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Title:
DITHIENOPHOSPHORINE COMPOUND, AND COLORLESS NEAR-INFRARED ABSORBING MATERIAL AND ELECTROCHROMIC MATERIAL EACH USING SAME
Document Type and Number:
WIPO Patent Application WO/2021/176755
Kind Code:
A1
Abstract:
This dithienophosphorine compound having a cation represented by the formula (wherein Y represents an oxygen atom or a sulfur atom; R1 represents a hydrogen atom, an alkyl group, an alkenyl group, an alkynyl group, an aryl group or a heteroaryl group; R2 represents a hydroxy group, an alkyl group, an alkoxy group, an alkenyl group, an alkynyl group, an aryl group or a heteroaryl group; each of R3, R4, R5 and R6 represents a hydrogen atom, an alkyl group, an alkenyl group or an aryl group; each of R7 and R8 represents an arylene group and/or a heteroarylene group; each of R9 and R10 represents a hydrogen atom, a halogen atom, a sulfonyl group, an alkyl group or an aryl group; each group may have a substituent; and R3, R4 and R7, and R5, R6 and R8 may combine with each other to form a ring together with an adjacent nitrogen atom) is an organic compound which has a maximum absorption wavelength in an NIR-II range (from 1,000 to 1,500 nm) although the molecular weight thereof is not extremely high, and which exhibits excellent solubility in an organic solvent, while having high structural selectivity.

Inventors:
NAKA AIKO (JP)
OEY STANLEY SURYA WINATA (JP)
Application Number:
PCT/JP2020/036443
Publication Date:
September 10, 2021
Filing Date:
September 25, 2020
Export Citation:
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Assignee:
UNIV KYOTO (JP)
International Classes:
C07F9/6578; C07B61/00; C09K3/00; C09K9/02; G02B5/22
Domestic Patent References:
WO2017155042A12017-09-14
WO2017155042A12017-09-14
Other References:
HIGASHINO, TOMOHIRO ET AL.: "Phosphole-Thiophene Hybrid: A Dual Role of Dithieno[3,4- b:3',4'-ddphosphole as Electron Acceptor and Electron Donor", THE JOURNAL OF ORGANIC CHEMISTRY, vol. 83, 2018, pages 3397 - 3402, XP055853393
AL MOUSAWI, ASSI ET AL.: "pi-Conjugated Dithienophosphole Derivatives as High Performance Photoinitiators for 3D Printing Resins", MACROMOLECULES, vol. 51, 21 February 2018 (2018-02-21), pages 1811 - 1821, XP055853394
ANGEW. CHEM. INT. ED., vol. 46, 2007, pages 3750
J. ORG. CHEM., vol. 80, 2015, pages 12146
J. ORG. CHEM., vol. 74, 2009, pages 1826 - 1834
ANGEW. CHEM. INT. ED., vol. 52, 2013, pages 8990 - 8994
Attorney, Agent or Firm:
SAEGUSA & PARTNERS (JP)
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