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Title:
DOUBLE-WALLED CARBON NANOTUBE, ALIGNED DOUBLE-WALLED CARBON NANOTUBE BULK STRUCTURE, AND PROCESS FOR PRODUCTION OF THE CARBON NANOTUBE OR THE BULK STRUCTURE
Document Type and Number:
WIPO Patent Application WO/2007/061143
Kind Code:
A1
Abstract:
Disclosed is an aligned double-walled carbon nanotube bulk structure which comprises multiple aligned double-walled carbon nanotubes and has a height of 0.1 μm or more. In the bulk structure, the double-walled carbon nanotubes can be produced by chemical vapor deposition (CVD) in the presence of a metal catalyst having a controlled particle size and a controlled thickness, preferably in the presence of water. It becomes possible to provide a double-walled carbon nanotube which is free from the catalyst contamination, has a high purity, is easy to control the alignment or growth, can be formed through the formation of a bulk structure, and has an excellent electron-emitting property (particularly, a bulk structure of aligned, double-walled carbon nanotubes) and also provide a technique for production of the carbon nanotube.

Inventors:
HATA KENJI (JP)
YAMADA TAKEO (JP)
YUMURA MOTOO (JP)
IIJIMA SUMIO (JP)
Application Number:
PCT/JP2006/324127
Publication Date:
May 31, 2007
Filing Date:
November 27, 2006
Export Citation:
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Assignee:
NAT INST OF ADVANCED IND SCIEN (JP)
HATA KENJI (JP)
YAMADA TAKEO (JP)
YUMURA MOTOO (JP)
IIJIMA SUMIO (JP)
International Classes:
C01B31/02; B01J20/20; B82B1/00; B82B3/00; B82Y30/00; B82Y40/00; B82Y99/00; H01G11/22; H01G11/24; H01G11/26; H01G11/36; H01G11/86; H01J1/304; H01J31/12; H01M4/02; H01M4/133; H01M4/587; H01M4/86; H01M4/88; H01M10/05; H01M12/06; H01M4/96
Domestic Patent References:
WO2002030816A12002-04-18
WO2004083113A12004-09-30
Foreign References:
JP2003500325A2003-01-07
JP2004277279A2004-10-07
JP2005097024A2005-04-14
JP2004182548A2004-07-02
Other References:
NAGAO H. ET AL.: "Fabrication of Dense Carbon Nanotube Film Using Microwave Plasma-Enhanced CVD", PROCEEDINGS OF PLASMA SCIENCE SYMPOSIUM 2005 AND THE 22ND SYMPOSIUM ON PLASMA PROCESSING, 26 January 2005 (2005-01-26), pages 367 - 368, XP002997550
HATA K. ET AL.: "Water-Assisted Highly Efficient Synthesis of Impurity-Free Single-Walled Carbon Nanotubes", SCIENCE, vol. 306, 19 November 2004 (2004-11-19), pages 1362 - 1364, XP002993037
REN W. ET AL.: "Aligned Double-Walled Carbon Nanotube Long Ropes with a Narrow Diameter Distribution", JOURNAL OF PHYSICAL CHEMISTRY B, vol. 109, no. 15, 21 April 2005 (2005-04-21), pages 7169 - 7173, XP003013361
ENDO M. ET AL.: "'Buckypaper' from coaxial nanotubes", NATURE, vol. 433, 3 February 2005 (2005-02-03), pages 476, XP003013362
Attorney, Agent or Firm:
NISHIZAWA, Toshio (11-1 Minami-Aoyama 6-chom, Minato-ku Tokyo 62, JP)
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