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Title:
DISPERSION STABILIZER FOR SUSPENSION POLYMERIZATION AND METHOD FOR PRODUCING VINYL RESIN USING SAME
Document Type and Number:
WIPO Patent Application WO/2014/069616
Kind Code:
A1
Abstract:
A dispersion stabilizer for suspension polymerization of vinyl compounds, which is composed of an aqueous emulsion. The aqueous emulsion contains a solid content that contains (A) a polyvinyl alcohol, (B) a polyvinyl ester and (C) a graft polymer that is obtained by graft polymerizing a vinyl ester monomer to a polyvinyl alcohol. The amount of the polyvinyl alcohol (A) relative to the total amount of the components (A), (B) and (C) is 0.1-18% by mass, and the amount of the graft polymer (C) relative to the total amount of the components (A), (B) and (C) is 7-80% by mass. The weight average molecular weight of the solid content as determined by gel permeation chromatography is 1,100,000 or less. This dispersion stabilizer for suspension polymerization has excellent polymerization stability and excellent handleability. In addition, a vinyl resin which is obtained using this dispersion stabilizer for suspension polymerization has good plasticizer absorbency.

Inventors:
FUKUHARA TADAHITO (JP)
KUMAKI YOUSUKE (JP)
Application Number:
PCT/JP2013/079675
Publication Date:
May 08, 2014
Filing Date:
November 01, 2013
Export Citation:
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Assignee:
KURARAY CO (JP)
International Classes:
C08F261/04; C08F2/20; C08L29/04; C08L31/02; C08L51/00
Domestic Patent References:
WO2008129936A12008-10-30
Foreign References:
JP2005082665A2005-03-31
JP2004189891A2004-07-08
JP2005334767A2005-12-08
JPH08283313A1996-10-29
JP2007091886A2007-04-12
JPH0827219A1996-01-30
JPH09100301A1997-04-15
JPH10147604A1998-06-02
JP2007063369A2007-03-15
JPH10168128A1998-06-23
JPH09132608A1997-05-20
JPH1081865A1998-03-31
JP2005082665A2005-03-31
Other References:
AKIO NAKAJIMA, KOBUNSHI KAGAKU, vol. 6, 1949
See also references of EP 2915827A4
Attorney, Agent or Firm:
NAKATSUKASA, Shigeki et al. (JP)
Shigeki Nakamu (JP)
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