent in organic synthesis, a starting material for producing a zinc oxide thin film by a MOCVD method and the like; and that is excellent in terms of heat stability so that metallic zinc particles are not deposited even over long-term handling. [Solution] The diethyl zinc composition used is obtained by adding a compound having a specific carbon-carbon double bond to diethyl zinc.

Inventors:
HAGA KENICHI (JP)
TOMIYASU SHIZUO (JP)
TOKUDOME KOHICHI (JP)
TOYOTA KOUJI (JP)
INABA KOICHIRO (JP)
Application Number:
PCT/JP2011/007019
Publication Date:
June 21, 2012
Filing Date:
December 15, 2011
Export Citation:
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Assignee:
TOSOH FINECHEM CORP (JP)
HAGA KENICHI (JP)
TOMIYASU SHIZUO (JP)
TOKUDOME KOHICHI (JP)
TOYOTA KOUJI (JP)
INABA KOICHIRO (JP)
International Classes:
C07F3/06; C07C11/12; C07C13/23
Domestic Patent References:
WO2009093175A12009-07-30
Foreign References:
JPH0987206A1997-03-31
JPH0770056A1995-03-14
JP2003300993A2003-10-21
JP2010510982A2010-04-08
JPS5063148A1975-05-29
US4402880A1983-09-06
US4407758A1983-10-04
US4385003A1983-05-24
US4385003A1983-05-24
US4402880A1983-09-06
US4407758A1983-10-04
Other References:
LOH, T. ET AL.: "Nickel-catalyzed homoallylation reaction of aldehydes with 1,3- dienes: stereochemical and mechanistic studies", ORGANIC LETTERS, vol. 4, no. 16, 2002, pages 2715 - 2717, XP055109150
DEHMLOW, E.V. ET AL.: "On the stereoselectivity of iodocarbene and -carbenoid additions to cyclic alkenes", TETRAHEDRON LETTERS, vol. 32, no. 43, 1991, pages 6105 - 6108, XP002639552
See also references of EP 2653474A4
YASUO KUNIYA, APPLIED ORGANOMETALLIC CHEMISTRY, vol. 5, 1991, pages 337 - 347
Attorney, Agent or Firm:
KOYAMA, YUU (JP)
Hill 有 (JP)
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Claims: